{"pageNumber":"3","pageRowStart":"50","pageSize":"25","recordCount":409,"records":[{"id":70117566,"text":"sir20145117 - 2014 - A reconnaissance spatial and temporal assessment of methane and inorganic constituents in groundwater in bedrock aquifers, Pike County, Pennsylvania, 2012-13","interactions":[],"lastModifiedDate":"2016-08-24T12:19:10","indexId":"sir20145117","displayToPublicDate":"2014-07-22T08:40:00","publicationYear":"2014","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":334,"text":"Scientific Investigations Report","code":"SIR","onlineIssn":"2328-0328","printIssn":"2328-031X","active":true,"publicationSubtype":{"id":5}},"seriesNumber":"2014-5117","title":"A reconnaissance spatial and temporal assessment of methane and inorganic constituents in groundwater in bedrock aquifers, Pike County, Pennsylvania, 2012-13","docAbstract":"<p>Pike County in northeastern Pennsylvania is underlain by the Devonian-age Marcellus Shale and other shales, formations that have potential for natural gas development. During 2012&ndash;13, the U.S. Geological Survey in cooperation with the Pike County Conservation District conducted a reconnaissance study to assess baseline shallow groundwater quality in bedrock aquifers prior to possible shale-gas development in the county. For the spatial component of the assessment, 20 wells were sampled in summer 2012 to provide data on the occurrence of methane and other aspects of existing groundwater quality throughout the county, including concentrations of inorganic constituents commonly present at low levels in shallow, fresh groundwater but elevated in brines. For the temporal component of the assessment, 4 of the 20 wells sampled in summer 2012 were sampled monthly from July&nbsp;2012 through June&nbsp;2013 to provide data on seasonal variability in groundwater quality. All water samples were analyzed for major ions, nutrients, selected inorganic trace constituents (including metals and other elements), stable isotopes of water, radon-222, gross alpha- and gross beta-particle activity, dissolved gases (methane, ethane, and ethene), and, if possible, isotopic composition of methane. Additional analyses for boron and strontium isotopes, age-dating of water, and radium-226 were done on water samples collected from six wells in June&nbsp;2013.</p>\n<p>Results of the summer 2012 sampling show that water from 16 (80&nbsp;percent) of 20&nbsp;wells had detectable concentrations of methane, but concentrations were less than 0.1&nbsp;milligram per liter (mg/L) in most well-water samples; only two well-water samples had concentrations greater than 1&nbsp;mg/L. The groundwater with elevated methane also had a chemical composition that differed in some respects (pH, selected major ions, and inorganic trace constituents) from groundwater with low methane concentrations. The two well-water samples with the highest methane concentrations (about 3.7 and 5.8&nbsp;mg/L) also had the highest pH values (8.7 and 8.3, respectively) and the highest concentrations of sodium, lithium, boron, fluoride, and bromide. Elevated concentrations of some other constituents, such as barium, strontium, and chloride, were not limited to well-water samples with elevated methane, although the two samples with elevated methane also had among the highest concentrations of these&nbsp;constituents.</p>\n<p>One sample with elevated methane concentrations also had elevated arsenic concentrations, with the arsenic concentration of 30 micrograms per liter (&mu;g/L) exceeding the drinking-water standard of 10 &micro;g/L for arsenic. No other sample from the 20 wells sampled in summer 2012 had concentrations of constituents that exceeded any established primary drinking-water standards. However, radon-222 activities ranging up to 4,500 picocuries per liter (pCi/L) exceeded the proposed drinking-water standard of 300&nbsp;pCi/L in 85&nbsp;percent of the 20 well-water&nbsp;samples.</p>\n<p>The isotopic composition methane in the two high-methane samples (&delta;C<sub>CH4</sub>&nbsp;values of -64.55 and -64.41&nbsp;per&nbsp;mil and &delta;D<sub>CH4</sub>&nbsp;values of -216.9 and -201.8&nbsp;per mil, respectively) indicates a predominantly microbial source for the methane formed by a carbon dioxide reduction process. The stable isotopic composition of water (&delta;D<sub>H20</sub>&nbsp;and &delta;<sup>18</sup>O<sub>H20</sub>) in samples from all 20 wells falls on the local meteoric line, indicating water in the wells was of relatively recent meteoric origin (modern precipitation), including samples with elevated methane&nbsp;concentrations.</p>\n<p>Analytical results for 4 of the 20&nbsp;wells sampled monthly for 1 year ending June&nbsp;2013 in order to assess temporal variability in groundwater quality show that concentrations of major ions generally varied by less than 20 percent, with most differences less than 4&nbsp;mg/L. Concentrations of methane varied by less than 1&nbsp;&mu;g/L (0.001&nbsp;mg/L) in samples from three wells with low methane and by as much as 1 mg/L (1,000&nbsp;&mu;g/L) in samples from one well with relatively high methane. The isotopic composition of methane in the one well with relatively high methane varied slightly in the monthly samples, ranging from about -64.5 to -64.8&nbsp;per&nbsp;mil for &delta;<sup>13</sup>C<sub>CH4</sub>&nbsp;and from about -217 to -228&nbsp;per&nbsp;mil for &delta;D<sub>CH4</sub>. The &delta;<sup>13</sup>C values for dissolved inorganic carbon (DIC) in water from this well were consistent with microbial methane formation by carbon dioxide reduction (drift-type methane) and varied little in the temporal samples, ranging from -10.5 to -10.1&nbsp;per&nbsp;mil.</p>\n<p>Additional analyses of samples collected in late June 2013 from six wells with a range of methane and trace constituent concentrations provided baseline data on strontium and boron isotopic compositions (<sup>87</sup>Sr/<sup>86</sup>Sr ratios and &delta;<sup>11</sup>B, respectively) that potentially may be used to differentiate among sources of these constituents. The strontium and boron isotopic composition determined in the six shallow Pike County groundwater samples had&nbsp;<sup>87</sup>Sr/<sup>86</sup>Sr ratios of 0.71426 to 0.71531 and &delta;<sup>11</sup>B values of 11.7 to 27.0&nbsp;per mil, which differ from those reported for brines in Devonian-age formations in&nbsp;Pennsylvania.</p>\n<p>The&nbsp;June&nbsp;2013 samples were also analyzed for radium-226 and age-dating dissolved gases. Activities of radium-226 ranged from 0.041 to 0.29&nbsp;pCi/L in water samples from the six wells and were less than the drinking-water standard of 5&nbsp;pCi/L for combined radium-226 and radium-228. Age-dating of groundwater using a method based on the presence of anthropogenic gases (chlorofluorocarbons and sulfur hexafluoride) released into the atmosphere yielded estimated recharge dates for water from these six wells that ranged from the 1940s to early 2000s. The oldest water was in samples from wells that had the highest methane concentrations and the youngest water was in samples from a continuously pumped 300-foot deep production&nbsp;well.</p>","language":"English","publisher":"U.S. Geological Survey","publisherLocation":"Reston, VA","doi":"10.3133/sir20145117","collaboration":"Prepared in cooperation with the Pike County Conservation District","usgsCitation":"Senior, L.A., 2014, A reconnaissance spatial and temporal assessment of methane and inorganic constituents in groundwater in bedrock aquifers, Pike County, Pennsylvania, 2012-13: U.S. Geological Survey Scientific Investigations Report 2014-5117, x, 91 p., https://doi.org/10.3133/sir20145117.","productDescription":"x, 91 p.","numberOfPages":"106","onlineOnly":"Y","additionalOnlineFiles":"N","ipdsId":"IP-054516","costCenters":[{"id":532,"text":"Pennsylvania Water Science Center","active":true,"usgs":true}],"links":[{"id":290640,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/sir20145117.jpg"},{"id":290637,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/sir/2014/5117/support/sir2014-5117.pdf","text":"Report","size":"5.42 MB","linkFileType":{"id":1,"text":"pdf"},"description":"Report"},{"id":290636,"type":{"id":15,"text":"Index Page"},"url":"https://pubs.usgs.gov/sir/2014/5117/"}],"scale":"2000000","projection":"Albers Equal-Area Conic Projection","country":"United States","state":"Pennsylvania","county":"Pike 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,{"id":70111860,"text":"ofr20141116 - 2014 - Baseline groundwater quality from 34 wells in Wayne County, Pennsylvania, 2011 and 2013","interactions":[],"lastModifiedDate":"2016-08-24T12:16:29","indexId":"ofr20141116","displayToPublicDate":"2014-07-11T09:16:00","publicationYear":"2014","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":330,"text":"Open-File Report","code":"OFR","onlineIssn":"2331-1258","printIssn":"0196-1497","active":true,"publicationSubtype":{"id":5}},"seriesNumber":"2014-1116","title":"Baseline groundwater quality from 34 wells in Wayne County, Pennsylvania, 2011 and 2013","docAbstract":"<p>Wayne County, Pennsylvania, is underlain by the Marcellus Shale, which currently (2014) is being developed elsewhere in Pennsylvania for natural gas. All residents of largely rural Wayne County rely on groundwater for water supply, primarily from bedrock aquifers (shales and sandstones). This study, conducted by the U.S. Geological Survey in cooperation with the Pennsylvania Department of Conservation and Natural Resources, Bureau of Topographic and Geologic Survey (Pennsylvania Geological Survey), provides a groundwater-quality baseline for Wayne County prior to development of the natural gas resource in the Marcellus Shale. Selected wells completed in the Devonian-age Catskill Formation, undifferentiated; the Poplar Gap and Packerton Members of the Catskill Formation, undivided; and the Long Run and Walcksville Members of the Catskill Formation, undivided, were sampled.</p>\n<p>Water samples were collected once from 34 domestic wells during August 2011 and August and September 2013 and analyzed to characterize their physical and chemical quality. Samples were analyzed for 45 constituents and properties, including nutrients, major ions, metals and trace elements, radioactivity, and dissolved gases, including methane and radon-222. The quality of the sampled groundwater was generally within U.S. Environmental Protection Agency (USEPA) drinking-water standards, although in some samples, the concentrations of a few constituents exceeded USEPA drinking-water standards and health advisories.</p>\n<p>The pH of water samples ranged from 5.5 to 9.3 with a median of 7.0. The pH was outside the USEPA secondary maximum contaminant level (SMCL) range of 6.5 to 8.5 in water samples from 14 of the 34 wells (41 percent). Eleven samples had a pH less than 6.5, and three samples had a pH greater than 8.5. Dissolved oxygen concentrations ranged from 0.2 to 11.5 milligrams per liter (mg/L) with a median of 4.7 mg/L. The dissolved oxygen concentration was less than 1 mg/L in water samples from 6 wells; 5 of these 6 water samples had a pH greater than 7.7.</p>\n<p>Concentrations of dissolved methane ranged from less than 0.00006 to 3.3 mg/L. Methane was detectable in 22 of the 34 wells sampled (65 percent). Methane concentrations were greatest in the 5 samples with pH of 7.8 or higher, ranging from 0.040 to 3.3 mg/L. These samples also had among the lowest concentrations of dissolved oxygen. Three water samples, which had sufficient dissolved methane concentrations (greater than 0.9 mg/L), were analyzed for isotopes of carbon and hydrogen in the methane. The isotopic ratio values fell within (two samples) or close to (one sample) the range for a thermogenic natural gas source.</p>\n<p>The total dissolved solids concentration ranged from 33 to 346 mg/L; the median concentration was 126 mg/L. Sodium concentrations ranged from 1.07 to 116 mg/L; the median concentration was 9.42 mg/L. The sodium concentration exceeded the USEPA health advisory for sodium of 20 mg/L in water samples from 7 of the 34 wells (21 percent).</p>\n<p>Concentrations of dissolved arsenic ranged from less than 0.06 to 21.8 micrograms per liter (&micro;g/L); the median concentration was 0.59 &micro;g/L. Water samples from 2 of the 34 wells (6 percent) exceeded the USEPA maximum contaminant level (MCL) of 10 &micro;g/L for arsenic. Concentrations of dissolved manganese ranged from less than 0.15 to 61.5 &micro;g/L; the median concentration was 0.42 &micro;g/L. A water sample from 1 of the 34 wells (3 percent) exceeded the USEPA SMCL of 50 &micro;g/L for manganese; the concentration was less than the USEPA lifetime health advisory of 300 &micro;g/L for manganese.</p>\n<p>Activities of radon-222 in water from the 34 sampled wells ranged from 110 to 7,180 picocuries per liter (pCi/L); the median activity was 2,105 pCi/L. Water samples from 33 of the 34 wells (97 percent) exceeded the proposed USEPA MCL of 300 pCi/L, and 4 water samples (12 percent) exceeded the USEPA proposed alternative MCL of 4,000 pCi/L for radon-222.</p>\n<p><span>Differences in groundwater chemistry were related to pH. Water with a pH greater than 7.6 generally had low dissolved oxygen concentrations, indicating reducing conditions in the aquifer. These high pH waters also had relatively elevated concentrations of methane, arsenic, boron, bromide, fluoride, lithium, and sodium but low concentrations of copper, nickel, and zinc. Water samples with a pH greater than 7.8 had methane concentrations equal to or greater than 0.04 mg/L.</span></p>","language":"English","publisher":"U.S. Geological Survey","publisherLocation":"Reston, VA","doi":"10.3133/ofr20141116","collaboration":"Prepared in cooperation with the Pennsylvania Department of Conservation and Natural Resources, Bureau of Topographic and Geologic Survey","usgsCitation":"Sloto, R.A., 2014, Baseline groundwater quality from 34 wells in Wayne County, Pennsylvania, 2011 and 2013: U.S. Geological Survey Open-File Report 2014-1116, vii, 24 p., https://doi.org/10.3133/ofr20141116.","productDescription":"vii, 24 p.","numberOfPages":"36","onlineOnly":"Y","additionalOnlineFiles":"N","ipdsId":"IP-056249","costCenters":[{"id":532,"text":"Pennsylvania Water Science Center","active":true,"usgs":true}],"links":[{"id":289776,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/ofr20141116.jpg"},{"id":289774,"type":{"id":15,"text":"Index 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,{"id":70073693,"text":"sir20135235 - 2014 - Occurrence and hydrogeochemistry of radiochemical constituents in groundwater of Jefferson County and surrounding areas, southwestern Montana, 2007 through 2010","interactions":[],"lastModifiedDate":"2014-07-31T16:03:46","indexId":"sir20135235","displayToPublicDate":"2014-06-03T12:35:00","publicationYear":"2014","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":334,"text":"Scientific Investigations Report","code":"SIR","onlineIssn":"2328-0328","printIssn":"2328-031X","active":true,"publicationSubtype":{"id":5}},"seriesNumber":"2013-5235","title":"Occurrence and hydrogeochemistry of radiochemical constituents in groundwater of Jefferson County and surrounding areas, southwestern Montana, 2007 through 2010","docAbstract":"<p>The U.S. Geological Survey, in cooperation with Jefferson County and the Jefferson Valley Conservation District, sampled groundwater in southwestern Montana to evaluate the occurrence and concentration of naturally-occurring radioactive constituents and to identify geologic settings and environmental conditions in which elevated concentrations occur. A total of 168 samples were collected from 128 wells within Broadwater, Deer Lodge, Jefferson, Lewis and Clark, Madison, Powell, and Silver Bow Counties from 2007 through 2010. Most wells were used for domestic purposes and were primary sources of drinking water for individual households. Water-quality samples were collected from wells completed within six generalized geologic units, and analyzed for constituents including uranium, radon, gross alpha-particle activity, and gross beta-particle activity. Thirty-eight wells with elevated concentrations or activities were sampled a second time to examine variability in water quality throughout time. These water-quality samples were analyzed for an expanded list of radioactive constituents including the following: three isotopes of uranium (uranium-234, uranium-235, and uranium-238), three isotopes of radium (radium-224, radium-226, and radium-228), and polonium-210. Existing U.S. Geological Survey and Montana Bureau of Mines and Geology uranium and radon water-quality data collected as part of other investigations through 2011 from wells within the study area were compiled as part of this investigation. Water-quality data from this study were compared to data collected nationwide by the U.S. Geological Survey through 2011.</p>\n<br>\n<p>Radionuclide samples for this study typically were analyzed within a few days after collection, and therefore data for this study may closely represent the concentrations and activities of water being consumed locally from domestic wells. Radioactive constituents were detected in water from every well sampled during this study regardless of location or geologic unit. Nearly 41 percent of sampled wells had at least one radioactive constituent concentration that exceeded U.S. Environmental Protection Agency drinking-water standards or screening levels. Uranium concentrations were higher than the U.S. Environmental Protection Agency maximum contaminant level (MCL) of 30 micrograms per liter in samples from 14 percent of the wells. Radon concentrations exceeded a proposed MCL of 4,000 picocuries per liter in 27 percent of the wells. Combined radium (radium-226 and radium-228) exceeded the MCL of 5 picocuries per liter in samples from 10 of 47 wells. About 40 percent (42 of 104 wells) of the wells had gross alpha-particle activities (72-hour count) at or greater than a screening level of 15 pCi/L. Gross beta-particle activity exceeded the U.S. Environmental Protection Agency 50 picocuries per liter screening level in samples from 5 of 104 wells. Maximum radium-224 and polonium-210 activities in study wells were 16.1 and 3.08 picocuries per liter, respectively; these isotopes are constituents of human-health concern, but the U.S. Environmental Protection Agency has not established MCLs for them.</p>\n<br>\n<p>Radioactive constituent concentrations or activities exceeded at least one established drinking-water standard, proposed drinking-water standard, or screening level in groundwater samples from five of six generalized geologic units assessed during this study. Radioactive constituent concentrations or activities were variable not only within each geologic unit, but also among wells that were completed in the same geologic unit and in close proximity to one another. Established or proposed drinking-water standards were exceeded most frequently in water from wells completed in the generalized geologic unit that includes rocks of the Boulder batholith and other Tertiary through Cretaceous igneous intrusive rocks (commonly described as granite). Specifically, of the wells completed in the Boulder batholith and related rocks sampled as part of this study, 24 percent exceeded the MCL of 30 micrograms per liter for uranium, 50 percent exceeded the proposed alternative MCL of 4,000 picocuries per liter for radon, and 27 percent exceeded the MCL of 5 micrograms per liter for combined radium-226 and radium-228.</p>\n<br>\n<p>Elevated radioactive constituent values were detected in samples representing a large range of field properties and water types. Correlations between radioactive constituents and pH, dissolved oxygen, and most major ions were not statistically significant (p-value > 0.05) or were weakly correlated with Spearman correlation coefficients (rho) ranging from -0.5 to 0.5. Moderate correlations did exist between gross beta-particle activity and potassium (rho = 0.72 to 0.82), likely because one potassium isotope (potassium-40) is a beta-particle emitter. Total dissolved solids and specific conductance also were moderately correlated (rho = 0.62 to 0.71) with gross alpha-particle and gross beta-particle activity, indicating that higher radioactivity values can be associated with higher total dissolved solids.</p>\n<br>\n<p>Correlations were evaluated among radioactive constituents. Moderate to strong correlations occurred between gross alpha-particle and beta-particle activities (rho = 0.77 to 0.96) and radium isotopes (rho = 0.78 to 0.92). Correlations between gross alpha-particle activity (72-hour count) and all analyzed radioactive constituents were statistically significant (p-value < 0.05), and therefore, gross alpha-particle activity likely may be used as a screening tool for determining the presence of radionuclides in area waters. In this study, gross alpha-particle activities of 7 picocuries per liter or greater were associated with all radioactive constituents whose concentrations exceeded drinking-water standards or screening levels.</p>\n<br>\n<p>Radiochemical results varied temporally in samples from several of the thirty-eight wells sampled at least twice during the study. The time between successive sampling events ranged from about 1 to 10 months for 29 wells to about 3 years for the other 9 wells. Radiochemical constituents that varied by greater than 30 percent between sampling events included uranium (29 percent of the resampled wells), and radon (11 percent of the resampled wells), gross alpha-particle activity (38 percent of the resampled wells), and gross beta-particle activity (15 percent of the resampled wells). Variability in uranium concentrations from two wells was sufficiently large that concentrations were less than the MCL in the first set of samples and greater than the MCL in the second.</p>\n<br>\n<p>Sample holding times affect analytical results in this study. Gross alpha-particle and gross beta-particle activities were measured twice, 72 hours and 30 days after sample collection. Gross alpha-particle activity decreased an average of 37 percent between measurements, indicating the presence of short-lived alpha-emitting radionuclides in these samples. Gross beta-particle activity increased an average of 31 percent between measurements, indicating ingrowth of longer-lived beta-emitting radionuclides.</p>","language":"English","publisher":"U.S. Geological Survey","publisherLocation":"Reston, VA","doi":"10.3133/sir20135235","issn":"2328-0328","collaboration":"Prepared in cooperation with Jefferson County and the Jefferson Valley Conservation District, Montana","usgsCitation":"Caldwell, R.R., Nimick, D.A., and DeVaney, R.M., 2014, Occurrence and hydrogeochemistry of radiochemical constituents in groundwater of Jefferson County and surrounding areas, southwestern Montana, 2007 through 2010: U.S. Geological Survey Scientific Investigations Report 2013-5235, Report: x, 61 p.; Downloads directory, https://doi.org/10.3133/sir20135235.","productDescription":"Report: x, 61 p.; Downloads directory","numberOfPages":"76","onlineOnly":"N","temporalStart":"2007-01-01","temporalEnd":"2010-12-31","ipdsId":"IP-042934","costCenters":[{"id":685,"text":"Wyoming-Montana Water Science Center","active":false,"usgs":true}],"links":[{"id":287984,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/sir20135235.jpg"},{"id":287981,"type":{"id":15,"text":"Index Page"},"url":"https://pubs.usgs.gov/sir/2013/5235/"},{"id":287982,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/sir/2013/5235/pdf/sir2013-5235.pdf"},{"id":287983,"type":{"id":7,"text":"Companion Files"},"url":"https://pubs.usgs.gov/sir/2013/5235/downloads/Appendix%20.xlsx"}],"scale":"100000","projection":"Universal Transverse Mercator projection","datum":"North American Datum of 1927","country":"United States","state":"Montana","county":"Jefferson County","geographicExtents":"{ \"type\": \"FeatureCollection\", \"features\": [ { \"type\": \"Feature\", \"properties\": {}, \"geometry\": { \"type\": \"Polygon\", \"coordinates\": [ [ [ -113.0,45.5 ], [ -113.0,47.0 ], [ -111.5,47.0 ], [ -111.5,45.5 ], [ -113.0,45.5 ] ] ] } } ] }","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"538ee05be4b0d497d49684d5","contributors":{"authors":[{"text":"Caldwell, Rodney R. 0000-0002-2588-715X caldwell@usgs.gov","orcid":"https://orcid.org/0000-0002-2588-715X","contributorId":2577,"corporation":false,"usgs":true,"family":"Caldwell","given":"Rodney","email":"caldwell@usgs.gov","middleInitial":"R.","affiliations":[{"id":685,"text":"Wyoming-Montana Water Science Center","active":false,"usgs":true}],"preferred":true,"id":489047,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Nimick, David A. dnimick@usgs.gov","contributorId":421,"corporation":false,"usgs":true,"family":"Nimick","given":"David","email":"dnimick@usgs.gov","middleInitial":"A.","affiliations":[{"id":5050,"text":"WY-MT Water Science Center","active":true,"usgs":true},{"id":573,"text":"Special Applications Science Center","active":true,"usgs":true}],"preferred":true,"id":489046,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"DeVaney, Rainie M.","contributorId":84668,"corporation":false,"usgs":true,"family":"DeVaney","given":"Rainie","email":"","middleInitial":"M.","affiliations":[],"preferred":false,"id":489048,"contributorType":{"id":1,"text":"Authors"},"rank":3}]}}
,{"id":70108159,"text":"70108159 - 2014 - Uranium and radon in private bedrock well water in Maine: geospatial analysis at two scales","interactions":[],"lastModifiedDate":"2014-06-09T15:11:37","indexId":"70108159","displayToPublicDate":"2014-05-01T14:57:23","publicationYear":"2014","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":1565,"text":"Environmental Science & Technology","onlineIssn":"1520-5851","printIssn":"0013-936X","active":true,"publicationSubtype":{"id":10}},"title":"Uranium and radon in private bedrock well water in Maine: geospatial analysis at two scales","docAbstract":"In greater Augusta of central Maine, 53 out of 1093 (4.8%) private bedrock well water samples from 1534 km<sup>2</sup> contained [U] >30 μg/L, the U.S. Environmental Protection Agency’s (EPA) Maximum Contaminant Level (MCL) for drinking water; and 226 out of 786 (29%) samples from 1135 km<sup>2</sup> showed [Rn] >4,000 pCi/L (148 Bq/L), the U.S. EPA’s Alternative MCL. Groundwater pH, calcite dissolution and redox condition are factors controlling the distribution of groundwater U but not Rn due to their divergent chemical and hydrological properties. Groundwater U is associated with incompatible elements (S, As, Mo, F, and Cs) in water samples within granitic intrusions. Elevated [U] and [Rn] are located within 5–10 km distance of granitic intrusions but do not show correlations with metamorphism at intermediate scales (100−101 km). This spatial association is confirmed by a high-density sampling (n = 331, 5–40 samples per km<sup>2</sup>) at local scales (≤10<sup>–1</sup> km) and the statewide sampling (n = 5857, 1 sample per 16 km<sup>2</sup>) at regional scales (10<sup>2</sup>–10<sup>3</sup> km). Wells located within 5 km of granitic intrusions are at risk of containing high levels of [U] and [Rn]. Approximately 48 800–63 900 and 324 000 people in Maine are estimated at risk of exposure to U (>30 μg/L) and Rn (>4000 pCi/L) in well water, respectively.","largerWorkType":{"id":2,"text":"Article"},"largerWorkTitle":"Environmental Science and Technology","largerWorkSubtype":{"id":10,"text":"Journal Article"},"language":"English","publisher":"American Chemical Society","publisherLocation":"Easton, PA","doi":"10.1021/es405020k","usgsCitation":"Yang, Q., Smitherman, P., Hess, C., Culbertson, C.W., Marvinney, R., and Zheng, Y., 2014, Uranium and radon in private bedrock well water in Maine: geospatial analysis at two scales: Environmental Science & Technology, v. 48, no. 8, p. 4298-4306, https://doi.org/10.1021/es405020k.","productDescription":"9 p.","startPage":"4298","endPage":"4306","numberOfPages":"9","ipdsId":"IP-052124","costCenters":[{"id":371,"text":"Maine Water Science Center","active":true,"usgs":true}],"links":[{"id":473008,"rank":0,"type":{"id":40,"text":"Open Access Publisher Index Page"},"url":"https://doi.org/10.1021/es405020k","text":"Publisher Index Page"},{"id":288184,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"},{"id":288183,"type":{"id":10,"text":"Digital Object Identifier"},"url":"https://dx.doi.org/10.1021/es405020k"}],"country":"United States","state":"Maine","city":"Augusta","geographicExtents":"{ \"type\": \"FeatureCollection\", \"features\": [ { \"type\": \"Feature\", \"properties\": {}, \"geometry\": { \"type\": \"Polygon\", \"coordinates\": [ [ [ -71.08,42.97 ], [ -71.08,47.46 ], [ -66.95,47.46 ], [ -66.95,42.97 ], [ -71.08,42.97 ] ] ] } } ] }","volume":"48","issue":"8","noUsgsAuthors":false,"publicationDate":"2014-03-28","publicationStatus":"PW","scienceBaseUri":"5396d776e4b0f7580bc0a92a","contributors":{"authors":[{"text":"Yang, Qiang","contributorId":27362,"corporation":false,"usgs":true,"family":"Yang","given":"Qiang","affiliations":[],"preferred":false,"id":493972,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Smitherman, Paul","contributorId":56976,"corporation":false,"usgs":true,"family":"Smitherman","given":"Paul","email":"","affiliations":[],"preferred":false,"id":493974,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Hess, C.T.","contributorId":39556,"corporation":false,"usgs":true,"family":"Hess","given":"C.T.","email":"","affiliations":[],"preferred":false,"id":493973,"contributorType":{"id":1,"text":"Authors"},"rank":3},{"text":"Culbertson, Charles W. cculbert@usgs.gov","contributorId":1607,"corporation":false,"usgs":true,"family":"Culbertson","given":"Charles","email":"cculbert@usgs.gov","middleInitial":"W.","affiliations":[{"id":371,"text":"Maine Water Science Center","active":true,"usgs":true}],"preferred":true,"id":493970,"contributorType":{"id":1,"text":"Authors"},"rank":4},{"text":"Marvinney, Robert G.","contributorId":23070,"corporation":false,"usgs":true,"family":"Marvinney","given":"Robert G.","affiliations":[],"preferred":false,"id":493971,"contributorType":{"id":1,"text":"Authors"},"rank":5},{"text":"Zheng, Yan","contributorId":99046,"corporation":false,"usgs":false,"family":"Zheng","given":"Yan","email":"","affiliations":[{"id":7255,"text":"City University of New York, Queens College","active":true,"usgs":false}],"preferred":false,"id":493975,"contributorType":{"id":1,"text":"Authors"},"rank":6}]}}
,{"id":70048954,"text":"ds803 - 2014 - Groundwater-quality data in the Klamath Mountains study unit, 2010: results from the California GAMA Program","interactions":[],"lastModifiedDate":"2014-03-28T15:39:06","indexId":"ds803","displayToPublicDate":"2014-03-28T15:19:00","publicationYear":"2014","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":310,"text":"Data Series","code":"DS","onlineIssn":"2327-638X","printIssn":"2327-0271","active":false,"publicationSubtype":{"id":5}},"seriesNumber":"803","title":"Groundwater-quality data in the Klamath Mountains study unit, 2010: results from the California GAMA Program","docAbstract":"<p>Groundwater quality in the 8,806-square-mile Klamath Mountains (KLAM) study unit was investigated by the U.S. Geological Survey (USGS) from October to December 2010, as part of the California State Water Resources Control Board (SWRCB) Groundwater Ambient Monitoring and Assessment (GAMA) Program’s Priority Basin Project (PBP). The GAMA-PBP was developed in response to the California Groundwater Quality Monitoring Act of 2001 and is being conducted in collaboration with the SWRCB and Lawrence Livermore National Laboratory (LLNL). The KLAM study unit was the thirty-third study unit to be sampled as part of the GAMA-PBP.</p>\n\n<br>\n\n<p>The GAMA Klamath Mountains study was designed to provide a spatially unbiased assessment of untreated-groundwater quality in the primary aquifer system and to facilitate statistically consistent comparisons of untreated-groundwater quality throughout California. The primary aquifer system is defined by the perforation intervals of wells listed in the California Department of Public Health (CDPH) database for the KLAM study unit. Groundwater quality in the primary aquifer system may differ from the quality in the shallower or deeper water-bearing zones; shallower groundwater may be more vulnerable to surficial contamination.</p>\n\n<br>\n\n<p>In the KLAM study unit, groundwater samples were collected from sites in Del Norte, Siskiyou, Humboldt, Trinity, Tehama, and Shasta Counties, California. Of the 39 sites sampled, 38 were selected by using a spatially distributed, randomized grid-based method to provide statistical representation of the primary aquifer system in the study unit (grid sites), and the remaining site was non-randomized (understanding site).</p>\n\n<br>\n\n<p>The groundwater samples were analyzed for basic field parameters, organic constituents (volatile organic compounds [VOCs] and pesticides and pesticide degradates), inorganic constituents (trace elements, nutrients, major and minor ions, total dissolved solids [TDS]), radon-222, gross alpha and gross beta radioactivity, and microbial indicators (total coliform and Escherichia coli [E. coli]). Isotopic tracers (stable isotopes of hydrogen and oxygen in water, isotopic ratios of dissolved strontium in water, and stable isotopes of carbon in dissolved inorganic carbon), dissolved noble gases, and age-dating tracers (tritium and carbon-14) were measured to help identify sources and ages of sampled groundwater.</p>\n\n<br>\n\n<p>Quality-control samples (field blanks, replicate sample pairs, and matrix spikes) were collected at 13 percent of the sites in the KLAM study unit, and the results were used to evaluate the quality of the data from the groundwater samples. Field blank samples rarely contained detectable concentrations of any constituent, indicating that contamination from sample collection or analysis was not a significant source of bias in the data for the groundwater samples. More than 99 percent of the replicate pair samples were within acceptable limits of variability. Matrix-spike sample recoveries were within the acceptable range (70 to 130 percent) for approximately 91 percent of the compounds.</p>\n\n<br>\n\n<p>This study did not evaluate the quality of water delivered to consumers. After withdrawal, groundwater typically is treated, disinfected, and (or) blended with other waters to maintain water quality. Regulatory benchmarks apply to water that is delivered to the consumer, not to untreated groundwater. However, to provide some context for the results, concentrations of constituents measured in the untreated groundwater were compared with regulatory and non-regulatory health-based benchmarks established by the U.S. Environmental Protection Agency (USEPA) and CDPH, and to non-health-based benchmarks established for aesthetic concerns by the CDPH. Comparisons between data collected for this study and benchmarks for drinking water are for illustrative purposes only and are not indicative of compliance or non-compliance with those benchmarks.</p>\n\n<br>\n\n<p>All concentrations of organic constituents from grid sites sampled in the KLAM study unit were less than health-based benchmarks. In total, VOCs were detected in 16 of the 38 grid sites sampled (approximately 42 percent), pesticides and pesticide degradates were detected in 8 grid sites (about 21 percent), and microbial indicators were detected in 14 grid sites (approximately 37 percent).</p>\n\n<br>\n\n<p>Inorganic constituents (trace elements, major and minor ions, nutrients, and uranium and other radioactive constituents) and microbial indicators were sampled for at 38 grid sites, and all concentrations were less than health-based benchmarks, with the exception of one detection of boron greater than the CDPH notification level of 1,000 micrograms per liter (μg/L). Generally, concentrations of inorganic constituents with non-health-based benchmarks (iron, manganese, chloride, and TDS) were less than the CDPH secondary maximum contaminant level (SMCL-CA). Exceptions include three detections of iron greater than the SMCL-CA of 300 μg/L, four detections of manganese greater than the SMCL-CA of 50 μg/L, one detection of chloride greater than the recommended SMCL-CA of 250 μg/L, and one detection of TDS greater than the recommended SMCL-CA of 500 μg/L.</p>","language":"English","publisher":"U.S. Geological Survey","publisherLocation":"Reston, VA","doi":"10.3133/ds803","collaboration":"A product of the California Groundwater Ambient Monitoring and Assessment (GAMA) Program; Prepared in cooperation with the California State Water Resources Control Board","usgsCitation":"Mathany, T., and Belitz, K., 2014, Groundwater-quality data in the Klamath Mountains study unit, 2010: results from the California GAMA Program: U.S. Geological Survey Data Series 803, x, 82 p., https://doi.org/10.3133/ds803.","productDescription":"x, 82 p.","numberOfPages":"96","ipdsId":"IP-036089","costCenters":[{"id":154,"text":"California Water Science Center","active":true,"usgs":true}],"links":[{"id":285119,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/ds803.jpg"},{"id":285117,"type":{"id":15,"text":"Index Page"},"url":"https://pubs.usgs.gov/ds/803/"},{"id":285118,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/ds/803/pdf/ds803.pdf"}],"projection":"Albers Equal Area Conic Projection","country":"United States","state":"California","geographicExtents":"{ \"type\": \"FeatureCollection\", \"features\": [ { \"type\": \"Feature\", \"properties\": {}, \"geometry\": { \"type\": \"Polygon\", \"coordinates\": [ [ [ -0.01611111111111111,8.333333333333334E-4 ], [ -0.01611111111111111,0.0011111111111111111 ], [ -0.01638888888888889,0.0011111111111111111 ], [ -0.01638888888888889,8.333333333333334E-4 ], [ -0.01611111111111111,8.333333333333334E-4 ] ] ] } } ] }","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"53517044e4b05569d805a245","contributors":{"authors":[{"text":"Mathany, Timothy M. 0000-0002-4747-5113","orcid":"https://orcid.org/0000-0002-4747-5113","contributorId":99949,"corporation":false,"usgs":true,"family":"Mathany","given":"Timothy M.","affiliations":[],"preferred":false,"id":485868,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Belitz, Kenneth 0000-0003-4481-2345 kbelitz@usgs.gov","orcid":"https://orcid.org/0000-0003-4481-2345","contributorId":442,"corporation":false,"usgs":true,"family":"Belitz","given":"Kenneth","email":"kbelitz@usgs.gov","affiliations":[{"id":27111,"text":"National Water Quality Program","active":true,"usgs":true},{"id":451,"text":"National Water Quality Assessment Program","active":true,"usgs":true},{"id":466,"text":"New England Water Science Center","active":true,"usgs":true},{"id":503,"text":"Office of Water Quality","active":true,"usgs":true},{"id":376,"text":"Massachusetts Water Science Center","active":true,"usgs":true}],"preferred":true,"id":485867,"contributorType":{"id":1,"text":"Authors"},"rank":2}]}}
,{"id":70048084,"text":"sir20135143 - 2013 - Distribution of indoor radon concentrations in Pennsylvania, 1990-2007","interactions":[],"lastModifiedDate":"2016-08-10T21:18:13","indexId":"sir20135143","displayToPublicDate":"2013-09-09T14:57:00","publicationYear":"2013","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":334,"text":"Scientific Investigations Report","code":"SIR","onlineIssn":"2328-0328","printIssn":"2328-031X","active":true,"publicationSubtype":{"id":5}},"seriesNumber":"2013-5143","title":"Distribution of indoor radon concentrations in Pennsylvania, 1990-2007","docAbstract":"<p>Results from 548,507 indoor radon tests from a database compiled by the Pennsylvania Department of Environmental Protection, Bureau of Radiation Protection, Radon Division, are evaluated in this report in an effort to determine areas where concentrations of radon are highest. Indoor radon concentrations were aggregated according to geologic unit and hydrogeologic setting for spatial analysis. Indoor radon concentrations greater than or equal to the U.S. Environmental Protection Agency (USEPA) action level of 4&nbsp;picocuries per liter (pCi/L) were observed for 39 percent of the test results; the highest concentration was&nbsp;1,866.4&nbsp;pCi/L.</p>\n<p>When analyzed according to Pennsylvania&rsquo;s geologic units, 93 of the&nbsp;188 (49.5&nbsp;percent) geologic units with indoor radon concentrations had median concentrations greater than the USEPA action level of 4&nbsp;pCi/L; most of these geologic units are located in the eastern part of the State and include metamorphic rocks, limestones, sandstones, shales, and glacial deposits. When analyzed according to Pennsylvania&rsquo;s hydrogeologic settings, 5 of the&nbsp;20 (25&nbsp;percent) settings had median indoor radon concentrations greater than the USEPA action level of 4&nbsp;pCi/L; these settings are located mostly in the south-central part of the&nbsp;State.</p>\n<p>Median indoor radon concentrations aggregated according to geologic units and hydrogeologic settings are useful for drawing general conclusions about the occurrence of indoor radon in specific geologic units and hydrogeologic settings, but the associated data and maps have limitations. The aggregated indoor radon data have testing and spatial accuracy limitations due to lack of available information regarding testing conditions and the imprecision of geocoded test locations. In addition, the associated data describing geologic units and hydrogeologic settings have spatial and interpretation accuracy limitations, which are a result of using statewide data to define conditions at test locations and geologic data that represent a broad interpretation of geologic units across the State. As a result, indoor air radon concentration distributions are not proposed for use in predicting individual concentrations at specific sites nor for use as a decision-making tool for property owners to decide whether to test for indoor radon concentrations at specific property&nbsp;locations.</p>","language":"English","publisher":"U.S. Geological Survey","publisherLocation":"Reston, VA","doi":"10.3133/sir20135143","usgsCitation":"Gross, E.L., 2013, Distribution of indoor radon concentrations in Pennsylvania, 1990-2007: U.S. Geological Survey Scientific Investigations Report 2013-5143, Report: viii, 31 p.; PARnGeo: Zip file; PARnHydroGeo: Zip file, https://doi.org/10.3133/sir20135143.","productDescription":"Report: viii, 31 p.; PARnGeo: Zip file; PARnHydroGeo: Zip file","numberOfPages":"43","onlineOnly":"Y","additionalOnlineFiles":"Y","temporalStart":"1990-01-01","temporalEnd":"2007-12-31","costCenters":[{"id":532,"text":"Pennsylvania Water Science Center","active":true,"usgs":true}],"links":[{"id":277434,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/sir20135143.png"},{"id":277433,"type":{"id":15,"text":"Index Page"},"url":"https://pubs.usgs.gov/sir/2013/5143/"},{"id":277432,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/sir/2013/5143/pdf/sir2013-5143.pdf","text":"Report","size":"16.5 MB","linkFileType":{"id":1,"text":"pdf"},"description":"Report"}],"scale":"100000","projection":"Albers Equal-Area Conic","country":"United 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,{"id":70047726,"text":"ds742 - 2013 - Groundwater-quality data in the Santa Barbara study unit, 2011: results from the California GAMA Program","interactions":[],"lastModifiedDate":"2013-08-20T14:54:49","indexId":"ds742","displayToPublicDate":"2013-08-20T14:42:00","publicationYear":"2013","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":310,"text":"Data Series","code":"DS","onlineIssn":"2327-638X","printIssn":"2327-0271","active":false,"publicationSubtype":{"id":5}},"seriesNumber":"742","subseriesTitle":"California Groundwater Ambient Monitoring and Assessment (GAMA) Program","title":"Groundwater-quality data in the Santa Barbara study unit, 2011: results from the California GAMA Program","docAbstract":"Groundwater quality in the 48-square-mile Santa Barbara study unit was investigated by the U.S. Geological Survey (USGS) from January to February 2011, as part of the California State Water Resources Control Board (SWRCB) Groundwater Ambient Monitoring and Assessment (GAMA) Program’s Priority Basin Project (PBP). The GAMA-PBP was developed in response to the California Groundwater Quality Monitoring Act of 2001 and is being conducted in collaboration with the SWRCB and Lawrence Livermore National Laboratory (LLNL). The Santa Barbara study unit was the thirty-fourth study unit to be sampled as part of the GAMA-PBP.\n\nThe GAMA Santa Barbara study was designed to provide a spatially unbiased assessment of untreated-groundwater quality in the primary aquifer system, and to facilitate statistically consistent comparisons of untreated-groundwater quality throughout California. The primary aquifer system is defined as those parts of the aquifers corresponding to the perforation intervals of wells listed in the California Department of Public Health (CDPH) database for the Santa Barbara study unit. Groundwater quality in the primary aquifer system may differ from the quality in the shallower or deeper water-bearing zones; shallow groundwater may be more vulnerable to surficial contamination.\n\nIn the Santa Barbara study unit located in Santa Barbara and Ventura Counties, groundwater samples were collected from 24 wells. Eighteen of the wells were selected by using a spatially distributed, randomized grid-based method to provide statistical representation of the study unit (grid wells), and six wells were selected to aid in evaluation of water-quality issues (understanding wells).\n\nThe groundwater samples were analyzed for organic constituents (volatile organic compounds [VOCs], pesticides and pesticide degradates, and pharmaceutical compounds); constituents of special interest (perchlorate and N-nitrosodimethylamine [NDMA]); naturally occurring inorganic constituents (trace elements, nutrients, major and minor ions, silica, total dissolved solids [TDS], alkalinity, and arsenic, chromium, and iron species); and radioactive constituents (radon-222 and gross alpha and gross beta radioactivity). Naturally occurring isotopes (stable isotopes of hydrogen and oxygen in water, stables isotopes of inorganic carbon and boron dissolved in water, isotope ratios of dissolved strontium, tritium activities, and carbon-14 abundances) and dissolved noble gases also were measured to help identify the sources and ages of the sampled groundwater. In total, 281 constituents and water-quality indicators were measured.\n\nThree types of quality-control samples (blanks, replicates, and matrix spikes) were collected at up to 12 percent of the wells in the Santa Barbara study unit, and the results for these samples were used to evaluate the quality of the data for the groundwater samples. Blanks rarely contained detectable concentrations of any constituent, suggesting that contamination from sample collection procedures was not a significant source of bias in the data for the groundwater samples. Replicate samples generally were within the limits of acceptable analytical reproducibility. Matrix-spike recoveries were within the acceptable range (70 to 130 percent) for approximately 82 percent of the compounds.\n\nThis study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, untreated groundwater typically is treated, disinfected, and (or) blended with other waters to maintain water quality. Regulatory benchmarks apply to water that is served to the consumer, not to untreated groundwater. However, to provide some context for the results, concentrations of constituents measured in the untreated groundwater were compared with regulatory and non-regulatory health-based benchmarks established by the U.S. Environmental Protection Agency (USEPA) and CDPH and to non-regulatory benchmarks established for aesthetic concerns by CDPH. Comparisons between data collected for this study and benchmarks for drinking water are for illustrative purposes only and are not indicative of compliance or non-compliance with those benchmarks. All organic constituents and most inorganic constituents that were detected in groundwater samples from the 18 grid wells in the Santa Barbara study unit were detected at concentrations less than drinking-water benchmarks.\n\nOf the 220 organic and special-interest constituents sampled for at the 18 grid wells, 13 were detected in groundwater samples; concentrations of all detected constituents were less than regulatory and non-regulatory health-based benchmarks. In total, VOCs were detected in 61 percent of the 18 grid wells sampled, pesticides and pesticide degradates were detected in 11 percent, and perchlorate was detected in 67 percent. Polar pesticides and their degradates, pharmaceutical compounds, and NDMA were not detected in any of the grid wells sampled in the Santa Barbara study unit.\n\nEighteen grid wells were sampled for trace elements, major and minor ions, nutrients, and radioactive constituents; most detected concentrations were less than health-based benchmarks. Exceptions are one detection of boron greater than the CDPH notification level (NL-CA) of 1,000 micrograms per liter (μg/L) and one detection of fluoride greater than the CDPH maximum contaminant level (MCL-CA) of 2 milligrams per liter (mg/L).\n\nResults for constituents with non-regulatory benchmarks set for aesthetic concerns from the grid wells showed that iron concentrations greater than the CDPH secondary maximum contaminant level (SMCL-CA) of 300 μg/L were detected in three grid wells. Manganese concentrations greater than the SMCL-CA of 50 μg/L were detected in seven grid wells. Chloride was detected at a concentration greater than the SMCL-CA recommended benchmark of 250 mg/L in four grid wells. Sulfate concentrations greater than the SMCL-CA recommended benchmark of 250 mg/L were measured in eight grid wells, and the concentration in one of these wells was also greater than the SMCL-CA upper benchmark of 500 mg/L. TDS concentrations greater than the SMCL-CA recommended benchmark of 500 mg/L were measured in 17 grid wells, and concentrations in six of these wells were also greater than the SMCL-CA upper benchmark of 1,000 mg/L.","language":"English","publisher":"U.S. Geological Survey","publisherLocation":"Reston, VA","doi":"10.3133/ds742","collaboration":"Prepared in cooperation with the California State Water Resources Control Board","usgsCitation":"Davis, T., Kulongoski, J., and Belitz, K., 2013, Groundwater-quality data in the Santa Barbara study unit, 2011: results from the California GAMA Program: U.S. Geological Survey Data Series 742, ix, 72 p., https://doi.org/10.3133/ds742.","productDescription":"ix, 72 p.","numberOfPages":"86","temporalStart":"2011-01-01","temporalEnd":"2011-02-28","costCenters":[{"id":154,"text":"California Water Science Center","active":true,"usgs":true}],"links":[{"id":276819,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/ds742.PNG"},{"id":276817,"type":{"id":15,"text":"Index Page"},"url":"https://pubs.usgs.gov/ds/742/"},{"id":276818,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/ds/742/pdf/ds742.pdf"}],"country":"United States","state":"California","county":"Santa Barbara County;Ventura County","geographicExtents":"{ \"type\": \"FeatureCollection\", \"features\": [ { \"type\": \"Feature\", \"properties\": {}, \"geometry\": { \"type\": \"Polygon\", \"coordinates\": [ [ [ -119.916667,34.333333 ], [ -119.916667,34.5 ], [ -119.416667,34.5 ], [ -119.416667,34.333333 ], [ -119.916667,34.333333 ] ] ] } } ] }","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"521481e1e4b06d85e08fb4c3","contributors":{"authors":[{"text":"Davis, Tracy A. 0000-0003-0253-6661","orcid":"https://orcid.org/0000-0003-0253-6661","contributorId":59339,"corporation":false,"usgs":true,"family":"Davis","given":"Tracy A.","affiliations":[],"preferred":false,"id":482830,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Kulongoski, Justin T. 0000-0002-3498-4154","orcid":"https://orcid.org/0000-0002-3498-4154","contributorId":94750,"corporation":false,"usgs":true,"family":"Kulongoski","given":"Justin T.","affiliations":[],"preferred":false,"id":482831,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Belitz, Kenneth 0000-0003-4481-2345 kbelitz@usgs.gov","orcid":"https://orcid.org/0000-0003-4481-2345","contributorId":442,"corporation":false,"usgs":true,"family":"Belitz","given":"Kenneth","email":"kbelitz@usgs.gov","affiliations":[{"id":27111,"text":"National Water Quality Program","active":true,"usgs":true},{"id":451,"text":"National Water Quality Assessment Program","active":true,"usgs":true},{"id":376,"text":"Massachusetts Water Science Center","active":true,"usgs":true},{"id":466,"text":"New England Water Science Center","active":true,"usgs":true},{"id":503,"text":"Office of Water Quality","active":true,"usgs":true}],"preferred":true,"id":482829,"contributorType":{"id":1,"text":"Authors"},"rank":3}]}}
,{"id":70047727,"text":"ds747 - 2013 - Groundwater-quality data in the Bear Valley and Selected Hard Rock Areas study unit, 2010: Results from the California GAMA Program","interactions":[],"lastModifiedDate":"2013-08-20T15:27:33","indexId":"ds747","displayToPublicDate":"2013-08-20T14:42:00","publicationYear":"2013","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":310,"text":"Data Series","code":"DS","onlineIssn":"2327-638X","printIssn":"2327-0271","active":false,"publicationSubtype":{"id":5}},"seriesNumber":"747","subseriesTitle":"California Groundwater Ambient Monitoring and Assessment (GAMA) Program","title":"Groundwater-quality data in the Bear Valley and Selected Hard Rock Areas study unit, 2010: Results from the California GAMA Program","docAbstract":"Groundwater quality in the 112-square-mile Bear Valley and Selected Hard Rock Areas (BEAR) study unit was investigated by the U.S. Geological Survey (USGS) from April to August 2010, as part of the California State Water Resources Control Board (SWRCB) Groundwater Ambient Monitoring and Assessment (GAMA) Program’s Priority Basin Project (PBP). The GAMA-PBP was developed in response to the California Groundwater Quality Monitoring Act of 2001 and is being conducted in collaboration with the SWRCB and Lawrence Livermore National Laboratory (LLNL). The BEAR study unit was the thirty-first study unit to be sampled as part of the GAMA-PBP. The GAMA Bear Valley and Selected Hard Rock Areas study was designed to provide a spatially unbiased assessment of untreated-groundwater quality in the primary aquifer system and to facilitate statistically consistent comparisons of untreated groundwater quality throughout California. The primary aquifer system is defined as the zones corresponding to the perforation intervals of wells listed in the California Department of Public Health (CDPH) database for the BEAR study unit. Groundwater quality in the primary aquifer system may differ from the quality in the shallow or deep water-bearing zones; shallow groundwater may be more vulnerable to surficial contamination. In the BEAR study unit, groundwater samples were collected from two study areas (Bear Valley and Selected Hard Rock Areas) in San Bernardino County. Of the 38 sampling sites, 27 were selected by using a spatially distributed, randomized grid-based method to provide statistical representation of the primary aquifer system in the study unit (grid sites), and the remaining 11 sites were selected to aid in the understanding of the potential groundwater-quality issues associated with septic tank use and with ski areas in the study unit (understanding sites). The groundwater samples were analyzed for organic constituents (volatile organic compounds [VOCs], pesticides and pesticide degradates, pharmaceutical compounds, and wastewater indicator compounds [WICs]), constituents of special interest (perchlorate, N-nitrosodimethylamine [NDMA], and 1,2,3-trichloropropane [1,2,3-TCP]), and inorganic constituents (trace elements, nutrients, dissolved organic carbon [DOC], major and minor ions, silica, total dissolved solids [TDS], alkalinity, and arsenic and iron species), and uranium and other radioactive constituents (radon-222 and activities of tritium and carbon-14). Isotopic tracers (of hydrogen and oxygen in water, of nitrogen and oxygen in dissolved nitrate, of dissolved boron, isotopic ratios of strontium in water, and of carbon in dissolved inorganic carbon) and dissolved noble gases (argon, helium-4, krypton, neon, and xenon) were measured to help identify the sources and ages of sampled groundwater. In total, groundwater samples were analyzed for 289 unique constituents and 8 water-quality indicators in the BEAR study unit. Quality-control samples (blanks, replicate pairs, or matrix spikes) were collected at 13 percent of the sites in the BEAR study unit, and the results for these samples were used to evaluate the quality of the data from the groundwater samples. Blank samples rarely contained detectable concentrations of any constituent, indicating that contamination from sample collection or analysis was not a significant source of bias in the data for the groundwater samples. Replicate pair samples all were within acceptable limits of variability. Matrix-spike sample recoveries were within the acceptable range (70 to 130 percent) for approximately 84 percent of the compounds. This study did not evaluate the quality of water delivered to consumers. After withdrawal, groundwater typically is treated, disinfected, and (or) blended with other waters to maintain water quality. Regulatory benchmarks apply to water that is delivered to the consumer, not to untreated groundwater. However, to provide some context for the results, concentrations of constituents measured in the untreated groundwater were compared with regulatory and non-regulatory health-based benchmarks established by the U.S. Environmental Protection Agency (USEPA) and CDPH, and to non-health-based benchmarks established for aesthetic concerns by CDPH. Comparisons between data collected for this study and benchmarks for drinking water are for illustrative purposes only and are not indicative of compliance or non-compliance with those benchmarks. All concentrations of organic and special-interest constituents from grid sites sampled in the BEAR study unit were less than health-based benchmarks. In total, VOCs were detected in 17 of the 27 grid sites sampled (approximately 63 percent), pesticides and pesticide degradates were detected in 4 grid sites (approximately 15 percent), and perchlorate was detected in 21 grid sites (approximately 78 percent). Inorganic constituents (trace elements, major and minor ions, nutrients, and uranium and other radioactive constituents) were sampled for at 27 grid sites; most concentrations were less than health-based benchmarks. Exceptions include one detection of arsenic greater than the USEPA maximum contaminant level (MCL-US) of 10 micrograms per liter (μg/L), three detections of uranium greater than the MCL-US of 30 μg/L, nine detections of radon-222 greater than the proposed MCL-US of 4,000 picocuries per liter (pCi/L), and one detection of fluoride greater than the CDPH maximum contaminant level (MCL-CA) of 2 milligrams per liter. Concentrations of inorganic constituents with non-health-based benchmarks (iron, manganese, chloride, and TDS) were less than the CDPH secondary maximum contaminant level (SMCL-CA) in most grid sites. Exceptions include two detections of iron greater than the SMCL-CA of 300 μg/L and one detection of manganese greater than the SMCL-CA of 50 μg/L.","language":"English","publisher":"U.S Geological Survey","publisherLocation":"Reston, VA","doi":"10.3133/ds747","collaboration":"Prepared in cooperation with the California State Water Resources Control Board","usgsCitation":"Mathany, T., and Belitz, K., 2013, Groundwater-quality data in the Bear Valley and Selected Hard Rock Areas study unit, 2010: Results from the California GAMA Program: U.S. Geological Survey Data Series 747, x, 86 p., https://doi.org/10.3133/ds747.","productDescription":"x, 86 p.","numberOfPages":"100","additionalOnlineFiles":"N","costCenters":[{"id":154,"text":"California Water Science Center","active":true,"usgs":true}],"links":[{"id":276822,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/ds747.jpg"},{"id":276820,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/ds/747/pdf/ds747.pdf"},{"id":276821,"type":{"id":15,"text":"Index Page"},"url":"https://pubs.usgs.gov/ds/747/"}],"country":"United States","state":"California","geographicExtents":"{ \"type\": \"FeatureCollection\", \"features\": [ { \"type\": \"Feature\", \"properties\": {}, \"geometry\": { \"type\": \"Polygon\", \"coordinates\": [ [ [ -117.26738,33.898917 ], [ -117.26738,34.530318 ], [ -116.368561,34.530318 ], [ -116.368561,33.898917 ], [ -117.26738,33.898917 ] ] ] } } ] }","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"521481e0e4b06d85e08fb4bf","contributors":{"authors":[{"text":"Mathany, Timothy M. 0000-0002-4747-5113","orcid":"https://orcid.org/0000-0002-4747-5113","contributorId":99949,"corporation":false,"usgs":true,"family":"Mathany","given":"Timothy M.","affiliations":[],"preferred":false,"id":482833,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Belitz, Kenneth 0000-0003-4481-2345 kbelitz@usgs.gov","orcid":"https://orcid.org/0000-0003-4481-2345","contributorId":442,"corporation":false,"usgs":true,"family":"Belitz","given":"Kenneth","email":"kbelitz@usgs.gov","affiliations":[{"id":27111,"text":"National Water Quality Program","active":true,"usgs":true},{"id":451,"text":"National Water Quality Assessment Program","active":true,"usgs":true},{"id":503,"text":"Office of Water Quality","active":true,"usgs":true},{"id":376,"text":"Massachusetts Water Science Center","active":true,"usgs":true},{"id":466,"text":"New England Water Science Center","active":true,"usgs":true}],"preferred":true,"id":482832,"contributorType":{"id":1,"text":"Authors"},"rank":2}]}}
,{"id":70047311,"text":"sir20135072 - 2013 - Naturally occurring contaminants in the Piedmont and Blue Ridge crystalline-rock aquifers and Piedmont Early Mesozoic basin siliciclastic-rock aquifers, eastern United States, 1994–2008","interactions":[],"lastModifiedDate":"2013-07-31T09:00:08","indexId":"sir20135072","displayToPublicDate":"2013-07-31T08:37:00","publicationYear":"2013","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":334,"text":"Scientific Investigations Report","code":"SIR","onlineIssn":"2328-0328","printIssn":"2328-031X","active":true,"publicationSubtype":{"id":5}},"seriesNumber":"2013-5072","title":"Naturally occurring contaminants in the Piedmont and Blue Ridge crystalline-rock aquifers and Piedmont Early Mesozoic basin siliciclastic-rock aquifers, eastern United States, 1994–2008","docAbstract":"Groundwater quality and aquifer lithologies in the Piedmont and Blue Ridge Physiographic Provinces in the eastern United States vary widely as a result of complex geologic history. Bedrock composition (mineralogy) and geochemical conditions in the aquifer directly affect the occurrence (presence in rock and groundwater) and distribution (concentration and mobility) of potential naturally occurring contaminants, such as arsenic and radionuclides, in drinking water. To evaluate potential relations between aquifer lithology and the spatial distribution of naturally occurring contaminants, the crystalline-rock aquifers of the Piedmont and Blue Ridge Physiographic Provinces and the siliciclastic-rock aquifers of the Early Mesozoic basin of the Piedmont Physiographic Province were divided into 14 lithologic groups, each having from 1 to 16 lithochemical subgroups, based on primary rock type, mineralogy, and weathering potential. Groundwater-quality data collected by the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Program from 1994 through 2008 from 346 wells and springs in various hydrogeologic and land-use settings from Georgia through New Jersey were compiled and analyzed for this study. Analyses for most constituents were for filtered samples, and, thus, the compiled data consist largely of dissolved concentrations. Concentrations were compared to criteria for protection of human health, such as U.S. Environmental Protection Agency (USEPA) drinking water maximum contaminant levels and secondary maximum contaminant levels or health-based screening levels developed by the USGS NAWQA Program in cooperation with the USEPA, the New Jersey Department of Environmental Protection, and Oregon Health & Science University. Correlations among constituent concentrations, pH, and oxidation-reduction (redox) conditions were used to infer geochemical controls on constituent mobility within the aquifers.\n\nOf the 23 trace-element constituents evaluated, arsenic, manganese, and zinc were detected in one or more water samples at concentrations greater than established human health-based criteria. Arsenic concentrations typically were less than 1 microgram per liter (µg/L) in most groundwater samples; however, concentrations of arsenic greater than 1 µg/L frequently were detected in groundwater from clastic lacustrine sedimentary rocks of the Early Mesozoic basin aquifers and from metamorphosed clastic sedimentary rocks of the Piedmont and Blue Ridge crystalline rock aquifers. Groundwater from these rock units had elevated pH compared to other rock units evaluated in this study. Of the nine samples for which arsenic concentration was greater than 10 µg/L, six were classified as oxic and three as anoxic, and seven had pH of 7.2 or greater. Manganese concentrations typically were less than 10 µg/L in most samples; however, 8.3 percent of samples from the Piedmont and Blue Ridge crystalline-rock aquifers and 3.0 percent of samples from the Early Mesozoic basin siliciclastic rock aquifers had manganese concentrations greater than the 300-µg/L health-based screening level. The positive correlation of manganese with iron and ammonia and the negative correlation of manganese with dissolved oxygen and nitrate are consistent with the reductive dissolution of manganese oxides in the aquifer. Zinc concentrations typically were less than 10 µg/L in the groundwater samples considered in the study, but 0.4 percent and 5.5 percent of the samples had concentrations greater than the health-based screening level of 2,000 µg/L and one-tenth of the health-based screening level, respectively. The mean rank concentration of zinc in groundwater from the quartz-rich sedimentary rock lithologic group was greater than that for other lithologic groups even after eliminating samples collected from wells constructed with galvanized casing.\n\nApproximately 90 percent of 275 groundwater samples had radon-222 concentrations that were greater than the proposed alternative maximum contaminant level of 300 picocuries per liter. In contrast, only 2.0 percent of 98 samples had combined radium (radium-226 plus radium-228) concentrations greater than the maximum contaminant level of 5.0 picocuries per liter, and 0.6 percent of 310 samples had uranium concentrations greater than the maximum contaminant level of 30 µg/L. Radon concentrations were highest in the Piedmont and Blue Ridge crystalline-rock aquifers, especially in granite, and elevated median concentrations were noted in the Piedmont Early Mesozoic basin aquifers, but without the extreme maximum concentrations found in the crystalline rocks (granites). Although the siliciclastic lithologies had a greater frequency of elevated uranium concentrations, radon and radium were commonly detected in water from both siliciclastic and crystalline lithologies. Uranium concentrations in groundwater from clastic sedimentary and clastic lacustrine/evaporite sedimentary lithologic groups within the Early Mesozoic basin aquifers, which had median concentrations of 3.6 and 3.1 µg/L, respectively, generally were higher than concentrations for other siliciclastic lithologic groups, which had median concentrations less than 1 µg/L. Although 89 percent of the 260 samples from crystalline-rock aquifers had uranium concentrations less than 1 µg/L, 0.8 percent had uranium concentrations greater than the 30-µg/L maximum contaminant level, and 6.5 percent had concentrations greater than 3 µg/L.","language":"English","publisher":"U.S. Geological Survey","publisherLocation":"Reston, VA","doi":"10.3133/sir20135072","collaboration":"National Water-Quality Assessment Program","usgsCitation":"Chapman, M.J., Cravotta, C.A., Szabo, Z., and Lindsay, B.D., 2013, Naturally occurring contaminants in the Piedmont and Blue Ridge crystalline-rock aquifers and Piedmont Early Mesozoic basin siliciclastic-rock aquifers, eastern United States, 1994–2008: U.S. Geological Survey Scientific Investigations Report 2013-5072, xi, 74 p.; Tables, https://doi.org/10.3133/sir20135072.","productDescription":"xi, 74 p.; Tables","numberOfPages":"90","onlineOnly":"Y","temporalStart":"1994-01-01","temporalEnd":"2008-01-01","costCenters":[{"id":476,"text":"North Carolina Water Science Center","active":true,"usgs":true}],"links":[{"id":275610,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/sir20135072.bmp"},{"id":275608,"type":{"id":15,"text":"Index Page"},"url":"https://pubs.usgs.gov/sir/2013/5072/"},{"id":275609,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/sir/2013/5072/pdf/sir2013-5072.pdf"},{"id":275607,"type":{"id":7,"text":"Companion Files"},"url":"https://pubs.usgs.gov/sir/2013/5072/table/Chapman_PIED6_Tables.xlsx"}],"country":"United States","state":"Alabama;Delaware;Georgia;Maryl;New Jersey;North Carolina;Pennsylvania;Virginia;West Virginia","otherGeospatial":"Piedmont And Blue Ridge Physiographic Provinces","geographicExtents":"{ \"type\": \"FeatureCollection\", \"features\": [ { \"type\": \"Feature\", \"properties\": {}, \"geometry\": { \"type\": \"Polygon\", \"coordinates\": [ [ [ -86.0,32.0 ], [ -86.0,44.0 ], [ -70.0,44.0 ], [ -70.0,32.0 ], [ -86.0,32.0 ] ] ] } } ] }","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"51fa2c7fe4b076c3a8d8261b","contributors":{"authors":[{"text":"Chapman, Melinda J. 0000-0003-4021-0320 mjchap@usgs.gov","orcid":"https://orcid.org/0000-0003-4021-0320","contributorId":1597,"corporation":false,"usgs":true,"family":"Chapman","given":"Melinda","email":"mjchap@usgs.gov","middleInitial":"J.","affiliations":[{"id":476,"text":"North Carolina Water Science Center","active":true,"usgs":true},{"id":493,"text":"Office of Ground Water","active":true,"usgs":true}],"preferred":true,"id":481691,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Cravotta, Charles A. III, 0000-0003-3116-4684 cravotta@usgs.gov","orcid":"https://orcid.org/0000-0003-3116-4684","contributorId":2193,"corporation":false,"usgs":true,"family":"Cravotta","given":"Charles","suffix":"III,","email":"cravotta@usgs.gov","middleInitial":"A.","affiliations":[{"id":532,"text":"Pennsylvania Water Science Center","active":true,"usgs":true}],"preferred":false,"id":481692,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Szabo, Zoltan 0000-0002-0760-9607 zszabo@usgs.gov","orcid":"https://orcid.org/0000-0002-0760-9607","contributorId":2240,"corporation":false,"usgs":true,"family":"Szabo","given":"Zoltan","email":"zszabo@usgs.gov","affiliations":[{"id":451,"text":"National Water Quality Assessment Program","active":true,"usgs":true}],"preferred":false,"id":481693,"contributorType":{"id":1,"text":"Authors"},"rank":3},{"text":"Lindsay, Bruce D.","contributorId":102360,"corporation":false,"usgs":true,"family":"Lindsay","given":"Bruce","email":"","middleInitial":"D.","affiliations":[],"preferred":false,"id":481694,"contributorType":{"id":1,"text":"Authors"},"rank":4}]}}
,{"id":70046638,"text":"sir20135085 - 2013 - Baseline groundwater quality from 20 domestic wells in Sullivan County, Pennsylvania, 2012","interactions":[],"lastModifiedDate":"2016-08-24T12:20:56","indexId":"sir20135085","displayToPublicDate":"2013-06-18T00:00:00","publicationYear":"2013","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":334,"text":"Scientific Investigations Report","code":"SIR","onlineIssn":"2328-0328","printIssn":"2328-031X","active":true,"publicationSubtype":{"id":5}},"seriesNumber":"2013-5085","title":"Baseline groundwater quality from 20 domestic wells in Sullivan County, Pennsylvania, 2012","docAbstract":"<p>Water samples were collected from 20 domestic wells during August and September 2012 and analyzed for 47&nbsp;constituents and properties, including nutrients, major ions, metals and trace elements, radioactivity, and dissolved gases, including methane and radon-222. This study, done in cooperation with the Pennsylvania Department of Conservation and Natural Resources, Bureau of Topographic and Geologic Survey (Pennsylvania Geological Survey), provides a groundwater-quality baseline for central and southern Sullivan County prior to drilling for natural gas in the Marcellus&nbsp;Shale.</p>\n<p>The analytical results for the 20&nbsp;groundwater samples collected during this study indicate that only one constituent (gross-alpha radioactivity) in one sample was found to exceed the U.S. Environmental Protection Agency (USEPA) primary drinking water maximum contaminant level (MCL). Water samples from 85&nbsp;percent of the sampled wells exceeded the proposed USEPA MCL of 300&nbsp;picocuries per liter (pCi/L) for radon-222; however, only two water samples (10&nbsp;percent of sampled wells) exceeded the proposed USEPA alternate maximum contaminant level (AMCL) of 4,000&nbsp;pCi/L for radon-222. In a few samples, the concentrations of total dissolved solids, iron, manganese, and chloride exceeded USEPA secondary maximum contaminant levels (SMCL). In addition, water samples from two wells contained methane concentrations greater than 1&nbsp;milligram per liter&nbsp;(mg/L).</p>\n<p>In general, most of the water-quality problems involve aesthetic considerations, such as taste or odor from elevated concentrations of total dissolved solids, iron, manganese, and chloride that develop from natural interactions of water and rock minerals in the subsurface. The total dissolved solids concentration ranged from 31 to 664&nbsp;mg/L; the median was 130&nbsp;mg/L. The total dissolved solids concentration in one water sample exceeded the USEPA SMCL of 500&nbsp;mg/L. Chloride concentrations ranged from 0.59 to 342&nbsp;mg/L; the median was 12.9&nbsp;mg/L. The concentration of chloride in one water sample exceeded the USEPA SMCL of 250&nbsp;mg/L. Concentrations of dissolved iron ranged from less than 3.2 to 6,590&nbsp;micrograms per liter (&micro;g/L); the median was 11.5&nbsp;&micro;g/L. The iron concentration in samples from 20&nbsp;percent of the sampled wells exceeded the USEPA SMCL of 300&nbsp;&micro;g/L. Concentrations of dissolved manganese ranged from less than 0.13 to 1,710&nbsp;&micro;g/L; the median was 38.5&nbsp;&micro;g/L. The manganese concentration in samples from 35&nbsp;percent of the sampled wells exceeded the USEPA SMCL of&nbsp;50&nbsp;&micro;g/L.</p>\n<p>Activities of radon-222 ranged from 169 to 15,300&nbsp;picocuries per liter (pCi/L); the median was 990&nbsp;pCi/L. The gross alpha-particle radioactivity ranged from below detection to 33&nbsp;pCi/L; the median was 1.5&nbsp;pCi/L. The gross alpha-particle radioactivity of one water sample exceeded the USEPA MCL of&nbsp;15&nbsp;pCi/L.</p>\n<p>Concentrations of dissolved methane ranged from less than 0.001 to 51.1&nbsp;mg/L. Methane was not detected in water samples from 13&nbsp;wells, and the methane concentration was less than 0.07&nbsp;mg/L in samples from five wells. The highest dissolved methane concentrations were 4.1 and 51.1&nbsp;mg/L, and the pH of the water from both wells was greater than 8. Water samples from these wells were analyzed for isotopes of carbon and hydrogen in the methane. The isotopic ratio values fell in the range for a thermogenic (natural gas) source. The water samples from these two wells had the highest concentrations of arsenic, boron, bromide, chloride, fluoride, lithium, molybdenum, and sodium of the 20&nbsp;wells&nbsp;sampled.</p>","language":"English","publisher":"U.S. Geological Survey","publisherLocation":"Reston, VA","doi":"10.3133/sir20135085","collaboration":"Prepared in cooperation with the Pennsylvania Department of Conservation and Natural Resources, Bureau of Topographic and Geologic Survey","usgsCitation":"Sloto, R.A., 2013, Baseline groundwater quality from 20 domestic wells in Sullivan County, Pennsylvania, 2012: U.S. Geological Survey Scientific Investigations Report 2013-5085, vi, 27 p., https://doi.org/10.3133/sir20135085.","productDescription":"vi, 27 p.","numberOfPages":"30","onlineOnly":"Y","additionalOnlineFiles":"N","temporalStart":"2013-08-01","temporalEnd":"2013-09-30","costCenters":[{"id":532,"text":"Pennsylvania Water Science Center","active":true,"usgs":true}],"links":[{"id":273887,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/sir20135085.png"},{"id":273883,"type":{"id":15,"text":"Index Page"},"url":"https://pubs.usgs.gov/sir/2013/5085/"},{"id":273884,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/sir/2013/5085/support/sir2013-5085.pdf","text":"Report","size":"3.1 MB","linkFileType":{"id":1,"text":"pdf"},"description":"Report"}],"country":"United States","state":"Pennsylvania","county":"Sullivan County","geographicExtents":"{\"type\":\"FeatureCollection\",\"features\":[{\"type\":\"Feature\",\"geometry\":{\"type\":\"Polygon\",\"coordinates\":[[[-76.2217,41.5447],[-76.225,41.5312],[-76.2277,41.5203],[-76.2322,41.5058],[-76.2527,41.4552],[-76.2732,41.4045],[-76.2829,41.3778],[-76.2962,41.3485],[-76.3097,41.3109],[-76.4076,41.3095],[-76.4472,41.2772],[-76.4673,41.2805],[-76.4942,41.2848],[-76.5143,41.2882],[-76.5271,41.2914],[-76.5454,41.297],[-76.5587,41.3007],[-76.574,41.3027],[-76.5954,41.3069],[-76.6045,41.312],[-76.6154,41.3193],[-76.673,41.3578],[-76.7514,41.4087],[-76.7609,41.4373],[-76.7669,41.4546],[-76.7686,41.4605],[-76.7693,41.461],[-76.7722,41.4714],[-76.7746,41.4778],[-76.7782,41.4878],[-76.7817,41.5001],[-76.7901,41.5224],[-76.7913,41.5255],[-76.7919,41.5278],[-76.7931,41.531],[-76.8002,41.5519],[-76.8104,41.5801],[-76.811,41.5815],[-76.8133,41.5901],[-76.8103,41.5896],[-76.8005,41.5887],[-76.7949,41.5882],[-76.787,41.5872],[-76.7569,41.5839],[-76.7496,41.5834],[-76.6993,41.5795],[-76.6938,41.579],[-76.679,41.578],[-76.6619,41.5765],[-76.6478,41.5755],[-76.6367,41.5745],[-76.5975,41.5715],[-76.5,41.5649],[-76.4454,41.5608],[-76.3277,41.5526],[-76.2487,41.5468],[-76.2432,41.5463],[-76.2383,41.5458],[-76.2217,41.5447]]]},\"properties\":{\"name\":\"Sullivan\",\"state\":\"PA\"}}]}","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"51c1734ee4b0dd0e00d92173","contributors":{"authors":[{"text":"Sloto, Ronald A. rasloto@usgs.gov","contributorId":424,"corporation":false,"usgs":true,"family":"Sloto","given":"Ronald","email":"rasloto@usgs.gov","middleInitial":"A.","affiliations":[{"id":532,"text":"Pennsylvania Water Science Center","active":true,"usgs":true}],"preferred":true,"id":479916,"contributorType":{"id":1,"text":"Authors"},"rank":1}]}}
,{"id":70046420,"text":"ofr20131095 - 2013 - Groundwater quality in western New York, 2011","interactions":[],"lastModifiedDate":"2013-06-11T16:22:15","indexId":"ofr20131095","displayToPublicDate":"2013-06-11T00:00:00","publicationYear":"2013","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":330,"text":"Open-File Report","code":"OFR","onlineIssn":"2331-1258","printIssn":"0196-1497","active":true,"publicationSubtype":{"id":5}},"seriesNumber":"2013-1095","title":"Groundwater quality in western New York, 2011","docAbstract":"Water samples collected from 16 production wells and 15 private residential wells in western New York from July through November 2011 were analyzed to characterize the groundwater quality. Fifteen of the wells were finished in sand and gravel aquifers, and 16 were finished in bedrock aquifers. Six of the 31 wells were sampled in a previous western New York study, which was conducted in 2006. Water samples from the 2011 study were analyzed for 147 physiochemical properties and constituents that included major ions, nutrients, trace elements, radionuclides, pesticides, volatile organic compounds (VOCs), and indicator bacteria. Results of the water-quality analyses are presented in tabular form for individual wells, and summary statistics for specific constituents are presented by aquifer type. The results are compared with Federal and New York State drinking-water standards, which typically are identical. The results indicate that groundwater generally is of acceptable quality, although at 30 of the 31 wells sampled, at least one of the following constituents was detected at a concentration that exceeded current or proposed Federal or New York State drinking-water standards: pH (two samples), sodium (eight samples), sulfate (three samples), total dissolved solids (nine samples), aluminum (two samples), arsenic (one sample), iron (ten samples), manganese (twelve samples), radon-222 (sixteen samples), benzene (one sample), and total coliform bacteria (nine samples). Existing drinking-water standards for color, chloride, fluoride, nitrate, nitrite, antimony, barium, beryllium, cadmium, chromium, copper, lead, mercury, selenium, silver, thallium, zinc, gross alpha radioactivity, uranium, fecal coliform, Escherichia coli, and heterotrophic bacteria were not exceeded in any of the samples collected. None of the pesticides analyzed exceeded existing drinking-water standards.","language":"English","publisher":"U.S. Geological Survey","publisherLocation":"Reston, VA","doi":"10.3133/ofr20131095","collaboration":"Prepared in cooperation with the New York State Department of Environmental Conservation","usgsCitation":"Reddy, J.E., 2013, Groundwater quality in western New York, 2011: U.S. Geological Survey Open-File Report 2013-1095, v, 28 p., https://doi.org/10.3133/ofr20131095.","productDescription":"v, 28 p.","numberOfPages":"38","onlineOnly":"Y","additionalOnlineFiles":"N","temporalStart":"2011-07-01","temporalEnd":"2011-11-30","costCenters":[{"id":474,"text":"New York Water Science Center","active":true,"usgs":true}],"links":[{"id":273621,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/ofr20131095.gif"},{"id":273619,"type":{"id":15,"text":"Index Page"},"url":"https://pubs.usgs.gov/of/2013/1095/"},{"id":273620,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/of/2013/1095/pdf/ofr2013-1095_reddy_508.pdf"}],"country":"United States","state":"New York","geographicExtents":"{ \"type\": \"FeatureCollection\", \"features\": [ { \"type\": \"Feature\", \"properties\": {}, \"geometry\": { \"type\": \"Polygon\", \"coordinates\": [ [ [ -74.259088,40.495908 ], [ -74.259088,40.915241 ], [ -73.700272,40.915241 ], [ -73.700272,40.495908 ], [ -74.259088,40.495908 ] ] ] } } ] }","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"51b838dae4b03203c522b18a","contributors":{"authors":[{"text":"Reddy, James E. 0000-0002-6998-7267 jreddy@usgs.gov","orcid":"https://orcid.org/0000-0002-6998-7267","contributorId":1080,"corporation":false,"usgs":true,"family":"Reddy","given":"James","email":"jreddy@usgs.gov","middleInitial":"E.","affiliations":[{"id":474,"text":"New York Water Science Center","active":true,"usgs":true}],"preferred":true,"id":479642,"contributorType":{"id":1,"text":"Authors"},"rank":1}]}}
,{"id":70044460,"text":"ds688 - 2013 - Groundwater-quality data in the Cascade Range and Modoc Plateau study unit, 2010-Results from the California GAMA Program","interactions":[],"lastModifiedDate":"2013-03-07T08:44:55","indexId":"ds688","displayToPublicDate":"2013-03-07T00:00:00","publicationYear":"2013","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":310,"text":"Data Series","code":"DS","onlineIssn":"2327-638X","printIssn":"2327-0271","active":false,"publicationSubtype":{"id":5}},"seriesNumber":"688","title":"Groundwater-quality data in the Cascade Range and Modoc Plateau study unit, 2010-Results from the California GAMA Program","docAbstract":"Groundwater quality in the 39,000-square-kilometer Cascade Range and Modoc Plateau (CAMP) study unit was investigated by the U.S. Geological Survey (USGS) from July through October 2010, as part of the California State Water Resources Control Board (SWRCB) Groundwater Ambient Monitoring and Assessment (GAMA) Program’s Priority Basin Project (PBP). The GAMA PBP was developed in response to the California Groundwater Quality Monitoring Act of 2001 and is being conducted in collaboration with the SWRCB and Lawrence Livermore National Laboratory (LLNL). The CAMP study unit is the thirty-second study unit to be sampled as part of the GAMA PBP. The GAMA CAMP study was designed to provide a spatially unbiased assessment of untreated-groundwater quality in the primary aquifer system and to facilitate statistically consistent comparisons of untreated-groundwater quality throughout California. The primary aquifer system is defined as that part of the aquifer corresponding to the open or screened intervals of wells listed in the California Department of Public Health (CDPH) database for the CAMP study unit. The quality of groundwater in shallow or deep water-bearing zones may differ from the quality of groundwater in the primary aquifer system; shallow groundwater may be more vulnerable to surficial contamination. In the CAMP study unit, groundwater samples were collected from 90 wells and springs in 6 study areas (Sacramento Valley Eastside, Honey Lake Valley, Cascade Range and Modoc Plateau Low Use Basins, Shasta Valley and Mount Shasta Volcanic Area, Quaternary Volcanic Areas, and Tertiary Volcanic Areas) in Butte, Lassen, Modoc, Plumas, Shasta, Siskiyou, and Tehama Counties. Wells and springs were selected by using a spatially distributed, randomized grid-based method to provide statistical representation of the study unit (grid wells). Groundwater samples were analyzed for field water-quality indicators, organic constituents, perchlorate, inorganic constituents, radioactive constituents, and microbial indicators. Naturally occurring isotopes and dissolved noble gases also were measured to provide a dataset that will be used to help interpret the sources and ages of the sampled groundwater in subsequent reports. In total, 221 constituents were investigated for this study. Three types of quality-control samples (blanks, replicates, and matrix spikes) were collected at approximately 10 percent of the wells in the CAMP study unit, and the results for these samples were used to evaluate the quality of the data for the groundwater samples. Blanks rarely contained detectable concentrations of any constituent, suggesting that contamination from sample collection procedures was not a significant source of bias in the data for the groundwater samples. Replicate samples generally were within the limits of acceptable analytical reproducibility. Matrix-spike recoveries were within the acceptable range (70 to 130 percent) for approximately 90 percent of the compounds. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, untreated groundwater typically is treated, disinfected, and (or) blended with other waters to maintain water quality. Regulatory benchmarks apply to water that is served to the consumer, not to untreated groundwater. However, to provide some context for the results, concentrations of constituents measured in the untreated groundwater were compared with regulatory and non-regulatory health-based benchmarks established by the U.S. Environmental Protection Agency (USEPA) and CDPH, and to non-regulatory benchmarks established for aesthetic concerns by CDPH. Comparisons between data collected for this study and benchmarks for drinking water are for illustrative purposes only and are not indicative of compliance or non-compliance with those benchmarks. All organic constituents and most inorganic constituents that were detected in groundwater samples from the 90 grid wells in the CAMP study unit were detected at concentrations less than drinking-water benchmarks. Of the 148 organic constituents analyzed, 27 were detected in groundwater samples; concentrations of all detected constituents were less than regulatory and nonregulatory health-based benchmarks, and all were less than 1/10 of benchmark levels. One or more organic constituents were detected in 52 percent of the grid wells in the CAMP study unit: VOCs were detected in 30 percent, and pesticides and pesticide degradates were detected in 31 percent. Trace elements, major ions, nutrients, and radioactive constituents were sampled for at 90 grid wells in the CAMP study unit, and most detected concentrations were less than health-based benchmarks. Exceptions include three detections of arsenic greater than the USEPA maximum contaminant level (MCL-US) of 10 micrograms per liter (µg/L), two detections of boron greater than the CDPH notification level (NL-CA) of 1,000 µg/L, two detections of molybdenum greater than the USEPA lifetime health advisory level (HAL-US) of 40 µg/L, two detections of vanadium greater than the CDPH notification level (NL-CA) of 50 µg/L, one detection of nitrate, as nitrogen, greater than the MCL-US of 10 milligrams per liter (mg/L), two detections of uranium greater than the MCL-US of 30 µg/L and the MCL-CA of 20 picocuries per liter (pCi/L), one detection of radon-222 greater than the proposed MCL-US of 4,000 pCi/L, and two detections of gross alpha particle activity greater than the MCL-US of 15 pCi/L. Results for inorganic constituents with non-regulatory benchmarks set for aesthetic concerns showed that iron concentrations greater than the CDPH secondary maximum contaminant level (SMCL-CA) of 300 µg/L were detected in four grid wells. Manganese concentrations greater than the SMCL-CA of 50 µg/L were detected in nine grid wells. Chloride and TDS were detected at concentrations greater than the upper SMCL-CA benchmarks of 500 mg/L and 1,000 mg/L, respectively, in one grid well. Microbial indicators (total coliform and Escherichia coli [E. coli]) were detected in 11 percent of the 83 grid wells sampled for these analyses in the CAMP study unit. The presence of total coliform was detected in nine grid wells, and the presence of E. coli was detected in one of these same grid wells.","language":"English","publisher":"U.S. Geological Survey","publisherLocation":"Reston, VA","doi":"10.3133/ds688","collaboration":"A product of the California Groundwater Ambient Monitoring and Assessment (GAMA) Program Prepared in cooperation with the California State Water Resources Control Board","usgsCitation":"Shelton, J.L., Fram, M.S., and Belitz, K., 2013, Groundwater-quality data in the Cascade Range and Modoc Plateau study unit, 2010-Results from the California GAMA Program: U.S. Geological Survey Data Series 688, x, 126 p., https://doi.org/10.3133/ds688.","productDescription":"x, 126 p.","numberOfPages":"138","onlineOnly":"Y","additionalOnlineFiles":"N","costCenters":[{"id":154,"text":"California Water Science Center","active":true,"usgs":true}],"links":[{"id":268879,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/ds688.jpg"},{"id":268877,"type":{"id":15,"text":"Index Page"},"url":"https://pubs.usgs.gov/ds/688/"},{"id":268878,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/ds/688/pdf/ds688.pdf"}],"projection":"Albers Equal Area Conic Projection","datum":"North American Datum of 1983","country":"United States","state":"California","geographicExtents":"{ \"type\": \"FeatureCollection\", \"features\": [ { \"type\": \"Feature\", \"properties\": {}, \"geometry\": { \"type\": \"Polygon\", \"coordinates\": [ [ [ -0.01611111111111111,8.333333333333334E-4 ], [ -0.01611111111111111,0.0011111111111111111 ], [ -0.01638888888888889,0.0011111111111111111 ], [ -0.01638888888888889,8.333333333333334E-4 ], [ -0.01611111111111111,8.333333333333334E-4 ] ] ] } } ] }","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"5139b6eee4b09608cc166b0b","contributors":{"authors":[{"text":"Shelton, Jennifer L. 0000-0001-8508-0270 jshelton@usgs.gov","orcid":"https://orcid.org/0000-0001-8508-0270","contributorId":1155,"corporation":false,"usgs":true,"family":"Shelton","given":"Jennifer","email":"jshelton@usgs.gov","middleInitial":"L.","affiliations":[{"id":154,"text":"California Water Science Center","active":true,"usgs":true}],"preferred":true,"id":475661,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Fram, Miranda S. 0000-0002-6337-059X mfram@usgs.gov","orcid":"https://orcid.org/0000-0002-6337-059X","contributorId":1156,"corporation":false,"usgs":true,"family":"Fram","given":"Miranda","email":"mfram@usgs.gov","middleInitial":"S.","affiliations":[{"id":154,"text":"California Water Science Center","active":true,"usgs":true}],"preferred":true,"id":475662,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Belitz, Kenneth 0000-0003-4481-2345 kbelitz@usgs.gov","orcid":"https://orcid.org/0000-0003-4481-2345","contributorId":442,"corporation":false,"usgs":true,"family":"Belitz","given":"Kenneth","email":"kbelitz@usgs.gov","affiliations":[{"id":27111,"text":"National Water Quality Program","active":true,"usgs":true},{"id":503,"text":"Office of Water Quality","active":true,"usgs":true},{"id":376,"text":"Massachusetts Water Science Center","active":true,"usgs":true},{"id":466,"text":"New England Water Science Center","active":true,"usgs":true},{"id":451,"text":"National Water Quality Assessment Program","active":true,"usgs":true}],"preferred":true,"id":475660,"contributorType":{"id":1,"text":"Authors"},"rank":3}]}}
,{"id":70042985,"text":"ofr20131021 - 2013 - Groundwater quality in the Mohawk River Basin, New York, 2011","interactions":[],"lastModifiedDate":"2013-01-29T18:11:14","indexId":"ofr20131021","displayToPublicDate":"2013-01-29T00:00:00","publicationYear":"2013","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":330,"text":"Open-File Report","code":"OFR","onlineIssn":"2331-1258","printIssn":"0196-1497","active":true,"publicationSubtype":{"id":5}},"seriesNumber":"2013-1021","title":"Groundwater quality in the Mohawk River Basin, New York, 2011","docAbstract":"Water samples were collected from 21 production and domestic wells in the Mohawk River Basin in New York in July 2011 to characterize groundwater quality in the basin. The samples were collected and processed using standard U.S. Geological Survey procedures and were analyzed for 148 physiochemical properties and constituents, including dissolved gases, major ions, nutrients, trace elements, pesticides, volatile organic compounds (VOCs), radionuclides, and indicator bacteria. The Mohawk River Basin covers 3,500 square miles in New York and is underlain by shale, sandstone, carbonate, and crystalline bedrock. The bedrock is overlain by till in much of the basin, but surficial deposits of saturated sand and gravel are present in some areas. Nine of the wells sampled in the Mohawk River Basin are completed in sand and gravel deposits, and 12 are completed in bedrock. Groundwater in the Mohawk River Basin was typically neutral or slightly basic; the water typically was very hard. Bicarbonate, chloride, calcium, and sodium were the major ions with the greatest median concentrations; the dominant nutrient was nitrate. Methane was detected in 15 samples. Strontium, iron, barium, boron, and manganese were the trace elements with the highest median concentrations. Four pesticides, all herbicides or their degradates, were detected in four samples at trace levels; three VOCs, including chloroform and two solvents, were detected in four samples. The greatest radon-222 activity, 2,300 picocuries per liter, was measured in a sample from a bedrock well, but the median radon activity was higher in samples from sand and gravel wells than in samples from bedrock wells. Coliform bacteria were detected in five samples with a maximum of 92 colony-forming units per 100 milliliters. Water quality in the Mohawk River Basin is generally good, but concentrations of some constituents equaled or exceeded current or proposed Federal or New York State drinking-water standards. The standards exceeded are color (1 sample), pH (1 sample), sodium (9 samples), chloride (1 sample), sulfate (2 samples), dissolved solids (7 samples), aluminum (3 samples), iron (8 samples), manganese (6 samples), radon-222 (10 samples), and bacteria (5 samples). Fecal coliform bacteria and Escherichia coli (E. coli) were each detected in one sample. Concentrations of fluoride, nitrate, nitrite, antimony, arsenic, barium, beryllium, cadmium, chromium, copper, lead, mercury, selenium, silver, thallium, zinc, and uranium, and gross alpha activities, did not exceed existing drinking-water standards in any of the samples collected. Methane concentrations in two samples were greater than 28 milligrams per liter, and the maximum measured concentration was 44.3 milligrams per liter.","language":"English","publisher":"U.S. Geological Survey","publisherLocation":"Reston, VA","doi":"10.3133/ofr20131021","collaboration":"Prepared in cooperation with the New York State Department of Environmental Conservation","usgsCitation":"Nystrom, E.A., and Scott, T., 2013, Groundwater quality in the Mohawk River Basin, New York, 2011: U.S. Geological Survey Open-File Report 2013-1021, vi, 43 p., https://doi.org/10.3133/ofr20131021.","productDescription":"vi, 43 p.","startPage":"i","endPage":"43","numberOfPages":"52","onlineOnly":"Y","additionalOnlineFiles":"N","temporalStart":"2011-01-01","temporalEnd":"2011-12-31","costCenters":[{"id":474,"text":"New York Water Science Center","active":true,"usgs":true}],"links":[{"id":266730,"type":{"id":15,"text":"Index Page"},"url":"https://pubs.usgs.gov/of/2013/1021/"},{"id":266732,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/ofr_2013_1021.gif"},{"id":266731,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/of/2013/1021/pdf/OFR2013-1021_nystrom_508.pdf"}],"country":"United States","state":"New York","otherGeospatial":"Mohawk River Basin","geographicExtents":"{ \"type\": \"FeatureCollection\", \"features\": [ { \"type\": \"Feature\", \"properties\": {}, \"geometry\": { \"type\": \"Polygon\", \"coordinates\": [ [ [ -79.76,40.48 ], [ -79.76,45.02 ], [ -71.86,45.02 ], [ -71.86,40.48 ], [ -79.76,40.48 ] ] ] } } ] }","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"5108ef6ee4b0d965cd9f22b0","contributors":{"authors":[{"text":"Nystrom, Elizabeth A. 0000-0002-0886-3439 nystrom@usgs.gov","orcid":"https://orcid.org/0000-0002-0886-3439","contributorId":1072,"corporation":false,"usgs":true,"family":"Nystrom","given":"Elizabeth","email":"nystrom@usgs.gov","middleInitial":"A.","affiliations":[{"id":474,"text":"New York Water Science Center","active":true,"usgs":true}],"preferred":true,"id":472738,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Scott, Tia-Marie 0000-0002-5677-0544 tia-mariescott@usgs.gov","orcid":"https://orcid.org/0000-0002-5677-0544","contributorId":5122,"corporation":false,"usgs":true,"family":"Scott","given":"Tia-Marie","email":"tia-mariescott@usgs.gov","affiliations":[{"id":474,"text":"New York Water Science Center","active":true,"usgs":true}],"preferred":true,"id":472739,"contributorType":{"id":1,"text":"Authors"},"rank":2}]}}
,{"id":70042813,"text":"sir20125253 - 2013 - Groundwater quality and the relation between pH values and occurrence of trace elements and radionuclides in water samples collected from private wells in part of the Kickapoo Tribe of Oklahoma Jurisdictional Area, central Oklahoma, 2011","interactions":[],"lastModifiedDate":"2013-01-24T13:52:51","indexId":"sir20125253","displayToPublicDate":"2013-01-24T00:00:00","publicationYear":"2013","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":334,"text":"Scientific Investigations Report","code":"SIR","onlineIssn":"2328-0328","printIssn":"2328-031X","active":true,"publicationSubtype":{"id":5}},"seriesNumber":"2012-5253","title":"Groundwater quality and the relation between pH values and occurrence of trace elements and radionuclides in water samples collected from private wells in part of the Kickapoo Tribe of Oklahoma Jurisdictional Area, central Oklahoma, 2011","docAbstract":"From 1999 to 2007, the Indian Health Service reported that gross alpha-particle activities and concentrations of uranium exceeded the Maximum Contaminant Levels for public drinking-water supplies in water samples from six private wells and two test wells in a rural residential neighborhood in the Kickapoo Tribe of Oklahoma Jurisdictional Area, in central Oklahoma. Residents in this rural area use groundwater from Quaternary-aged terrace deposits and the Permian-aged Garber-Wellington aquifer for domestic purposes. Uranium and other trace elements, specifically arsenic, chromium, and selenium, occur naturally in rocks composing the Garber-Wellington aquifer and in low concentrations in groundwater throughout its extent. Previous studies have shown that pH values above 8.0 from cation-exchange processes in the aquifer cause selected metals such as arsenic, chromium, selenium, and uranium to desorb (if present) from mineral surfaces and become mobile in water. On the basis of this information, the U.S. Geological Survey, in cooperation with the Kickapoo Tribe of Oklahoma, conducted a study in 2011 to describe the occurrence of selected trace elements and radionuclides in groundwater and to determine if pH could be used as a surrogate for laboratory analysis to quickly and inexpensively identify wells that might contain high concentrations of uranium and other trace elements. The pH and specific conductance of groundwater from 59 private wells were measured in the field in an area of about 18 square miles in Lincoln and Pottawatomie Counties. Twenty of the 59 wells also were sampled for dissolved concentrations of major ions, trace elements, gross alpha-particle and gross beta-particle activities, uranium, radium-226, radium-228, and radon-222 gas. Arsenic concentrations exceeded the Maximum Contaminant Level of 10 micrograms per liter in one sample having a concentration of 24.7 micrograms per liter. Selenium concentrations exceeded the Maximum Contaminant Level of 50 micrograms per liter in one sample having a concentration of 147 micrograms per liter. Both samples had alkaline pH values, 8.0 and 8.4, respectively. Uranium concentrations ranged from 0.02 to 383 micrograms per liter with 5 of 20 samples exceeding the Maximum Contaminant Level of 30 micrograms per liter; the five wells with uranium concentrations exceeding 30 micrograms per liter had pH values ranging from 8.0 to 8.5. Concentrations of uranium and radon-222 and gross alpha-particle activity showed a positive relation to pH, with the highest concentrations and activity in samples having pH values of 8.0 or above. The groundwater samples contained dissolved oxygen and high concentrations of bicarbonate; these characteristics are also factors in increasing uranium solubility.  Concentrations of radium-226 and radium-228 (combined) ranged from 0.03 to 1.7 picocuries per liter, with a median concentration of 0.45 picocuries per liter for all samples. Radon-222 concentrations ranged from 95 to 3,600 picocuries per liter with a median concentration of 261 picocuries per liter. Eight samples having pH values ranging from 8.0 to 8.7 exceeded the proposed Maximum Contaminant Level of 300 picocuries per liter for radon-222. Eight samples exceeded the 15 picocuries per liter Maximum Contaminant Level for gross alpha-particle activity at 72 hours (after sample collection) and at 30 days (after the initial count); those samples had pH values ranging from 8.0 to 8.5. Gross beta-particle activity increased in 15 of 21 samples during the interval from 72 hours to 30 days. The increase in gross beta-particle activity over time probably was caused by the ingrowth and decay of uranium daughter products that emit beta particles. Water-quality data collected for this study indicate that pH values above 8.0 are associated with potentially high concentrations of uranium and radon-222 and high gross alpha-particle activity in the study area. High pH values also are associated with potentially high concentrations of arsenic, chromium, and selenium in groundwater when these elements occur in the aquifer matrix along groundwater-flow paths.","language":"English","publisher":"U.S. Geological Survey","publisherLocation":"Reston, VA","doi":"10.3133/sir20125253","collaboration":"Prepared in cooperation with the Kickapoo Tribe of Oklahoma","usgsCitation":"Becker, C., 2013, Groundwater quality and the relation between pH values and occurrence of trace elements and radionuclides in water samples collected from private wells in part of the Kickapoo Tribe of Oklahoma Jurisdictional Area, central Oklahoma, 2011: U.S. Geological Survey Scientific Investigations Report 2012-5253, vii, 47 p., https://doi.org/10.3133/sir20125253.","productDescription":"vii, 47 p.","numberOfPages":"60","costCenters":[{"id":516,"text":"Oklahoma Water Science Center","active":true,"usgs":true}],"links":[{"id":266417,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/sir_2012_5253.gif"},{"id":266416,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/sir/2012/5253/SIR2012-5253.pdf"},{"id":266415,"type":{"id":15,"text":"Index Page"},"url":"https://pubs.usgs.gov/sir/2012/5253/"}],"scale":"100000","projection":"Albers Equal Area Conic projection","datum":"North American Datum, 1983","country":"United States","state":"Oklahoma","otherGeospatial":"Kickapoo Tribe Of Oklahoma Jurisdictional Area","geographicExtents":"{ \"type\": \"FeatureCollection\", \"features\": [ { \"type\": \"Feature\", \"properties\": {}, \"geometry\": { \"type\": \"Polygon\", \"coordinates\": [ [ [ -98.00,35.83 ], [ -98.00,36.16 ], [ -95.67,36.16 ], [ -95.67,35.83 ], [ -98.00,35.83 ] ] ] } } ] }","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"51026617e4b0d4f5ea817bf9","contributors":{"authors":[{"text":"Becker, Carol 0000-0001-6652-4542 cjbecker@usgs.gov","orcid":"https://orcid.org/0000-0001-6652-4542","contributorId":2489,"corporation":false,"usgs":true,"family":"Becker","given":"Carol","email":"cjbecker@usgs.gov","affiliations":[{"id":516,"text":"Oklahoma Water Science Center","active":true,"usgs":true}],"preferred":true,"id":472319,"contributorType":{"id":1,"text":"Authors"},"rank":1}]}}
,{"id":70041307,"text":"sir20125156 - 2012 - Estimated probability of arsenic in groundwater from bedrock aquifers in New Hampshire, 2011","interactions":[],"lastModifiedDate":"2016-08-10T15:53:54","indexId":"sir20125156","displayToPublicDate":"2012-12-04T00:00:00","publicationYear":"2012","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":334,"text":"Scientific Investigations Report","code":"SIR","onlineIssn":"2328-0328","printIssn":"2328-031X","active":true,"publicationSubtype":{"id":5}},"seriesNumber":"2012-5156","title":"Estimated probability of arsenic in groundwater from bedrock aquifers in New Hampshire, 2011","docAbstract":"<p>Probabilities of arsenic occurrence in groundwater from bedrock aquifers at concentrations of 1, 5, and 10 micrograms per liter (&micro;g/L) were estimated during 2011 using multivariate logistic regression. These estimates were developed for use by the New Hampshire Environmental Public Health Tracking Program. About 39 percent of New Hampshire bedrock groundwater was identified as having at least a 50 percent chance of containing an arsenic concentration greater than or equal to 1 &micro;g/L. This compares to about 7 percent of New Hampshire bedrock groundwater having at least a 50 percent chance of containing an arsenic concentration equaling or exceeding 5 &micro;g/L and about 5 percent of the State having at least a 50 percent chance for its bedrock groundwater to contain concentrations at or above 10 &micro;g/L. The southeastern counties of Merrimack, Strafford, Hillsborough, and Rockingham have the greatest potential for having arsenic concentrations above 5 and 10 &micro;g/L in bedrock groundwater.</p>\n<p>Significant predictors of arsenic in groundwater from bedrock aquifers for all three thresholds analyzed included geologic, geochemical, land use, hydrologic, topographic, and demographic factors. Among the three thresholds evaluated, there were some differences in explanatory variables, but many variables were the same. More than 250 individual predictor variables were assembled for this study and tested as potential predictor variables for the models. More than 1,700 individual measurements of arsenic concentration from a combination of public and private water-supply wells served as the dependent (or predicted) variable in the models.</p>\n<p>The statewide maps generated by the probability models are not designed to predict arsenic concentration in any single well, but they are expected to provide useful information in areas of the State that currently contain little to no data on arsenic concentration. They also may aid in resource decision making, in determining potential risk for private wells, and in ecological-level analysis of disease outcomes. The approach for modeling arsenic in groundwater could also be applied to other environmental contaminants that have potential implications for human health, such as uranium, radon, fluoride, manganese, volatile organic compounds, nitrate, and bacteria.</p>","language":"English","publisher":"U.S. Geological Survey","publisherLocation":"Reston, VA","doi":"10.3133/sir20125156","collaboration":"Prepared in cooperation with the New Hampshire Department of Health and Human Services and the New Hampshire Department of Environmental Services","usgsCitation":"Ayotte, J., Cahillane, M., Hayes, L., and Robinson, K.W., 2012, Estimated probability of arsenic in groundwater from bedrock aquifers in New Hampshire, 2011: U.S. Geological Survey Scientific Investigations Report 2012-5156, Report: vi, 25 p.; Geospatial Data, https://doi.org/10.3133/sir20125156.","productDescription":"Report: vi, 25 p.; Geospatial 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England Water Science Center","active":true,"usgs":true},{"id":466,"text":"New England Water Science Center","active":true,"usgs":true}],"preferred":true,"id":469510,"contributorType":{"id":1,"text":"Authors"},"rank":3},{"text":"Robinson, Keith W. kwrobins@usgs.gov","contributorId":2969,"corporation":false,"usgs":true,"family":"Robinson","given":"Keith","email":"kwrobins@usgs.gov","middleInitial":"W.","affiliations":[],"preferred":true,"id":469511,"contributorType":{"id":1,"text":"Authors"},"rank":4}]}}
,{"id":70040977,"text":"sir20125139 - 2012 - Evaluation of volatile organic compound (VOC) blank data and application of study reporting levels to groundwater data collected for the California GAMA Priority Basin Project, May 2004 through September 2010","interactions":[],"lastModifiedDate":"2012-11-27T20:00:08","indexId":"sir20125139","displayToPublicDate":"2012-11-27T00:00:00","publicationYear":"2012","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":334,"text":"Scientific Investigations Report","code":"SIR","onlineIssn":"2328-0328","printIssn":"2328-031X","active":true,"publicationSubtype":{"id":5}},"seriesNumber":"2012-5139","title":"Evaluation of volatile organic compound (VOC) blank data and application of study reporting levels to groundwater data collected for the California GAMA Priority Basin Project, May 2004 through September 2010","docAbstract":"Volatile organic compounds (VOCs) were analyzed in quality-control samples collected for the California Groundwater Ambient Monitoring and Assessment (GAMA) Program Priority Basin Project. From May 2004 through September 2010, a total of 2,026 groundwater samples, 211 field blanks, and 109 source-solution blanks were collected and analyzed for concentrations of 85 VOCs. Results from analyses of these field and source-solution blanks and of 2,411 laboratory instrument blanks during the same time period were used to assess the quality of data for the 2,026 groundwater samples. Eighteen VOCs were detected in field blanks or source-solution blanks: acetone, benzene, bromodichloromethane, 2-butanone, carbon disulfide, chloroform, 1,1-dichloroethene, dichloromethane, ethylbenzene, tetrachloroethene, styrene, tetrahydrofuran, toluene, trichloroethene, trichlorofluoromethane, 1,2,4-trimethylbenzene, <i>m</i>- and <i>p</i>-xylenes, and <i>o</i>-xylene.\n\nThe objective of the evaluation of the VOC-blank data was to determine if study reporting levels (SRLs) were needed for any of the VOCs detected in blanks to ensure the quality of the data from groundwater samples. An SRL is equivalent to a raised reporting level that is used in place of the reporting level used by the analyzing laboratory [long‑term method detection level (LT-MDL) or laboratory reporting level (LRL)] to reduce the probability of reporting false-positive detections. Evaluation of VOC-blank data was done in three stages: (1) identification of a set of representative quality‑control field blanks (QCFBs) to be used for calculation of SRLs and identification of VOCs amenable to the SRL approach, (2) evaluation of potential sources of contamination to blanks and groundwater samples by VOCs detected in field blanks, and (3) selection of appropriate SRLs from among four potential SRLs for VOCs detected in field blanks and application of those SRLs to the groundwater data. An important conclusion from this study is that to ensure the quality of the data from groundwater samples, it was necessary to apply different methods of determining SRLs from field blank data to different VOCs, rather than use the same method for all VOCs.\n\nFour potential SRL values were defined by using three approaches: two values were defined by using a binomial probability method based on one-sided, nonparametric upper confidence limits, one was defined as equal to the maximum concentration detected in the field blanks, and one was defined as equal to the maximum laboratory method detection level used during the period when samples were collected for the project. The differences in detection frequencies and concentrations among different types of blanks (laboratory instrument blanks, source-solution blanks, and field blanks collected with three different sampling equipment configurations) and groundwater samples were used to infer the sources and mechanisms of contamination for each VOC detection in field blanks. Other chemical data for the groundwater samples (oxidation-reduction state, co-occurrence of VOCs, groundwater age) and ancillary information about the well sites (land use, presence of known sources of contamination) were used to evaluate whether the patterns of detections of VOCs in groundwater samples before and after application of potential SRLs were plausible. On this basis, the appropriate SRL was selected for each VOC that was determined to require an SRL.\n\nThe SRLs for ethylbenzene [0.06 microgram per liter (μg/L)], <i>m</i>- and <i>p</i>-xylenes (0.33 μg/L), <i>o</i>-xylene (0.12 μg/L), toluene (0.69 μg/L), and 1,2,4-trimethylbenzene (0.56 μg/L) corresponded to the highest concentrations detected in the QCFBs and were selected because they resulted in the most censoring of groundwater data. Comparisons of hydrocarbon ratios in groundwater samples and blanks and comparisons between detection frequencies of the five hydrocarbons in groundwater samples and different types of blanks suggested three dominant sources of contamination that affected groundwater samples and blanks: (1) ethylbenzene, <i>m</i>- and <i>p</i>-xylenes, <i>o</i>-xylene, and toluene from fuel or exhaust components sorbed onto sampling lines, (2) toluene from vials and the source blank water, and (3) 1,2,4-trimethylbenzene from materials used for collection of samples for radon-222 analysis.","language":"English","publisher":"U.S. Geological Survey","publisherLocation":"Reston, VA","doi":"10.3133/sir20125139","collaboration":"A product of the California Groundwater Ambient Monitoring and Assessment (GAMA) Program Prepared in cooperation with the California State Water Resources Control Board","usgsCitation":"Fram, M.S., Olsen, L., and Belitz, K., 2012, Evaluation of volatile organic compound (VOC) blank data and application of study reporting levels to groundwater data collected for the California GAMA Priority Basin Project, May 2004 through September 2010: U.S. Geological Survey Scientific Investigations Report 2012-5139, viii, 94 p.; col. ill.; maps (col.), https://doi.org/10.3133/sir20125139.","productDescription":"viii, 94 p.; col. ill.; maps (col.)","startPage":"i","endPage":"94","numberOfPages":"106","additionalOnlineFiles":"N","temporalStart":"2004-05-01","temporalEnd":"2010-09-30","costCenters":[{"id":154,"text":"California Water Science Center","active":true,"usgs":true}],"links":[{"id":263432,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/sir_2012_5139.jpg"},{"id":263430,"type":{"id":15,"text":"Index Page"},"url":"https://pubs.usgs.gov/sir/2012/5139/"},{"id":263431,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/sir/2012/5139/pdf/sir20125139.pdf"}],"country":"United States","state":"California","geographicExtents":"{ \"type\": \"FeatureCollection\", \"features\": [ { \"type\": \"Feature\", \"properties\": {}, \"geometry\": { \"type\": \"Polygon\", \"coordinates\": [ [ [ -124.41,32.53 ], [ -124.41,42.01 ], [ -114.13,42.01 ], [ -114.13,32.53 ], [ -124.41,32.53 ] ] ] } } ] }","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"50dca8b1e4b0d55926e3ec23","contributors":{"authors":[{"text":"Fram, Miranda S. 0000-0002-6337-059X mfram@usgs.gov","orcid":"https://orcid.org/0000-0002-6337-059X","contributorId":1156,"corporation":false,"usgs":true,"family":"Fram","given":"Miranda","email":"mfram@usgs.gov","middleInitial":"S.","affiliations":[{"id":154,"text":"California Water Science Center","active":true,"usgs":true}],"preferred":true,"id":469184,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Olsen, Lisa D. ldolsen@usgs.gov","contributorId":2707,"corporation":false,"usgs":true,"family":"Olsen","given":"Lisa D.","email":"ldolsen@usgs.gov","affiliations":[{"id":509,"text":"Office of the Associate Director for Water","active":true,"usgs":true}],"preferred":true,"id":469185,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Belitz, Kenneth 0000-0003-4481-2345 kbelitz@usgs.gov","orcid":"https://orcid.org/0000-0003-4481-2345","contributorId":442,"corporation":false,"usgs":true,"family":"Belitz","given":"Kenneth","email":"kbelitz@usgs.gov","affiliations":[{"id":27111,"text":"National Water Quality Program","active":true,"usgs":true},{"id":503,"text":"Office of Water Quality","active":true,"usgs":true},{"id":451,"text":"National Water Quality Assessment Program","active":true,"usgs":true},{"id":376,"text":"Massachusetts Water Science Center","active":true,"usgs":true},{"id":466,"text":"New England Water Science Center","active":true,"usgs":true}],"preferred":true,"id":469183,"contributorType":{"id":1,"text":"Authors"},"rank":3}]}}
,{"id":70040809,"text":"sir20125186 - 2012 - Groundwater quality in West Virginia, 1993-2008","interactions":[],"lastModifiedDate":"2012-11-19T10:45:15","indexId":"sir20125186","displayToPublicDate":"2012-11-19T00:00:00","publicationYear":"2012","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":334,"text":"Scientific Investigations Report","code":"SIR","onlineIssn":"2328-0328","printIssn":"2328-031X","active":true,"publicationSubtype":{"id":5}},"seriesNumber":"2012-5186","title":"Groundwater quality in West Virginia, 1993-2008","docAbstract":"Approximately 42 percent of all West Virginians rely on groundwater for their domestic water supply. However, prior to 2008, the quality of the West Virginia’s groundwater resource was largely unknown. The need for a statewide assessment of groundwater quality prompted the U.S. Geological Survey (USGS), in cooperation with West Virginia Department of Environmental Protection (WVDEP), Division of Water and Waste Management, to develop an ambient groundwater-quality monitoring program.\n\nThe USGS West Virginia Water Science Center sampled 300 wells, of which 80 percent were public-supply wells, over a 10-year period, 1999–2008. Sites for this statewide ambient groundwater-quality monitoring program were selected to provide wide areal coverage and to represent a variety of environmental settings. The resulting 300 samples were supplemented with data from a related monitoring network of 24 wells and springs.\n\nAll samples were analyzed for field measurements (water temperature, pH, specific conductance, and dissolved oxygen), major ions, trace elements, nutrients, volatile organic compounds, fecal indicator bacteria, and radon-222. Sub-sets of samples were analyzed for pesticides or semi-volatile organic compounds; site selection was based on local land use.\n\nSamples were grouped for comparison by geologic age of the aquifer, Groups included Cambrian, Ordovician, Silurian, Devonian, Pennsylvanian, Permian, and Quaternary aquifers. A comparison of samples indicated that geologic age of the aquifer was the largest contributor to variability in groundwater quality.\n\nThis study did not attempt to characterize drinking water provided through public water systems. All samples were of raw, untreated groundwater. Drinking-water criteria apply to water that is served to the public, not to raw water. However, drinking water criteria, including U.S. Environmental Protection Agency (USEPA) maximum contaminant level (MCL), non-enforceable secondary maximum contaminant level (SMCL), non-enforceable proposed MCL, or non-enforceable advisory health-based screening level (HBSL), were used as benchmarks against which to compare analytical results.\n\nConstituent concentrations were less than the MCLs in most samples. However, some samples exceeded non-enforceable SMCLs, proposed MCLs, or advisory HBSLs. Radon-222 concentrations exceeded the proposed MCL of 300 pCi/L in 45 percent of samples, and iron concentrations exceeded the SMCL of 300 µg/L in 57 percent of samples. Manganese concentrations were greater than the SMCL (50 µg/L) in 62 percent of samples and greater than the HBSL (300 µg/L) in 25 percent of the samples. Other sampled constituents, including organic compounds and trace elements, exceeded drinking-water criteria at much lower frequencies.\n\nThe radon-222 median concentrations in samples from Cambrian, Ordovician, Silurian, Permian, and Quaternary aquifers exceeded the proposed 300 pCi/L MCL. Although median radon concentrations for wells in Devonian, Mississippian, and Pennsylvanian aquifers were less than the proposed MCL, radon concentrations greater than the proposed MCL were measured in samples from aquifers of all geologic ages.\n\nThe median iron concentrations for samples from Devonian and Pennsylvanian aquifers were greater than the 300 µg/L SMCL. Iron concentrations exceeded the SMCL in aquifers of all geologic ages, except Cambrian. Median concentrations of manganese exceeded the SMCL in samples from Devonian, Pennsylvanian, and Quaternary aquifers. As with iron, manganese concentrations were found to exceed the SMCL in at least one sample from aquifers of all geologic ages, except Cambrian.\n\nPesticides were detected most frequently and in higher concentrations in limestone-dominated areas. Most of West Virginia’s agriculture is concentrated in those areas.\n\nThis study, the most comprehensive assessment of West Virginia groundwater quality to date, indicates the water quality of West Virginia’s groundwater is generally good; in the majority of cases raw-water samples met primary drinking water-criteria. However, some constituents, notably iron and manganese, exceeded the secondary drinking criteria in more than half the samples.","language":"English","publisher":"U.S. Geological Survey","publisherLocation":"Reston, VA","doi":"10.3133/sir20125186","collaboration":"Prepared in cooperation with the West Virginia Department of Environmental Protection, Division of Water and Waste Management","usgsCitation":"Chambers, D., Kozar, M.D., White, J.S., and Paybins, K.S., 2012, Groundwater quality in West Virginia, 1993-2008: U.S. Geological Survey Scientific Investigations Report 2012-5186, viii, 47 p.; col. ill.; maps (col.), https://doi.org/10.3133/sir20125186.","productDescription":"viii, 47 p.; col. ill.; maps (col.)","startPage":"i","endPage":"47","numberOfPages":"60","onlineOnly":"Y","additionalOnlineFiles":"N","temporalStart":"1993-01-01","temporalEnd":"2008-12-31","costCenters":[{"id":642,"text":"West Virginia Water Science Center","active":true,"usgs":true}],"links":[{"id":263260,"type":{"id":15,"text":"Index Page"},"url":"https://pubs.usgs.gov/sir/2012/5186/"},{"id":263261,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/sir/2012/5186/pdf/sir2012-5186.pdf"},{"id":263262,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/sir_2012_5186.png"}],"country":"United States","state":"West Virginia","geographicExtents":"{ \"type\": \"FeatureCollection\", \"features\": [ { \"type\": \"Feature\", \"properties\": {}, \"geometry\": { \"type\": \"Polygon\", \"coordinates\": [ [ [ -82.64,37.2 ], [ -82.64,40.64 ], [ -77.72,40.64 ], [ -77.72,37.2 ], [ -82.64,37.2 ] ] ] } } ] }","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"50abfb7ce4b0afbc75eb980c","contributors":{"authors":[{"text":"Chambers, Douglas B. 0000-0002-5275-5427 dbchambe@usgs.gov","orcid":"https://orcid.org/0000-0002-5275-5427","contributorId":2520,"corporation":false,"usgs":true,"family":"Chambers","given":"Douglas B.","email":"dbchambe@usgs.gov","affiliations":[{"id":642,"text":"West Virginia Water Science Center","active":true,"usgs":true}],"preferred":true,"id":469068,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Kozar, Mark D. 0000-0001-7755-7657 mdkozar@usgs.gov","orcid":"https://orcid.org/0000-0001-7755-7657","contributorId":1963,"corporation":false,"usgs":true,"family":"Kozar","given":"Mark","email":"mdkozar@usgs.gov","middleInitial":"D.","affiliations":[{"id":37280,"text":"Virginia and West Virginia Water Science Center ","active":true,"usgs":true}],"preferred":true,"id":469067,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"White, Jeremy S. 0000-0002-1501-1074 jswhite@usgs.gov","orcid":"https://orcid.org/0000-0002-1501-1074","contributorId":3905,"corporation":false,"usgs":true,"family":"White","given":"Jeremy","email":"jswhite@usgs.gov","middleInitial":"S.","affiliations":[{"id":642,"text":"West Virginia Water Science Center","active":true,"usgs":true}],"preferred":false,"id":469070,"contributorType":{"id":1,"text":"Authors"},"rank":3},{"text":"Paybins, Katherine S. 0000-0002-3967-5043 kpaybins@usgs.gov","orcid":"https://orcid.org/0000-0002-3967-5043","contributorId":2805,"corporation":false,"usgs":true,"family":"Paybins","given":"Katherine","email":"kpaybins@usgs.gov","middleInitial":"S.","affiliations":[{"id":642,"text":"West Virginia Water Science Center","active":true,"usgs":true}],"preferred":true,"id":469069,"contributorType":{"id":1,"text":"Authors"},"rank":4}]}}
,{"id":70040485,"text":"ofr20121212 - 2012 - Surface-water radon-222 distribution along the west-central Florida shelf","interactions":[],"lastModifiedDate":"2025-05-13T18:14:42.538922","indexId":"ofr20121212","displayToPublicDate":"2012-10-25T00:00:00","publicationYear":"2012","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":330,"text":"Open-File Report","code":"OFR","onlineIssn":"2331-1258","printIssn":"0196-1497","active":true,"publicationSubtype":{"id":5}},"seriesNumber":"2012-1212","title":"Surface-water radon-222 distribution along the west-central Florida shelf","docAbstract":"In February 2009 and August 2009, the spatial distribution of radon-222 in surface water was mapped along the west-central Florida shelf as collaboration between the Response of Florida Shelf Ecosystems to Climate Change project and a U.S. Geological Survey Mendenhall Research Fellowship project. This report summarizes the surface distribution of radon-222 from two cruises and evaluates potential physical controls on radon-222 fluxes. Radon-222 is an inert gas produced overwhelmingly in sediment and has a short half-life of 3.8 days; activities in surface water ranged between 30 and 170 becquerels per cubic meter. Overall, radon-222 activities were enriched in nearshore surface waters relative to offshore waters. Dilution in offshore waters is expected to be the cause of the low offshore activities. While thermal stratification of the water column during the August survey may explain higher radon-222 activities relative to the February survey, radon-222 activity and integrated surface-water inventories decreased exponentially from the shoreline during both cruises. By estimating radon-222 evasion by wind from nearby buoy data and accounting for internal production from dissolved radium-226, its radiogenic long-lived parent, a simple one-dimensional model was implemented to determine the role that offshore mixing, benthic influx, and decay have on the distribution of excess radon-222 inventories along the west Florida shelf. For multiple statistically based boundary condition scenarios (first quartile, median, third quartile, and maximum radon-222 inshore of 5 kilometers), the cross-shelf mixing rates and average nearshore submarine groundwater discharge (SGD) rates varied from 100.38 to 10-3.4 square kilometers per day and 0.00 to 1.70 centimeters per day, respectively. This dataset and modeling provide the first attempt to assess cross-shelf mixing and SGD on such a large spatial scale. Such estimates help scale up SGD rates that are often made at 1- to 10-meter resolution to a coarser but more regionally applicable scale of 1- to 10-kilometer resolution. More stringent analyses and model evaluation are required, but results and analyses presented in this report provide the foundation for conducting a more rigorous statistical assessment.","language":"English","publisher":"U.S. Geological Survey","publisherLocation":"Reston, VA","doi":"10.3133/ofr20121212","usgsCitation":"Smith, C.G., and Robbins, L.L., 2012, Surface-water radon-222 distribution along the west-central Florida shelf: U.S. Geological Survey Open-File Report 2012-1212, ii, 22 p., https://doi.org/10.3133/ofr20121212.","productDescription":"ii, 22 p.","numberOfPages":"26","onlineOnly":"Y","costCenters":[{"id":574,"text":"St. Petersburg Coastal and Marine Science Center","active":true,"usgs":true}],"links":[{"id":262797,"rank":1,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.er.usgs.gov/thumbnails/ofr_2012_1212.jpg"},{"id":262791,"rank":3,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/of/2012/1212/pdf/OFR-2012-1212-hi-res.pdf","linkFileType":{"id":1,"text":"pdf"}},{"id":262790,"rank":2,"type":{"id":15,"text":"Index Page"},"url":"https://pubs.usgs.gov/of/2012/1212/","linkFileType":{"id":5,"text":"html"}}],"country":"United States","state":"Florida","geographicExtents":"{ \"type\": \"FeatureCollection\", \"features\": [ { \"type\": \"Feature\", \"properties\": {}, \"geometry\": { \"type\": \"Polygon\", \"coordinates\": [ [ [ -84.000000,25.000000 ], [ -84.000000,30.000000 ], [ -81.000000,30.000000 ], [ -81.000000,25.000000 ], [ -84.000000,25.000000 ] ] ] } } ] }","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"508a51d9e4b07fc5688448c1","contributors":{"authors":[{"text":"Smith, Christopher G. 0000-0002-8075-4763 cgsmith@usgs.gov","orcid":"https://orcid.org/0000-0002-8075-4763","contributorId":3410,"corporation":false,"usgs":true,"family":"Smith","given":"Christopher","email":"cgsmith@usgs.gov","middleInitial":"G.","affiliations":[{"id":186,"text":"Coastal and Marine Geology Program","active":true,"usgs":true},{"id":574,"text":"St. Petersburg Coastal and Marine Science Center","active":true,"usgs":true},{"id":24708,"text":"Lower Mississippi-Gulf Water Science Center","active":true,"usgs":true}],"preferred":true,"id":468423,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Robbins, L. L.","contributorId":71156,"corporation":false,"usgs":true,"family":"Robbins","given":"L.","email":"","middleInitial":"L.","affiliations":[],"preferred":false,"id":468422,"contributorType":{"id":1,"text":"Authors"},"rank":2}]}}
,{"id":70040150,"text":"70040150 - 2012 - Sources of fecal indicator bacteria to groundwater, Malibu Lagoon and the near-shore ocean, Malibu, California, USA","interactions":[],"lastModifiedDate":"2012-10-02T17:16:14","indexId":"70040150","displayToPublicDate":"2012-10-02T00:00:00","publicationYear":"2012","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":791,"text":"Annals of Environmental Science","active":true,"publicationSubtype":{"id":10}},"title":"Sources of fecal indicator bacteria to groundwater, Malibu Lagoon and the near-shore ocean, Malibu, California, USA","docAbstract":"Onsite wastewater treatment systems (OWTS) used to treat residential and commercial sewage near Malibu, California have been implicated as a possible source of fecal indicator bacteria (FIB) to Malibu Lagoon and the near-shore ocean. For this to occur, treated wastewater must first move through groundwater before discharging to the Lagoon or ocean. In July 2009 and April 2010, &delta;<sup>18</sup>O and &delta;D data showed that some samples from water-table wells contained as much as 70% wastewater; at that time FIB concentrations in those samples were generally less than the detection limit of 1 Most Probable Number (MPN) per 100 milliliters (mL). In contrast, Malibu Lagoon had total coliform, <i>Escherichia coli</i>, and enterococci concentrations as high as 650,000, 130,000, and 5,500 MPN per 100 mL, respectively, and as many as 12% of samples from nearby ocean beaches exceeded the U.S. Environmental Protection Agency single sample enterococci standard for marine recreational water of 104 MPN per 100 mL. Human-associated <i>Bacteroidales</i>, an indicator of human-fecal contamination, were not detected in water from wells, Malibu Lagoon, or the near-shore ocean. Similarly, microarray (PhyloChip) data show <i>Bacteroidales</i> and <i>Fimicutes</i> Operational Taxanomic Units (OTUs) present in OWTS were largely absent in groundwater; in contrast, 50% of <i>Bacteroidales</i> and <i>Fimicutes</i> OTUs present in the near-shore ocean were also present in gull feces. Terminal-Restriction Length Fragment Polymorphism (T-RFLP) and phospholipid fatty acid (PLFA) data showed that microbial communities in groundwater were different and less abundant than communities in OWTS, Malibu Lagoon, or the near-shore ocean. However, organic compounds indicative of wastewater (such as fecal sterols, bisphenol-A and cosmetics) were present in groundwater having a high percentage of wastewater and were present in groundwater discharging to the ocean. FIB in the near-shore ocean varied with tides, ocean swells, and waves. Movement of water from Malibu Lagoon through the sand berm at the mouth of the Lagoon contributed FIB to the adjacent beach at low tide. Similar increases in FIB concentrations did not occur at beaches adjacent to unsewered residential development, although wastewater indicator compounds and radon-222 (indicative of groundwater discharge) were present. High FIB concentrations at high tide were not related to groundwater discharge, but may be related to FIB associated with debris accumulated along the high-tide line.","largerWorkType":{"id":2,"text":"Article"},"largerWorkTitle":"Annals of Environmental Science","largerWorkSubtype":{"id":10,"text":"Journal Article"},"language":"English","publisher":"Northeastern University","publisherLocation":"Boston, MA","usgsCitation":"Izbicki, J., Swarzenski, P.W., Burton, C., Van De Werfhorst, L., Holden, P.A., and Dubinsky, E.A., 2012, Sources of fecal indicator bacteria to groundwater, Malibu Lagoon and the near-shore ocean, Malibu, California, USA: Annals of Environmental Science, v. 6.","numberOfPages":"52","onlineOnly":"Y","costCenters":[{"id":154,"text":"California Water Science Center","active":true,"usgs":true}],"links":[{"id":262189,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"},{"id":262185,"rank":100,"type":{"id":15,"text":"Index Page"},"url":"https://hdl.handle.net/2047/d20002615","linkFileType":{"id":5,"text":"html"}},{"id":262186,"rank":200,"type":{"id":11,"text":"Document"},"url":"https://iris.lib.neu.edu/cgi/viewcontent.cgi?article=1092&context=aes","linkFileType":{"id":5,"text":"html"}}],"country":"United States","state":"California","city":"Malibu","geographicExtents":"{ \"type\": \"FeatureCollection\", \"features\": [ { \"type\": \"Feature\", \"properties\": {}, \"geometry\": { \"type\": \"Polygon\", \"coordinates\": [ [ [ -118.7,34.0175 ], [ -118.7,34.034166666666664 ], [ -118.6675,34.034166666666664 ], [ -118.6675,34.0175 ], [ -118.7,34.0175 ] ] ] } } ] }","volume":"6","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"506c01ebe4b05073318eead3","contributors":{"authors":[{"text":"Izbicki, John A. 0000-0003-0816-4408 jaizbick@usgs.gov","orcid":"https://orcid.org/0000-0003-0816-4408","contributorId":1375,"corporation":false,"usgs":true,"family":"Izbicki","given":"John A.","email":"jaizbick@usgs.gov","affiliations":[{"id":595,"text":"U.S. Geological Survey","active":false,"usgs":true}],"preferred":false,"id":467769,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Swarzenski, Peter W. 0000-0003-0116-0578 pswarzen@usgs.gov","orcid":"https://orcid.org/0000-0003-0116-0578","contributorId":1070,"corporation":false,"usgs":true,"family":"Swarzenski","given":"Peter","email":"pswarzen@usgs.gov","middleInitial":"W.","affiliations":[{"id":520,"text":"Pacific Coastal and Marine Science Center","active":true,"usgs":true}],"preferred":true,"id":467768,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Burton, Carmen A. 0000-0002-6381-8833","orcid":"https://orcid.org/0000-0002-6381-8833","contributorId":41793,"corporation":false,"usgs":true,"family":"Burton","given":"Carmen A.","affiliations":[],"preferred":false,"id":467770,"contributorType":{"id":1,"text":"Authors"},"rank":3},{"text":"Van De Werfhorst, Laurie","contributorId":101138,"corporation":false,"usgs":true,"family":"Van De Werfhorst","given":"Laurie","email":"","affiliations":[],"preferred":false,"id":467773,"contributorType":{"id":1,"text":"Authors"},"rank":4},{"text":"Holden, Patricia A.","contributorId":56090,"corporation":false,"usgs":true,"family":"Holden","given":"Patricia","email":"","middleInitial":"A.","affiliations":[],"preferred":false,"id":467771,"contributorType":{"id":1,"text":"Authors"},"rank":5},{"text":"Dubinsky, Eric A.","contributorId":60069,"corporation":false,"usgs":true,"family":"Dubinsky","given":"Eric","email":"","middleInitial":"A.","affiliations":[],"preferred":false,"id":467772,"contributorType":{"id":1,"text":"Authors"},"rank":6}]}}
,{"id":70040137,"text":"70040137 - 2012 - An assessment of radon in groundwater in New York State","interactions":[],"lastModifiedDate":"2012-10-02T17:16:14","indexId":"70040137","displayToPublicDate":"2012-10-02T00:00:00","publicationYear":"2012","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":1885,"text":"Health Physics - The Safety Radiation Journal","active":true,"publicationSubtype":{"id":10}},"title":"An assessment of radon in groundwater in New York State","docAbstract":"Abstract: A set of 317 samples collected from wells throughout New York State (excluding Long Island) from 2003 through 2008 was used to assess the distribution of radon gas in drinking water. Previous studies have documented high concentrations of radon in groundwater from granitic and metamorphic bedrock, but there have been only limited characterizations of radon in water from sedimentary rock and unconsolidated sand-and-gravel deposits in New York. Approximately 8% of the samples from bedrock wells exceed 89 Bq L<sup>-1</sup> (eight times the proposed regulatory limit), but only 2% of samples from sand-and-gravel wells exceed 44 Bq L<sup>-1</sup>. Specific metamorphic and sedimentary rock formations in New York are associated with the high radon concentrations, indicating that specific areas of New York could be targeted with efforts to reduce the risk of exposure to radon in groundwater. Additionally, radon in groundwater from the sand-and-gravel aquifers was found to be directly correlated to radon in indoor air when assessed by county.","largerWorkType":{"id":2,"text":"Article"},"largerWorkTitle":"Health Physics - The Safety Radiation Journal","largerWorkSubtype":{"id":10,"text":"Journal Article"},"language":"English","publisher":"Wolters Kluwer Health","publisherLocation":"Riverwoods, IL","doi":"10.1097/HP.0b013e31824dadbe","usgsCitation":"Shaw, S.B., and Eckhardt, D., 2012, An assessment of radon in groundwater in New York State: Health Physics - The Safety Radiation Journal, v. 103, no. 3, p. 311-316, https://doi.org/10.1097/HP.0b013e31824dadbe.","productDescription":"6 p.","startPage":"311","endPage":"316","costCenters":[{"id":474,"text":"New York Water Science Center","active":true,"usgs":true}],"links":[{"id":262190,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"},{"id":262182,"rank":9999,"type":{"id":10,"text":"Digital Object Identifier"},"url":"https://dx.doi.org/10.1097/HP.0b013e31824dadbe"}],"country":"United States","state":"New York","geographicExtents":"{ \"type\": \"FeatureCollection\", \"features\": [ { \"type\": \"Feature\", \"properties\": {}, \"geometry\": { \"type\": \"Polygon\", \"coordinates\": [ [ [ -79.75138888888888,40.48444444444444 ], [ -79.75138888888888,45.00111111111111 ], [ -71.78388888888888,45.00111111111111 ], [ -71.78388888888888,40.48444444444444 ], [ -79.75138888888888,40.48444444444444 ] ] ] } } ] }","volume":"103","issue":"3","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"506c01cae4b05073318eeaca","contributors":{"authors":[{"text":"Shaw, Stephen B.","contributorId":40700,"corporation":false,"usgs":true,"family":"Shaw","given":"Stephen","email":"","middleInitial":"B.","affiliations":[],"preferred":false,"id":467756,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Eckhardt, David A.V.","contributorId":80233,"corporation":false,"usgs":true,"family":"Eckhardt","given":"David A.V.","affiliations":[],"preferred":false,"id":467757,"contributorType":{"id":1,"text":"Authors"},"rank":2}]}}
,{"id":70040051,"text":"ds718 - 2012 - Groundwater-quality and quality-control data for two monitoring wells near Pavillion, Wyoming, April and May 2012","interactions":[],"lastModifiedDate":"2012-09-26T17:16:49","indexId":"ds718","displayToPublicDate":"2012-09-26T00:00:00","publicationYear":"2012","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":310,"text":"Data Series","code":"DS","onlineIssn":"2327-638X","printIssn":"2327-0271","active":false,"publicationSubtype":{"id":5}},"seriesNumber":"718","title":"Groundwater-quality and quality-control data for two monitoring wells near Pavillion, Wyoming, April and May 2012","docAbstract":"In June 2010, the U.S. Environmental Protection Agency installed two deep monitoring wells (MW01 and MW02) near Pavillion, Wyoming, to study groundwater quality. During April and May 2012, the U.S Geological Survey, in cooperation with the Wyoming Department of Environmental Quality, collected groundwater-quality data and quality-control data from monitoring well MW01 and, following well redevelopment, quality-control data for monitoring well MW02. Two groundwater-quality samples were collected from well MW01&mdash;one sample was collected after purging about 1.5 borehole volumes, and a second sample was collected after purging 3 borehole volumes. Both samples were collected and processed using methods designed to minimize atmospheric contamination or changes to water chemistry. Groundwater-quality samples were analyzed for field water-quality properties (water temperature, pH, specific conductance, dissolved oxygen, oxidation potential); inorganic constituents including naturally occurring radioactive compounds (radon, radium-226 and radium-228); organic constituents; dissolved gasses; stable isotopes of methane, water, and dissolved inorganic carbon; and environmental tracers (carbon-14, chlorofluorocarbons, sulfur hexafluoride, tritium, helium, neon, argon, krypton, xenon, and the ratio of helium-3 to helium-4). Quality-control sample results associated with well MW01 were evaluated to determine the extent to which environmental sample analytical results were affected by bias and to evaluate the variability inherent to sample collection and laboratory analyses. Field documentation, environmental data, and quality-control data for activities that occurred at the two monitoring wells during April and May 2012 are presented.","language":"English","publisher":"U.S. Geological Survey","publisherLocation":"Reston, VA","doi":"10.3133/ds718","collaboration":"In cooperation with the Wyoming Department of Environmental Quality","usgsCitation":"Wright, P., McMahon, P.B., Mueller, D.K., and Clark, M.L., 2012, Groundwater-quality and quality-control data for two monitoring wells near Pavillion, Wyoming, April and May 2012: U.S. Geological Survey Data Series 718, vi, 23 p.; col. ill.; map (col.); Downloads Directory, https://doi.org/10.3133/ds718.","productDescription":"vi, 23 p.; col. ill.; map (col.); Downloads Directory","startPage":"i","endPage":"23","numberOfPages":"32","onlineOnly":"Y","additionalOnlineFiles":"Y","costCenters":[{"id":684,"text":"Wyoming Water Science Center","active":false,"usgs":true}],"links":[{"id":262102,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/ds_718.gif"},{"id":262094,"rank":100,"type":{"id":15,"text":"Index Page"},"url":"https://pubs.usgs.gov/ds/718/","linkFileType":{"id":5,"text":"html"}},{"id":262095,"rank":300,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/ds/718/DS718_508.pdf","linkFileType":{"id":1,"text":"pdf"}},{"id":262096,"rank":9999,"type":{"id":7,"text":"Companion Files"},"url":"https://pubs.usgs.gov/ds/718/downloads/","linkFileType":{"id":5,"text":"html"}}],"country":"United States","state":"Wyoming","city":"Pavillion","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"50de6ad2e4b0e31bb02a30ab","contributors":{"authors":[{"text":"Wright, Peter R. prwright@usgs.gov","contributorId":1828,"corporation":false,"usgs":true,"family":"Wright","given":"Peter R.","email":"prwright@usgs.gov","affiliations":[],"preferred":true,"id":467573,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"McMahon, Peter B. 0000-0001-7452-2379 pmcmahon@usgs.gov","orcid":"https://orcid.org/0000-0001-7452-2379","contributorId":724,"corporation":false,"usgs":true,"family":"McMahon","given":"Peter","email":"pmcmahon@usgs.gov","middleInitial":"B.","affiliations":[{"id":191,"text":"Colorado Water Science Center","active":true,"usgs":true}],"preferred":true,"id":467570,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Mueller, David K. mueller@usgs.gov","contributorId":1585,"corporation":false,"usgs":true,"family":"Mueller","given":"David","email":"mueller@usgs.gov","middleInitial":"K.","affiliations":[{"id":503,"text":"Office of Water Quality","active":true,"usgs":true}],"preferred":true,"id":467571,"contributorType":{"id":1,"text":"Authors"},"rank":3},{"text":"Clark, Melanie L. mlclark@usgs.gov","contributorId":1827,"corporation":false,"usgs":true,"family":"Clark","given":"Melanie","email":"mlclark@usgs.gov","middleInitial":"L.","affiliations":[{"id":5050,"text":"WY-MT Water Science Center","active":true,"usgs":true}],"preferred":true,"id":467572,"contributorType":{"id":1,"text":"Authors"},"rank":4}]}}
,{"id":70040012,"text":"ofr20121166 - 2012 - Nearshore morphology, benthic structure, hydrodynamics, and coastal groundwater discharge near Kahekili Beach Park, Maui, Hawaii","interactions":[],"lastModifiedDate":"2025-05-14T13:56:05.174887","indexId":"ofr20121166","displayToPublicDate":"2012-09-24T00:00:00","publicationYear":"2012","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":330,"text":"Open-File Report","code":"OFR","onlineIssn":"2331-1258","printIssn":"0196-1497","active":true,"publicationSubtype":{"id":5}},"seriesNumber":"2012-1166","title":"Nearshore morphology, benthic structure, hydrodynamics, and coastal groundwater discharge near Kahekili Beach Park, Maui, Hawaii","docAbstract":"This report presents a brief summary of recent fieldwork conducted off Kahekili Beach Park, Maui, Hawaii, the site of the newly established U.S. Coral Reef Task Force priority study area at Kaanapali and the Hawaii Department of Land and Natural Resources, Division of Aquatic Resources, Kahekili Herbivore Fisheries Management Area (HFMA). The goals of this fieldwork are to provide new baseline information to help guide future studies and to provide first insights into rates and drivers of coastal groundwater discharge and associated constituent loadings into the priority study area's coastal waters. This study presents the first swath acoustic mapping information, in situ oceanographic instrument measurements, and coastal groundwater discharge estimates at this site based on the submarine groundwater discharge tracer radon-222 (<sup>222</sup>Rn). Coastal groundwater discharge rates ranged from about 22 to 50 centimeters per day, depending on proximity of the sampling mooring to the primary discharge vent. The water chemistry of the discharging groundwater was at times dramatically different than ambient seawater. For example, at the primary vent site at Kahekili, the concentrations of total dissolved nitrogen (TDN), dissolved silicate (DSi), and total dissolved phosphorus (TDP) in the discharging groundwater were 43.75 micromolar (&mu;M), 583.49 &mu;M, and 12.04 &mu;M, respectively. These data extend our basic understanding of the morphology, benthic structure, and oceanographic setting of this vent site and provide a first estimate of the magnitude and physical forcings of submarine groundwater discharge and associated trace metals and nutrient loads here.","language":"English","publisher":"U.S. Geological Survey","publisherLocation":"Reston, VA","doi":"10.3133/ofr20121166","usgsCitation":"Swarzenski, P.W., Storlazzi, C., Presto, M., Gibbs, A.E., Smith, C.G., Dimova, N.T., Dailer, M.L., and Logan, J., 2012, Nearshore morphology, benthic structure, hydrodynamics, and coastal groundwater discharge near Kahekili Beach Park, Maui, Hawaii: U.S. Geological Survey Open-File Report 2012-1166, iv, 34 p., https://doi.org/10.3133/ofr20121166.","productDescription":"iv, 34 p.","numberOfPages":"38","onlineOnly":"Y","costCenters":[{"id":520,"text":"Pacific Coastal and Marine Science Center","active":true,"usgs":true}],"links":[{"id":262028,"rank":1,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/ofr_2012_1166.bmp"},{"id":262027,"rank":3,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/of/2012/1166/of2012-1166.pdf","linkFileType":{"id":1,"text":"pdf"}},{"id":262026,"rank":2,"type":{"id":15,"text":"Index Page"},"url":"https://pubs.usgs.gov/of/2012/1166/","linkFileType":{"id":5,"text":"html"}}],"country":"United States","state":"Hawai'i","otherGeospatial":"Kahekili Beach Park, Maui","geographicExtents":"{ \"type\": \"FeatureCollection\", \"features\": [ { \"type\": \"Feature\", \"properties\": {}, \"geometry\": { \"type\": \"Polygon\", \"coordinates\": [ [ [ -156.70083333333332,20.9175 ], [ -156.70083333333332,20.966666666666665 ], [ -156.6675,20.966666666666665 ], [ -156.6675,20.9175 ], [ -156.70083333333332,20.9175 ] ] ] } } ] }","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"50e09619e4b0fec3206ee811","contributors":{"authors":[{"text":"Swarzenski, Peter W. 0000-0003-0116-0578 pswarzen@usgs.gov","orcid":"https://orcid.org/0000-0003-0116-0578","contributorId":1070,"corporation":false,"usgs":true,"family":"Swarzenski","given":"Peter","email":"pswarzen@usgs.gov","middleInitial":"W.","affiliations":[{"id":520,"text":"Pacific Coastal and Marine Science Center","active":true,"usgs":true}],"preferred":true,"id":467447,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Storlazzi, Curt D. 0000-0001-8057-4490","orcid":"https://orcid.org/0000-0001-8057-4490","contributorId":77889,"corporation":false,"usgs":true,"family":"Storlazzi","given":"Curt D.","affiliations":[],"preferred":false,"id":467454,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Presto, M. Katherine","contributorId":30192,"corporation":false,"usgs":true,"family":"Presto","given":"M. Katherine","affiliations":[],"preferred":false,"id":467450,"contributorType":{"id":1,"text":"Authors"},"rank":3},{"text":"Gibbs, Ann E. 0000-0002-0883-3774 agibbs@usgs.gov","orcid":"https://orcid.org/0000-0002-0883-3774","contributorId":2644,"corporation":false,"usgs":true,"family":"Gibbs","given":"Ann","email":"agibbs@usgs.gov","middleInitial":"E.","affiliations":[{"id":520,"text":"Pacific Coastal and Marine Science Center","active":true,"usgs":true}],"preferred":true,"id":467448,"contributorType":{"id":1,"text":"Authors"},"rank":4},{"text":"Smith, Christopher G. 0000-0002-8075-4763 cgsmith@usgs.gov","orcid":"https://orcid.org/0000-0002-8075-4763","contributorId":3410,"corporation":false,"usgs":true,"family":"Smith","given":"Christopher","email":"cgsmith@usgs.gov","middleInitial":"G.","affiliations":[{"id":186,"text":"Coastal and Marine Geology Program","active":true,"usgs":true},{"id":24708,"text":"Lower Mississippi-Gulf Water Science Center","active":true,"usgs":true},{"id":574,"text":"St. Petersburg Coastal and Marine Science Center","active":true,"usgs":true}],"preferred":true,"id":467449,"contributorType":{"id":1,"text":"Authors"},"rank":5},{"text":"Dimova, Natasha T.","contributorId":50769,"corporation":false,"usgs":true,"family":"Dimova","given":"Natasha","email":"","middleInitial":"T.","affiliations":[],"preferred":false,"id":467453,"contributorType":{"id":1,"text":"Authors"},"rank":6},{"text":"Dailer, Meghan L.","contributorId":42471,"corporation":false,"usgs":true,"family":"Dailer","given":"Meghan","email":"","middleInitial":"L.","affiliations":[],"preferred":false,"id":467452,"contributorType":{"id":1,"text":"Authors"},"rank":7},{"text":"Logan, Joshua B.","contributorId":34470,"corporation":false,"usgs":true,"family":"Logan","given":"Joshua B.","affiliations":[],"preferred":false,"id":467451,"contributorType":{"id":1,"text":"Authors"},"rank":8}]}}
,{"id":70039803,"text":"ofr20121150 - 2012 - Baseline groundwater quality in national park units within the Marcellus and Utica Shale gas plays, New York, Pennsylvania, and West Virginia, 2011","interactions":[],"lastModifiedDate":"2017-06-10T11:11:26","indexId":"ofr20121150","displayToPublicDate":"2012-09-04T00:00:00","publicationYear":"2012","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":330,"text":"Open-File Report","code":"OFR","onlineIssn":"2331-1258","printIssn":"0196-1497","active":true,"publicationSubtype":{"id":5}},"seriesNumber":"2012-1150","title":"Baseline groundwater quality in national park units within the Marcellus and Utica Shale gas plays, New York, Pennsylvania, and West Virginia, 2011","docAbstract":"Groundwater samples were collected from 15 production wells and 1 spring at 9 national park units in New York, Pennsylvania, and West Virginia in July and August 2011 and analyzed to characterize the quality of these water supplies. The sample sites generally were selected to represent areas of potential effects on water quality by drilling and development of gas wells in Marcellus Shale and Utica Shale areas of the northeastern United States. The groundwater samples were analyzed for 53 constituents, including nutrients, major inorganic constituents, trace elements, chemical oxygen demand, radioactivity, and dissolved gases, including methane and radon-222. Results indicated that the groundwater used for water supply at the selected national park units is generally of acceptable quality, although concentrations of some constituents exceeded at least one drinking-water guideline at several wells. Nine analytes were detected in concentrations that exceeded Federal drinking-water standards, mostly secondary standards that define aesthetic properties of water, such as taste and odor. One sample had an arsenic concentration that exceeded the U.S. Environmental Protection Agency maximum contaminant level (MCL) of 10 micrograms per liter (&mu;g/L). The pH, which is a measure of acidity (hydrogen ion activity), ranged from 4.8 to 8.4, and in 5 of the 16 samples, the pH values were outside the accepted U.S. Environmental Protection Agency secondary maximum contaminant level (SMCL) range of 6.5 to 8.5. The concentration of total dissolved solids exceeded the SMCL of 500 milligrams per liter (mg/L) at four sites. The sulfate concentration exceeded the SMCL of 250 mg/L concentration in one sample, and the fluoride concentration exceeded the SMCL of 2 mg/L in one sample. Sodium concentrations exceeded the U.S. Environmental Protection Agency drinking water health advisory of 60 mg/L at four sites. Iron concentrations exceeded the SMCL of 300 &mu;g/L in two samples, and manganese concentrations exceeded the SMCL of 50 &mu;g/L in five samples. Radon-222 concentrations exceeded the proposed U.S. Environmental Protection Agency MCL of 300 picocuries per liter in eight samples.","language":"English","publisher":"U.S. Geological Survey","publisherLocation":"Reston, VA","doi":"10.3133/ofr20121150","collaboration":"Prepared in cooperation with the National Park Service","usgsCitation":"Eckhardt, D., and Sloto, R.A., 2012, Baseline groundwater quality in national park units within the Marcellus and Utica Shale gas plays, New York, Pennsylvania, and West Virginia, 2011: U.S. Geological Survey Open-File Report 2012-1150, v, 20 p., https://doi.org/10.3133/ofr20121150.","productDescription":"v, 20 p.","numberOfPages":"30","onlineOnly":"Y","costCenters":[{"id":474,"text":"New York Water Science Center","active":true,"usgs":true}],"links":[{"id":260137,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/ofr_2012_1150.gif"},{"id":260131,"rank":100,"type":{"id":15,"text":"Index Page"},"url":"https://pubs.usgs.gov/of/2012/1150/","linkFileType":{"id":5,"text":"html"}},{"id":260132,"rank":300,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/of/2012/1150/pdf/ofr2012-1150_report_508.pdf","linkFileType":{"id":1,"text":"pdf"}}],"projection":"Universal Transverse Mercator projection, Zone 18","datum":"North American Datum 1983","country":"United States","state":"New York;Pennsylvania;West Virginia","otherGeospatial":"Marcellus Shale Extent;Utica Shale Extent","geographicExtents":"{ \"type\": \"FeatureCollection\", \"features\": [ { \"type\": \"Feature\", \"properties\": {}, \"geometry\": { \"type\": \"Polygon\", \"coordinates\": [ [ [ -86,36 ], [ -86,46 ], [ -74,46 ], [ -74,36 ], [ -86,36 ] ] ] } } ] }","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"5059efd9e4b0c8380cd4a4a9","contributors":{"authors":[{"text":"Eckhardt, David A.V.","contributorId":80233,"corporation":false,"usgs":true,"family":"Eckhardt","given":"David A.V.","affiliations":[],"preferred":false,"id":466953,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Sloto, Ronald A. rasloto@usgs.gov","contributorId":424,"corporation":false,"usgs":true,"family":"Sloto","given":"Ronald","email":"rasloto@usgs.gov","middleInitial":"A.","affiliations":[{"id":532,"text":"Pennsylvania Water Science Center","active":true,"usgs":true}],"preferred":true,"id":466952,"contributorType":{"id":1,"text":"Authors"},"rank":2}]}}
,{"id":70039630,"text":"sir20125042 - 2012 - Groundwater quality and simulation of sources of water to wells in the Marsh Creek valley at the U.S. Geological Survey Northern Appalachian Research Laboratory, Tioga County, Pennsylvania","interactions":[],"lastModifiedDate":"2012-08-18T01:01:45","indexId":"sir20125042","displayToPublicDate":"2012-08-17T00:00:00","publicationYear":"2012","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":334,"text":"Scientific Investigations Report","code":"SIR","onlineIssn":"2328-0328","printIssn":"2328-031X","active":true,"publicationSubtype":{"id":5}},"seriesNumber":"2012-5042","title":"Groundwater quality and simulation of sources of water to wells in the Marsh Creek valley at the U.S. Geological Survey Northern Appalachian Research Laboratory, Tioga County, Pennsylvania","docAbstract":"This report provides a November 2010 snapshot of groundwater quality and an analysis of the sources of water to wells at the U.S. Geological Survey (USGS) Northern Appalachian Research Laboratory (NARL) near Wellsboro, Pennsylvania. The laboratory, which conducts fisheries research, currently (2011) withdraws 1,000 gallons per minute of high-quality groundwater from three wells completed in the glacial sand and gravel aquifer beneath the Marsh Creek valley; a fourth well that taps the same aquifer provides the potable supply for the facility. The study was conducted to document the source areas and quality of the water supply for this Department of Interior facility, which is surrounded by the ongoing development of natural gas from the Marcellus Shale. Groundwater samples were collected from the four wells used by the NARL and from two nearby domestic-supply wells. The domestic-supply wells withdraw groundwater from bedrock of the Catskill Formation. Samples were analyzed for major ions, nutrients, trace metals, radiochemicals, dissolved gases, and stable isotopes of oxygen and hydrogen in water and carbon in dissolved carbonate to document groundwater quality. Organic constituents (other than hydrocarbon gases) associated with hydraulic fracturing and other human activities were not analyzed as part of this assessment. Results show low concentrations of all constituents. Only radon, which ranged from 980 to 1,310 picocuries per liter, was somewhat elevated. These findings are consistent with the pristine nature of the aquifer in the Marsh Creek valley, which is the reason the laboratory was sited at this location. The sources of water and areas contributing recharge to wells were identified by the use of a previously documented MODFLOW groundwater-flow model for the following conditions: (1) withdrawals of 1,000 to 3,000 gallons per minute from the NARL wells, (2) average or dry hydrologic conditions, and (3) withdrawals of 1,000 gallons per minute from a new well 3,500 feet to the southwest that was drilled to provide water for Marcellus gas-well operations. Results of simulations indicate that during average hydrologic conditions, infiltration from Straight Run, a tributary to Marsh Creek, provides nearly all the water to the NARL wells. During dry conditions, the areas contributing recharge expand such that Asaph Run contributes about half of the water to the NARL wells when withdrawals are 1,000 or 2,000 gallons per minute. The addition of a simulated withdrawal of 1,000 gallons per minute from the nearby new well does not substantially affect the sources of water captured by the NARL wells. These results are subject to some limitations. The water-quality samples represent a snapshot of groundwater chemistry for only one hydrologic condition; the concentrations of some constituents may change temporally. In addition, samples were collected and analyzed for hydrocarbon gases, but not organic constituents associated with hydraulic fracturing; additional sampling for these constituents would provide a more complete water-quality baseline. The sources contributing water to the NARL wells and the new well were simulated by use of a simplified one-layer model of the glacial sand and gravel aquifer for steady-state conditions that in reality are never achieved. Steady-state simulations of dry hydrologic conditions show that it is possible for the NARL wells to capture water from Asaph Run; however, maps of simulated groundwater time-of-travel indicate that a dry period of unusually long duration would be required. A better analysis could be done by recalibrating the groundwater-flow model with a finite-difference grid having multiple layers, cells smaller than the 200-foot by 200-foot cells used in this study, and transient stress periods.","language":"English","publisher":"U.S. Geological Survey","publisherLocation":"Reston, VA","doi":"10.3133/sir20125042","usgsCitation":"Risser, D.W., and Breen, K.J., 2012, Groundwater quality and simulation of sources of water to wells in the Marsh Creek valley at the U.S. Geological Survey Northern Appalachian Research Laboratory, Tioga County, Pennsylvania: U.S. Geological Survey Scientific Investigations Report 2012-5042, vii, 41 p., https://doi.org/10.3133/sir20125042.","productDescription":"vii, 41 p.","numberOfPages":"54","onlineOnly":"Y","costCenters":[{"id":532,"text":"Pennsylvania Water Science Center","active":true,"usgs":true}],"links":[{"id":259705,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/sir_2012_5042.png"},{"id":259701,"rank":300,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/sir/2012/5042/pdf/sir2012-5042.pdf","linkFileType":{"id":1,"text":"pdf"}},{"id":259700,"rank":100,"type":{"id":15,"text":"Index Page"},"url":"https://pubs.usgs.gov/sir/2012/5042/","linkFileType":{"id":5,"text":"html"}}],"scale":"2400","country":"United States","state":"Pennsylvania","county":"Tioga County","city":"Wellsboro","otherGeospatial":"Asaph Run;Marsh Creek;Straight Run","geographicExtents":"{ \"type\": \"FeatureCollection\", \"features\": [ { \"type\": \"Feature\", \"properties\": {}, \"geometry\": { \"type\": \"Polygon\", \"coordinates\": [ [ [ -77.41666666666667,41.766666666666666 ], [ -77.41666666666667,41.78333333333333 ], [ -77.38333333333334,41.78333333333333 ], [ -77.38333333333334,41.766666666666666 ], [ -77.41666666666667,41.766666666666666 ] ] ] } } ] }","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"505a2daee4b0c8380cd5bfa9","contributors":{"authors":[{"text":"Risser, Dennis W. 0000-0001-9597-5406 dwrisser@usgs.gov","orcid":"https://orcid.org/0000-0001-9597-5406","contributorId":898,"corporation":false,"usgs":true,"family":"Risser","given":"Dennis","email":"dwrisser@usgs.gov","middleInitial":"W.","affiliations":[{"id":532,"text":"Pennsylvania Water Science Center","active":true,"usgs":true}],"preferred":true,"id":466636,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Breen, Kevin J. 0000-0002-9447-6469 kjbreen@usgs.gov","orcid":"https://orcid.org/0000-0002-9447-6469","contributorId":219,"corporation":false,"usgs":true,"family":"Breen","given":"Kevin","email":"kjbreen@usgs.gov","middleInitial":"J.","affiliations":[{"id":501,"text":"Office of Science Quality and Integrity","active":true,"usgs":true}],"preferred":true,"id":466635,"contributorType":{"id":1,"text":"Authors"},"rank":2}]}}
,{"id":70039606,"text":"ds659 - 2012 - Groundwater-quality data in the Borrego Valley, Central Desert, and Low-Use Basins of the Mojave and Sonoran Deserts study unit, 2008-2010--Results from the California GAMA Program","interactions":[],"lastModifiedDate":"2012-08-16T01:02:05","indexId":"ds659","displayToPublicDate":"2012-08-15T00:00:00","publicationYear":"2012","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":310,"text":"Data Series","code":"DS","onlineIssn":"2327-638X","printIssn":"2327-0271","active":false,"publicationSubtype":{"id":5}},"seriesNumber":"659","title":"Groundwater-quality data in the Borrego Valley, Central Desert, and Low-Use Basins of the Mojave and Sonoran Deserts study unit, 2008-2010--Results from the California GAMA Program","docAbstract":"Groundwater quality in the 12,103-square-mile Borrego Valley, Central Desert, and Low-Use Basins of the Mojave and Sonoran Deserts (CLUB) study unit was investigated by the U.S. Geological Survey (USGS) from December 2008 to March 2010, as part of the California State Water Resources Control Board (SWRCB) Groundwater Ambient Monitoring and Assessment (GAMA) Program's Priority Basin Project (PBP). The GAMA-PBP was developed in response to the California Groundwater Quality Monitoring Act of 2001 and is being conducted in collaboration with the SWRCB and Lawrence Livermore National Laboratory (LLNL). The CLUB study unit was the twenty-eighth study unit to be sampled as part of the GAMA-PBP. The GAMA CLUB study was designed to provide a spatially unbiased assessment of untreated-groundwater quality in the primary aquifer systems, and to facilitate statistically consistent comparisons of untreated-groundwater quality throughout California. The primary aquifer systems (hereinafter referred to as primary aquifers) are defined as parts of aquifers corresponding to the perforation intervals of wells listed in the California Department of Public Health (CDPH) database for the CLUB study unit. The quality of groundwater in shallow or deep water-bearing zones may differ from the quality of groundwater in the primary aquifers; shallow groundwater may be more vulnerable to surficial contamination. In the CLUB study unit, groundwater samples were collected from 52 wells in 3 study areas (Borrego Valley, Central Desert, and Low-Use Basins of the Mojave and Sonoran Deserts) in San Bernardino, Riverside, Kern, San Diego, and Imperial Counties. Forty-nine of the wells were selected by using a spatially distributed, randomized grid-based method to provide statistical representation of the study unit (grid wells), and three wells were selected to aid in evaluation of water-quality issues (understanding wells). The groundwater samples were analyzed for organic constituents (volatile organic compounds [VOCs], pesticides and pesticide degradates, and pharmaceutical compounds), constituents of special interest (perchlorate and <i>N</i>-nitrosodimethylamine [NDMA]), naturally-occurring inorganic constituents (trace elements, nutrients, major and minor ions, silica, total dissolved solids [TDS], alkalinity, and species of inorganic chromium), and radioactive constituents (radon-222, radium isotopes, and gross alpha and gross beta radioactivity). Naturally-occurring isotopes (stable isotopes of hydrogen, oxygen, boron, and strontium in water, stable isotopes of carbon in dissolved inorganic carbon, activities of tritium, and carbon-14 abundance) and dissolved noble gases also were measured to help identify the sources and ages of sampled groundwater. In total, 223 constituents and 12 water-quality indicators were investigated. Three types of quality-control samples (blanks, replicates, and matrix spikes) were collected at up to 10 percent of the wells in the CLUB study unit, and the results for these samples were used to evaluate the quality of the data for the groundwater samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that contamination from sample collection procedures was not a significant source of bias in the data for the groundwater samples. Replicate samples generally were within the limits of acceptable analytical reproducibility. Median matrix-spike recoveries were within the acceptable range (70 to 130 percent) for approximately 85 percent of the compounds. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, untreated groundwater typically is treated, disinfected, and (or) blended with other waters to maintain water quality. Regulatory benchmarks apply to water that is delivered to the consumer, not to untreated groundwater. However, to provide some context for the results, concentrations of constituents measured in the untreated groundwater were compared with regulatory and non-regulatory health-based benchmarks established by the U.S. Environmental Protection Agency (USEPA) and CDPH, and to non-regulatory benchmarks established for aesthetic concerns by CDPH. Comparisons between data collected for this study and benchmarks for drinking water are for illustrative purposes only and are not indicative of compliance or non-compliance with those benchmarks. Most inorganic constituents detected in groundwater samples from the 49 grid wells were detected at concentrations less than drinking-water benchmarks. In addition, all detections of organic constituents from the CLUB study-unit grid-well samples were less than health-based benchmarks. In total, VOCs were detected in 17 of the 49 grid wells sampled (approximately 35 percent), pesticides and pesticide degradates were detected in 5 of the 47 grid wells sampled (approximately 11 percent), and perchlorate was detected in 41 of 49 grid wells sampled (approximately 84 percent). Trace elements, major and minor ions, and nutrients were sampled for at 39 grid wells, and radioactive constituents were sampled for at 23 grid wells; most detected concentrations were less than health-based benchmarks. Exceptions in the grid-well samples include seven detections of arsenic greater than the USEPA maximum contaminant level (MCL-US) of 10 micrograms per liter (&mu;g/L); four detections of boron greater than the CDPH notification level (NL-CA) of 1,000 &mu;g/L; six detections of molybdenum greater than the USEPA lifetime health advisory level (HAL-US) of 40 &mu;g/L; two detections of uranium greater than the MCL-US of 30 &mu;g/L; nine detections of fluoride greater than the CDPH maximum contaminant level (MCL-CA) of 2 milligrams per liter (mg/L); one detection of nitrite plus nitrate (NO<sub>2-</sub>+NO<sub>3-</sub>), as nitrogen, greater than the MCL-US of 10 mg/L; and four detections of gross alpha radioactivity (72-hour count), and one detection of gross alpha radioactivity (30-day count), greater than the MCL-US of 15 picocuries per liter. Results for constituents with non-regulatory benchmarks set for aesthetic concerns showed that a manganese concentration greater than the CDPH secondary maximum contaminant level (SMCL-CA) of 50 &mu;g/L was detected in one grid well. Chloride concentrations greater than the recommended SMCL-CA benchmark of 250 mg/L were detected in three grid wells, and one of these wells also had a concentration that was greater than the upper SMCL-CA benchmark of 500 mg/L. Sulfate concentrations greater than the recommended SMCL-CA benchmark of 250 mg/L were measured in six grid wells. TDS concentrations greater than the SMCL-CA recommended benchmark of 500 mg/L were measured in 20 grid wells, and concentrations in 2 of these wells also were greater than the SMCL-CA upper benchmark of 1,000 mg/L.","language":"English","publisher":"U.S. Geological Survey","publisherLocation":"Reston, VA","doi":"10.3133/ds659","collaboration":"Prepared in cooperation with the California State Water Resources Control Board A Product of the California Groundwater Ambient Monitoring and Assessment (GAMA) Program","usgsCitation":"Mathany, T., Wright, M.T., Beuttel, B.S., and Belitz, K., 2012, Groundwater-quality data in the Borrego Valley, Central Desert, and Low-Use Basins of the Mojave and Sonoran Deserts study unit, 2008-2010--Results from the California GAMA Program: U.S. Geological Survey Data Series 659, x, 100 p.; maps (col.); Tables; Appendix, https://doi.org/10.3133/ds659.","productDescription":"x, 100 p.; maps (col.); Tables; Appendix","startPage":"i","endPage":"100","numberOfPages":"114","additionalOnlineFiles":"N","temporalStart":"2008-01-01","temporalEnd":"2010-12-31","costCenters":[{"id":154,"text":"California Water Science Center","active":true,"usgs":true}],"links":[{"id":259614,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/ds_659.jpg"},{"id":259609,"rank":100,"type":{"id":15,"text":"Index Page"},"url":"https://pubs.usgs.gov/ds/659/","linkFileType":{"id":5,"text":"html"}},{"id":259610,"rank":300,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/ds/659/pdf/ds659.pdf","linkFileType":{"id":1,"text":"pdf"}}],"country":"United States","state":"California","otherGeospatial":"Borrego Valley;Mojave Desert;Sonoran Desert","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"505a2dcfe4b0c8380cd5c040","contributors":{"authors":[{"text":"Mathany, Timothy M. 0000-0002-4747-5113","orcid":"https://orcid.org/0000-0002-4747-5113","contributorId":99949,"corporation":false,"usgs":true,"family":"Mathany","given":"Timothy M.","affiliations":[],"preferred":false,"id":466560,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Wright, Michael T. 0000-0003-0653-6466 mtwright@usgs.gov","orcid":"https://orcid.org/0000-0003-0653-6466","contributorId":1508,"corporation":false,"usgs":true,"family":"Wright","given":"Michael","email":"mtwright@usgs.gov","middleInitial":"T.","affiliations":[],"preferred":false,"id":466558,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Beuttel, Brandon S. bbeuttel@usgs.gov","contributorId":5069,"corporation":false,"usgs":true,"family":"Beuttel","given":"Brandon","email":"bbeuttel@usgs.gov","middleInitial":"S.","affiliations":[],"preferred":true,"id":466559,"contributorType":{"id":1,"text":"Authors"},"rank":3},{"text":"Belitz, Kenneth 0000-0003-4481-2345 kbelitz@usgs.gov","orcid":"https://orcid.org/0000-0003-4481-2345","contributorId":442,"corporation":false,"usgs":true,"family":"Belitz","given":"Kenneth","email":"kbelitz@usgs.gov","affiliations":[{"id":503,"text":"Office of Water Quality","active":true,"usgs":true},{"id":466,"text":"New England Water Science Center","active":true,"usgs":true},{"id":376,"text":"Massachusetts Water Science Center","active":true,"usgs":true},{"id":451,"text":"National Water Quality Assessment Program","active":true,"usgs":true},{"id":27111,"text":"National Water Quality Program","active":true,"usgs":true}],"preferred":true,"id":466557,"contributorType":{"id":1,"text":"Authors"},"rank":4}]}}
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