Joel M. Galloway Andrew G. Hunt Kenneth Belitz Bryant C. Jurgens Tyler D. Johnson Peter B. McMahon 2020 <div id="abstracts" class="Abstracts u-font-serif"><div id="abs0010" class="abstract author" lang="en"><div id="abssec0010"><p id="abspara0010">Thirty water wells were sampled in 2018 to understand the geochemistry and age of groundwater in the Williston Basin and assess potential effects of shale-oil production from the Three Forks-Bakken petroleum system (TBPS) on groundwater quality. Two geochemical groups are identified using hierarchical cluster analysis. Group 1 represents the younger (median<span>&nbsp;</span>⁴He&nbsp;=&nbsp;21.49&nbsp;×&nbsp;10⁻⁸&nbsp;cm³<span>&nbsp;</span>STP/g), less chemically evolved water. Group 2 represents the older (median<span>&nbsp;</span>⁴He&nbsp;=&nbsp;1389&nbsp;×&nbsp;10⁻⁸&nbsp;cm³<span>&nbsp;</span>STP/g), more chemically evolved water. At least two samples from each group contain elevated Cl concentrations (&gt;70&nbsp;mg/L). Br/Cl, B/Cl, and Li/Cl ratios indicate multiple sources account for the elevated Cl concentrations: septic-system leachate/road deicing salt, lignite beds in the aquifers, Pierre Shale beneath the aquifers, and water associated with the TBPS (one sample).<span>&nbsp;</span>³H and<span>&nbsp;</span>¹⁴C data indicate that 10.8, 21.6, and 67.6% of the samples are modern (post-1952), mixed age, and premodern (pre-1953), respectively. Lumped-parameter modeling of<span>&nbsp;</span>³H, SF₆,<span>&nbsp;</span>³He, and<span>&nbsp;</span>¹⁴C concentrations indicates mean ages of the modern and premodern fractions range from ~1 to 30 years and 1300 to &gt;30,000 years, respectively. Group 2 contains the highest CH₄<span>&nbsp;</span>concentrations (0.0018–32&nbsp;mg/L). δ¹³C–CH₄<span>&nbsp;</span>and C₁/C₂+C₃<span>&nbsp;</span>data in groundwater (−91.7 to −70.0‰ and 1280 to 13,600) indicate groundwater CH₄<span>&nbsp;</span>is biogenic in origin and not from thermogenic shale gas. Four volatile organic compounds (VOCs) were detected in two samples. One mixed-age sample contains chloroform (0.25&nbsp;μg/L) and dichloromethane (0.05&nbsp;μg/L), which are probably associated with septic leachate. One premodern sample contains butane (0.082&nbsp;μg/L) and n-pentane (0.032&nbsp;μg/L), which are probably associated with thermogenic gas from a nearby oil well. The data indicate hydrocarbon production activities do not currently (2018) widely affect Cl, CH₄, and VOC concentrations in groundwater. The predominance of premodern recharge in the aquifers indicates the groundwater moves relatively slowly, which could inhibit widespread chemical movement in groundwater overlying the TBPS. Comparison of groundwater-age data from five major unconventional hydrocarbon-production areas indicates aquifer zones used for water supply in the TBPS area have a lower risk of widespread chemical movement in groundwater than similar aquifer zones in the Fayetteville (Arkansas) and Marcellus (Pennsylvania) Shale production areas, but have a higher risk than similar aquifer zones in the Eagle Ford (Texas) and Haynesville (Texas, Louisiana) Shale production areas.</p></div></div></div> application/pdf 10.1016/j.apgeochem.2020.104833 en Elsevier Geochemistry and age of groundwater in the Williston Basin, USA: Assessing potential effects of shale-oil production on groundwater quality article