Ingrid M. Verstraeten
Thomas F. Kraemer
John Karl Bohlke
2007
<p><span>Effects of surface-water irrigation on an alluvial aquifer were evaluated using chemical and isotopic data including </span><i>δ</i><sup>2</sup><span>H, </span><i>δ</i><sup>18</sup><span>O, </span><sup>3</sup><span>H, </span><i>δ</i><sup>3</sup><span>He, Ar, Ne, N</span><sub>2</sub><span>, </span><i>δ</i><sup>15</sup><span>N, and </span><sup>234</sup><span>U/</span><sup>238</sup><span>U activity ratios in a transect of nested wells in the North Platte River valley in western Nebraska, USA. The data were used to evaluate sources and fluxes of H</span><sub>2</sub><span>O, </span><span class="math"><span id="MathJax-Element-1-Frame" class="MathJax_SVG" data-mathml="<math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><msubsup is="true"><mrow is="true"><mtext is="true">NO</mtext></mrow><mrow is="true"><mn is="true">3</mn></mrow><mrow is="true"><mo is="true">-</mo></mrow></msubsup></mrow></math>"><span class="MJX_Assistive_MathML">NO3-</span></span></span><span> and U, all of which were strongly affected by irrigated agriculture. Combined results indicate that the alluvial aquifer was dominated by irrigation water that had distinctive chemical and isotopic features that were inherited from the North Platte River or acquired from agricultural soils or recharge processes. Values of </span><i>δ</i><sup>2</sup><span>H, </span><i>δ</i><sup>18</sup><span>O, Ar and Ne indicate that most of the ground water in the alluvial aquifer was irrigation water that was derived from the North Platte River and distributed during the growing season. The irrigation water was identified by an evaporated isotopic signature that was acquired by the river in major upstream reservoirs in Wyoming, and by relatively warm gas-equilibration temperatures related to warm-season recharge. Apparent </span><sup>3</sup><span>H–</span><sup>3</sup><span>He ages indicate that the ground water in the alluvium was stratified and mostly <30</span><span> </span><span>a old, with apparent recharge rates varying widely from about 0.2 to >3.0</span><span> </span><span>m/a. Age gradients and </span><span class="math"><span id="MathJax-Element-2-Frame" class="MathJax_SVG" data-mathml="<math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><msubsup is="true"><mrow is="true"><mtext is="true">NO</mtext></mrow><mrow is="true"><mn is="true">3</mn></mrow><mrow is="true"><mo is="true">-</mo></mrow></msubsup></mrow></math>"><span class="MJX_Assistive_MathML">NO3-</span></span></span><span> concentrations indicate that recharge occurred by a combination of focused leakage from irrigation canals (rapid local recharge, low </span><span class="math"><span id="MathJax-Element-3-Frame" class="MathJax_SVG" data-mathml="<math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><msubsup is="true"><mrow is="true"><mtext is="true">NO</mtext></mrow><mrow is="true"><mn is="true">3</mn></mrow><mrow is="true"><mo is="true">-</mo></mrow></msubsup></mrow></math>"><span class="MJX_Assistive_MathML">NO3-</span></span></span><span>) and distributed infiltration beneath the irrigated agricultural fields (lower recharge, high </span><span class="math"><span id="MathJax-Element-4-Frame" class="MathJax_SVG" data-mathml="<math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><msubsup is="true"><mrow is="true"><mtext is="true">NO</mtext></mrow><mrow is="true"><mn is="true">3</mn></mrow><mrow is="true"><mo is="true">-</mo></mrow></msubsup></mrow></math>"><span class="MJX_Assistive_MathML">NO3-</span></span></span><span>). Large amounts of U with relatively low </span><sup>234</sup><span>U/</span><sup>238</sup><span>U activity ratios were present in the alluvial aquifer as a result of irrigation with U-bearing river water, and minor amounts of U with higher </span><sup>234</sup><span>U/</span><sup>238</sup><span>U activity ratios were added locally from basal and underlying volcanic-rich sediments. Distributions of </span><span class="math"><span id="MathJax-Element-5-Frame" class="MathJax_SVG" data-mathml="<math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><msubsup is="true"><mrow is="true"><mtext is="true">NO</mtext></mrow><mrow is="true"><mn is="true">3</mn></mrow><mrow is="true"><mo is="true">-</mo></mrow></msubsup></mrow></math>"><span class="MJX_Assistive_MathML">NO3-</span></span></span><span>, </span><span class="math"><span id="MathJax-Element-6-Frame" class="MathJax_SVG" data-mathml="<math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><mi is="true">&#x3B4;</mi><msup is="true"><mrow is="true" /><mrow is="true"><mn is="true">15</mn></mrow></msup><mtext is="true">N</mtext><mo stretchy="false" is="true">[</mo><msubsup is="true"><mrow is="true"><mtext is="true">NO</mtext></mrow><mrow is="true"><mn is="true">3</mn></mrow><mrow is="true"><mo is="true">-</mo></mrow></msubsup><mo stretchy="false" is="true">]</mo></mrow></math>"><span class="MJX_Assistive_MathML">δ15N[NO3-]</span></span></span><span>, dissolved gases, and ground-water ages indicate that </span><span class="math"><span id="MathJax-Element-7-Frame" class="MathJax_SVG" data-mathml="<math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><msubsup is="true"><mrow is="true"><mtext is="true">NO</mtext></mrow><mrow is="true"><mn is="true">3</mn></mrow><mrow is="true"><mo is="true">-</mo></mrow></msubsup></mrow></math>"><span class="MJX_Assistive_MathML">NO3-</span></span></span><span> concentrations increased and </span><span class="math"><span id="MathJax-Element-8-Frame" class="MathJax_SVG" data-mathml="<math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><mi is="true">&#x3B4;</mi><msup is="true"><mrow is="true" /><mrow is="true"><mn is="true">15</mn></mrow></msup><mtext is="true">N</mtext><mo stretchy="false" is="true">[</mo><msubsup is="true"><mrow is="true"><mtext is="true">NO</mtext></mrow><mrow is="true"><mn is="true">3</mn></mrow><mrow is="true"><mo is="true">-</mo></mrow></msubsup><mo stretchy="false" is="true">]</mo></mrow></math>"><span class="MJX_Assistive_MathML">δ15N[NO3-]</span></span></span><span> values decreased in distributed recharge in the last few decades, possibly in relation to a documented increase in the agricultural use of artificial fertilizers. Canal leakage caused substantial dilution of </span><span class="math"><span id="MathJax-Element-9-Frame" class="MathJax_SVG" data-mathml="<math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><msubsup is="true"><mrow is="true"><mtext is="true">NO</mtext></mrow><mrow is="true"><mn is="true">3</mn></mrow><mrow is="true"><mo is="true">-</mo></mrow></msubsup></mrow></math>"><span class="MJX_Assistive_MathML">NO3-</span></span></span><span>within the alluvial aquifer, whereas denitrification occurred mainly near the bottom of the alluvium. The average residence time of the irrigation water within the aquifer was relatively short (about 9</span><span> </span><span>a) and reactions such as respiration, denitrification and U exchange in the saturated zone had relatively little effect on the overall composition of the alluvial ground water in comparison to what they might have had in the absence of irrigation recharge.</span></p>
application/pdf
10.1016/j.apgeochem.2006.08.019
en
Elsevier
Effects of surface-water irrigation on sources, fluxes, and residence times of water, nitrate, and uranium in an alluvial aquifer
article