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The Chemical Analysis of Argonne Premium Coal Samples

Edited by Curtis A. Palmer
U.S. Geological Survey Bulletin 2144


Determination of 29 Elements in 8 Argonne Premium Coal Samples by Instrumental Neutron Activation Analysis

By Curtis A. Palmer

Table 1. Comparison of concentrations determined (in micrograms per gram, µg/g) from this study with literature values.

[Concentrations in this study were determined by instrumental neutron activation analysis (INAA). Blank, no values available from listed source]

Element NIST 1633, fly ash NIST 1632b, bituminous coal
This study Literature1 This study Literature2
Na 3,060±64 3,200±400 513±5 515±11
K 16,000±640 16,100±1,500 740±37 748±28
Sc 27.3±0.27 27±1 2.060±0.02 1.9
Cr 113.4±8.6 127±6 10.4±0.3 11
Fe 62,600±630 62,000±3,000 7,780±160 7,590±450
Co 40.8±2.0 41.5±1.2 2.33±0.04 2.29±0.17
Ni 92±10 98±9 8.1±2 6.1±0.27
Zn 183±9.5 216±25 11.7±1.4 11.89±0.78
As 56.0±1.6 58.0±4 3.80±0.11 3.73±0.09
Se 9.0±0.54 10.2±1.4 1.24±0.10 1.29±0.11
Br 6.5±0.32 12±4 21.3±1.1 17
Rb 10±6.3 125±10 4.2±0.76 5.05±0.11
Sr 1,340±67 1,700±300 97±5.8 102
Sb 6.61±0.2 6.9±0.6 .259±0.01 .24
Cs 7.76±0.23 8.6±1.1 .414±0.012 .44
Ba 2,450±74 2,700±200 69±2.8 67.5±2.1
La 80.4±1.6 82±2 4.80±0.01 5.1
Ce 139±2.7 146±15 9.19±0.18 9
Nd 55±7.2 57.8±1.6 <12  
Sm 14.2±0.3 12.4±0.9 .899±0.009 .87
Eu 2.68±0.08 2.5±0.4 .176±0.004 .17
Tb 1.79±0.054 1.9±0.3 .104±0.003  
Yb 5.99±0.18 7±3 .366±0.01  
Lu 1.12±0.046 1.0±0.1 .099±0.004  
Hf 7.12±0.21 7.9±0.4 .410±0.002 .43
Ta 2.03±0.06 1.8±0.3 .194±0.03  
W 4.93±0.25 4.6±1.6 .52±0.05 .48
Th 23.1±0.46 24.8±2.2 1.321±0.026 1.342±0.036
U 10.7±0.9 12.0±0.5 .42±0.05 .436±0.012

1 Values taken from Insov and others (1975).
2 Values taken from NIST (National Institute of Standards and Technology) 1632b Certificate (National Bureau of Standards, 1985). Values with no error listed are NIST information values; all others are NIST certified values.

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