A.J. Rondinone B.C. Chakoumakos S. Circone L.A. Stern S. H. Kirby Y. Ishii C.J. Rawn 2003 Neutron powder diffraction data confirm that hydrate samples synthesized with propane crystallize as structure type II hydrate. The structure has been modeled using rigid-body constraints to describe C3H8 molecules located in the eight larger polyhedral cavities of a deuterated host lattice. Data were collected at 12, 40, 100, 130, 160, 190, 220, and 250 K and used to calculate the thermal expansivity from the temperature dependence of the lattice parameters. The data collected allowed for full structural refinement of atomic coordinates and the atomic-displacement parameters. application/pdf 10.1139/p03-022 en Neutron powder diffraction studies as a function of temperature of structure II hydrate formed from propane article