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<oai_dc:dc xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd">
  <dc:contributor>T. F. Kraemer</dc:contributor>
  <dc:contributor>A. Shapiro</dc:contributor>
  <dc:creator>W.W. Wood</dc:creator>
  <dc:date>2004</dc:date>
  <dc:description>&lt;div class="abstract-group"&gt;&lt;div class="article-section__content en main"&gt;&lt;p&gt;Ground waters from fractured igneous and high‐grade sialic metamorphic rocks frequently have elevated activity of dissolved radon (&lt;sup&gt;222&lt;/sup&gt;Rn). A chemically based model is proposed whereby radium (&lt;sup&gt;226&lt;/sup&gt;Ra) from the decay of uranium (&lt;sup&gt;238&lt;/sup&gt;U) diffuses through the primary porosity of the rock to the water‐transmitting fracture where it is sorbed on weathering products. Sorption of&lt;span&gt;&amp;nbsp;&lt;/span&gt;&lt;sup&gt;226&lt;/sup&gt;Ra on the fracture surface maintains an activity gradient in the rock matrix, ensuring a continuous supply of&lt;span&gt;&amp;nbsp;&lt;/span&gt;&lt;sup&gt;226&lt;/sup&gt;Ra to fracture surfaces. As a result of the relatively long half‐life of&lt;span&gt;&amp;nbsp;&lt;/span&gt;&lt;sup&gt;226&lt;/sup&gt;Ra (1601 years), significant activity can accumulate on fracture surfaces. The proximity of this sorbed&lt;span&gt;&amp;nbsp;&lt;/span&gt;&lt;sup&gt;226&lt;/sup&gt;Ra to the active ground water flow system allows its decay progeny&lt;span&gt;&amp;nbsp;&lt;/span&gt;&lt;sup&gt;222&lt;/sup&gt;Rn to enter directly into the water. Laboratory analyses of primary porosity and diffusion coefficients of the rock matrix, radon emanation, and ion exchange at fracture surfaces are consistent with the requirements of a diffusion/ion‐exchange model. A dipole‐brine injection/withdrawal experiment conducted between bedrock boreholes in the high‐grade metamorphic and granite rocks at the Hubbard Brook Experimental Forest, Grafton County, New Hampshire, United States (42°56′N, 71°43′W) shows a large activity of&lt;span&gt;&amp;nbsp;&lt;/span&gt;&lt;sup&gt;226&lt;/sup&gt;Ra exchanged from fracture surfaces by a magnesium brine. The&lt;span&gt;&amp;nbsp;&lt;/span&gt;&lt;sup&gt;226&lt;/sup&gt;Ra activity removed by the exchange process is 34 times greater than that of&lt;span&gt;&amp;nbsp;&lt;/span&gt;&lt;sup&gt;238&lt;/sup&gt;U activity. These observations are consistent with the diffusion/ion‐exchange model. Elutriate isotopic ratios of&lt;span&gt;&amp;nbsp;&lt;/span&gt;&lt;sup&gt;223&lt;/sup&gt;Ra/&lt;sup&gt;226&lt;/sup&gt;Ra and&lt;span&gt;&amp;nbsp;&lt;/span&gt;&lt;sup&gt;238&lt;/sup&gt;U/&lt;sup&gt;226&lt;/sup&gt;Ra are also consistent with the proposed chemically based diffusion/ion‐exchange model.&lt;/p&gt;&lt;/div&gt;&lt;/div&gt;</dc:description>
  <dc:format>application/pdf</dc:format>
  <dc:identifier>10.1111/j.1745-6584.2004.tb02624.x</dc:identifier>
  <dc:language>en</dc:language>
  <dc:publisher>Wiley</dc:publisher>
  <dc:title>Radon (222Rn) in ground water of fractured rocks: A diffusion/ion exchange model</dc:title>
  <dc:type>article</dc:type>
</oai_dc:dc>