We employ a novel approach that combines pulse-chase feeding and multi-labelled stable isotopes to determine gut passage time (GPT), gut retention time (GRT), food ingestion rate (IR) and assimilation efficiency (AE) of three trace elements for a freshwater gastropod. Lettuce isotopically enriched in 53Cr, 65Cu and 106Cd was fed for 2 h to Lymnaea stagnalis. The release of tracers in feces and water was monitored for 48 h, during which unlabelled lettuce was provided ad libidum. The first defecation of 53Cr occurred after 5 h of depuration (GPT), whereas 90% of the ingested 53Cr was recovered in the feces after 22.5 h of depuration (GRT). 53Chromium was not significantly accumulated in the soft tissues upon exposure. In contrast, 65Cu and 106Cd assimilation was detectable for most experimental snails, i.e., 65/63Cu and 106/114Cd ratios in exposed snails were higher than those for controls. Food IR during the labelled feeding phase was 0.16 ± 0.07 g g−1 d−1. IR was inferred from the amount of 53Cr egested in the feces during depuration and the concentration of 53Cr in the labelled lettuce. Assimilation efficiencies (±95% CI) determined using mass balance calculations were 84 ± 4% for Cu and 85 ± 3% for Cd. The ratio method yields similar AE estimates. Expanding the application of this novel stable isotope tracer technique to other metals in a wide variety of species will provide unique opportunities to evaluate the interplay between digestive processes and dietary influx of metals. Understanding the biological processes that modulate dietborne metal uptake is crucial to assess the toxicity of dietborne metals.
","language":"English","publisher":"Elsevier","doi":"10.1016/j.aquatox.2007.03.016","issn":"0166445X","usgsCitation":"Croteau, M.N., Luoma, S.N., and Pellet, B., 2007, Determining metal assimilation efficiency in aquatic invertebrates using enriched stable metal isotope tracers: Aquatic Toxicology, v. 83, no. 2, p. 116-125, https://doi.org/10.1016/j.aquatox.2007.03.016.","productDescription":"10 p.","startPage":"116","endPage":"125","numberOfPages":"10","costCenters":[{"id":589,"text":"Toxic Substances Hydrology Program","active":true,"usgs":true}],"links":[{"id":240315,"rank":1,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"volume":"83","issue":"2","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"5059fff0e4b0c8380cd4f4b2","contributors":{"authors":[{"text":"Croteau, Marie Noele 0000-0003-0346-3580 mcroteau@usgs.gov","orcid":"https://orcid.org/0000-0003-0346-3580","contributorId":895,"corporation":false,"usgs":true,"family":"Croteau","given":"Marie","email":"mcroteau@usgs.gov","middleInitial":"Noele","affiliations":[{"id":37277,"text":"WMA - Earth System Processes Division","active":true,"usgs":true},{"id":438,"text":"National Research Program - Western Branch","active":true,"usgs":true}],"preferred":true,"id":424540,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Luoma, Samuel N. 0000-0001-5443-5091 snluoma@usgs.gov","orcid":"https://orcid.org/0000-0001-5443-5091","contributorId":2287,"corporation":false,"usgs":true,"family":"Luoma","given":"Samuel","email":"snluoma@usgs.gov","middleInitial":"N.","affiliations":[{"id":438,"text":"National Research Program - Western Branch","active":true,"usgs":true}],"preferred":true,"id":424541,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Pellet, B.","contributorId":99377,"corporation":false,"usgs":true,"family":"Pellet","given":"B.","email":"","affiliations":[],"preferred":false,"id":424542,"contributorType":{"id":1,"text":"Authors"},"rank":3}]}} ,{"id":70029837,"text":"70029837 - 2007 - Geoelectrical evidence of bicontinuum transport in groundwater","interactions":[],"lastModifiedDate":"2019-10-18T06:43:32","indexId":"70029837","displayToPublicDate":"2007-01-01T00:00:00","publicationYear":"2007","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":1807,"text":"Geophysical Research Letters","active":true,"publicationSubtype":{"id":10}},"title":"Geoelectrical evidence of bicontinuum transport in groundwater","docAbstract":"Bicontinuum models and rate-limited mass transfer (RLMT) explain complex transport behavior (e.g., long tailing and rebound) in heterogeneous geologic media, but experimental verification is problematic because geochemical samples represent the mobile component of the pore space. Here, we present geophysical evidence of RLMT at the field scale during an aquifer-storage and recovery experiment in a fractured limestone aquifer in Charleston, South Carolina. We observe a hysteretic relation between measurements of porefluid conductivity and bulk electrical conductivity; this hysteresis contradicts advective-dispersive transport and the standard petrophysical model relating pore-fluid and bulk conductivity, but can be explained by considering bicontinuum transport models that include first-order RLMT. Using a simple numerical model, we demonstrate that geoelectrical measurements are sensitive to bicontinuum transport and RLMT parameters, which are otherwise difficult to infer from direct, hydrologic measurements.
","language":"English","publisher":"American Geophysical Union","doi":"10.1029/2007GL030019","issn":"00948276","usgsCitation":"Singha, K., Day-Lewis, F.D., and Lane, J.W., 2007, Geoelectrical evidence of bicontinuum transport in groundwater: Geophysical Research Letters, v. 34, no. 12, L12401, 5 p., https://doi.org/10.1029/2007GL030019.","productDescription":"L12401, 5 p.","costCenters":[{"id":493,"text":"Office of Ground Water","active":true,"usgs":true},{"id":589,"text":"Toxic Substances Hydrology Program","active":true,"usgs":true}],"links":[{"id":240314,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"country":"United States","state":"South Carolina","city":"Charleston","geographicExtents":"{\n \"type\": \"FeatureCollection\",\n \"features\": [\n {\n \"type\": \"Feature\",\n \"properties\": {},\n \"geometry\": {\n \"type\": \"Polygon\",\n \"coordinates\": [\n [\n [\n -80.29632568359375,\n 32.54681317351514\n ],\n [\n -79.5794677734375,\n 32.54681317351514\n ],\n [\n -79.5794677734375,\n 33.13065128220441\n ],\n [\n -80.29632568359375,\n 33.13065128220441\n ],\n [\n -80.29632568359375,\n 32.54681317351514\n ]\n ]\n ]\n }\n }\n ]\n}","volume":"34","issue":"12","noUsgsAuthors":false,"publicationDate":"2007-06-23","publicationStatus":"PW","scienceBaseUri":"505a1744e4b0c8380cd5545f","contributors":{"authors":[{"text":"Singha, K.","contributorId":51431,"corporation":false,"usgs":true,"family":"Singha","given":"K.","affiliations":[],"preferred":false,"id":424539,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Day-Lewis, Frederick D. 0000-0003-3526-886X daylewis@usgs.gov","orcid":"https://orcid.org/0000-0003-3526-886X","contributorId":1672,"corporation":false,"usgs":true,"family":"Day-Lewis","given":"Frederick","email":"daylewis@usgs.gov","middleInitial":"D.","affiliations":[{"id":486,"text":"OGW Branch of Geophysics","active":true,"usgs":true},{"id":493,"text":"Office of Ground Water","active":true,"usgs":true},{"id":37277,"text":"WMA - Earth System Processes Division","active":true,"usgs":true}],"preferred":true,"id":424538,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Lane, John W. Jr. 0000-0002-3558-243X jwlane@usgs.gov","orcid":"https://orcid.org/0000-0002-3558-243X","contributorId":189168,"corporation":false,"usgs":true,"family":"Lane","given":"John","suffix":"Jr.","email":"jwlane@usgs.gov","middleInitial":"W.","affiliations":[{"id":486,"text":"OGW Branch of Geophysics","active":true,"usgs":true},{"id":493,"text":"Office of Ground Water","active":true,"usgs":true}],"preferred":false,"id":424537,"contributorType":{"id":1,"text":"Authors"},"rank":3}]}} ,{"id":70029836,"text":"70029836 - 2007 - Increased groundwater to stream discharge from permafrost thawing in the Yukon River basin: Potential impacts on lateral export of carbon and nitrogen","interactions":[],"lastModifiedDate":"2018-10-17T10:06:39","indexId":"70029836","displayToPublicDate":"2007-01-01T00:00:00","publicationYear":"2007","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":1807,"text":"Geophysical Research Letters","active":true,"publicationSubtype":{"id":10}},"title":"Increased groundwater to stream discharge from permafrost thawing in the Yukon River basin: Potential impacts on lateral export of carbon and nitrogen","docAbstract":"Arctic and subarctic watersheds are undergoing climate warming, permafrost thawing, and thermokarst formation resulting in quantitative shifts in surface water - groundwater interaction at the basin scale. Groundwater currently comprises almost one fourth of Yukon River water discharged to the Bering Sea and contributes 5-10% of the dissolved organic carbon (DOC) and nitrogen (DON) and 35-45% of the dissolved inorganic carbon (DIC) and nitrogen (DIN) loads. Long-term strearnflow records (>30 yrs) of the Yukon River basin indicate a general upward trend in groundwater contribution to streamflow of 0.7-0.9%/yr and no pervasive change in annual flow. We propose that the increases in groundwater contributions were caused predominately by climate warming and permafrost thawing that enhances infiltration and supports deeper flowpaths. The increased groundwater fraction may result in decreased DOC and DON and increased DIC and DIN export when annual flow remains unchanged.","largerWorkType":{"id":2,"text":"Article"},"largerWorkTitle":"Geophysical Research Letters","largerWorkSubtype":{"id":10,"text":"Journal Article"},"language":"English","doi":"10.1029/2007GL030216","issn":"00948276","usgsCitation":"Walvoord, M.A., and Striegl, R.G., 2007, Increased groundwater to stream discharge from permafrost thawing in the Yukon River basin: Potential impacts on lateral export of carbon and nitrogen: Geophysical Research Letters, v. 34, no. 12, https://doi.org/10.1029/2007GL030216.","costCenters":[{"id":589,"text":"Toxic Substances Hydrology Program","active":true,"usgs":true}],"links":[{"id":477214,"rank":10000,"type":{"id":40,"text":"Open Access Publisher Index Page"},"url":"https://doi.org/10.1029/2007gl030216","text":"Publisher Index Page"},{"id":240313,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"},{"id":212775,"rank":9999,"type":{"id":10,"text":"Digital Object Identifier"},"url":"https://dx.doi.org/10.1029/2007GL030216"}],"volume":"34","issue":"12","noUsgsAuthors":false,"publicationDate":"2007-06-28","publicationStatus":"PW","scienceBaseUri":"505a39f9e4b0c8380cd61ae1","contributors":{"authors":[{"text":"Walvoord, Michelle Ann 0000-0003-4269-8366 walvoord@usgs.gov","orcid":"https://orcid.org/0000-0003-4269-8366","contributorId":147211,"corporation":false,"usgs":true,"family":"Walvoord","given":"Michelle","email":"walvoord@usgs.gov","middleInitial":"Ann","affiliations":[{"id":5044,"text":"National Research Program - Central Branch","active":true,"usgs":true}],"preferred":true,"id":424536,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Striegl, Robert G. 0000-0002-8251-4659 rstriegl@usgs.gov","orcid":"https://orcid.org/0000-0002-8251-4659","contributorId":1630,"corporation":false,"usgs":true,"family":"Striegl","given":"Robert","email":"rstriegl@usgs.gov","middleInitial":"G.","affiliations":[{"id":200,"text":"Coop Res Unit Seattle","active":true,"usgs":true},{"id":5044,"text":"National Research Program - Central Branch","active":true,"usgs":true},{"id":37277,"text":"WMA - Earth System Processes Division","active":true,"usgs":true},{"id":36183,"text":"Hydro-Ecological Interactions Branch","active":true,"usgs":true}],"preferred":false,"id":424535,"contributorType":{"id":1,"text":"Authors"},"rank":2}]}} ,{"id":70029805,"text":"70029805 - 2007 - Distributed energy-balance modeling of snow-cover evolution and melt in rugged terrain: Tobacco Root Mountains, Montana, USA","interactions":[],"lastModifiedDate":"2012-03-12T17:21:07","indexId":"70029805","displayToPublicDate":"2007-01-01T00:00:00","publicationYear":"2007","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":2342,"text":"Journal of Hydrology","active":true,"publicationSubtype":{"id":10}},"title":"Distributed energy-balance modeling of snow-cover evolution and melt in rugged terrain: Tobacco Root Mountains, Montana, USA","docAbstract":"A distributed energy-balance model was developed for simulating snowpack evolution and melt in rugged terrain. The model, which was applied to a 43-km2 watershed in the Tobacco Root Mountains, Montana, USA, used measured ambient data from nearby weather stations to drive energy-balance calculations and to constrain the model of Liston and Sturm [Liston, G.E., Sturm, M., 1998. A snow-transport model for complex terrain. Journal of Glaciology 44 (148), 498-516] for calculating the initial snowpack thickness. Simulated initial snow-water equivalent ranged between 1 cm and 385 cm w.e. (water equivalent) with high values concentrated on east-facing slopes below tall summits. An interpreted satellite image of the snowcover distribution on May 6, 1998, closely matched the simulated distribution with the greatest discrepancy occurring in the floor of the main trunk valley. Model simulations indicated that snowmelt commenced early in the melt season, but rapid meltout of snow cover did not occur until after the average energy balance of the entire watershed became positive about 45 days into the melt season. Meltout was fastest in the lower part of the watershed where warmer temperatures and tree cover enhanced the energy income of the underlying snow. An interpreted satellite image of the snowcover distribution on July 9, 1998 compared favorably with the simulated distribution, and melt curves for modeled canopy-covered cells mimicked the trends measured at nearby snow pillow stations. By the end of the simulation period (August 3), 28% of the watershed remained snow covered, most of which was concentrated in the highest parts of the watershed where initially thick accumulations had been shaded by surrounding summits. The results of this study provide further demonstration of the critical role that topography plays in the timing and magnitude of snowmelt from high mountain watersheds. ?? 2006 Elsevier B.V. All rights reserved.","largerWorkType":{"id":2,"text":"Article"},"largerWorkTitle":"Journal of Hydrology","largerWorkSubtype":{"id":10,"text":"Journal Article"},"language":"English","doi":"10.1016/j.jhydrol.2006.12.012","issn":"00221694","usgsCitation":"Letsinger, S., and Olyphant, G., 2007, Distributed energy-balance modeling of snow-cover evolution and melt in rugged terrain: Tobacco Root Mountains, Montana, USA: Journal of Hydrology, v. 336, no. 1-2, p. 48-60, https://doi.org/10.1016/j.jhydrol.2006.12.012.","startPage":"48","endPage":"60","numberOfPages":"13","costCenters":[],"links":[{"id":212805,"rank":9999,"type":{"id":10,"text":"Digital Object Identifier"},"url":"https://dx.doi.org/10.1016/j.jhydrol.2006.12.012"},{"id":240349,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"volume":"336","issue":"1-2","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"505a0254e4b0c8380cd4ffe8","contributors":{"authors":[{"text":"Letsinger, S.L.","contributorId":50731,"corporation":false,"usgs":true,"family":"Letsinger","given":"S.L.","affiliations":[],"preferred":false,"id":424403,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Olyphant, G.A.","contributorId":51023,"corporation":false,"usgs":true,"family":"Olyphant","given":"G.A.","email":"","affiliations":[],"preferred":false,"id":424404,"contributorType":{"id":1,"text":"Authors"},"rank":2}]}} ,{"id":70029750,"text":"70029750 - 2007 - Role of chemotaxis in the transport of bacteria through saturated porous media","interactions":[],"lastModifiedDate":"2018-10-17T11:27:44","indexId":"70029750","displayToPublicDate":"2007-01-01T00:00:00","publicationYear":"2007","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":664,"text":"Advances in Water Resources","active":true,"publicationSubtype":{"id":10}},"title":"Role of chemotaxis in the transport of bacteria through saturated porous media","docAbstract":"Populations of chemotactic bacteria are able to sense and respond to chemical gradients in their surroundings and direct their migration toward increasing concentrations of chemicals that they perceive to be beneficial to their survival. It has been suggested that this phenomenon may facilitate bioremediation processes by bringing bacteria into closer proximity to the chemical contaminants that they degrade. To determine the significance of chemotaxis in these processes it is necessary to quantify the magnitude of the response and compare it to other groundwater processes that affect the fate and transport of bacteria. We present a systematic approach toward quantifying the chemotactic response of bacteria in laboratory scale experiments by starting with simple, well-defined systems and gradually increasing their complexity. Swimming properties of individual cells were assessed from trajectories recorded by a tracking microscope. These properties were used to calculate motility and chemotaxis coefficients of bacterial populations in bulk aqueous media which were compared to experimental results of diffusion studies. Then effective values of motility and chemotaxis coefficients in single pores, pore networks and packed columns were analyzed. These were used to estimate the magnitude of the chemotactic response in porous media and to compare with dispersion coefficients reported in the field. This represents a compilation of many studies over a number of years. While there are certainly limitations with this approach for ultimately quantifying motility and chemotaxis in granular aquifer media, it does provide insight into what order of magnitude responses are possible and which characteristics of the bacteria and media are expected to be important.
","largerWorkType":{"id":2,"text":"Article"},"largerWorkTitle":"Advances in Water Resources","largerWorkSubtype":{"id":10,"text":"Journal Article"},"language":"English","publisher":"Elsevier","doi":"10.1016/j.advwatres.2006.05.019","issn":"03091708","usgsCitation":"Ford, R., and Harvey, R.W., 2007, Role of chemotaxis in the transport of bacteria through saturated porous media: Advances in Water Resources, v. 30, no. 6-7, p. 1608-1617, https://doi.org/10.1016/j.advwatres.2006.05.019.","productDescription":"10 p.","startPage":"1608","endPage":"1617","numberOfPages":"10","costCenters":[{"id":589,"text":"Toxic Substances Hydrology Program","active":true,"usgs":true}],"links":[{"id":213030,"rank":9999,"type":{"id":10,"text":"Digital Object Identifier"},"url":"https://dx.doi.org/10.1016/j.advwatres.2006.05.019"},{"id":240610,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"volume":"30","issue":"6-7","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"505aae49e4b0c8380cd87072","contributors":{"authors":[{"text":"Ford, R.M.","contributorId":95689,"corporation":false,"usgs":true,"family":"Ford","given":"R.M.","email":"","affiliations":[],"preferred":false,"id":424118,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Harvey, Ronald W. 0000-0002-2791-8503 rwharvey@usgs.gov","orcid":"https://orcid.org/0000-0002-2791-8503","contributorId":564,"corporation":false,"usgs":true,"family":"Harvey","given":"Ronald","email":"rwharvey@usgs.gov","middleInitial":"W.","affiliations":[{"id":5044,"text":"National Research Program - Central Branch","active":true,"usgs":true}],"preferred":true,"id":424117,"contributorType":{"id":1,"text":"Authors"},"rank":2}]}} ,{"id":70029740,"text":"70029740 - 2007 - Formation of mixed Al-Fe colloidal sorbent and dissolved-colloidal partitioning of Cu and Zn in the Cement Creek - Animas River Confluence, Silverton, Colorado","interactions":[],"lastModifiedDate":"2023-08-02T11:33:46.512511","indexId":"70029740","displayToPublicDate":"2007-01-01T00:00:00","publicationYear":"2007","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":835,"text":"Applied Geochemistry","active":true,"publicationSubtype":{"id":10}},"title":"Formation of mixed Al-Fe colloidal sorbent and dissolved-colloidal partitioning of Cu and Zn in the Cement Creek - Animas River Confluence, Silverton, Colorado","docAbstract":"Transport and chemical transformations of dissolved and colloidal Al, Fe, Cu and Zn were studied by detailed sampling in the mixing zone downstream from the confluence of Cement Creek (pH 4.1) with the Animas River (pH 7.6). Complete mixing resulted in circumneutral pH in the downstream reach of the 1300 m study area. All four metals were transported through this mixing zone without significant losses to the streambed, and they exhibited transformations from dissolved to colloidal forms to varying degrees during the mixing process. Nearly all of the Al formed colloidal hydrous Al oxides (HAO) as pH increased (4.8–6.5), whereas colloidal hydrous Fe oxides (HFO) were supplied by Cement Creek as well as formed in the mixing zone primarily at higher pH (>6.5). The short travel time through the mixing zone (approx. 40 min) and pH limited the formation of HFO from dissolved Fe2+ supplied by Cement Creek. Although the proportions of HAO and HFO varied as the streams mixed, the colloidal sorbent typically was enriched in HAO relative to HFO by a factor of 1.5–2.1 (by mole) in the pH range where dissolved-to-colloidal partitioning of Cu and Zn was observed. Model simulations of sorption by HFO (alone) greatly underestimated the dissolved-to-colloidal partitioning of Zn. Previous studies have shown that HAO–HFO mixtures can sorb greater amounts of Zn than HFO alone, but the high Zn-to-sorbent ratio in this mixing zone could also account for greater partitioning. In contrast to Zn, comparisons with model simulations did not show that Cu sorption was greater than that for HFO alone, and also indicated that sorption was possibly less than what would be expected for a non-interactive mixture of these two sorbents. These field results for Cu, however, might be influenced by (organic) complexation or other factors in this natural system. Laboratory mixing experiments using natural source waters (upstream of the confluence) showed that the presence of HFO in the mixed sorbent resulted in greater Cu partitioning than for HAO alone, and that the effect was greater with increasing (mole fraction) HFO. This was consistent with field results that showed greater Cu sorption when additional HFO was formed in the downstream reach of the mixing zone. Further research is needed to identify the significance of surface-related mechanisms specific to HAO–HFO mixtures that could affect the partitioning of Cu in natural systems.
Climate scientists have concluded that the earth’s surface air temperature warmed by 0.6 °C during the 20th century, and that warming induced by increasing concentrations of greenhouse gases is likely to continue in the 21st century, accompanied by changes in the hydrologic cycle. Climate change has important implications in the Catskill region of southeastern New York State, because the region is a source of water supply for New York City. We used the non-parametric Mann–Kendall test to evaluate annual, monthly, and multi-month trends in air temperature, precipitation amount, stream runoff, and potential evapotranspiration (PET) in the region during 1952–2005 based on data from 9 temperature sites, 12 precipitation sites, and 8 stream gages. A general pattern of warming temperatures and increased precipitation, runoff, and PET is evident in the region. Regional annual mean air temperature increased significantly by 0.6 °C per 50 years during the period; the greatest increases and largest number of significant upward trends were in daily minimum air temperature. Daily maximum air temperature showed the greatest increase during February through April, whereas minimum air temperature showed the greatest increase during May through September. Regional mean precipitation increased significantly by 136 mm per 50 years, nearly double that of the regional mean increase in runoff, which was not significant. Regional mean PET increased significantly by 19 mm per 50 years, about one-seventh that of the increase in precipitation amount, and broadly consistent with increased runoff during 1952–2005, despite the lack of significance in the mean regional runoff trend. Peak snowmelt as approximated by the winter–spring center of volume of stream runoff generally shifted from early April at the beginning of the record to late March at the end of the record, consistent with a decreasing trend in April runoff and an increasing trend in maximum March air temperature. This change indicates an increased supply of water to reservoirs earlier in the year. Additionally, the supply of water to reservoirs at the beginning of winter is greater as indicated by the timing of the greatest increases in precipitation and runoff—both occurred during summer and fall. The future balance between changes in air temperature and changes in the timing and amount of precipitation in the region will have important implications for the available water supply in the region.
","language":"English","publisher":"Elsevier","doi":"10.1016/j.jhydrol.2006.12.019","issn":"00221694","usgsCitation":"Burns, D.A., Klaus, J., and McHale, M.R., 2007, Recent climate trends and implications for water resources in the Catskill Mountain region, New York, USA: Journal of Hydrology, v. 336, no. 1-2, p. 155-170, https://doi.org/10.1016/j.jhydrol.2006.12.019.","productDescription":"16 p.","startPage":"155","endPage":"170","numberOfPages":"16","onlineOnly":"N","additionalOnlineFiles":"N","costCenters":[],"links":[{"id":240479,"rank":1,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"country":"United States","state":"New York","otherGeospatial":"Catskill region","geographicExtents":"{\n \"type\": \"FeatureCollection\",\n \"features\": [\n {\n \"type\": \"Feature\",\n \"properties\": {},\n \"geometry\": {\n \"type\": \"Polygon\",\n \"coordinates\": [\n [\n [\n -75.3607177734375,\n 42.004407212963585\n ],\n [\n -75.3277587890625,\n 41.96357478222518\n ],\n [\n -75.26184082031249,\n 41.93088998442502\n ],\n [\n -75.2508544921875,\n 41.87774145109676\n ],\n [\n -75.1959228515625,\n 41.85319643776675\n ],\n [\n -75.157470703125,\n 41.84501267270692\n ],\n [\n -75.1080322265625,\n 41.832735062152615\n ],\n [\n -75.1025390625,\n 41.78769700539063\n ],\n [\n -75.047607421875,\n 41.73852846935917\n ],\n [\n -75.05859375,\n 41.66060124302088\n ],\n [\n -75.05859375,\n 41.60722821271717\n ],\n [\n -75.03662109375,\n 41.549700145132725\n ],\n [\n -74.9871826171875,\n 41.492120839687786\n ],\n [\n -74.937744140625,\n 41.47154438707647\n ],\n [\n -74.8883056640625,\n 41.45507852101139\n ],\n [\n -74.8388671875,\n 41.430371882652814\n ],\n [\n -74.77294921875,\n 41.42625319507272\n ],\n [\n -74.7344970703125,\n 41.413895564677304\n ],\n [\n -74.7015380859375,\n 41.372686481864655\n ],\n [\n -74.68505859374999,\n 41.35207214451295\n ],\n [\n -74.50927734375,\n 41.281934557995356\n ],\n [\n -74.3719482421875,\n 41.33970040774419\n ],\n [\n -74.102783203125,\n 41.430371882652814\n ],\n [\n -73.85009765625,\n 41.51680395810118\n ],\n [\n -73.7841796875,\n 41.590796851056005\n ],\n [\n -73.7017822265625,\n 41.70982942509964\n ],\n [\n -73.6468505859375,\n 41.83682786072714\n ],\n [\n -73.6138916015625,\n 42.04521345501039\n ],\n [\n -73.6688232421875,\n 42.313877566161864\n ],\n [\n -73.707275390625,\n 42.45588764197166\n ],\n [\n -73.7841796875,\n 42.742978093466434\n ],\n [\n -73.8885498046875,\n 42.867912483915305\n ],\n [\n -74.1522216796875,\n 42.93631775765237\n ],\n [\n -74.498291015625,\n 42.93631775765237\n ],\n [\n -74.86083984375,\n 42.93631775765237\n ],\n [\n -75.1409912109375,\n 42.81555136172695\n ],\n [\n -75.25634765625,\n 42.68243539838623\n ],\n [\n -75.35522460937499,\n 42.459940352216556\n ],\n [\n -75.3607177734375,\n 42.004407212963585\n ]\n ]\n ]\n }\n }\n ]\n}","volume":"336","issue":"1-2","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"505a95f0e4b0c8380cd81d0b","contributors":{"authors":[{"text":"Burns, Douglas A. 0000-0001-6516-2869","orcid":"https://orcid.org/0000-0001-6516-2869","contributorId":29450,"corporation":false,"usgs":true,"family":"Burns","given":"Douglas","email":"","middleInitial":"A.","affiliations":[],"preferred":false,"id":423932,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Klaus, Julian","contributorId":173770,"corporation":false,"usgs":false,"family":"Klaus","given":"Julian","email":"","affiliations":[{"id":7107,"text":"Univ. of Freiburg, Germany","active":true,"usgs":false}],"preferred":false,"id":423934,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"McHale, Michael R. 0000-0003-3780-1816 mmchale@usgs.gov","orcid":"https://orcid.org/0000-0003-3780-1816","contributorId":1735,"corporation":false,"usgs":true,"family":"McHale","given":"Michael","email":"mmchale@usgs.gov","middleInitial":"R.","affiliations":[{"id":474,"text":"New York Water Science Center","active":true,"usgs":true}],"preferred":true,"id":423933,"contributorType":{"id":1,"text":"Authors"},"rank":3}]}} ,{"id":70029699,"text":"70029699 - 2007 - Nitrification in the euphotic zone as evidenced by nitrate dual isotopic composition: Observations from Monterey Bay, California","interactions":[],"lastModifiedDate":"2018-10-17T12:30:04","indexId":"70029699","displayToPublicDate":"2007-01-01T00:00:00","publicationYear":"2007","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":1836,"text":"Global Biogeochemical Cycles","active":true,"publicationSubtype":{"id":10}},"title":"Nitrification in the euphotic zone as evidenced by nitrate dual isotopic composition: Observations from Monterey Bay, California","docAbstract":"Coupled measurements of nitrate (NO3−), nitrogen (N), and oxygen (O) isotopic composition (δ15NNO3 and δ18ONO3) were made in surface waters of Monterey Bay to investigate multiple N cycling processes occurring within surface waters. Profiles collected throughout the year at three sites exhibit a wide range of values, suggesting simultaneous and variable influence of both phytoplankton NO3− assimilation and nitrification within the euphotic zone. Specifically, increases in δ18ONO3 were consistently greater than those in δ15NNO3. A coupled isotope steady state box model was used to estimate the amount of NO3− supplied by nitrification in surface waters relative to that supplied from deeper water. The model highlights the importance of the branching reaction during ammonium (NH4+) consumption, in which NH4+ either serves as a substrate for regenerated production or for nitrification. Our observations indicate that a previously unrecognized proportion of nitrate‐based productivity, on average 15 to 27%, is supported by nitrification in surface waters and should not be considered new production. This work also highlights the need for a better understanding of isotope effects of NH4+ oxidation, NH4+ assimilation, and NO3− assimilation in marine environments.
Regional ground-water recharge estimates for Minnesota were compared to estimates made on the basis of four local- and basin-scale methods. Three local-scale methods (unsaturated-zone water balance, water-table fluctuations (WTF) using three approaches, and age dating of ground water) yielded point estimates of recharge that represent spatial scales from about 1 to about 1000 m2. A fourth method (RORA, a basin-scale analysis of streamflow records using a recession-curve-displacement technique) yielded recharge estimates at a scale of 10–1000s of km2. The RORA basin-scale recharge estimates were regionalized to estimate recharge for the entire State of Minnesota on the basis of a regional regression recharge (RRR) model that also incorporated soil and climate data. Recharge rates estimated by the RRR model compared favorably to the local and basin-scale recharge estimates. RRR estimates at study locations were about 41% less on average than the unsaturated-zone water-balance estimates, ranged from 44% greater to 12% less than estimates that were based on the three WTF approaches, were about 4% less than the age dating of ground-water estimates, and were about 5% greater than the RORA estimates. Of the methods used in this study, the WTF method is the simplest and easiest to apply. Recharge estimates made on the basis of the UZWB method were inconsistent with the results from the other methods. Recharge estimates using the RRR model could be a good source of input for regional ground-water flow models; RRR model results currently are being applied for this purpose in USGS studies elsewhere.
","language":"English","publisher":"Elsevier","doi":"10.1016/j.jhydrol.2006.10.010","issn":"00221694","usgsCitation":"Delin, G., Healy, R.W., Lorenz, D., and Nimmo, J., 2007, Comparison of local- to regional-scale estimates of ground-water recharge in Minnesota, USA: Journal of Hydrology, v. 334, no. 1-2, p. 231-249, https://doi.org/10.1016/j.jhydrol.2006.10.010.","productDescription":"19 p.","startPage":"231","endPage":"249","numberOfPages":"19","onlineOnly":"N","additionalOnlineFiles":"N","costCenters":[{"id":392,"text":"Minnesota Water Science Center","active":true,"usgs":true}],"links":[{"id":239641,"rank":1,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"country":"United 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R.","affiliations":[],"preferred":false,"id":432923,"contributorType":{"id":1,"text":"Authors"},"rank":4}]}} ,{"id":70031701,"text":"70031701 - 2007 - Near infrared spectroscopic examination of charred pine wood, bark, cellulose and lignin: Implications for the quantitative determination of charcoal in soils","interactions":[],"lastModifiedDate":"2018-10-17T08:11:56","indexId":"70031701","displayToPublicDate":"2007-01-01T00:00:00","publicationYear":"2007","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":2398,"text":"Journal of Near Infrared Spectroscopy","active":true,"publicationSubtype":{"id":10}},"title":"Near infrared spectroscopic examination of charred pine wood, bark, cellulose and lignin: Implications for the quantitative determination of charcoal in soils","docAbstract":"The objective of this research was to investigate the effect of charring on near infrared spectra of materials likely to be present in forest fires in order to determine the feasibility of determining charred carbon in soils. Four materials (cellulose, lignin, pine bark and pine wood) and char from these materials created by charring for various durations (1 to 168 h) and at various temperatures (200 to 450??C) were studied. Near infrared spectra and measures of acidity (total acids, carboxylic acids, lactones and phenols as determined by titration) were available for 56 different samples (Not all samples charred at all temperatures/durations). Results showed spectral changes that varied with the material, temperature and duration of charring. Examination of spectra and correlation plots indicated that changes in the constituents of the materials in question, such as loss of OH groups in carbohydrates, rather than direct determination of typical products produced by charring, such as carboxylic acids, lactones and phenols, were the basis for the spectral changes. Finally, while the spectral changes resulting from charring appeared to be relatively unique to each material, PLS calibrations for total acids, carboxylic acids, lactones and phenols were successfully created (with R2 of 0.991, 0.943, 0.931 and 0.944, respectively) indicating that there is a sufficient commonality in the changes to develop calibrations without the need for unique calibrations for each specific set of charring conditions (i.e. material, temperature and time of heating).
","largerWorkType":{"id":2,"text":"Article"},"largerWorkTitle":"Journal of Near Infrared Spectroscopy","largerWorkSubtype":{"id":10,"text":"Journal Article"},"language":"English","doi":"10.1255/jnirs.742","issn":"09670335","usgsCitation":"Reeves, J.B., McCarty, G.W., Rutherford, D.W., and Wershaw, R.L., 2007, Near infrared spectroscopic examination of charred pine wood, bark, cellulose and lignin: Implications for the quantitative determination of charcoal in soils: Journal of Near Infrared Spectroscopy, v. 15, no. 5, p. 307-315, https://doi.org/10.1255/jnirs.742.","productDescription":"9 p.","startPage":"307","endPage":"315","costCenters":[{"id":589,"text":"Toxic Substances Hydrology Program","active":true,"usgs":true}],"links":[{"id":240081,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"},{"id":212578,"rank":9999,"type":{"id":10,"text":"Digital Object Identifier"},"url":"https://dx.doi.org/10.1255/jnirs.742"}],"volume":"15","issue":"5","noUsgsAuthors":false,"publicationDate":"2007-10-01","publicationStatus":"PW","scienceBaseUri":"505a63d2e4b0c8380cd726fe","contributors":{"authors":[{"text":"Reeves, James B. III","contributorId":40693,"corporation":false,"usgs":true,"family":"Reeves","given":"James","suffix":"III","email":"","middleInitial":"B.","affiliations":[],"preferred":false,"id":432750,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"McCarty, Gregory W.","contributorId":192367,"corporation":false,"usgs":false,"family":"McCarty","given":"Gregory","email":"","middleInitial":"W.","affiliations":[],"preferred":false,"id":432748,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Rutherford, David W. dwruther@usgs.gov","contributorId":1325,"corporation":false,"usgs":true,"family":"Rutherford","given":"David","email":"dwruther@usgs.gov","middleInitial":"W.","affiliations":[],"preferred":true,"id":432747,"contributorType":{"id":1,"text":"Authors"},"rank":3},{"text":"Wershaw, Robert L. rwershaw@usgs.gov","contributorId":4856,"corporation":false,"usgs":true,"family":"Wershaw","given":"Robert","email":"rwershaw@usgs.gov","middleInitial":"L.","affiliations":[],"preferred":true,"id":432749,"contributorType":{"id":1,"text":"Authors"},"rank":4}]}} ,{"id":70031016,"text":"70031016 - 2007 - Identifying sources of nitrogen to Hanalei Bay, Kauai, utilizing the nitrogen isotope signature of macroalgae","interactions":[],"lastModifiedDate":"2023-07-31T12:20:02.840178","indexId":"70031016","displayToPublicDate":"2007-01-01T00:00:00","publicationYear":"2007","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":1565,"text":"Environmental Science & Technology","onlineIssn":"1520-5851","printIssn":"0013-936X","active":true,"publicationSubtype":{"id":10}},"title":"Identifying sources of nitrogen to Hanalei Bay, Kauai, utilizing the nitrogen isotope signature of macroalgae","docAbstract":"Sewage effluent, storm runoff, discharge from polluted rivers, and inputs of groundwater have all been suggested as potential sources of land derived nutrients into Hanalei Bay, Kauai. We determined the nitrogen isotopic signatures (δ15N) of different nitrate sources to Hanalei Bay along with the isotopic signature recorded by 11 species of macroalgal collected in the Bay. The macroalgae integrate the isotopic signatures of the nitrate sources over time, thus these data along with the nitrate to dissolved inorganic phosphate molar ratios (N:P) of the macroalgae were used to determine the major nitrate source to the bay ecosystem and which of the macro-nutrients is limiting algae growth, respectively. Relatively low δ15N values (average −0.5‰) were observed in all algae collected throughout the Bay; implicating fertilizer, rather than domestic sewage, as an important external source of nitrogen to the coastal water around Hanalei. The N:P ratio in the algae compared to the ratio in the Bay waters imply that the Hanalei Bay coastal ecosystem is nitrogen limited and thus, increased nitrogen input may potentially impact this coastal ecosystem and specifically the coral reefs in the Bay. Identifying the major source of nutrient loading to the Bay is important for risk assessment and potential remediation plans.
The mid-1970s marked a major turning point in human history, for it was at that moment that the ability of the Earth’s ecosystems to absorb most of the biological impacts of human activities appears to have been exceeded by the magnitude of those impacts. This conclusion is based partly upon estimates of the rate of carbon dioxide emission during the combustion of fossil fuels, relative to the rate of its uptake by terrestrial ecosystems (Loh, 2002). A very different threshold, however, had already been crossed several decades earlier with the birth of the modern chemical industry, which produced novel substances for which no such natural assimilative capacity existed. Among these new chemical compounds, none has posed a greater challenge to the planet’s ecosystems than synthetic pesticides, compounds that have been intentionally released into the hydrologic system in vast quantities—several hundred million pounds of active ingredient (a.i.) per year in the United States alone (Donaldson et al., 2002)—for many decades. To gauge the extent to which we are currently able to assess the environmental implications of this new development in the Earth’s history, this chapter presents an overview of current understanding regarding the sources, transport, fate, and biological effects of pesticides, their transformation products, and selected adjuvants in the hydrologic system. (Adjuvants are the so-called inert ingredients included in commercial pesticide formulations to enhance the effectiveness of the active ingredients.)
","largerWorkType":{"id":4,"text":"Book"},"largerWorkTitle":"Treatise on geochemistry","largerWorkSubtype":{"id":15,"text":"Monograph"},"language":"English","publisher":"Elsevier","doi":"10.1016/B0-08-043751-6/09056-3","usgsCitation":"Barbash, J.E., 2007, The geochemistry of pesticides, chap. 9.15 of Treatise on geochemistry, v. 9, 43 p., https://doi.org/10.1016/B0-08-043751-6/09056-3.","productDescription":"43 p.","onlineOnly":"N","additionalOnlineFiles":"N","costCenters":[{"id":622,"text":"Washington Water Science Center","active":true,"usgs":true}],"links":[{"id":321867,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"volume":"9","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"574eb5dde4b0ee97d51a840a","contributors":{"authors":[{"text":"Barbash, Jack E. 0000-0001-9854-8880 jbarbash@usgs.gov","orcid":"https://orcid.org/0000-0001-9854-8880","contributorId":1003,"corporation":false,"usgs":true,"family":"Barbash","given":"Jack","email":"jbarbash@usgs.gov","middleInitial":"E.","affiliations":[{"id":622,"text":"Washington Water Science Center","active":true,"usgs":true}],"preferred":true,"id":630837,"contributorType":{"id":1,"text":"Authors"},"rank":1}]}} ,{"id":70031572,"text":"70031572 - 2007 - Linking ground-water age and chemistry data along flow paths: Implications for trends and transformations of nitrate and pesticides","interactions":[],"lastModifiedDate":"2018-09-26T15:48:13","indexId":"70031572","displayToPublicDate":"2007-01-01T00:00:00","publicationYear":"2007","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":2233,"text":"Journal of Contaminant Hydrology","active":true,"publicationSubtype":{"id":10}},"title":"Linking ground-water age and chemistry data along flow paths: Implications for trends and transformations of nitrate and pesticides","docAbstract":"Tracer-based ground-water ages, along with the concentrations of pesticides, nitrogen species, and other redox-active constituents, were used to evaluate the trends and transformations of agricultural chemicals along flow paths in diverse hydrogeologic settings. A range of conditions affecting the transformation of nitrate and pesticides (e.g., thickness of unsaturated zone, redox conditions) was examined at study sites in Georgia, North Carolina, Wisconsin, and California. Deethylatrazine (DEA), a transformation product of atrazine, was typically present at concentrations higher than those of atrazine at study sites with thick unsaturated zones but not at sites with thin unsaturated zones. Furthermore, the fraction of atrazine plus DEA that was present as DEA did not increase as a function of ground-water age. These findings suggest that atrazine degradation occurs primarily in the unsaturated zone with little or no degradation in the saturated zone. Similar observations were also made for metolachlor and alachlor. The fraction of the initial nitrate concentration found as excess N2 (N2 derived from denitrification) increased with ground-water age only at the North Carolina site, where oxic conditions were generally limited to the top 5??m of saturated thickness. Historical trends in fluxes to ground water were evaluated by relating the times of recharge of ground-water samples, estimated using chlorofluorocarbon concentrations, with concentrations of the parent compound at the time of recharge, estimated by summing the molar concentrations of the parent compound and its transformation products in the age-dated sample. Using this approach, nitrate concentrations were estimated to have increased markedly from 1960 to the present at all study sites. Trends in concentrations of atrazine, metolachlor, alachlor, and their degradates were related to the timing of introduction and use of these compounds. Degradates, and to a lesser extent parent compounds, were detected in ground water dating back to the time these compounds were introduced.
","language":"English","publisher":"Elsevier","doi":"10.1016/j.jconhyd.2007.05.007","issn":"01697722","usgsCitation":"Tesoriero, A., Saad, D.A., Burow, K., Frick, E.A., Puckett, L., and Barbash, J., 2007, Linking ground-water age and chemistry data along flow paths: Implications for trends and transformations of nitrate and pesticides: Journal of Contaminant Hydrology, v. 94, no. 1-2, p. 139-155, https://doi.org/10.1016/j.jconhyd.2007.05.007.","productDescription":"17 p.","startPage":"139","endPage":"155","onlineOnly":"N","additionalOnlineFiles":"N","costCenters":[{"id":154,"text":"California Water Science Center","active":true,"usgs":true},{"id":622,"text":"Washington Water Science Center","active":true,"usgs":true}],"links":[{"id":239700,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"},{"id":212242,"rank":9999,"type":{"id":10,"text":"Digital Object Identifier"},"url":"https://dx.doi.org/10.1016/j.jconhyd.2007.05.007"}],"volume":"94","issue":"1-2","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"505a47d3e4b0c8380cd679e0","contributors":{"authors":[{"text":"Tesoriero, A. J.","contributorId":99127,"corporation":false,"usgs":true,"family":"Tesoriero","given":"A. J.","affiliations":[],"preferred":false,"id":432179,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Saad, D. A.","contributorId":85212,"corporation":false,"usgs":true,"family":"Saad","given":"D.","email":"","middleInitial":"A.","affiliations":[],"preferred":false,"id":432178,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Burow, K.R. 0000-0001-6006-6667","orcid":"https://orcid.org/0000-0001-6006-6667","contributorId":48283,"corporation":false,"usgs":true,"family":"Burow","given":"K.R.","affiliations":[],"preferred":false,"id":432175,"contributorType":{"id":1,"text":"Authors"},"rank":3},{"text":"Frick, E. A.","contributorId":61840,"corporation":false,"usgs":true,"family":"Frick","given":"E.","email":"","middleInitial":"A.","affiliations":[],"preferred":false,"id":432176,"contributorType":{"id":1,"text":"Authors"},"rank":4},{"text":"Puckett, L.J.","contributorId":27503,"corporation":false,"usgs":true,"family":"Puckett","given":"L.J.","email":"","affiliations":[],"preferred":false,"id":432174,"contributorType":{"id":1,"text":"Authors"},"rank":5},{"text":"Barbash, J.E.","contributorId":62783,"corporation":false,"usgs":true,"family":"Barbash","given":"J.E.","email":"","affiliations":[],"preferred":false,"id":432177,"contributorType":{"id":1,"text":"Authors"},"rank":6}]}} ,{"id":70031018,"text":"70031018 - 2007 - Estimating the bankfull velocity and discharge for rivers using remotely sensed river morphology information","interactions":[],"lastModifiedDate":"2012-03-12T17:21:05","indexId":"70031018","displayToPublicDate":"2007-01-01T00:00:00","publicationYear":"2007","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":2342,"text":"Journal of Hydrology","active":true,"publicationSubtype":{"id":10}},"title":"Estimating the bankfull velocity and discharge for rivers using remotely sensed river morphology information","docAbstract":"A method to estimate the bankfull velocity and discharge in rivers that uses the morphological variables of the river channel, including bankfull width, channel slope, and meander length was developed and tested. Because these variables can be measured remotely from topographic and river alignment information derived from aerial photos and satellite imagery, it is possible that the bankfull state of flow can be estimated for rivers entirely from remotely-sensed information. Defining the bankfull hydraulics of rivers would also provide a reference condition for remote tracking of dynamic variables including width, stage, and slope, and for quantifying relative change in flow conditions of rivers over large regions. This could provide a more efficient method to inventory and quantify river hydraulic attributes and dynamics.","largerWorkType":{"id":2,"text":"Article"},"largerWorkTitle":"Journal of Hydrology","largerWorkSubtype":{"id":10,"text":"Journal Article"},"language":"English","doi":"10.1016/j.jhydrol.2007.04.011","issn":"00221694","usgsCitation":"Bjerklie, D., 2007, Estimating the bankfull velocity and discharge for rivers using remotely sensed river morphology information: Journal of Hydrology, v. 341, no. 3-4, p. 144-155, https://doi.org/10.1016/j.jhydrol.2007.04.011.","startPage":"144","endPage":"155","numberOfPages":"12","costCenters":[],"links":[{"id":211644,"rank":9999,"type":{"id":10,"text":"Digital Object Identifier"},"url":"https://dx.doi.org/10.1016/j.jhydrol.2007.04.011"},{"id":238971,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"volume":"341","issue":"3-4","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"505a0b57e4b0c8380cd526a3","contributors":{"authors":[{"text":"Bjerklie, D.M.","contributorId":68923,"corporation":false,"usgs":true,"family":"Bjerklie","given":"D.M.","affiliations":[],"preferred":false,"id":429656,"contributorType":{"id":1,"text":"Authors"},"rank":1}]}} ,{"id":70031568,"text":"70031568 - 2007 - Intersex (Testicular Oocytes) in smallmouth bass from the Potomac River and selected nearby drainages","interactions":[],"lastModifiedDate":"2018-10-17T13:41:04","indexId":"70031568","displayToPublicDate":"2007-01-01T00:00:00","publicationYear":"2007","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":2177,"text":"Journal of Aquatic Animal Health","active":true,"publicationSubtype":{"id":10}},"title":"Intersex (Testicular Oocytes) in smallmouth bass from the Potomac River and selected nearby drainages","docAbstract":"Intersex, or the presence of characteristics of both sexes, in fishes that are normally gonochoristic has been used as an indicator of exposure to estrogenic compounds. In 2003, during health assessments conducted in response to kills and a high prevalence of skin lesions observed in smallmouth bass Micropterus dolomieu in the South Branch of the Potomac River, the presence of immature oocytes within testes was noted. To evaluate this condition, a severity index (0-4) was developed based on the distribution of oocytes within the testes. Using gonad samples collected from 2003 to 2005, the number of histologic sections needed to accurately detect the condition in mature smallmouth bass was statistically evaluated. The reliability of detection depended on the severity index and the number of sections examined. Examining five transverse sections taken along the length of the gonad resulted in a greater than 90% probability of detecting testicular oocytes when the severity index exceeded 0.5. Using the severity index we compared smallmouth bass collected at selected sites within the South Branch during three seasons in 2004. Seasonal differences in severity and prevalence were observed. The highest prevalence and severity were consistently noted during the prespawn-spawning season, when compared with the postspawn season. In 2005, smallmouth bass were collected at selected out-of-basin sites in West Virginia where fish kills and external skin lesions have not been reported, as well as at sites in the Shenandoah River, Virginia (part of the Potomac drainage), where kills and lesions occurred in 2004-2005. The prevalence of testicular oocytes is discussed in terms of human population and agricultural intensity.
","language":"English","publisher":"Taylor and Francis","doi":"10.1577/H07-031.1","issn":"08997659","usgsCitation":"Blazer, V., Iwanowicz, L., Iwanowicz, D.D., Smith, D.R., Young, J.A., Hedrick, J., Foster, S., and Reeser, S., 2007, Intersex (Testicular Oocytes) in smallmouth bass from the Potomac River and selected nearby drainages: Journal of Aquatic Animal Health, v. 19, no. 4, p. 242-253, https://doi.org/10.1577/H07-031.1.","productDescription":"12 p.","startPage":"242","endPage":"253","numberOfPages":"12","costCenters":[{"id":589,"text":"Toxic Substances Hydrology Program","active":true,"usgs":true}],"links":[{"id":239631,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"country":"United States","otherGeospatial":"Potomac River","geographicExtents":"{\n \"type\": \"FeatureCollection\",\n \"features\": [\n {\n \"type\": \"Feature\",\n \"properties\": {},\n \"geometry\": {\n \"type\": \"Polygon\",\n \"coordinates\": [\n [\n [\n -79.6893310546875,\n 38.052416771864834\n ],\n [\n -79.6893310546875,\n 39.8928799002948\n ],\n [\n -77.080078125,\n 39.8928799002948\n ],\n [\n -77.080078125,\n 38.052416771864834\n ],\n [\n -79.6893310546875,\n 38.052416771864834\n ]\n ]\n ]\n }\n }\n ]\n}","volume":"19","issue":"4","noUsgsAuthors":false,"publicationDate":"2007-12-01","publicationStatus":"PW","scienceBaseUri":"505a3da7e4b0c8380cd63722","contributors":{"authors":[{"text":"Blazer, Vicki S. 0000-0001-6647-9614 vblazer@usgs.gov","orcid":"https://orcid.org/0000-0001-6647-9614","contributorId":149414,"corporation":false,"usgs":true,"family":"Blazer","given":"Vicki S.","email":"vblazer@usgs.gov","affiliations":[{"id":365,"text":"Leetown Science Center","active":true,"usgs":true}],"preferred":false,"id":432162,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Iwanowicz, Luke R. 0000-0002-1197-6178 liwanowicz@usgs.gov","orcid":"https://orcid.org/0000-0002-1197-6178","contributorId":150383,"corporation":false,"usgs":true,"family":"Iwanowicz","given":"Luke R. ","email":"liwanowicz@usgs.gov","affiliations":[{"id":365,"text":"Leetown Science Center","active":true,"usgs":true}],"preferred":false,"id":432160,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Iwanowicz, Deborah D. 0000-0002-9613-8594 diwanowicz@usgs.gov","orcid":"https://orcid.org/0000-0002-9613-8594","contributorId":2253,"corporation":false,"usgs":true,"family":"Iwanowicz","given":"Deborah","email":"diwanowicz@usgs.gov","middleInitial":"D.","affiliations":[{"id":365,"text":"Leetown Science Center","active":true,"usgs":true}],"preferred":true,"id":432163,"contributorType":{"id":1,"text":"Authors"},"rank":3},{"text":"Smith, David R. 0000-0001-6074-9257 drsmith@usgs.gov","orcid":"https://orcid.org/0000-0001-6074-9257","contributorId":168442,"corporation":false,"usgs":true,"family":"Smith","given":"David","email":"drsmith@usgs.gov","middleInitial":"R.","affiliations":[{"id":365,"text":"Leetown Science Center","active":true,"usgs":true}],"preferred":true,"id":432161,"contributorType":{"id":1,"text":"Authors"},"rank":4},{"text":"Young, John A. 0000-0002-4500-3673 jyoung@usgs.gov","orcid":"https://orcid.org/0000-0002-4500-3673","contributorId":3777,"corporation":false,"usgs":true,"family":"Young","given":"John","email":"jyoung@usgs.gov","middleInitial":"A.","affiliations":[{"id":365,"text":"Leetown Science Center","active":true,"usgs":true}],"preferred":true,"id":432159,"contributorType":{"id":1,"text":"Authors"},"rank":5},{"text":"Hedrick, J.D.","contributorId":105511,"corporation":false,"usgs":true,"family":"Hedrick","given":"J.D.","email":"","affiliations":[],"preferred":false,"id":432164,"contributorType":{"id":1,"text":"Authors"},"rank":6},{"text":"Foster, S.W.","contributorId":36753,"corporation":false,"usgs":true,"family":"Foster","given":"S.W.","email":"","affiliations":[],"preferred":false,"id":432158,"contributorType":{"id":1,"text":"Authors"},"rank":7},{"text":"Reeser, S.J.","contributorId":9460,"corporation":false,"usgs":true,"family":"Reeser","given":"S.J.","email":"","affiliations":[],"preferred":false,"id":432157,"contributorType":{"id":1,"text":"Authors"},"rank":8}]}} ,{"id":70031528,"text":"70031528 - 2007 - Use of a watershed model to characterize the fate and transport of fluometuron, a soil-applied cotton herbicide, in surface water","interactions":[],"lastModifiedDate":"2012-03-12T17:21:14","indexId":"70031528","displayToPublicDate":"2007-01-01T00:00:00","publicationYear":"2007","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":2040,"text":"International Journal of Environmental Analytical Chemistry","active":true,"publicationSubtype":{"id":10}},"title":"Use of a watershed model to characterize the fate and transport of fluometuron, a soil-applied cotton herbicide, in surface water","docAbstract":"The Soil and Water Assessment Tool (SWAT) was used to characterize the fate and transport of fluometuron (a herbicide used on cotton) in the Bogue Phalia Basin in northwestern Mississippi, USA. SWAT is a basin-scale watershed model, able to simulate hydrological, chemical, and sediment transport processes. After adjustments to a few parameters (specifically the SURLAG variable, the runoff curve number, Manning's N for overland flow, soil available water capacity, and the base-flow alpha factor) the SWAT model fit the observed streamflow well (the Coefficient of Efficiency and R2 were greater than 60). The results from comparing observed fluometuron concentrations with simulated concentrations were reasonable. The simulated concentrations (which were daily averages) followed the pattern of observed concentrations (instantaneous values) closely, but could be off in magnitude at times. Further calibration might have improved the fit, but given the uncertainties in the input data, it was not clear that any improvement would be due to a better understanding of the input variables. ?? 2007 Taylor & Francis.","largerWorkType":{"id":2,"text":"Article"},"largerWorkTitle":"International Journal of Environmental Analytical Chemistry","largerWorkSubtype":{"id":10,"text":"Journal Article"},"language":"English","doi":"10.1080/03067310701627819","issn":"03067319","usgsCitation":"Coupe, R., 2007, Use of a watershed model to characterize the fate and transport of fluometuron, a soil-applied cotton herbicide, in surface water: International Journal of Environmental Analytical Chemistry, v. 87, no. 13-14, p. 883-896, https://doi.org/10.1080/03067310701627819.","startPage":"883","endPage":"896","numberOfPages":"14","costCenters":[],"links":[{"id":212538,"rank":9999,"type":{"id":10,"text":"Digital Object Identifier"},"url":"https://dx.doi.org/10.1080/03067310701627819"},{"id":240035,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"volume":"87","issue":"13-14","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"505bbea1e4b08c986b3296cc","contributors":{"authors":[{"text":"Coupe, R.H.","contributorId":84778,"corporation":false,"usgs":true,"family":"Coupe","given":"R.H.","affiliations":[],"preferred":false,"id":431965,"contributorType":{"id":1,"text":"Authors"},"rank":1}]}} ,{"id":70031526,"text":"70031526 - 2007 - A simple pore water hydrogen diffusion syringe sampler","interactions":[],"lastModifiedDate":"2018-10-16T09:32:52","indexId":"70031526","displayToPublicDate":"2007-01-01T00:00:00","publicationYear":"2007","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":1861,"text":"Ground Water","active":true,"publicationSubtype":{"id":10}},"title":"A simple pore water hydrogen diffusion syringe sampler","docAbstract":"Molecular hydrogen (H2) is an important intermediate product and electron donor in microbial metabolism. Concentrations of dissolved H 2 are often diagnostic of the predominant terminal electron-accepting processes in ground water systems or aquatic sediments. H2 concentrations are routinely measured in ground water monitoring wells but are rarely measured in saturated aquatic sediments due to a lack of simple and practical sampling methods. This report describes the design and development (including laboratory and field testing) of a simple, syringe-based H 2 sampler in (1) saturated, riparian sediments, (2) surface water bed sediments, and (3) packed intervals of a fractured bedrock borehole that are inaccessible by standard pumped methods.
","largerWorkType":{"id":2,"text":"Article"},"largerWorkTitle":"Ground Water","largerWorkSubtype":{"id":10,"text":"Journal Article"},"language":"English","doi":"10.1111/j.1745-6584.2007.00362.x","issn":"0017467X","usgsCitation":"Vroblesky, D., Chapelle, F.H., and Bradley, P.M., 2007, A simple pore water hydrogen diffusion syringe sampler: Ground Water, v. 45, no. 6, p. 798-802, https://doi.org/10.1111/j.1745-6584.2007.00362.x.","productDescription":"5 p.","startPage":"798","endPage":"802","costCenters":[{"id":589,"text":"Toxic Substances Hydrology Program","active":true,"usgs":true}],"links":[{"id":240033,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"},{"id":212536,"rank":9999,"type":{"id":10,"text":"Digital Object Identifier"},"url":"https://dx.doi.org/10.1111/j.1745-6584.2007.00362.x"}],"volume":"45","issue":"6","noUsgsAuthors":false,"publicationDate":"2007-08-09","publicationStatus":"PW","scienceBaseUri":"5059e591e4b0c8380cd46e2b","contributors":{"authors":[{"text":"Vroblesky, Don vroblesk@usgs.gov","contributorId":207411,"corporation":false,"usgs":true,"family":"Vroblesky","given":"Don","email":"vroblesk@usgs.gov","affiliations":[{"id":13634,"text":"South Atlantic Water Science Center","active":true,"usgs":true}],"preferred":true,"id":431958,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Chapelle, Francis H. chapelle@usgs.gov","contributorId":1350,"corporation":false,"usgs":true,"family":"Chapelle","given":"Francis","email":"chapelle@usgs.gov","middleInitial":"H.","affiliations":[{"id":559,"text":"South Carolina Water Science Center","active":true,"usgs":true},{"id":13634,"text":"South Atlantic Water Science Center","active":true,"usgs":true}],"preferred":true,"id":431959,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Bradley, Paul M. 0000-0001-7522-8606 pbradley@usgs.gov","orcid":"https://orcid.org/0000-0001-7522-8606","contributorId":361,"corporation":false,"usgs":true,"family":"Bradley","given":"Paul","email":"pbradley@usgs.gov","middleInitial":"M.","affiliations":[{"id":13634,"text":"South Atlantic Water Science Center","active":true,"usgs":true}],"preferred":true,"id":431957,"contributorType":{"id":1,"text":"Authors"},"rank":3}]}} ,{"id":70031443,"text":"70031443 - 2007 - Composition of pore water in lake sediments, research site \"B\", Osage County, Oklahoma: Implications for lake water quality and benthic organisms","interactions":[],"lastModifiedDate":"2020-09-17T20:39:56.522711","indexId":"70031443","displayToPublicDate":"2007-01-01T00:00:00","publicationYear":"2007","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":835,"text":"Applied Geochemistry","active":true,"publicationSubtype":{"id":10}},"title":"Composition of pore water in lake sediments, research site \"B\", Osage County, Oklahoma: Implications for lake water quality and benthic organisms","docAbstract":"Shallow ground water at US Geological Survey research site B in northeastern Oklahoma is contaminated with NaCl-rich brine from past and present oil production operations. Contaminated ground water provides a potential source of salts, metals, and hydrocarbons to sediment and water of adjacent Skiatook Lake. A former brine storage pit 10 m in diameter that is now submerged just offshore from site B provides an additional source of contamination. Cores of the upper 16–40 cm of lake sediment were taken at the submerged brine pit, near an offshore saline seep, and at a location containing relatively uncontaminated lake sediment. Pore waters from each 2-cm interval were separated by centrifugation and analyzed for dissolved anions, cations, and trace elements. High concentrations of dissolved Cl− in pore waters (200–5000 mg/L) provide the most direct evidence of contamination, and contrast sharply with an average value of only about 37 mg/L in Skiatook Lake. Chloride/Br− mass ratios of 220–240 in contaminated pore waters are comparable to values in contaminated well waters collected onshore. Dissolved concentrations of Se, Pb, Cu and Ni in Cl−-rich pore waters exceed current US Environmental Protection Agency criteria for probable toxicity to aquatic life. At the submerged brine storage pit, the increase of Cl− concentration with depth is consistent with diffusion-dominant transport from deeper contaminated sediments. Near the offshore saline seep, pore water Cl− concentrations are consistently high and vary irregularly with depth, indicating probable Cl− transport by layer-directed advective flow. Estimated annual contributions of Cl− to the lake from the brine storage pit (∼20 kg) and the offshore seep (∼9 kg) can be applied to any number of similar sources. Generous estimates of the number of such sources at site B indicate minimal impact on water quality in the local inlet of Skiatook Lake. Similar methodologies can be applied at other sites of NaCl contamination surrounding Skiatook Lake and elsewhere.
","language":"English","publisher":"Elsevier","doi":"10.1016/j.apgeochem.2007.04.013","usgsCitation":"Zielinski, R.A., Herkelrath, W.N., and Otton, J.K., 2007, Composition of pore water in lake sediments, research site \"B\", Osage County, Oklahoma: Implications for lake water quality and benthic organisms: Applied Geochemistry, v. 22, no. 10, p. 2177-2192, https://doi.org/10.1016/j.apgeochem.2007.04.013.","productDescription":"16 p.","startPage":"2177","endPage":"2192","numberOfPages":"16","costCenters":[{"id":589,"text":"Toxic Substances Hydrology Program","active":true,"usgs":true}],"links":[{"id":239822,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"country":"United States","state":"Oklahoma","county":"Osage","otherGeospatial":"Skiatook Lake","geographicExtents":"{\n \"type\": \"FeatureCollection\",\n \"features\": [\n {\n \"type\": \"Feature\",\n \"properties\": {},\n \"geometry\": {\n \"type\": \"Polygon\",\n \"coordinates\": [\n [\n [\n -96.29825592041016,\n 36.28967012684225\n ],\n [\n -96.06994628906249,\n 36.28967012684225\n ],\n [\n -96.06994628906249,\n 36.446694448546836\n ],\n [\n -96.29825592041016,\n 36.446694448546836\n ],\n [\n -96.29825592041016,\n 36.28967012684225\n ]\n ]\n ]\n }\n }\n ]\n}","volume":"22","issue":"10","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"5059f92ae4b0c8380cd4d490","contributors":{"authors":[{"text":"Zielinski, Robert A. 0000-0002-4047-5129 rzielinski@usgs.gov","orcid":"https://orcid.org/0000-0002-4047-5129","contributorId":1593,"corporation":false,"usgs":true,"family":"Zielinski","given":"Robert","email":"rzielinski@usgs.gov","middleInitial":"A.","affiliations":[{"id":164,"text":"Central Energy Resources Science Center","active":true,"usgs":true}],"preferred":true,"id":431517,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Herkelrath, William N. 0000-0002-6149-5524 wnherkel@usgs.gov","orcid":"https://orcid.org/0000-0002-6149-5524","contributorId":2612,"corporation":false,"usgs":true,"family":"Herkelrath","given":"William","email":"wnherkel@usgs.gov","middleInitial":"N.","affiliations":[{"id":438,"text":"National Research Program - Western Branch","active":true,"usgs":true}],"preferred":true,"id":431516,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Otton, James K. jkotton@usgs.gov","contributorId":1170,"corporation":false,"usgs":true,"family":"Otton","given":"James","email":"jkotton@usgs.gov","middleInitial":"K.","affiliations":[{"id":164,"text":"Central Energy Resources Science Center","active":true,"usgs":true}],"preferred":true,"id":431515,"contributorType":{"id":1,"text":"Authors"},"rank":3}]}} ,{"id":70031439,"text":"70031439 - 2007 - Geochemical and geophysical examination of submarine groundwater discharge and associated nutrient loading estimates into Lynch Cove, Hood Canal, WA","interactions":[],"lastModifiedDate":"2017-03-03T13:53:19","indexId":"70031439","displayToPublicDate":"2007-01-01T00:00:00","publicationYear":"2007","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":1565,"text":"Environmental Science & Technology","onlineIssn":"1520-5851","printIssn":"0013-936X","active":true,"publicationSubtype":{"id":10}},"title":"Geochemical and geophysical examination of submarine groundwater discharge and associated nutrient loading estimates into Lynch Cove, Hood Canal, WA","docAbstract":"Geochemical tracer data (i.e., 222Rn and four naturally occurring Ra isotopes), electromagnetic (EM) seepage meter results, and high-resolution, stationary electrical resistivity images were used to examine the bi-directional (i.e., submarine groundwater discharge and recharge) exchange of a coastal aquifer with seawater. Our study site for these experiments was Lynch Cove, the terminus of Hood Canal, WA, where fjord-like conditions dramatically limit water column circulation that can lead to recurring summer-time hypoxic events. In such a system a precise nutrient budget may be particularly sensitive to groundwater-derived nutrient loading. Shore-perpendicular time-series subsurface resistivity profiles show clear, decimeter-scale tidal modulation of the coastal aquifer in response to large, regional hydraulic gradients, hydrologically transmissive glacial terrain, and large (4-5 m) tidal amplitudes. A 5-day 222Rn time-series shows a strong inverse covariance between 222Rn activities (0.5−29 dpm L-1) and water level fluctuations, and provides compelling evidence for tidally modulated exchange of groundwater across the sediment/water interface. Mean Rn-derived submarine groundwater discharge (SGD) rates of 85 ± 84 cm d-1 agree closely in the timing and magnitude with EM seepage meter results that showed discharge during low tide and recharge during high tide events. To evaluate the importance of fresh versus saline SGD, Rn-derived SGD rates (as a proxy of total SGD) were compared to excess 226Ra-derived SGD rates (as a proxy for the saline contribution of SGD). The calculated SGD rates, which include a significant (>80%) component of recycled seawater, are used to estimate associated nutrient (NH4+, Si, PO43-, NO3 + NO2, TDN) loads to Lynch Cove. The dissolved inorganic nitrogen (DIN = NH4 + NO2 + NO3) SGD loading estimate of 5.9 × 104 mol d-1 is 1−2 orders of magnitude larger than similar estimates derived from atmospheric deposition and surface water runoff, respectively.
","language":"English","publisher":"American Chemical Society","doi":"10.1021/es070881a","issn":"0013936X","usgsCitation":"Swarzenski, P., Simonds, F., Paulson, A., Kruse, S., and Reich, C., 2007, Geochemical and geophysical examination of submarine groundwater discharge and associated nutrient loading estimates into Lynch Cove, Hood Canal, WA: Environmental Science & Technology, v. 41, no. 20, p. 7022-7029, https://doi.org/10.1021/es070881a.","productDescription":"8 p.","startPage":"7022","endPage":"7029","onlineOnly":"N","additionalOnlineFiles":"N","costCenters":[{"id":186,"text":"Coastal and Marine Geology Program","active":true,"usgs":true},{"id":622,"text":"Washington Water Science Center","active":true,"usgs":true}],"links":[{"id":239757,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"country":"United States","state":"Washington","otherGeospatial":"Hood Canal, Lynch Cove","volume":"41","issue":"20","noUsgsAuthors":false,"publicationDate":"2007-09-19","publicationStatus":"PW","scienceBaseUri":"505a15d0e4b0c8380cd54f58","contributors":{"authors":[{"text":"Swarzenski, P.W. 0000-0003-0116-0578","orcid":"https://orcid.org/0000-0003-0116-0578","contributorId":29487,"corporation":false,"usgs":true,"family":"Swarzenski","given":"P.W.","affiliations":[],"preferred":false,"id":431505,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Simonds, F. W.","contributorId":54616,"corporation":false,"usgs":true,"family":"Simonds","given":"F. W.","affiliations":[],"preferred":false,"id":431508,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Paulson, A.J. apaulson@usgs.gov","contributorId":89617,"corporation":false,"usgs":true,"family":"Paulson","given":"A.J.","email":"apaulson@usgs.gov","affiliations":[],"preferred":false,"id":431509,"contributorType":{"id":1,"text":"Authors"},"rank":3},{"text":"Kruse, S.","contributorId":33103,"corporation":false,"usgs":true,"family":"Kruse","given":"S.","email":"","affiliations":[],"preferred":false,"id":431506,"contributorType":{"id":1,"text":"Authors"},"rank":4},{"text":"Reich, C.","contributorId":41787,"corporation":false,"usgs":true,"family":"Reich","given":"C.","email":"","affiliations":[],"preferred":false,"id":431507,"contributorType":{"id":1,"text":"Authors"},"rank":5}]}} ,{"id":70031403,"text":"70031403 - 2007 - Physically based estimation of soil water retention from textural data: General framework, new models, and streamlined existing models","interactions":[],"lastModifiedDate":"2023-07-18T11:05:02.903393","indexId":"70031403","displayToPublicDate":"2007-01-01T00:00:00","publicationYear":"2007","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":3674,"text":"Vadose Zone Journal","active":true,"publicationSubtype":{"id":10}},"title":"Physically based estimation of soil water retention from textural data: General framework, new models, and streamlined existing models","docAbstract":"Numerous models are in widespread use for the estimation of soil water retention from more easily measured textural data. Improved models are needed for better prediction and wider applicability. We developed a basic framework from which new and existing models can be derived to facilitate improvements. Starting from the assumption that every particle has a characteristic dimension R associated uniquely with a matric pressure ψ and that the form of the ψ–R relation is the defining characteristic of each model, this framework leads to particular models by specification of geometric relationships between pores and particles. Typical assumptions are that particles are spheres, pores are cylinders with volume equal to the associated particle volume times the void ratio, and that the capillary inverse proportionality between radius and matric pressure is valid. Examples include fixed-pore-shape and fixed-pore-length models. We also developed alternative versions of the model of Arya and Paris that eliminate its interval-size dependence and other problems. The alternative models are calculable by direct application of algebraic formulas rather than manipulation of data tables and intermediate results, and they easily combine with other models (e.g., incorporating structural effects) that are formulated on a continuous basis. Additionally, we developed a family of models based on the same pore geometry as the widely used unsaturated hydraulic conductivity model of Mualem. Predictions of measurements for different suitable media show that some of the models provide consistently good results and can be chosen based on ease of calculations and other factors.
","language":"English","publisher":"Soil Science Society of America","doi":"10.2136/vzj2007.0019","issn":"15391663","usgsCitation":"Nimmo, J.R., Herkelrath, W.N., and Laguna, L., 2007, Physically based estimation of soil water retention from textural data: General framework, new models, and streamlined existing models: Vadose Zone Journal, v. 6, no. 4, p. 766-773, https://doi.org/10.2136/vzj2007.0019.","productDescription":"8 p.","startPage":"766","endPage":"773","numberOfPages":"8","costCenters":[{"id":589,"text":"Toxic Substances Hydrology Program","active":true,"usgs":true}],"links":[{"id":498910,"rank":2,"type":{"id":40,"text":"Open Access Publisher Index Page"},"url":"https://doi.org/10.2136/vzj2007.0019","text":"Publisher Index Page"},{"id":239755,"rank":1,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"volume":"6","issue":"4","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"505a7af0e4b0c8380cd7918e","contributors":{"authors":[{"text":"Nimmo, John R. 0000-0001-8191-1727 jrnimmo@usgs.gov","orcid":"https://orcid.org/0000-0001-8191-1727","contributorId":757,"corporation":false,"usgs":true,"family":"Nimmo","given":"John","email":"jrnimmo@usgs.gov","middleInitial":"R.","affiliations":[{"id":37277,"text":"WMA - Earth System Processes Division","active":true,"usgs":true},{"id":438,"text":"National Research Program - Western Branch","active":true,"usgs":true}],"preferred":true,"id":431354,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Herkelrath, William N. 0000-0002-6149-5524 wnherkel@usgs.gov","orcid":"https://orcid.org/0000-0002-6149-5524","contributorId":2612,"corporation":false,"usgs":true,"family":"Herkelrath","given":"William","email":"wnherkel@usgs.gov","middleInitial":"N.","affiliations":[{"id":438,"text":"National Research Program - Western Branch","active":true,"usgs":true}],"preferred":true,"id":431355,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Laguna, Luna","contributorId":12694,"corporation":false,"usgs":true,"family":"Laguna","given":"Luna","email":"","affiliations":[],"preferred":false,"id":431353,"contributorType":{"id":1,"text":"Authors"},"rank":3}]}} ]}