The Chemical Analysis of Argonne Premium Coal Samples
Edited by Curtis A. Palmer
U.S. Geological Survey Bulletin 2144
Determination of 29 Elements in 8 Argonne Premium Coal Samples by Instrumental Neutron Activation Analysis
By Curtis A. Palmer
Table 1. Comparison of concentrations determined (in micrograms per gram, µg/g) from this study with literature values.
[Concentrations in this study were determined by instrumental neutron activation analysis (INAA). Blank, no values available from listed source]
Element | NIST 1633, fly ash | NIST 1632b, bituminous coal | ||
This study | Literature1 | This study | Literature2 | |
Na | 3,060±64 | 3,200±400 | 513±5 | 515±11 |
K | 16,000±640 | 16,100±1,500 | 740±37 | 748±28 |
Sc | 27.3±0.27 | 27±1 | 2.060±0.02 | 1.9 |
Cr | 113.4±8.6 | 127±6 | 10.4±0.3 | 11 |
Fe | 62,600±630 | 62,000±3,000 | 7,780±160 | 7,590±450 |
Co | 40.8±2.0 | 41.5±1.2 | 2.33±0.04 | 2.29±0.17 |
Ni | 92±10 | 98±9 | 8.1±2 | 6.1±0.27 |
Zn | 183±9.5 | 216±25 | 11.7±1.4 | 11.89±0.78 |
As | 56.0±1.6 | 58.0±4 | 3.80±0.11 | 3.73±0.09 |
Se | 9.0±0.54 | 10.2±1.4 | 1.24±0.10 | 1.29±0.11 |
Br | 6.5±0.32 | 12±4 | 21.3±1.1 | 17 |
Rb | 10±6.3 | 125±10 | 4.2±0.76 | 5.05±0.11 |
Sr | 1,340±67 | 1,700±300 | 97±5.8 | 102 |
Sb | 6.61±0.2 | 6.9±0.6 | .259±0.01 | .24 |
Cs | 7.76±0.23 | 8.6±1.1 | .414±0.012 | .44 |
Ba | 2,450±74 | 2,700±200 | 69±2.8 | 67.5±2.1 |
La | 80.4±1.6 | 82±2 | 4.80±0.01 | 5.1 |
Ce | 139±2.7 | 146±15 | 9.19±0.18 | 9 |
Nd | 55±7.2 | 57.8±1.6 | <12 | |
Sm | 14.2±0.3 | 12.4±0.9 | .899±0.009 | .87 |
Eu | 2.68±0.08 | 2.5±0.4 | .176±0.004 | .17 |
Tb | 1.79±0.054 | 1.9±0.3 | .104±0.003 | |
Yb | 5.99±0.18 | 7±3 | .366±0.01 | |
Lu | 1.12±0.046 | 1.0±0.1 | .099±0.004 | |
Hf | 7.12±0.21 | 7.9±0.4 | .410±0.002 | .43 |
Ta | 2.03±0.06 | 1.8±0.3 | .194±0.03 | |
W | 4.93±0.25 | 4.6±1.6 | .52±0.05 | .48 |
Th | 23.1±0.46 | 24.8±2.2 | 1.321±0.026 | 1.342±0.036 |
U | 10.7±0.9 | 12.0±0.5 | .42±0.05 | .436±0.012 |
1 Values taken
from Insov and others (1975).
2 Values
taken from NIST (National Institute of Standards and Technology) 1632b Certificate
(National Bureau of Standards, 1985). Values with no error listed are NIST information
values; all others are NIST certified values.
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