Geochemical reaction path modeling is useful for rapidly assessing the extent of water-aqueous-gas interactions both in natural systems and in industrial processes. Modeling of some systems, such as those at low temperature with relatively high hydrologic flow rates, or those perturbed by the subsurface injection of industrial waste such as CO2 or H2S, must account for the relatively slow kinetics of mineral-gas-water interactions. We have therefore compiled parameters conforming to a general Arrhenius-type rate equation, for over 70 minerals, including phases from all the major classes of silicates, most carbonates, and many other non-silicates. The compiled dissolution rate constants range from -0.21 log moles m-2 s-1 for halite, to -17.44 log moles m-2 s-1 for kyanite, for conditions far from equilibrium, at 25 °C, and pH near neutral. These data have been added to a computer code that simulates an infinitely well-stirred batch reactor, allowing computation of mass transfer as a function of time. Actual equilibration rates are expected to be much slower than those predicted by the selected computer code, primarily because actual geochemical processes commonly involve flow through porous or fractured media, wherein the development of concentration gradients in the aqueous phase near mineral surfaces, which results in decreased absolute chemical affinity and slower reaction rates. Further differences between observed and computed reaction rates may occur because of variables beyond the scope of most geochemical simulators, such as variation in grain size, aquifer heterogeneity, preferred fluid flow paths, primary and secondary mineral coatings, and secondary minerals that may lead to decreased porosity and clogged pore throats.
2.1 Rate Equations
2.2 Data Reduction
2.3 Limitations and Uncertainties
3.1.1 SiO2 Polymorphs
22.214.171.124 Amorphous SiO2, Cristobalite, and SiO2 Polymorph Precipitation
126.96.36.199 Plagioclase Feldspars
3.1.3 Feldspathoids: Nepheline and Leucite
3.2.1 Olivine Group
3.2.2 Garnet Group
3.2.3 Al2SiO5 Group
3.2.5 Epidote Group
3.3.1 Cordierite and Tourmaline
3.4.1 Pyroxene Group / Pyroxenoid Group
3.4.2 Amphibole Group
3.5.1 Mica Group
3.5.2 Clay Group.
3.5.3 Miscellaneous Phyllosilicates
This report is available online in Portable Document Format (PDF). If you do not have the Adobe Acrobat PDF Reader, it is available for free download from Adobe Systems Incorporated.
Download the Report (PDF, 2.5MB).
Document Accessibility: Adobe Systems Incorporated has information about PDFs and the visually impaired. This information provides tools to help make PDF files accessible. These tools convert Adobe PDF documents into HTML or ASCII text, which then can be read by a number of common screen-reading programs that synthesize text as audible speech. In addition, an accessible version of Acrobat Reader 6.0 for Windows (English only), which contains support for screen readers, is available. These tools and the accessible reader may be obtained free from Adobe at Adobe Access.
|AccessibilityFOIAPrivacyPolicies and Notices|
|U.S. Department of the Interior, U.S. Geological Survey
Persistent URL: http://pubs.water.usgs.gov/ofr20041068
Page Contact Information: GS Pubs Web Contact
Last modified: Saturday, January 12 2013, 11:10:51 PM