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Open-File Report 2012–1150
Prepared in cooperation with the National Park Service
Baseline Groundwater Quality in National Park Units Within the Marcellus and Utica Shale Gas Plays, New York, Pennsylvania, and West Virginia, 2011
By David A.V. Eckhardt and Ronald A. Sloto
Abstract
Groundwater samples were collected from 15 production wells and 1 spring at 9 national park units in New York, Pennsylvania, and West Virginia in July and August 2011 and analyzed to characterize the quality of these water supplies. The sample sites generally were selected to represent areas of potential effects on water quality by drilling and development of gas wells in Marcellus Shale and Utica Shale areas of the northeastern United States. The groundwater samples were analyzed for 53 constituents, including nutrients, major inorganic constituents, trace elements, chemical oxygen demand, radioactivity, and dissolved gases, including methane and radon-222.
Results indicated that the groundwater used for water supply at the selected national park units is generally of acceptable quality, although concentrations of some constituents exceeded at least one drinking-water guideline at several wells. Nine analytes were detected in concentrations that exceeded Federal drinking-water standards, mostly secondary standards that define aesthetic properties of water, such as taste and odor. One sample had an arsenic concentration that exceeded the U.S. Environmental Protection Agency maximum contaminant level (MCL) of 10 micrograms per liter (μg/L). The pH, which is a measure of acidity (hydrogen ion activity), ranged from 4.8 to 8.4, and in 5 of the 16 samples, the pH values were outside the accepted U.S. Environmental Protection Agency secondary maximum contaminant level (SMCL) range of 6.5 to 8.5. The concentration of total dissolved solids exceeded the SMCL of 500 milligrams per liter (mg/L) at four sites. The sulfate concentration exceeded the SMCL of 250 mg/L concentration in one sample, and the fluoride concentration exceeded the SMCL of 2 mg/L in one sample. Sodium concentrations exceeded the U.S. Environmental Protection Agency drinking water health advisory of 60 mg/L at four sites. Iron concentrations exceeded the SMCL of 300 μg/L in two samples, and manganese concentrations exceeded the SMCL of 50 μg/L in five samples. Radon-222 concentrations exceeded the proposed U.S. Environmental Protection Agency MCL of 300 picocuries per liter in eight samples.
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First posted August 30, 2012
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Suggested citation:
Eckhardt, D.A., and Sloto, R.A., 2012, Baseline groundwater quality in national park units within the Marcellus and
Utica Shale gas plays, New York, Pennsylvania, and West Virginia, 2011: U.S. Geological Survey Open-File Report
2012–1150, 20 p., at http://pubs.usgs.gov/of/2012/1150/.
Contents
Abstract
Introduction
Methods
Site Selection
Sampling and Analytical Methods
Baseline Groundwater Quality in the National Park Units
Summary of Water-Quality Results
Results for Individual Park Units
Delaware Water Gap National Recreation Area
Allegheny Portage Railroad National Historic Site
Johnstown Flood National Monument
Flight 93 National Memorial
Fort Necessity National Battlefield
New River Gorge National River
Upper Delaware National Scenic and Recreational River
Saratoga National Historic Park
Martin Van Buren National Historic Site
Summary
References Cited