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The Chemical Analysis of Argonne Premium Coal Samples

Edited by Curtis A. Palmer
U.S. Geological Survey Bulletin 2144


Determination of 25 Elements in Coal Ash from 8 Argonne Premium Coal Samples by Inductively Coupled Argon Plasma-Atomic Emission Spectrometry

By Paul H. Briggs

Table 6. Concentrations of major oxides (in weight percent) and trace elements (in parts per million) in two coal reference materials ashed and then digested by sinter decomposition.

[USGS, U.S. Geological Survey; ICAP-AES, inductively coupled argon plasma-atomic emission spectrometry; NIST, National Institute of Standards and Technology, formerly the National Bureau of Standards]

USGS CLB-1 NIST 1632a
  This study, ICAP-AES J.S. Kane (USGS, unpub. data, 1990)1,2 This study, ICAP-AES Gladney and others (1984)1,2
Al2O3 (%) 18 19 23 24
CaO (%) 2.6 2.9 1.4 1.4
Fe2O3 (%) 14 16 6.6 6.8
K2O (%) .87 .96 2.1 2.1
MgO (%) .53 .62 .70 .85
P2O5 (%) .89 .95 .22 .25
SiO2 (%) 30 33 53 55
TiO2 (%) .91 .98 1.1 1.2
B (ppm) 82 46 220 230
Ba (ppm) 430 470 440 530
Zr (ppm) 170 160 230 230
% ash 7.8   23.5  

1Reported on a whole-coal basis and converted to an ash basis for comparison.
2Compilation of data obtained by various methods.

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