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Publications—Open-File Report 98–409

A Review of Semivolatile and Volatile Organic Compounds in Highway Runoff and Urban Stormwater

By Thomas J. Lopes and Shannon G. Dionne

U.S. Geological Survey Open-File Report 98–409

A Contribution to the National Highway Runoff Data and Methodology Synthesis.

ONLINE ONLY


This report is available in Portable Document Format (PDF):

OFR 98–409 (373 KB)  – 73 pages


Abstract

Many studies have been conducted since 1970 to characterize concentrations of semivolatile organic compounds (SVOCs) in highway runoff and urban stormwater. To a lesser extent, studies also have characterized concentrations of volatile organic compounds (VOCs), estimated loads of SVOCs, and assessed potential impacts of these contaminants on receiving streams. This review evaluates the quality of existing data on SVOCs and VOCs in highway runoff and urban stormĖ water and summarizes significant findings. Studies related to highways are emphasized when possible. The review included 44 articles and reports that focused primarily on SVOCs and VOCs. Only 17 of these publications are related to highways, and 5 of these 17 are themselves review papers. SVOCs in urban stormwater and sediments during the late 1970ís to mid-1980ís were the subject of most studies.

Criteria used to evaluate data quality included documentation of sampling protocols, analytical methods, minimum reporting limit (MRL) or method detection limit (MDL), qualityassurance protocols, and quality-control samples. The largest deficiency in documenting data quality was that only 10 percent of the studies described where water samples were collected in the stream cross section. About 80 percent of SVOCs in runoff are in the suspended solids. Because suspended solids can vary significantly even in narrow channels, concentrations from discrete point samples and contaminant loads estimated from those samples are questionable without information on sample location or how well streamflow was mixed. Thirty percent or fewer of the studies documented the MRL, MDL, cleaning of samplers, or use of field quality-control samples. Comparing results of different studies and evaluating the quality of environmental data, especially for samples with low concentrations, is difficult without this information.

The most significant factor affecting SVOC concentrations in water is suspended solids concentration. In sediment, the most significant factors affecting SVOC concentrations are organic carbon content and distance from sources such as highways and power plants. Petroleum hydrocarbons, oil and grease, and polycyclic aromatic hydrocarbons (PAHs) in crankcase oil and vehicle emissions are the major SVOCs detected in highway runoff and urban stormwater.

The few loading factors and regression equations that were developed in the 1970ís and 1980ís have limited use in estimating current (1998) loads of SVOCs on a national scale. These factors and equations are based on few data and use inconsistent units, and some are independent of rainfall. Also, more cars on the road today have catalytic converters, and fuels that were used in 1998 are cleaner than when loading factors and regression equations were developed.

Comparisons to water-quality and sedimentquality criteria and guidelines indicate that PAHs, phenolic compounds, and phthalates in runoff and sediment exceeded U.S. Environmental Protection Agency drinking-water and aquatic-life standards and guidelines. PAHs in stream sediments adjacent to highways have the highest potential for adverse effects on receiving streams.

Few data exist on VOCs in highway runoff. VOCs were detected in precipitation adjacent to a highway in England, and chloromethane, toluene, xylenes, 1,2,4-trimethylbenzene, and 1,2,3-trichloropropane were detected in runoff from a highway in Texas. In urban stormwater, gasoline-related compounds were detected in as many as 23 percent of the samples. Land use could be the most significant factor affecting the occurrence of VOCs, with highest concentrations of VOCs found in industrial areas. Temperature is another factor affecting the occurrence and concentrations of VOCs. Urban land surfaces are the primary nonpoint source of VOCs in stormwater. However, the atmosphere is a potential source of hydrophilic VOCs in stormwater, especially during cold seasons when partitioning of VOCs from air into water is greatest. Tetrachloroethene, dichloromethane, and benzene were the only VOCs detected in stormwater that exceeded U.S. Environmental Protection Agency drinking-water standards.

Contents

Abstract

Introduction

Objectives and Scope

Criteria for Data Quality

Monitoring Trace Organic Chemicals

Sample Collection

Analytical Methods and Minimum Reporting and Detection Limits

Quality Assurance and Quality Control

Summary of Study Results

Semivolatile Organic Compounds

Occurrence

Related Factors

Sources

Load Estimates

Comparison to Water-Quality and Sediment-Quality Standards and Guidelines

Volatile Organic Compounds

Occurrence

Related Factors

Sources

Comparison to Water-Quality Standards

Information Needs

Summary

References Cited


This report is available online in Portable Document Format (PDF). If you do not have the Adobe Acrobat PDF Reader, it is available for free download from Adobe Systems Incorporated.

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Suggested Citation:
Lopes, T.J., Dionne, S.G., 1998, A review of semivolatile and volatile organic compounds in highway runoff and urban stormwater: U.S. Geological Survey Open File Report 98-409, 67 p.


For additional information write to:

Director,
USGS Massachusetts–Rhode Island Water Science Center
10 Bearfoot Road
Northborough, MA 01532

or visit our Web site at:
http://ma.water.usgs.gov



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