(For further information on spectrsocopy, see:
TITLE: Jarosite WS368 (Pb) DESCRIPT
MINERAL: Pb-bearing jarosite (Alunite group)
COLLECTION_LOCALITY: Tombstone, Arizona
ORIGINAL_DONOR: Wards Science Collection
CURRENT_SAMPLE_LOCATION: USGS Denver Spectroscopy Laboratory
ULTIMATE_SAMPLE_LOCATION: USGS Denver Spectroscopy Laboratory
40 kV - 30 mA, 6.5-9.5 keV (plumjaro.out), 7.3-9.5 keV (plumjar2.out,
References: JCPDS #18-698, 22-827, and 5-417; Szymanski (1985);
pattern for K-jarosite GDS98
Found: an alunite, probably K-jarosite, plus subordinate cerussite and quartz.
Sought but not found: plumbojarosite
Comments: Three phases found. Uncorrected alunite 2 theta values were refined to a hexagonal/rhombohedral unit cell having a=7.301 (2) and c=17.050(7). These dimensions and the yellowish ochre color suggest that the alunite is Fe-rich; the pattern closely matches that of K-jarosite except that the strong (012) reflection is missing. There is no evidence of the double cell (c=33.8 angstroms) characteristic of plumbojarosite (in which a large divalent cation replaces the alkali).
J.S. Huebner,J. Pickrell, T. Schaefer, unpublished data, written communication, USGS, Reston, VA (1994).
COMPOSITIONAL_ANALYSIS_TYPE: None # XRF, EM(WDS), ICP(Trace), WChem
Comparison with a spectrum of cerussite indicates that any cerussite is not detected spectrally. Since the spectral features of this sample differ from those of low temperature K-jarosite (GDS98), this may indicate the presence of Pb in the sample. Because this sample also contains some cerussite, any chemical analysis must be done on the jarosite portion only. This has yet to be done. G. Swayze.
SPECTRAL_PURITY: 1c2_3_4_ # 1= 0.2-3, 2= 1.5-6, 3= 6-25, 4= 20-150 microns
|LIB_SPECTRA:||splib04a r 2498||0.2-3.0µm||200||g.s.=|
|LIB_SPECTRA:||splib05a r 3834||0.2-3.0µm||200||g.s.=|
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