The full report is available in pdf. Links to the pdf.
The accurate determination of an organic contaminants physico-chemical properties is essential for predicting its environmental impact and fate. Approximately 700 publications (19442001) were reviewed and all known aqueous solubilities (Sw) and octanol-water partition coefficients (Kow) for the organochlorine pesticide, DDT, and its persistent metabolite, DDE were compiled and examined. Two problems are evident with the available database: 1) egregious errors in reporting data and references, and 2) poor data quality and/or inadequate documentation of procedures. The published literature (particularly the collative literature such as compilation articles and handbooks) is characterized by a preponderance of unnecessary data duplication. Numerous data and citation errors are also present in the literature. The percentage of original Sw and Kow data in compilations has decreased with time, and in the most recent publications (199497) it composes only 626 percent of the reported data. The variability of original DDT/DDE Sw and Kow data spans 24 orders of magnitude, and there is little indication that the uncertainty in these properties has declined over the last 5 decades. A criteria-based evaluation of DDT/DDE Sw and Kow data sources shows that 95100 percent of the database literature is of poor or unevaluatable quality. The accuracy and reliability of the vast majority of the data are unknown due to inadequate documentation of the methods of determination used by the authors. [For example, estimates of precision have been reported for only 20 percent of experimental Sw data and 10 percent of experimental Kow data.] Computational methods for estimating these parameters have been increasingly substituted for direct or indirect experimental determination despite the fact that the data used for model development and validation may be of unknown reliability. Because of the prevalence of errors, the lack of methodological documentation, and unsatisfactory data quality, the reliability of the DDT/ DDE Sw and Kow database is questionable. The nature and extent of the errors documented in this study are probably indicative of a more general problem in the literature of hydrophobic organic compounds. Under these circumstances, estimation of critical environmental parameters on the basis of Sw and Kow (for example, bioconcentration factors, equilibrium partition coefficients) is inadvisable because it will likely lead to incorrect environmental risk assessments. The current state of the database indicates that much greater efforts are needed to: 1) halt the proliferation of erroneous data and references, 2) initiate a coordinated program to develop improved methods of property determination, 3) establish and maintain consistent reporting requirements for physico-chemical property data, and 4) create a mechanism for archiving reliable data for widespread use in the scientific/regulatory community.
Published Original Data
Assessment of DDT/DDE Sw and Kow Original Data Sources
Effect of Methodology
Summary and Conclusions
Appendix A: Data of Uncertain Origin
Appendix B: Assessment of DDT/DDE Sw and Kow Original Data Sources using a Criteria-based Rating System
The text and graphics are presented here in pdf format (print quality):
The full report is 1.8MB
If you have Adobe Acrobat Reader installed on your computer, you may view and/or print the PDF version of this report. If you do not have Acrobat Reader, you may download it here.
Users with visual disabilities can visit this site for conversion tools and information to help make PDF files accessible.
|AccessibilityFOIAPrivacyPolicies and Notices|
|U.S. Department of the Interior, U.S. Geological Survey
Persistent URL: http://pubs.water.usgs.gov/wri014201
Page Contact Information: Contact USGS
Last modified: Thursday, September 01 2005, 03:32:13 PM