<?xml version='1.0' encoding='utf-8'?>
<oai_dc:dc xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd">
  <dc:contributor>B.R. Adams</dc:contributor>
  <dc:creator>S. L. Abidi</dc:creator>
  <dc:date>1987</dc:date>
  <dc:description>Complete &lt;sup&gt;1&lt;/sup&gt;H and &lt;sup&gt;13&lt;/sup&gt;C resonance assignments of antimycin A&lt;sub&gt;1&lt;/sub&gt; were accomplished by two-dimensional NMR techniques, viz. &lt;sup&gt;1&lt;/sup&gt;H homonuclear COSY correlation, heteronuclear &lt;sup&gt;13&lt;/sup&gt;C-&lt;sup&gt;1&lt;/sup&gt;H chemical shift correlation and long-range heteronuclear &lt;sup&gt;13&lt;/sup&gt;C-&lt;sup&gt;1&lt;/sup&gt;H COLOC correlation. Antimycin A&lt;sub&gt;1&lt;/sub&gt; was found to consist of two isomeric components in a 2:1 ratio based on NMR spectroscopic evidence. The structure of the major component was newly assigned as the 8-isopentanoic acid ester. The spectra of the minor component were consistent with the known structure of antimycin A&lt;sub&gt;1&lt;/sub&gt;.</dc:description>
  <dc:format>application/pdf</dc:format>
  <dc:identifier>10.1002/mrc.1260251212</dc:identifier>
  <dc:language>en</dc:language>
  <dc:publisher>Wiley</dc:publisher>
  <dc:title>1H and 13C resonance designation of antimycin A1 by two-dimensional NMR spectroscopy</dc:title>
  <dc:type>article</dc:type>
</oai_dc:dc>