METHODS FOR SAMPLING AND
INORGANIC ANALYSIS OF COAL
U.S. Geological Survey
Bulletin 1823
Edited by D.W. Golightly and F.O. Simon
Table 6. D.C. Arc Spectrographic Analyses of NBS Standard Reference Material Coal Fly Ash
[Concentration units are %(cg/g) for the first group of elements, including Si through Mn, and ppm (m g/g) for the group of elements that includes As through Zr.]
1633 | 1633A | |||||||||||||
ELEMENT | NBS VALUEa | USGS AVERAGEb | NBS VALUEa | USGS AVERAGEc | ||||||||||
Si(%) | 27 | ± | 3.3 | 22.8 | ± | 0.8* | 26 | ± | 2.6 | |||||
Al | 17 | ± | 2.8 | 14 | 18 | ± | 3.1 | |||||||
Fe | 8.0 | ± | 0.93 | 9.40 | ± | 0.10* | 11 | ± | 1.7 | |||||
Mg | 2.2 | ± | 0.32 | 0.455 | ± | 0.010* | 0.71 | ± | 0.14 | |||||
Ca | 5.4 | ± | 1.2 | 1.11 | ± | 0.01* | 1.3 | ± | 0.31 | |||||
Na | 0.25 | ± | 0.03 | 0.17 | ± | 0.01* | 0.16 | ± | 0.03 | |||||
K | 1.72 | 1.3 | ± | 0.15 | 1.88 | ± | 0.06* | 1.5 | ± | 0.19 | ||||
Ti | 0.80 | ± | 0.15 | 0.8 | 0.85 | ± | 0.18 | |||||||
Mn | 0.0493 | ± | 0.0007* | 0.076 | ± | 0.011 | 0.0190 | 0.026 | ± | 0.0777 | ||||
As(ppm) | 61 | ± | 6* | <100d | 145 | ± | 15* | 190 | ± | 49 | ||||
B | 430 | 440 | ± | 46 | 32 | ± | 4.0 | |||||||
Ba | 1600 | ± | 490 | 1500 | 910 | ± | 160 | |||||||
Be | 12 | 15 | ± | 1.5 | 12 | 14 | ± | 1.9 | ||||||
Ce | 170 | ± | 29 | 180 | 160 | ± | 53 | |||||||
Co | 38 | 38 | ± | 4.9 | 46 | 38 | ± | 6.2 | ||||||
Cr | 131 | ± | 2* | 120 | ± | 23 | 196 | ± | 6* | 180 | ± | 33 | ||
Cu | 128 | ± | 5* | 100 | ± | 25 | 118 | ± | 3* | 93 | ± | 21 | ||
Eu | 3.1 | ± | 0.5 | 4 | 3.4 | ± | 0.6 | |||||||
Ga | 49 | 39 | ± | 5.8 | 58 | 54 | ± | 11 | ||||||
La | 96 | ± | 13 | |||||||||||
Mo | -- | -- | 29 | 28 | ± | 6.2 | ||||||||
Nd | 60 | ± | 15 | 100 | ± | 29 | ||||||||
Ni | 98 | ± | 3* | 110 | ± | 15 | 127 | ± | 4* | 140 | ± | 19 | ||
Pb | 70 | ± | 4* | 74 | ± | 9.0 | 72.4 | ± | 0.4* | 76 | ± | 12 | ||
Sc | 25 | ± | 4.0 | 40 | 29 | ± | 5.7 | |||||||
Sr | 1380 | 1700 | ± | 230 | 830 | ± | 30* | 900 | ± | 140 | ||||
V | 214 | ± | 8* | 200 | ± | 24 | 300 | 240 | ± | 36 | ||||
Y | 53 | ± | 7.8 | |||||||||||
Yb | 6.6 | ± | 0.9 | |||||||||||
Zn | 210 | ± | 20* | 260 | ± | 21 | 220 | ± | 10 | 270 | ± | 41 | ||
Zr | 180 | ± | 29 | |||||||||||
a certified
values indicated with *; others not certified b average of 35 determinations 2/83 to 7/83 c average of 31 determinations 6/83 to 3/84 d lower limit of determination |
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