This report is also available as a pdf.
The Roubidoux aquifer in Ottawa County Oklahoma is used extensively as a source of water for public supplies, commerce, industry, and rural water districts. Water in the Roubidoux aquifer in eastern Ottawa County has relatively low dissolved- solids concentrations (less than 200 mg/L) with calcium, magnesium, and bicarbonate as the major ions. The Boone Formation is stratigraphically above the Roubidoux aquifer and is the host rock for zinc and lead sulfide ores, with the richest deposits located in the vicinity of the City of Picher. Mining in what became known as the Picher mining district began in the early 1900’s and continued until about 1970. The water in the abandoned zinc and lead mines contains high concentrations of calcium, magnesium, bicarbonate, sulfate, fluoride, cadmium, copper, iron, lead, manganese, nickel, and zinc. Water from the abandoned mines is a potential source of contamination to the Roubidoux aquifer and to wells completed in the Roubidoux aquifer.
Water samples were collected from wells completed in the Roubidoux aquifer in the Picher mining district and from wells outside the mining district to determine if 10 public supply wells in the mining district are contaminated. The chemical analyses indicate that at least 7 of the 10 public supply wells in the Picher mining district are contaminated by mine water. Application of the Mann-Whitney test indicated that the concentrations of some chemical constituents that are indicators of mine-water contamination are different in water samples from wells in the mining area as compared to wells outside the mining area. Application of the Wilcoxon signed-rank test showed that the concentrations of some chemical constituents that are indicators of mine-water contamination were higher in current (1992-93) data than in historic (1981-83) data, except for pH, which was lower in current than in historic data. pH and sulfate, alkalinity, bicarbonate, magnesium, iron, and tritium concentrations consistently indicate that the Cardin, Commerce 1, Commerce 3, Picher 2, Picher 3, Picher 4, and Quapaw 2 wells are contaminated.
Purpose and scope
Description of the Study Area
Definition of the Roubidoux Aquifer
History of Abandoned Zinc and Lead Mines
Background Water Quality
Abandoned Zinc and Lead Mines
Comparison Between Water in the Roubidoux Aquifer and the Abandoned Mines
Water-Quality Field Investigation
Analysis of Environmental Data
Comparison of Picher Mining District to Background Water Quality
Comparison of Current to Historic Water Quality
Contamination of Wells by Mine Water
Comparison of Produced Water to Water-Quality Standards
1. Physical properties and concentrations of major ions and trace elements in water samples from wells
2. Concentrations of major ions and trace elements in quality-assurance blank samples
This report is available online in Portable Document Format (PDF). If you do not have the Adobe Acrobat PDF Reader, it is available for free download from Adobe Systems Incorporated.
Document Accessibility: Adobe Systems Incorporated has information about PDFs and the visually impaired. This information provides tools to help make PDF files accessible. These tools convert Adobe PDF documents into HTML or ASCII text, which then can be read by a number of common screen-reading programs that synthesize text as audible speech. In addition, an accessible version of Acrobat Reader 5.0 for Windows (English only), which contains support for screen readers, is available. These tools and the accessible reader may be obtained free from Adobe at Adobe Access.
For more information about water resources in Minnesota is available on the World Wide Web at http://ok.water.usgs.gov.
|AccessibilityFOIAPrivacyPolicies and Notices|
|U.S. Department of the Interior, U.S. Geological Survey
Persistent URL: http://pubs.water.usgs.gov/wri954150
Page Contact Information: GS Pubs Web Contact
Last modified: Thursday, September 01 2005, 02:25:02 PM