{"pageNumber":"457","pageRowStart":"11400","pageSize":"25","recordCount":16504,"records":[{"id":70017904,"text":"70017904 - 1993 - Meromixis in hypersaline Mono Lake, California. 3. Biogeochemical response to stratification and overturn","interactions":[],"lastModifiedDate":"2019-03-06T10:20:53","indexId":"70017904","displayToPublicDate":"1993-01-01T00:00:00","publicationYear":"1993","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":2620,"text":"Limnology and Oceanography","active":true,"publicationSubtype":{"id":10}},"title":"Meromixis in hypersaline Mono Lake, California. 3. Biogeochemical response to stratification and overturn","docAbstract":"<div class=\"article-section__content en main\"><p>Mono Lake is a terminal, saline lake that became ectogenically meromictic in 1982–1983 and remained stratified until November 1988. During this period, the monimolimnion remained anoxic and nearly isothermal, while the upper mixolimnion was well oxygenated and exhibited a seasonal thermal regime. Dissolved sulfide and methane increased in the monimolimnion as a result of diffusive flux from the sediments. Winter mixing down to the chemocline distributed sulfide and methane throughout the mixolimnion. Lakewide inventories of dissolved sulfide and methane reflected the balance between increased concentrations and decreased monimolimnion volume over time. At overturn, the entire water column was isothermal and anoxic. Dissolved sulfide (380 × 10<sup>6</sup><span>&nbsp;</span>mol) was oxidized in 1 week by molecular oxygen. Methane (12 × 10<sup>6</sup><span>&nbsp;</span>mol) was removed more slowly by microbial oxidation and ventilation across the air‐water interface.</p></div>","language":"English","publisher":"Wiley","doi":"10.4319/lo.1993.38.5.1040","usgsCitation":"Miller, L., Jellison, R., Oremland, R.S., and Culbertson, C.W., 1993, Meromixis in hypersaline Mono Lake, California. 3. Biogeochemical response to stratification and overturn: Limnology and Oceanography, v. 38, no. 5, p. 1040-1051, https://doi.org/10.4319/lo.1993.38.5.1040.","productDescription":"12 p.","startPage":"1040","endPage":"1051","costCenters":[{"id":589,"text":"Toxic Substances Hydrology Program","active":true,"usgs":true}],"links":[{"id":479502,"rank":1,"type":{"id":40,"text":"Open Access Publisher Index Page"},"url":"https://doi.org/10.4319/lo.1993.38.5.1040","text":"Publisher Index Page"},{"id":228354,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"country":"United States","state":"California","otherGeospatial":"Mono Lake","volume":"38","issue":"5","noUsgsAuthors":false,"publicationDate":"2003-12-22","publicationStatus":"PW","scienceBaseUri":"505a543fe4b0c8380cd6cf10","contributors":{"authors":[{"text":"Miller, Laurence G. 0000-0002-7807-3475 lgmiller@usgs.gov","orcid":"https://orcid.org/0000-0002-7807-3475","contributorId":2460,"corporation":false,"usgs":true,"family":"Miller","given":"Laurence G.","email":"lgmiller@usgs.gov","affiliations":[{"id":438,"text":"National Research Program - Western Branch","active":true,"usgs":true}],"preferred":true,"id":377883,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Jellison, R.","contributorId":103428,"corporation":false,"usgs":true,"family":"Jellison","given":"R.","email":"","affiliations":[],"preferred":false,"id":377886,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Oremland, Ronald S. 0000-0001-7382-0147 roremlan@usgs.gov","orcid":"https://orcid.org/0000-0001-7382-0147","contributorId":931,"corporation":false,"usgs":true,"family":"Oremland","given":"Ronald","email":"roremlan@usgs.gov","middleInitial":"S.","affiliations":[{"id":37277,"text":"WMA - Earth System Processes Division","active":true,"usgs":true},{"id":438,"text":"National Research Program - Western Branch","active":true,"usgs":true}],"preferred":true,"id":377885,"contributorType":{"id":1,"text":"Authors"},"rank":3},{"text":"Culbertson, Charles W. cculbert@usgs.gov","contributorId":1607,"corporation":false,"usgs":true,"family":"Culbertson","given":"Charles","email":"cculbert@usgs.gov","middleInitial":"W.","affiliations":[{"id":371,"text":"Maine Water Science Center","active":true,"usgs":true}],"preferred":true,"id":377884,"contributorType":{"id":1,"text":"Authors"},"rank":4}]}}
,{"id":70017920,"text":"70017920 - 1993 - Stable isotope enrichment in paleowaters of the southeast Atlantic coastal plain, United States","interactions":[],"lastModifiedDate":"2019-03-06T10:22:57","indexId":"70017920","displayToPublicDate":"1993-01-01T00:00:00","publicationYear":"1993","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":3338,"text":"Science","active":true,"publicationSubtype":{"id":10}},"title":"Stable isotope enrichment in paleowaters of the southeast Atlantic coastal plain, United States","docAbstract":"<div class=\"panel-pane pane-highwire-panel-tabs-container article__body\"><div class=\"pane-content\"><div id=\"panels-ajax-tab-container-highwire_article_tabs\" class=\"panels-ajax-tab-container\" data-panels-ajax-tab-preloaded=\"jnl_sci_tab_art\"><div class=\"panels-ajax-tab-wrap-jnl_sci_tab_art\"><div class=\"panel-display panel-1col clearfix\"><div class=\"panel-panel panel-col\"><div><div class=\"panel-pane pane-highwire-markup\"><div class=\"pane-content\"><div class=\"highwire-markup\"><div id=\"content-block-markup\" data-highwire-cite-ref-tooltip-instance=\"highwire_reflinks_tooltip\" data-highwire-glossary-tooltip-instance=\"highwire_reflinks_tooltip\"><div class=\"article abstract-view \"><div id=\"abstract-1\" class=\"section abstract\"><p id=\"p-1\">Paleowaters from the Floridan aquifer system in the southeastern Atlantic coastal plain have higher D/H and<span>&nbsp;</span><sup>18</sup>O/<sup>16</sup>O ratios than local Holocene ground water. Maximum δ<sup>18</sup>O enrichments in ground water having adjusted radiocarbon ages of 20,000 to 26,000 years are 0.7 to 2.3 per mil. The trend in isotopic enrichment in paleowaters is the reverse of that normally observed in continental glacial age ground water. Dissolved nitrogen and argon concentrations indicate, however, that the average recharge temperature was 5.3°C cooler than that today. The data indicate cool conditions in the southeast Atlantic coastal plain during the last glacial maximum, with recharge limited primarily to late summer tropical cyclones and hurricanes.</p></div></div></div></div></div></div></div></div></div></div></div></div></div>","language":"English","publisher":"Science","doi":"10.1126/science.262.5142.2016","issn":"00368075","usgsCitation":"Plummer, N., 1993, Stable isotope enrichment in paleowaters of the southeast Atlantic coastal plain, United States: Science, v. 262, no. 5142, p. 2016-2020, https://doi.org/10.1126/science.262.5142.2016.","productDescription":"5 p.","startPage":"2016","endPage":"2020","costCenters":[{"id":589,"text":"Toxic Substances Hydrology Program","active":true,"usgs":true}],"links":[{"id":228540,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"volume":"262","issue":"5142","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"505b9676e4b08c986b31b506","contributors":{"authors":[{"text":"Plummer, Niel 0000-0002-4020-1013 nplummer@usgs.gov","orcid":"https://orcid.org/0000-0002-4020-1013","contributorId":190100,"corporation":false,"usgs":true,"family":"Plummer","given":"Niel","email":"nplummer@usgs.gov","affiliations":[{"id":436,"text":"National Research Program - Eastern Branch","active":true,"usgs":true}],"preferred":true,"id":377917,"contributorType":{"id":1,"text":"Authors"},"rank":1}]}}
,{"id":70017959,"text":"70017959 - 1993 - Nonpoint source contamination of the Mississippi river and its tributaries by herbicides","interactions":[],"lastModifiedDate":"2019-03-07T06:45:47","indexId":"70017959","displayToPublicDate":"1993-01-01T00:00:00","publicationYear":"1993","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":1565,"text":"Environmental Science & Technology","onlineIssn":"1520-5851","printIssn":"0013-936X","active":true,"publicationSubtype":{"id":10}},"title":"Nonpoint source contamination of the Mississippi river and its tributaries by herbicides","docAbstract":"A study of the Mississippi River and its tributaries during July-August 1991, October-November 1991, and April-May 1992 has indicated that the entire navigable reach of the river is contaminated with a complex mixture of agrochemicals and their transformation products derived from nonpoint sources. Twenty-three compounds were identified, including triazine, chloroacetanilide, thiocarbamate, phenylurea, pyridazine, and organophosphorus pesticides. The upper and middle Mississippi River Basin farm lands are major sources of herbicides applied to corn, soybeans, and sorghum. Farm lands in the lower Mississippi River Basin are a major source of rice and cotton herbicides. Inputs of the five major herbicides atrazine, cyanazine, metolachlor, alachlor, and simazine to the Mississippi River are mainly from the Minnesota, Des Moines, Missouri, and Ohio Rivers. Ratios of desethylatrazine/atrazine potentially are useful indicators of groundwater and surface water interactions in the Mississippi River. These ratios suggested that during baseflow conditions, there is a significant groundwater contribution to the river. The Mississippi River thus serves as a drainage channel for pesticide-contaminated surface and groundwater from the midwestern United States. Conservative estimates of annual mass transport indicated that about 160 t of atrazine, 71 t of cyanazine, 56 t of metolachlor, and 18 t of alachlor were discharged into the Gulf of Mexico in 1991.","language":"English","publisher":"ACS","doi":"10.1021/es00045a008","issn":"0013936X","usgsCitation":"Pereira, W.E., and Hostettler, F., 1993, Nonpoint source contamination of the Mississippi river and its tributaries by herbicides: Environmental Science & Technology, v. 27, no. 8, p. 1542-1552, https://doi.org/10.1021/es00045a008.","productDescription":"11 p. ","startPage":"1542","endPage":"1552","costCenters":[{"id":589,"text":"Toxic Substances Hydrology Program","active":true,"usgs":true}],"links":[{"id":228357,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"volume":"27","issue":"8","noUsgsAuthors":false,"publicationDate":"2002-05-01","publicationStatus":"PW","scienceBaseUri":"505a67a4e4b0c8380cd73413","contributors":{"authors":[{"text":"Pereira, W. E.","contributorId":46981,"corporation":false,"usgs":true,"family":"Pereira","given":"W.","email":"","middleInitial":"E.","affiliations":[],"preferred":false,"id":378038,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Hostettler, F. D.","contributorId":99563,"corporation":false,"usgs":true,"family":"Hostettler","given":"F. D.","affiliations":[],"preferred":false,"id":378039,"contributorType":{"id":1,"text":"Authors"},"rank":2}]}}
,{"id":70017968,"text":"70017968 - 1993 - Spatial variability of triazine herbicides in the Lower Mississippi River","interactions":[],"lastModifiedDate":"2019-03-06T05:52:24","indexId":"70017968","displayToPublicDate":"1993-01-01T00:00:00","publicationYear":"1993","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":1565,"text":"Environmental Science & Technology","onlineIssn":"1520-5851","printIssn":"0013-936X","active":true,"publicationSubtype":{"id":10}},"title":"Spatial variability of triazine herbicides in the Lower Mississippi River","docAbstract":"<p>No abstract available.&nbsp;</p>","language":"English","publisher":"ACS","doi":"10.1021/es00047a018","issn":"0013936X","usgsCitation":"Moody, J.A., and Goolsby, D.A., 1993, Spatial variability of triazine herbicides in the Lower Mississippi River: Environmental Science & Technology, v. 27, no. 10, p. 2120-2126, https://doi.org/10.1021/es00047a018.","productDescription":"7 p.","startPage":"2120","endPage":"2126","costCenters":[{"id":589,"text":"Toxic Substances Hydrology Program","active":true,"usgs":true}],"links":[{"id":228495,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"volume":"27","issue":"10","noUsgsAuthors":false,"publicationDate":"2002-05-01","publicationStatus":"PW","scienceBaseUri":"505b94b5e4b08c986b31ac02","contributors":{"authors":[{"text":"Moody, J. A.","contributorId":32930,"corporation":false,"usgs":true,"family":"Moody","given":"J.","email":"","middleInitial":"A.","affiliations":[],"preferred":false,"id":378061,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Goolsby, D. A.","contributorId":50508,"corporation":false,"usgs":true,"family":"Goolsby","given":"D.","email":"","middleInitial":"A.","affiliations":[],"preferred":false,"id":378062,"contributorType":{"id":1,"text":"Authors"},"rank":2}]}}
,{"id":70018018,"text":"70018018 - 1993 - Calibrated models as management tools for stream-aquifer systems: The case of central Kansas, USA","interactions":[],"lastModifiedDate":"2025-03-06T16:31:39.49638","indexId":"70018018","displayToPublicDate":"1993-01-01T00:00:00","publicationYear":"1993","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":2342,"text":"Journal of Hydrology","active":true,"publicationSubtype":{"id":10}},"title":"Calibrated models as management tools for stream-aquifer systems: The case of central Kansas, USA","docAbstract":"<p><span>We address the problem of declining streamflows in interconnected stream-aquifer systems and explore possible management options to address the problem for two areas of central Kansas: the Arkansas River valley from Kinsley to Great Bend and the lower Rattlesnake Creek-Quivira National Wildlife Refuge area. The approach we followed implements, calibrates, and partially validates for the study areas a stream-aquifer numerical model combined with a parameter estimation package and sensitivity analysis. Hydrologic budgets for both predevelopment and developed conditions indicate significant differences in the hydrologic components of the study areas resulting from development. The predevelopment water budgets give an estimate of natural ground-water recharge, whereas the budgets for developed conditions give an estimate of induced recharge, indicating that major ground-water development changes the recharge-discharge regime of the model areas with time. Such stream-aquifer models serve to link proposed actions to hydrologic effects, as is clearly demonstrated by the effects of various management alternatives on the streamflows of the Arkansas River and Rattlesnake Creek. Thus we show that a possible means of restoring specified streamflows in the area is to implement protective stream corridors with restricted ground-water extraction.</span></p>","language":"English","publisher":"Elsevier","doi":"10.1016/0022-1694(93)90140-5","issn":"00221694","usgsCitation":"Sophocleous, M., and Perkins, S., 1993, Calibrated models as management tools for stream-aquifer systems: The case of central Kansas, USA: Journal of Hydrology, v. 152, no. 1-4, p. 31-56, https://doi.org/10.1016/0022-1694(93)90140-5.","productDescription":"26 p.","startPage":"31","endPage":"56","numberOfPages":"26","costCenters":[],"links":[{"id":228409,"rank":1,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"volume":"152","issue":"1-4","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"5059f30be4b0c8380cd4b582","contributors":{"authors":[{"text":"Sophocleous, M.","contributorId":13373,"corporation":false,"usgs":true,"family":"Sophocleous","given":"M.","email":"","affiliations":[],"preferred":false,"id":378208,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Perkins, S.P.","contributorId":12211,"corporation":false,"usgs":true,"family":"Perkins","given":"S.P.","email":"","affiliations":[],"preferred":false,"id":378207,"contributorType":{"id":1,"text":"Authors"},"rank":2}]}}
,{"id":70018021,"text":"70018021 - 1993 - Flooding of Sinking Creek, Garretts Spring karst drainage basin, Jessamine and Woodford counties, Kentucky, USA","interactions":[],"lastModifiedDate":"2012-03-12T17:19:58","indexId":"70018021","displayToPublicDate":"1993-01-01T00:00:00","publicationYear":"1993","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":1539,"text":"Environmental Geology","active":true,"publicationSubtype":{"id":10}},"title":"Flooding of Sinking Creek, Garretts Spring karst drainage basin, Jessamine and Woodford counties, Kentucky, USA","docAbstract":"Tashamingo Subdivision in Sinking Creek karst valley, a tributary of the Garretts Spring drainage basin in Jessamine and Woodford counties, Kentucky, was flooded in February 1989. To determine the cause of flooding, the groundwater basin boundary was mapped, discharge data were measured to determine intake capacity of swallets, and hydrologic modeling of the basin was conducted. Swallet capacity was determined to be limited by the hydraulic parameters of the conduit, rather than by obstruction by trash. Flooding from a precipitation event is more likely, and will be higher, when antecedent soil moisture conditions in the watershed are near saturation. Hydrologic modeling shows that suburban development of 20 percent of the southeast basin will cause a small increase in flood stage at Tashamingo Subdivision. ?? 1993 Springer-Verlag.","largerWorkType":{"id":2,"text":"Article"},"largerWorkTitle":"Environmental Geology","largerWorkSubtype":{"id":10,"text":"Journal Article"},"language":"English","publisherLocation":"Springer-Verlag","doi":"10.1007/BF00767507","issn":"01775146","usgsCitation":"Currens, J., and Graham, C., 1993, Flooding of Sinking Creek, Garretts Spring karst drainage basin, Jessamine and Woodford counties, Kentucky, USA: Environmental Geology, v. 22, no. 4, p. 337-344, https://doi.org/10.1007/BF00767507.","startPage":"337","endPage":"344","numberOfPages":"8","costCenters":[],"links":[{"id":206114,"rank":9999,"type":{"id":10,"text":"Digital Object Identifier"},"url":"https://dx.doi.org/10.1007/BF00767507"},{"id":228456,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"volume":"22","issue":"4","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"505a1187e4b0c8380cd54014","contributors":{"authors":[{"text":"Currens, J.C.","contributorId":72036,"corporation":false,"usgs":true,"family":"Currens","given":"J.C.","email":"","affiliations":[],"preferred":false,"id":378215,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Graham, C.D.R.","contributorId":85736,"corporation":false,"usgs":true,"family":"Graham","given":"C.D.R.","email":"","affiliations":[],"preferred":false,"id":378216,"contributorType":{"id":1,"text":"Authors"},"rank":2}]}}
,{"id":70018027,"text":"70018027 - 1993 - Dissolved inorganic nitrogen composition, transformation, retention, and transport in naturally phosphate-rich and phosphate-poor tropical streams","interactions":[],"lastModifiedDate":"2019-03-04T19:56:40","indexId":"70018027","displayToPublicDate":"1993-01-01T00:00:00","publicationYear":"1993","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":1169,"text":"Canadian Journal of Fisheries and Aquatic Sciences","active":true,"publicationSubtype":{"id":10}},"title":"Dissolved inorganic nitrogen composition, transformation, retention, and transport in naturally phosphate-rich and phosphate-poor tropical streams","docAbstract":"<div class=\"box-pad border-lightgray margin-bottom\"><div><div class=\"abstractSection\"><div class=\"abstractSection abstractInFull\"><p class=\"first last\">The composition, transformation, and transport of dissolved inorganic nitrogen (DIN) was compared in waters associated with two lowland streams in Costa Rica. The Salto River is enriched by geothermal-based soluble reactive phosphorus (SRP), which raises the concentration up to 200 μg/L whereas Pantano Creek, an unimpacted tributary, has an SRP concentration &lt;10 μg/L. Ammonium concentration in springs adjacent to the Salto and Pantano was typically greater than channel water (13 of 22 locations) whereas nitrate concentration was less (20 of 22 locations). Ground waters were typically high in ammonium relative to nitrate whereas channel waters were high in nitrate relative to ammonium. Sediment slurry studies indicated nitrification potential in two sediment types, firm clay (3.34 μg N∙cm<sup>−3</sup>∙d<sup>−1</sup>) and uncompacted organic-rich sediment (1.76 μg N∙cm<sup>−3</sup>∙d<sup>−1</sup>). Ammonium and nitrate amendments to each stream separately resulted in nitrate concentrations in excess of that expected after correction for dilution using a conservative tracer. SRP concentration was not affected by DIN amendment to either stream. SRP concentration in the Pantano appeared to be regulated by abiotic sediment exchange reactions whereas DIN composition and concentration were regulated by a combination of biotic and abiotic processes.</p></div></div></div></div>","language":"English","publisher":"Canadian Science Publishing","doi":"10.1139/f93-077","usgsCitation":"Triska, F., Pringle, C.M., Zellweger, G.W., Duff, J., and Avanzino, R., 1993, Dissolved inorganic nitrogen composition, transformation, retention, and transport in naturally phosphate-rich and phosphate-poor tropical streams: Canadian Journal of Fisheries and Aquatic Sciences, v. 50, no. 3, p. 665-675, https://doi.org/10.1139/f93-077.","productDescription":"11 p.","startPage":"665","endPage":"675","costCenters":[{"id":589,"text":"Toxic Substances Hydrology Program","active":true,"usgs":true}],"links":[{"id":228545,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"},{"id":269546,"type":{"id":10,"text":"Digital Object Identifier"},"url":"https://dx.doi.org/10.1139/f93-077"}],"volume":"50","issue":"3","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"505a0234e4b0c8380cd4ff41","contributors":{"authors":[{"text":"Triska, F.J.","contributorId":69560,"corporation":false,"usgs":true,"family":"Triska","given":"F.J.","email":"","affiliations":[],"preferred":false,"id":378232,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Pringle, C. M.","contributorId":72902,"corporation":false,"usgs":false,"family":"Pringle","given":"C.","email":"","middleInitial":"M.","affiliations":[],"preferred":false,"id":378233,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Zellweger, G. W.","contributorId":55445,"corporation":false,"usgs":true,"family":"Zellweger","given":"G.","email":"","middleInitial":"W.","affiliations":[],"preferred":false,"id":378230,"contributorType":{"id":1,"text":"Authors"},"rank":3},{"text":"Duff, J.H.","contributorId":60377,"corporation":false,"usgs":true,"family":"Duff","given":"J.H.","email":"","affiliations":[],"preferred":false,"id":378231,"contributorType":{"id":1,"text":"Authors"},"rank":4},{"text":"Avanzino, R.J.","contributorId":37336,"corporation":false,"usgs":true,"family":"Avanzino","given":"R.J.","affiliations":[],"preferred":false,"id":378229,"contributorType":{"id":1,"text":"Authors"},"rank":5}]}}
,{"id":70018031,"text":"70018031 - 1993 - A finite-volume Eulerian-Lagrangian Localized Adjoint Method for solution of the advection-dispersion equation","interactions":[],"lastModifiedDate":"2019-03-06T07:15:06","indexId":"70018031","displayToPublicDate":"1993-01-01T00:00:00","publicationYear":"1993","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":3722,"text":"Water Resources Research","onlineIssn":"1944-7973","printIssn":"0043-1397","active":true,"publicationSubtype":{"id":10}},"title":"A finite-volume Eulerian-Lagrangian Localized Adjoint Method for solution of the advection-dispersion equation","docAbstract":"<p><span>A new mass-conservative method for solution of the one-dimensional advection-dispersion equation is derived and discussed. Test results demonstrate that the finite-volume Eulerian-Lagrangian localized adjoint method (FVELLAM) outperforms standard finite-difference methods, in terms of accuracy and efficiency, for solute transport problems that are dominated by advection. For dispersion-dominated problems, the performance of the method is similar to that of standard methods. Like previous ELLAM formulations, FVELLAM systematically conserves mass globally with all types of boundary conditions. FVELLAM differs from other ELLAM approaches in that integrated finite differences, instead of finite elements, are used to approximate the governing equation. This approach, in conjunction with a forward tracking scheme, greatly facilitates mass conservation. The mass storage integral is numerically evaluated at the current time level, and quadrature points are then tracked forward in time to the next level. Forward tracking permits straightforward treatment of inflow boundaries, thus avoiding the inherent problem in backtracking, as used by most characteristic methods, of characteristic lines intersecting inflow boundaries. FVELLAM extends previous ELLAM results by obtaining mass conservation locally on Lagrangian space-time elements. Details of the integration, tracking, and boundary algorithms are presented. Test results are given for problems in Cartesian and radial coordinates.</span></p>","language":"English","publisher":"American Geophysical Union","doi":"10.1029/93WR00403","usgsCitation":"Healy, R.W., and Russell, T., 1993, A finite-volume Eulerian-Lagrangian Localized Adjoint Method for solution of the advection-dispersion equation: Water Resources Research, v. 29, no. 7, p. 2399-2413, https://doi.org/10.1029/93WR00403.","productDescription":"15 p.","startPage":"2399","endPage":"2413","costCenters":[{"id":589,"text":"Toxic Substances Hydrology Program","active":true,"usgs":true}],"links":[{"id":228596,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"volume":"29","issue":"7","noUsgsAuthors":false,"publicationDate":"2010-07-09","publicationStatus":"PW","scienceBaseUri":"5059e3dbe4b0c8380cd46269","contributors":{"authors":[{"text":"Healy, R. W.","contributorId":89872,"corporation":false,"usgs":true,"family":"Healy","given":"R.","email":"","middleInitial":"W.","affiliations":[],"preferred":false,"id":378242,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Russell, T.F.","contributorId":86811,"corporation":false,"usgs":true,"family":"Russell","given":"T.F.","email":"","affiliations":[],"preferred":false,"id":378241,"contributorType":{"id":1,"text":"Authors"},"rank":2}]}}
,{"id":70018044,"text":"70018044 - 1993 - Simulation and mapping of soil-water conditions in the Great Plains","interactions":[],"lastModifiedDate":"2013-02-19T10:54:39","indexId":"70018044","displayToPublicDate":"1993-01-01T00:00:00","publicationYear":"1993","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":3718,"text":"Water Resources Bulletin","printIssn":"0043-1370","active":true,"publicationSubtype":{"id":10}},"title":"Simulation and mapping of soil-water conditions in the Great Plains","docAbstract":"Soil-water conditions provide valuable insight into the hydrologic system in an area. A soil-water balance quantitatively summarizes soil-water conditions and is based on climatic, soil, and vegetation characteristics that vary spatially and temporally. Soil-water balances in the Great Plains of the central United States were simulated for 1951-1980. Results of the simulations were mean annual estimates of infiltration, runoff, actual evapotranspiration, potential recharge, and consumptive water and irrigation requirements at 152 climatic data stations. A method was developed using a geographic information system to integrate and map the simulation results on the basis of spatially variable climatic, soil, and vegetation characteristics. As an example, simulated mean annual potential recharge was mapped. Mean annual potential-recharge rates ranged from less than 0.5 inch in much of the north-central and southwestern Great Plains to more than 10 inches in parts of eastern Texas and southwestern Arkansas.","largerWorkType":{"id":2,"text":"Article"},"largerWorkTitle":"Water Resources Bulletin","largerWorkSubtype":{"id":10,"text":"Journal Article"},"language":"English","publisher":"American Water Resources Association","doi":"10.1111/j.1752-1688.1993.tb03255.x","issn":"00431370","usgsCitation":"Zelt, R.B., and Dugan, J.T., 1993, Simulation and mapping of soil-water conditions in the Great Plains: Water Resources Bulletin, v. 29, no. 6, p. 939-948, https://doi.org/10.1111/j.1752-1688.1993.tb03255.x.","startPage":"939","endPage":"948","numberOfPages":"10","costCenters":[],"links":[{"id":267685,"type":{"id":10,"text":"Digital Object Identifier"},"url":"https://dx.doi.org/10.1111/j.1752-1688.1993.tb03255.x"},{"id":228743,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"volume":"29","issue":"6","noUsgsAuthors":false,"publicationDate":"2007-06-08","publicationStatus":"PW","scienceBaseUri":"505b8fe6e4b08c986b3191e0","contributors":{"authors":[{"text":"Zelt, R. B.","contributorId":34913,"corporation":false,"usgs":true,"family":"Zelt","given":"R.","email":"","middleInitial":"B.","affiliations":[],"preferred":false,"id":378298,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Dugan, J. T.","contributorId":67890,"corporation":false,"usgs":true,"family":"Dugan","given":"J.","email":"","middleInitial":"T.","affiliations":[],"preferred":false,"id":378299,"contributorType":{"id":1,"text":"Authors"},"rank":2}]}}
,{"id":70018217,"text":"70018217 - 1993 - Hydrology and chemistry of groundwater and seasonal ponds in the Atlantic Coastal Plain in Delaware, USA","interactions":[],"lastModifiedDate":"2025-03-06T16:40:04.417204","indexId":"70018217","displayToPublicDate":"1993-01-01T00:00:00","publicationYear":"1993","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":2342,"text":"Journal of Hydrology","active":true,"publicationSubtype":{"id":10}},"title":"Hydrology and chemistry of groundwater and seasonal ponds in the Atlantic Coastal Plain in Delaware, USA","docAbstract":"<p><span>The hydrochemistry of small seasonal ponds was investigated by studying relations between ground-water and surface water in a forested Coastal Plain drainage basin. Observation of changes in the water table in a series of wells equipped with automatic water-level recorders showed that the relation between water-table configuration and basin topography changes seasonally, and particularly in response to spring recharge. Furthermore, in this study area the water table is not a subdued expression of the land surface topography, as is commonly assumed. During the summer and fall months, a water-table trough underlies sandy ridges separating the seasonal ponds, and maximum water-table altitudes prevail in the sediments beneath the dry pond bottoms. As the ponds fill with water during the winter, maximum water-table altitudes shift to the upland-margin zone adjacent to the seasonal ponds. Increases in pond stage are associated with the development of transient water-table mounds at the upland-margin wells during the spring. The importance of small local-flow systems adjacent to the seasonal ponds also is shown by the similarities in the chemistry of the shallow groundwater in the upland margin and water in the seasonal ponds. The upland margin and surface water samples have low pH (generally less than 5.0), and contain large concentrations of dissolved aluminum (generally more than 100 μg 1</span><sup>−1</sup><span>), and low bicarbonate concentrations (2 mg l</span><sup>4</sup><span>&nbsp;or less). In contrast, the parts of the surficial aquifer that do not experience transient mounding have higher pH and larger concentrations of bicarbonate. These results suggest that an understanding of the hydrochemistry of seasonally ponded wetlands requires intensive study of the adjacent shallow groundwater-flow system.</span></p>","language":"English","publisher":"Elsevier","doi":"10.1016/0022-1694(93)90048-E","issn":"00221694","usgsCitation":"Phillips, P.J., and Shedlock, R.J., 1993, Hydrology and chemistry of groundwater and seasonal ponds in the Atlantic Coastal Plain in Delaware, USA: Journal of Hydrology, v. 141, no. 1-4, p. 157-178, https://doi.org/10.1016/0022-1694(93)90048-E.","productDescription":"22 p.","startPage":"157","endPage":"178","numberOfPages":"22","costCenters":[],"links":[{"id":227590,"rank":1,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"volume":"141","issue":"1-4","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"505a36bbe4b0c8380cd6095c","contributors":{"authors":[{"text":"Phillips, P. J.","contributorId":31728,"corporation":false,"usgs":true,"family":"Phillips","given":"P.","email":"","middleInitial":"J.","affiliations":[],"preferred":false,"id":378902,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Shedlock, R. J.","contributorId":91510,"corporation":false,"usgs":true,"family":"Shedlock","given":"R.","email":"","middleInitial":"J.","affiliations":[],"preferred":false,"id":378903,"contributorType":{"id":1,"text":"Authors"},"rank":2}]}}
,{"id":70018232,"text":"70018232 - 1993 - Use of principal-component, correlation, and stepwise multiple-regression analyses to investigate selected physical and hydraulic properties of carbonate-rock aquifers","interactions":[],"lastModifiedDate":"2025-03-06T16:37:56.888342","indexId":"70018232","displayToPublicDate":"1993-01-01T00:00:00","publicationYear":"1993","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":2342,"text":"Journal of Hydrology","active":true,"publicationSubtype":{"id":10}},"title":"Use of principal-component, correlation, and stepwise multiple-regression analyses to investigate selected physical and hydraulic properties of carbonate-rock aquifers","docAbstract":"<p><span>Correlation analysis in conjunction with principal-component and multiple-regression analyses were applied to laboratory chemical and petrographic data to assess the usefulness of these techniques in evaluating selected physical and hydraulic properties of carbonate-rock aquifers in central Pennsylvania. Correlation and principal-component analyses were used to establish relations and associations among variables, to determine dimensions of property variation of samples, and to filter the variables containing similar information. Principal-component and correlation analyses showed that porosity is related to other measured variables and that permeability is most related to porosity and grain size. Four principal components are found to be significant in explaining the variance of data. Stepwise multiple-regression analysis was used to see how well the measured variables could predict porosity and (or) permeability for this suite of rocks. The variation in permeability and porosity is not totally predicted by the other variables, but the regression is significant at the 5% significance level.</span></p>","language":"English","publisher":"Elsevier","doi":"10.1016/0022-1694(93)90080-S","issn":"00221694","usgsCitation":"Brown, C.E., 1993, Use of principal-component, correlation, and stepwise multiple-regression analyses to investigate selected physical and hydraulic properties of carbonate-rock aquifers: Journal of Hydrology, v. 147, no. 1-4, p. 169-195, https://doi.org/10.1016/0022-1694(93)90080-S.","productDescription":"27 p.","startPage":"169","endPage":"195","numberOfPages":"27","costCenters":[],"links":[{"id":227146,"rank":1,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"volume":"147","issue":"1-4","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"505bbf5de4b08c986b329b00","contributors":{"authors":[{"text":"Brown, C. Erwin","contributorId":96261,"corporation":false,"usgs":true,"family":"Brown","given":"C.","email":"","middleInitial":"Erwin","affiliations":[],"preferred":false,"id":378938,"contributorType":{"id":1,"text":"Authors"},"rank":1}]}}
,{"id":70018251,"text":"70018251 - 1993 - The role of water exchange between a stream channel and its hyporheic zone in nitrogen cycling at the terrestrial-aquatic interface","interactions":[],"lastModifiedDate":"2019-03-04T20:04:05","indexId":"70018251","displayToPublicDate":"1993-01-01T00:00:00","publicationYear":"1993","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":1919,"text":"Hydrobiologia","onlineIssn":"1573-5117","printIssn":"0018-8158","active":true,"publicationSubtype":{"id":10}},"title":"The role of water exchange between a stream channel and its hyporheic zone in nitrogen cycling at the terrestrial-aquatic interface","docAbstract":"<p>The subsurface riparian zone was examined as an ecotone with two interfaces. Inland is a terrestrial boundary, where transport of water and dissolved solutes is toward the channel and controlled by watershed hydrology. Streamside is an aquatic boundary, where exchange of surface water and dissolved solutes is bi-directional and flux is strongly influenced by channel hydraulics. Streamside, bi-directional exchange of water was qualitatively defined using biologically conservative tracers in a third order stream. In several experiments, penetration of surface water extended 18 m inland. Travel time of water from the channel to bankside sediments was highly variable. Subsurface chemical gradients were indirectly related to the travel time. Sites with long travel times tended to be low in nitrate and DO (dissolved oxygen) but high in ammonium and DOC (dissolved organic carbon). Sites with short travel times tended to be high in nitrate and DO but low in ammonium and DOC. Ammonium concentration of interstitial water also was influenced by sorption-desorption processes that involved clay minerals in hyporheic sediments. Denitrification potential in subsurface sediments increased with distance from the channel, and was limited by nitrate at inland sites and by DO in the channel sediments. Conversely, nitrification potential decreased with distance from the channel, and was limited by DO at inland sites and by ammonium at channel locations. Advection of water and dissolved oxygen away from the channel resulted in an oxidized subsurface habitat equivalent to that previously defined as the hyporheic zone. The hyporheic zone is viewed as stream habitat because of its high proportion of surface water and the occurrence of channel organisms. Beyond the channel's hydrologic exchange zone, interstitial water is often chemically reduced. Interstitial water that has not previously entered the channel, groundwater, is viewed as a terrestrial component of the riparian ecotone. Thus, surface water habitats may extend under riparian vegetation, and terrestrial groundwater habitats may be found beneath the stream channel.&nbsp;</p>","language":"English","publisher":"Kluwer Academic Publishers","doi":"10.1007/BF00007177","issn":"00188158","usgsCitation":"Triska, F., Duff, J., and Avanzino, R., 1993, The role of water exchange between a stream channel and its hyporheic zone in nitrogen cycling at the terrestrial-aquatic interface: Hydrobiologia, v. 251, no. 1-3, p. 167-184, https://doi.org/10.1007/BF00007177.","productDescription":"18 p.","startPage":"167","endPage":"184","costCenters":[{"id":589,"text":"Toxic Substances Hydrology Program","active":true,"usgs":true}],"links":[{"id":227411,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"},{"id":205913,"rank":9999,"type":{"id":10,"text":"Digital Object Identifier"},"url":"https://dx.doi.org/10.1007/BF00007177"}],"volume":"251","issue":"1-3","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"505bafa2e4b08c986b32493c","contributors":{"authors":[{"text":"Triska, F.J.","contributorId":69560,"corporation":false,"usgs":true,"family":"Triska","given":"F.J.","email":"","affiliations":[],"preferred":false,"id":379011,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Duff, J.H.","contributorId":60377,"corporation":false,"usgs":true,"family":"Duff","given":"J.H.","email":"","affiliations":[],"preferred":false,"id":379010,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Avanzino, R.J.","contributorId":37336,"corporation":false,"usgs":true,"family":"Avanzino","given":"R.J.","affiliations":[],"preferred":false,"id":379009,"contributorType":{"id":1,"text":"Authors"},"rank":3}]}}
,{"id":70018255,"text":"70018255 - 1993 - Application of mixed-mode, solid-phase extraction in environmental and clinical chemistry. Combining hydrogen-bonding, cation-exchange and Van der Waals interactions","interactions":[],"lastModifiedDate":"2019-03-06T06:41:59","indexId":"70018255","displayToPublicDate":"1993-01-01T00:00:00","publicationYear":"1993","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":2214,"text":"Journal of Chromatography A","active":true,"publicationSubtype":{"id":10}},"title":"Application of mixed-mode, solid-phase extraction in environmental and clinical chemistry. Combining hydrogen-bonding, cation-exchange and Van der Waals interactions","docAbstract":"Silica- and styrene-divinylbenzene-based mixed-mode resins that contain C8, C18 and sulphonated cation-exchange groups were compared for their efficiency in isolation of neutral triazine compounds from water and of the basic drug, benzoylecgonine, from urine. The triazine compounds were isolated by a combination of Van der Waals and hydrogen-bonding interactions, and benzoylecgonine was isolated by Van der Waals interactions and cation exchange. All analytes were eluted with a polar organic solvent contaning 2% ammonium hydroxide. Larger recoveries (95%) were achieved on copolymerized mixed-mode resins where C18 and sulfonic acid are in closer proximity than on 'blended' mixed-mode resins (60-70% recovery).","language":"English","publisher":"Elsevier","doi":"10.1016/0021-9673(93)80349-D","issn":"00219673","usgsCitation":"Mills, M.S., Thurman, E., and Pedersen, M., 1993, Application of mixed-mode, solid-phase extraction in environmental and clinical chemistry. Combining hydrogen-bonding, cation-exchange and Van der Waals interactions: Journal of Chromatography A, v. 629, no. 1, p. 11-21, https://doi.org/10.1016/0021-9673(93)80349-D.","productDescription":"11 p.","startPage":"11","endPage":"21","costCenters":[{"id":589,"text":"Toxic Substances Hydrology Program","active":true,"usgs":true}],"links":[{"id":227459,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"},{"id":205925,"rank":9999,"type":{"id":10,"text":"Digital Object Identifier"},"url":"https://dx.doi.org/10.1016/0021-9673(93)80349-D"}],"volume":"629","issue":"1","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"5059eca8e4b0c8380cd493f1","contributors":{"authors":[{"text":"Mills, M. S.","contributorId":96279,"corporation":false,"usgs":true,"family":"Mills","given":"M.","email":"","middleInitial":"S.","affiliations":[],"preferred":false,"id":379022,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Thurman, E.M.","contributorId":102864,"corporation":false,"usgs":true,"family":"Thurman","given":"E.M.","affiliations":[],"preferred":false,"id":379023,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Pedersen, M.J.","contributorId":28483,"corporation":false,"usgs":true,"family":"Pedersen","given":"M.J.","email":"","affiliations":[],"preferred":false,"id":379021,"contributorType":{"id":1,"text":"Authors"},"rank":3}]}}
,{"id":70018258,"text":"70018258 - 1993 - Effect of treated-sewage contamination upon bacterial energy charge, adenine nucleotides, and DNA content in a sandy aquifer on Cape Cod","interactions":[],"lastModifiedDate":"2023-01-20T15:53:35.041163","indexId":"70018258","displayToPublicDate":"1993-01-01T00:00:00","publicationYear":"1993","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":850,"text":"Applied and Environmental Microbiology","active":true,"publicationSubtype":{"id":10}},"title":"Effect of treated-sewage contamination upon bacterial energy charge, adenine nucleotides, and DNA content in a sandy aquifer on Cape Cod","docAbstract":"<p>Changes in adenylate energy charge (EC<sub>A</sub>) and in total adenine nucleotides (A<sub>T</sub>) and DNA content (both normalized to the abundance of free-living, groundwater bacteria) in response to carbon loading were determined for a laboratory-grown culture and for a contaminated aquifer. The latter study involved a 3-km-long transect through a contaminant plume resulting from continued on-land discharge of secondary sewage to a shallow, sandy aquifer on Cape Cod, Mass. With the exception of the most contaminated groundwater immediately downgradient from the contaminant source, DNA and adenylate levels correlated strongly with bacterial abundance and decreased exponentially with increasing distance downgradient. EC<sub>A</sub>s&nbsp;(0.53 to 0.60) and the ratios of ATP to DNA (0.001 to 0.003) were consistently low, suggesting that the unattached bacteria in this groundwater study are metabolically stressed, despite any eutrophication that might have occurred. Elevated EC<sub>A</sub>s&nbsp;(up to 0.74) were observed in glucose-amended groundwater, confirming that the metabolic state of this microbial community could be altered. In general, per-bacterium DNA and ATP contents were approximately twofold higher in the plume than in surrounding groundwater, although EC<sub>A</sub> and per-bacterium levels of A<sub>T</sub> differed little in the plume and the surrounding uncontaminated groundwater. However, per-bacterium levels of DNA and A<sub>T</sub> varied six- and threefold, respectively, during a 6-h period of decreasing growth rate for an unidentified pseudomonad isolated from contaminated groundwater and grown in batch culture.</p>","language":"English","publisher":"American Society for Microbiology","doi":"10.1128/aem.59.7.2304-2310.1993","issn":"00992240","usgsCitation":"Metge, D.W., Brooks, M.H., Smith, R.L., and Harvey, R.W., 1993, Effect of treated-sewage contamination upon bacterial energy charge, adenine nucleotides, and DNA content in a sandy aquifer on Cape Cod: Applied and Environmental Microbiology, v. 59, no. 7, p. 2304-2310, https://doi.org/10.1128/aem.59.7.2304-2310.1993.","productDescription":"7 p.","startPage":"2304","endPage":"2310","costCenters":[{"id":589,"text":"Toxic Substances Hydrology Program","active":true,"usgs":true}],"links":[{"id":479531,"rank":2,"type":{"id":40,"text":"Open Access Publisher Index Page"},"url":"https://doi.org/10.1128/aem.59.7.2304-2310.1993","text":"Publisher Index Page"},{"id":227504,"rank":1,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"country":"United States","state":"Massachusetts","otherGeospatial":"Cape Cod","geographicExtents":"{\n  \"type\": \"FeatureCollection\",\n  \"features\": [\n    {\n      \"type\": \"Feature\",\n      \"properties\": {},\n      \"geometry\": {\n        \"coordinates\": [\n          [\n            [\n              -70.4838165276592,\n              41.77887286415148\n            ],\n            [\n              -70.52226867609615,\n              41.77375219500422\n            ],\n            [\n              -70.5497344964086,\n              41.77989694891966\n            ],\n            [\n              -70.56621398859664,\n              41.770679597272874\n            ],\n            [\n              -70.58132018976809,\n              41.75428992370044\n            ],\n        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mhbrooks@usgs.gov","contributorId":4386,"corporation":false,"usgs":true,"family":"Brooks","given":"Myron","email":"mhbrooks@usgs.gov","middleInitial":"H.","affiliations":[],"preferred":true,"id":379032,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Smith, Richard L. 0000-0002-3829-0125 rlsmith@usgs.gov","orcid":"https://orcid.org/0000-0002-3829-0125","contributorId":1592,"corporation":false,"usgs":true,"family":"Smith","given":"Richard","email":"rlsmith@usgs.gov","middleInitial":"L.","affiliations":[{"id":38175,"text":"Toxics Substances Hydrology Program","active":true,"usgs":true},{"id":37277,"text":"WMA - Earth System Processes Division","active":true,"usgs":true},{"id":5044,"text":"National Research Program - Central Branch","active":true,"usgs":true},{"id":36183,"text":"Hydro-Ecological Interactions Branch","active":true,"usgs":true}],"preferred":true,"id":379031,"contributorType":{"id":1,"text":"Authors"},"rank":3},{"text":"Harvey, Ronald W. 0000-0002-2791-8503 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,{"id":70018285,"text":"70018285 - 1993 - Heat flow from four new research drill holes in the Western Cascades, Oregon, U.S.A.","interactions":[],"lastModifiedDate":"2019-04-08T10:18:39","indexId":"70018285","displayToPublicDate":"1993-01-01T00:00:00","publicationYear":"1993","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":1828,"text":"Geothermics","active":true,"publicationSubtype":{"id":10}},"title":"Heat flow from four new research drill holes in the Western Cascades, Oregon, U.S.A.","docAbstract":"<p><span>Conceptual models of the thermal structure of the Oregon Cascade Range propose either (1) a narrow zone of magmatic heat sources, flanked by shallow heat-flow anomalies caused by lateral ground-water flow; or (2) a wide zone of magmatic heat sources, with localized, generally negligible ground-water effects. The proposed narrow heat source coincides with the Quaternary volcanic arc, whereas the wider heat source would extend 10–30 km west of the arc. To test the models, four new heat-flow holes were sited west of the Quaternary arc but within the area of the proposed wide heat source. The sites are separated from the Quaternary arc by topographic divides and (or) major river valleys, so that heating by regional-scale ground-water flow seems unlikely. Measured heat flow (76±5 mW mm</span><sup>−2</sup><span>) was significantly lower than the values predicted by interpolation from an existing heat-flow contour map (95±7 mW m</span><sup>−2</sup><span>). The lower values are consistent with a narrow zone of magmatic heat sources. The complete heat-flow data set consists mostly of shallow (100–200 m) data and defines lobate highs around hot-spring groups in the Western Cascades. However, all of the deepest holes in the study area (44°–45°15′N) show hydrologic gradient disturbances extending to depths &gt;200 m, so the shallow data must be extrapolated with caution.</span></p>","language":"English","publisher":"Elsevier","doi":"10.1016/0375-6505(93)90040-T","issn":"03756505","usgsCitation":"Ingebritsen, S.E., Scholl, M.A., and Sherrod, D.R., 1993, Heat flow from four new research drill holes in the Western Cascades, Oregon, U.S.A.: Geothermics, v. 22, no. 3, p. 151-163, https://doi.org/10.1016/0375-6505(93)90040-T.","productDescription":"13 p.","startPage":"151","endPage":"163","costCenters":[{"id":615,"text":"Volcano Hazards Program","active":true,"usgs":true}],"links":[{"id":227151,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"country":"United States","state":"Oregon","otherGeospatial":"Western Cascades","volume":"22","issue":"3","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"505a2fffe4b0c8380cd5d2a8","contributors":{"authors":[{"text":"Ingebritsen, S. E.","contributorId":8078,"corporation":false,"usgs":true,"family":"Ingebritsen","given":"S.","email":"","middleInitial":"E.","affiliations":[],"preferred":false,"id":379104,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Scholl, M. A.","contributorId":86365,"corporation":false,"usgs":true,"family":"Scholl","given":"M.","email":"","middleInitial":"A.","affiliations":[],"preferred":false,"id":379106,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Sherrod, D. R.","contributorId":44559,"corporation":false,"usgs":true,"family":"Sherrod","given":"D.","email":"","middleInitial":"R.","affiliations":[],"preferred":false,"id":379105,"contributorType":{"id":1,"text":"Authors"},"rank":3}]}}
,{"id":70018295,"text":"70018295 - 1993 - Summary of revised potentiometric-surface map for Yucca Mountain and vicinity, Nevada","interactions":[],"lastModifiedDate":"2012-03-12T17:19:23","indexId":"70018295","displayToPublicDate":"1993-01-01T00:00:00","publicationYear":"1993","noYear":false,"publicationType":{"id":24,"text":"Conference Paper"},"publicationSubtype":{"id":19,"text":"Conference Paper"},"title":"Summary of revised potentiometric-surface map for Yucca Mountain and vicinity, Nevada","docAbstract":"The revised map for the potentiometric surface of the uppermost saturated zone in Tertiary volcanic rocks at Yucca Mountain, Nevada, is based mainly on 1988 water levels. Refinement of the water-level corrections has increased understanding of the area immediately east-southeast and hydrologically downgradient of Yucca Mountain. This small-gradient area is a nearly horizontal surface which corresponds to the likely direction of ground-water flow from Yucca Mountain - east-southeast. To the west of Yucca Mountain, water levels are approximately 45 m higher than those in the small-gradient area, and to the east of the northern part of Yucca Mountain water levels are approximately 300 m higher than those in the small-gradient area. Water levels are higher to the west of Yucca Mountain apparently because of a barrier to ground-water flow formed by the Solitario Canyon fault and a splay of the fault, and water levels are higher to the north apparently because of a semi-perched ground-water system.","largerWorkTitle":"High Level Radioactive Waste Management","conferenceTitle":"Proceedings of the 4th Annual International Conference on High Level Radioactive Waste Management","conferenceDate":"26 April 1993 through 30 April 1993","conferenceLocation":"Las Vegas, NV, USA","language":"English","publisher":"Publ by ASCE","publisherLocation":"New York, NY, United States","isbn":"0872629503","usgsCitation":"Ervin, E.M., Luckey, R.R., and Burkhardt, D., 1993, Summary of revised potentiometric-surface map for Yucca Mountain and vicinity, Nevada, <i>in</i> High Level Radioactive Waste Management, Las Vegas, NV, USA, 26 April 1993 through 30 April 1993, p. 1554-1558.","startPage":"1554","endPage":"1558","numberOfPages":"5","costCenters":[],"links":[{"id":227288,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"505b9ed8e4b08c986b31e18c","contributors":{"authors":[{"text":"Ervin, E. M.","contributorId":76782,"corporation":false,"usgs":true,"family":"Ervin","given":"E.","email":"","middleInitial":"M.","affiliations":[],"preferred":false,"id":379140,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Luckey, R. R.","contributorId":93055,"corporation":false,"usgs":true,"family":"Luckey","given":"R.","email":"","middleInitial":"R.","affiliations":[],"preferred":false,"id":379141,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Burkhardt, D.J.","contributorId":53398,"corporation":false,"usgs":true,"family":"Burkhardt","given":"D.J.","email":"","affiliations":[],"preferred":false,"id":379139,"contributorType":{"id":1,"text":"Authors"},"rank":3}]}}
,{"id":70018315,"text":"70018315 - 1993 - Variations in aqueous sulfate concentrations at Panola Mountain, Georgia","interactions":[],"lastModifiedDate":"2024-10-24T11:18:40.358182","indexId":"70018315","displayToPublicDate":"1993-01-01T00:00:00","publicationYear":"1993","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":2342,"text":"Journal of Hydrology","active":true,"publicationSubtype":{"id":10}},"title":"Variations in aqueous sulfate concentrations at Panola Mountain, Georgia","docAbstract":"<div id=\"preview-section-abstract\"><div id=\"abstracts\" class=\"Abstracts u-font-serif\"><div id=\"aep-abstract-id4\" class=\"abstract author\"><div id=\"aep-abstract-sec-id5\"><div class=\"u-margin-s-bottom\">Aqueous sulfate concentrations were measured in incident precipitation, canopy throughfall, stemflow, soil water, groundwater, and streamwater at three locations in a 41 ha forested watershed at Panola Mountain State Park in the Georgia Piedmont. To evaluate the variations in sulfate concentrations, sampling intensity was increased during storms by automated collection of surface water and by incremental subsampling of rainfall, throughfall, and soil solution. Canopy throughfall, stemflow, and runoff from a bedrock outcrop in the watershed headwaters were enriched in sulfate relative to incident precipitation due to washoff of dry deposition that accumulated between storms. Soil waters collected from zero-tension lysimeters at 15 cm and 50 cm below land surface also were enriched in sulfate relative to precipitation, groundwater and streamwater. Sulfate concentrations in groundwater and in streamwater at base flow varied in an annual sinusoidal pattern with winter maxima and summer minima. Stream discharge and groundwater levels varied in a similar annual pattern in phase with the sulfate concentrations. The temporal variability of sulfate concentrations at most groundwater sites was small relative to the spatial variability among groundwater sites. Streamwater sulfate concentrations during base flow were controlled by low-sulfate groundwater discharge. As flow increased, an increasing proportion of shallow, high-sulfate groundwater and soil water contributed to streamflow. The dominant control on stream sulfate concentration shifted from sulfate retention by adsorption in the mineral soil at base flow to mobilization of sulfate from the upper, organic-rich horizons of the soil at high flow.</div></div></div></div></div><div id=\"preview-section-introduction\"><br></div>","language":"English","publisher":"Elsevier","doi":"10.1016/0022-1694(93)90284-G","issn":"00221694","usgsCitation":"Shanley, J.B., and Peters, N., 1993, Variations in aqueous sulfate concentrations at Panola Mountain, Georgia: Journal of Hydrology, v. 146, no. C, p. 361-382, https://doi.org/10.1016/0022-1694(93)90284-G.","productDescription":"22 p.","startPage":"361","endPage":"382","numberOfPages":"22","costCenters":[],"links":[{"id":227596,"rank":1,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"volume":"146","issue":"C","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"505bc178e4b08c986b32a5b0","contributors":{"authors":[{"text":"Shanley, J. B.","contributorId":52226,"corporation":false,"usgs":true,"family":"Shanley","given":"J.","email":"","middleInitial":"B.","affiliations":[],"preferred":false,"id":379200,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Peters, N.E.","contributorId":33332,"corporation":false,"usgs":true,"family":"Peters","given":"N.E.","email":"","affiliations":[],"preferred":false,"id":379199,"contributorType":{"id":1,"text":"Authors"},"rank":2}]}}
,{"id":70018321,"text":"70018321 - 1993 - Seismic reflection profiling: essential geophysical data for Yucca mountain, Nevada","interactions":[],"lastModifiedDate":"2012-03-12T17:19:13","indexId":"70018321","displayToPublicDate":"1993-01-01T00:00:00","publicationYear":"1993","noYear":false,"publicationType":{"id":24,"text":"Conference Paper"},"publicationSubtype":{"id":19,"text":"Conference Paper"},"title":"Seismic reflection profiling: essential geophysical data for Yucca mountain, Nevada","docAbstract":"Yucca Mountain, Nevada, consists of a thick sequence of ashflow tuffs and lavas fractured into intact blocks with east-dipping strata, marginal broken zones characterized by dense faulting and brecciation, and intervening down-to-the-west fault zones with locally atypical west-dipping strata. Uncertainty in the structural setting of Yucca Mountain has resulted in multiple interpretations of the role and style of faulting. One interpretation describes steep normal faulting extending to seismogenic depth (10 to 15 km), and an alternate explanation suggests listric faults and a major low-angle detachment between the Tertiary volcanic sequence and the underlying Paleozoic rocks. Resolution of the deep geology is critical to evaluations of the potential tectonic and hydrologic hazards of the site. Seismic reflection profiling will provide essential data for defining the subsurface geometry of Yucca Mountain and for distinguishing between alternate interpretations of the structure of the mountain.","largerWorkTitle":"High Level Radioactive Waste Management","conferenceTitle":"Proceedings of the 4th Annual International Conference on High Level Radioactive Waste Management","conferenceDate":"26 April 1993 through 30 April 1993","conferenceLocation":"Las Vegas, NV, USA","language":"English","publisher":"Publ by ASCE","publisherLocation":"New York, NY, United States","isbn":"0872629503","usgsCitation":"Hunter, W., Spengler, R., and Brocher, T., 1993, Seismic reflection profiling: essential geophysical data for Yucca mountain, Nevada, <i>in</i> High Level Radioactive Waste Management, Las Vegas, NV, USA, 26 April 1993 through 30 April 1993, p. 1835-1839.","startPage":"1835","endPage":"1839","numberOfPages":"5","costCenters":[],"links":[{"id":226978,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"505b8b4ae4b08c986b31771a","contributors":{"authors":[{"text":"Hunter, W.C.","contributorId":22769,"corporation":false,"usgs":true,"family":"Hunter","given":"W.C.","email":"","affiliations":[],"preferred":false,"id":379218,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Spengler, R.W.","contributorId":7281,"corporation":false,"usgs":true,"family":"Spengler","given":"R.W.","email":"","affiliations":[],"preferred":false,"id":379217,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Brocher, T.M. 0000-0002-9740-839X","orcid":"https://orcid.org/0000-0002-9740-839X","contributorId":69994,"corporation":false,"usgs":true,"family":"Brocher","given":"T.M.","affiliations":[],"preferred":false,"id":379219,"contributorType":{"id":1,"text":"Authors"},"rank":3}]}}
,{"id":70018324,"text":"70018324 - 1993 - Effects of small-scale vertical variations in well-screen inflow rates and concentrations of organic compounds on the collection of representative ground-water-quality samples","interactions":[],"lastModifiedDate":"2019-03-06T06:02:52","indexId":"70018324","displayToPublicDate":"1993-01-01T00:00:00","publicationYear":"1993","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":1861,"text":"Ground Water","active":true,"publicationSubtype":{"id":10}},"title":"Effects of small-scale vertical variations in well-screen inflow rates and concentrations of organic compounds on the collection of representative ground-water-quality samples","docAbstract":"Because a water sample collected from a well is an integration of water from different depths along the well screen, measured concentrations can be biased if analyte concentrations are not uniform along the length of the well screen. The resulting concentration in the sample, therefore, is a function of variations in well-screen inflow rate and analyte concentration with depth. A multiport sampler with seven short screened intervals was designed and used to investigate small-scale vertical variations in water chemistry and aquifer hydraulic conductivity in ground water contaminated by leaded gasoline at Galloway Township, Atlantic County, New Jersey. The multiport samplers were used to collect independent samples from seven intervals within the screened zone that were flow-rate weighted and integrated to simulate a 5-foot-long, 2.375-inch- outside-diameter conventional wire-wound screen. The integration of the results of analyses of samples collected from two multiport samplers showed that a conventional 5-foot-long well screen would integrate contaminant concentrations over its length and resulted in an apparent contaminant concentration that was a little as 28 percent of the maximum concentration observed in the multiport sampler.","language":"English","publisher":"Wiley","doi":"10.1111/j.1745-6584.1993.tb01812.x","issn":"0017467X","usgsCitation":"Gibs, J., Brown, G.A., Turner, K.S., MacLeod, C., Jelinski, J., and Koehnlein, S.A., 1993, Effects of small-scale vertical variations in well-screen inflow rates and concentrations of organic compounds on the collection of representative ground-water-quality samples: Ground Water, v. 31, no. 2, p. 201-208, https://doi.org/10.1111/j.1745-6584.1993.tb01812.x.","productDescription":"8 p.","startPage":"201","endPage":"208","costCenters":[{"id":589,"text":"Toxic Substances Hydrology Program","active":true,"usgs":true}],"links":[{"id":227021,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"volume":"31","issue":"2","noUsgsAuthors":false,"publicationDate":"2005-08-04","publicationStatus":"PW","scienceBaseUri":"505a07d0e4b0c8380cd51850","contributors":{"authors":[{"text":"Gibs, Jacob jgibs@usgs.gov","contributorId":1729,"corporation":false,"usgs":true,"family":"Gibs","given":"Jacob","email":"jgibs@usgs.gov","affiliations":[],"preferred":true,"id":379228,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Brown, G. Allan","contributorId":29788,"corporation":false,"usgs":true,"family":"Brown","given":"G.","email":"","middleInitial":"Allan","affiliations":[],"preferred":false,"id":379229,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Turner, Kenneth S.","contributorId":80966,"corporation":false,"usgs":true,"family":"Turner","given":"Kenneth","email":"","middleInitial":"S.","affiliations":[],"preferred":false,"id":379232,"contributorType":{"id":1,"text":"Authors"},"rank":3},{"text":"MacLeod, Cecilia L.","contributorId":62250,"corporation":false,"usgs":true,"family":"MacLeod","given":"Cecilia L.","affiliations":[],"preferred":false,"id":379230,"contributorType":{"id":1,"text":"Authors"},"rank":4},{"text":"Jelinski, James","contributorId":82184,"corporation":false,"usgs":true,"family":"Jelinski","given":"James","email":"","affiliations":[],"preferred":false,"id":379233,"contributorType":{"id":1,"text":"Authors"},"rank":5},{"text":"Koehnlein, Susan A.","contributorId":80550,"corporation":false,"usgs":true,"family":"Koehnlein","given":"Susan","email":"","middleInitial":"A.","affiliations":[],"preferred":false,"id":379231,"contributorType":{"id":1,"text":"Authors"},"rank":6}]}}
,{"id":70018326,"text":"70018326 - 1993 - Surface chemistry of ferrihydrite: Part 1. EXAFS studies of the geometry of coprecipitated and adsorbed arsenate","interactions":[],"lastModifiedDate":"2019-03-04T20:20:24","indexId":"70018326","displayToPublicDate":"1993-01-01T00:00:00","publicationYear":"1993","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":1759,"text":"Geochimica et Cosmochimica Acta","active":true,"publicationSubtype":{"id":10}},"title":"Surface chemistry of ferrihydrite: Part 1. EXAFS studies of the geometry of coprecipitated and adsorbed arsenate","docAbstract":"<p>EXAFS spectra were collected on both the As and Fe K-edges from samples of two-line ferrihydrite with adsorbed (ADS) and coprecipitated (CPT) arsenate prepared over a range of conditions and arsenate surface coverages. Spectra also were collected for arsenate adsorbed on the surfaces of three FeOOH crystalline polymorphs, α (goethite), β (akaganeite), and γ (lepidocrocite), and as a free ion in aqueous: solution. Analyses of the As EXAFS show clear evidence for inner sphere bidentate (bridging) arsenate complexes on the ferrihydrite surface and on the surfaces of the crystalline FeOOH polymorphs. The bridging arsenate is attached to adjacent apices of edge-sharing Fe oxyhydroxyl octahedra. The arsenic-iron distance at the interface (<span class=\"math\"><span id=\"MathJax-Element-1-Frame\" class=\"MathJax_SVG\" data-mathml=\"<math xmlns=&quot;http://www.w3.org/1998/Math/MathML&quot;><mtext>3.28 &amp;#xB1;0.01</mtext><mtext>A</mtext><mtext>&amp;#x30A;</mtext></math>\"><span class=\"MJX_Assistive_MathML\">3.28 ±0.01Å</span></span></span>) is close to that expected for this geometry on the FeOOH polymorph surfaces, but is slightly shorter on the ferrihydrite surfaces (<span class=\"math\"><span id=\"MathJax-Element-2-Frame\" class=\"MathJax_SVG\" data-mathml=\"<math xmlns=&quot;http://www.w3.org/1998/Math/MathML&quot;><mtext>3.25 &amp;#xB1; 0.02</mtext><mtext>A</mtext><mtext>&amp;#x30A;</mtext></math>\"><span class=\"MJX_Assistive_MathML\">3.25 ± 0.02Å</span></span></span>). Mono-dentate arsenate linkages (<span class=\"math\"><span id=\"MathJax-Element-3-Frame\" class=\"MathJax_SVG\" data-mathml=\"<math xmlns=&quot;http://www.w3.org/1998/Math/MathML&quot;><mtext>3.60 &amp;#xB1; 0.03</mtext><mtext>A</mtext><mtext>&amp;#x30A;</mtext></math>\"><span class=\"MJX_Assistive_MathML\">3.60 ± 0.03Å</span></span></span>) also occur on the ferrihydrite, but are not generally observed on the crystalline FeOOH polymorphs. The proportion of monodentate bonds appears largest for adsorption samples with the smallest<span>&nbsp;</span><span class=\"math\"><span id=\"MathJax-Element-4-Frame\" class=\"MathJax_SVG\" data-mathml=\"<math xmlns=&quot;http://www.w3.org/1998/Math/MathML&quot;><mtext>As</mtext><mtext>Fe</mtext></math>\"><span class=\"MJX_Assistive_MathML\">AsFe</span></span></span>molar ratio. In all cases the arsenate tetrahedral complex is relatively undistorted with As-O bonds of<span>&nbsp;</span><span class=\"math\"><span id=\"MathJax-Element-5-Frame\" class=\"MathJax_SVG\" data-mathml=\"<math xmlns=&quot;http://www.w3.org/1998/Math/MathML&quot;><mtext>1.66 &amp;#xB1; 0.01</mtext><mtext>A</mtext><mtext>&amp;#x30A;</mtext></math>\"><span class=\"MJX_Assistive_MathML\">1.66 ± 0.01Å</span></span></span>. Precipitation of arsenate or scorodite-like phases was not observed for any samples, all of which were prepared at a pH value of 8.</p><p>The Fe EXAFS results confirm that the Fe-Fe correlations in the ferrihydrite are progressively disrupted in the CPT samples as the<span>&nbsp;</span><span class=\"math\"><span id=\"MathJax-Element-6-Frame\" class=\"MathJax_SVG\" data-mathml=\"<math xmlns=&quot;http://www.w3.org/1998/Math/MathML&quot;><mtext>As</mtext><mtext>Fe</mtext></math>\"><span class=\"MJX_Assistive_MathML\">AsFe</span></span></span><span>&nbsp;</span>ratio is increased. Coherent crystallite size is probably no more than 10 Å in diameter and no Fe oxyhydroxyl octahedra corner-sharing linkages (as would be present in FeOOH polymorphs) are observed at the largest<span>&nbsp;</span><span class=\"math\"><span id=\"MathJax-Element-7-Frame\" class=\"MathJax_SVG\" data-mathml=\"<math xmlns=&quot;http://www.w3.org/1998/Math/MathML&quot;><mtext>As</mtext><mtext>Fe</mtext></math>\"><span class=\"MJX_Assistive_MathML\">AsFe</span></span></span><span>&nbsp;</span>ratios. Comparison of the number and type of Fe-Fe neighbors with the topological constraints imposed by the arsenate saturation limit in the CPT samples (about 0.7<span>&nbsp;</span><span class=\"math\"><span id=\"MathJax-Element-8-Frame\" class=\"MathJax_SVG\" data-mathml=\"<math xmlns=&quot;http://www.w3.org/1998/Math/MathML&quot;><mtext>As</mtext><mtext>Fe</mtext></math>\"><span class=\"MJX_Assistive_MathML\">AsFe</span></span></span>) indicates ferrihydrite units consisting mainly of Fe oxyhydroxyl octahedra arranged in short dioctahedral chains with minimal interchain linking by octahedra corners. This is consistent with an enlarged surface area and a larger proportion of sites for bidentate arsenate bonding in CPT samples as compared to the ADS samples, which saturate with arsenate at lower<span>&nbsp;</span><span class=\"math\"><span id=\"MathJax-Element-9-Frame\" class=\"MathJax_SVG\" data-mathml=\"<math xmlns=&quot;http://www.w3.org/1998/Math/MathML&quot;><mtext>As</mtext><mtext>Fe</mtext></math>\"><span class=\"MJX_Assistive_MathML\">AsFe</span></span></span><span>&nbsp;</span>ratios. The latter samples have larger crystallite sizes and a definite proportion of ferric octahedra sharing corners. The ratio of corner-sharing to edge-sharing Fe oxyhydroxyl octahedra in the ADS samples, and CPT samples with small As loadings, is very similar to what would be present in very small particles of goethite or akaganeite.</p><p>The difference in the polymeric structure of ADS and CPT samples at higher<span>&nbsp;</span><span class=\"math\"><span id=\"MathJax-Element-10-Frame\" class=\"MathJax_SVG\" data-mathml=\"<math xmlns=&quot;http://www.w3.org/1998/Math/MathML&quot;><mtext>As</mtext><mtext>Fe</mtext></math>\"><span class=\"MJX_Assistive_MathML\">AsFe</span></span></span><span>&nbsp;</span>ratios is due to strong arsenate bidentate adsorption that poisons the surface of particles of ferrihydrite precipitated in the presence of substantial arsenate, limiting their normal crystallization, and preventing further Fe-O-Fe polymerization. If the arsenate is applied after precipitation much less adsorption occurs since polymerization has already progressed. In both ADS and CPT samples, Fe-O-Fe polymerization increases with age, though at different rates for each type of sample.</p>","language":"English","publisher":"Elsevier","doi":"10.1016/0016-7037(93)90567-G","issn":"00167037","usgsCitation":"Waychunas, G., Rea, B., Fuller, C.C., and Davis, J., 1993, Surface chemistry of ferrihydrite: Part 1. EXAFS studies of the geometry of coprecipitated and adsorbed arsenate: Geochimica et Cosmochimica Acta, v. 57, no. 10, p. 2251-2269, https://doi.org/10.1016/0016-7037(93)90567-G.","productDescription":"19 p.","startPage":"2251","endPage":"2269","costCenters":[{"id":589,"text":"Toxic Substances Hydrology Program","active":true,"usgs":true}],"links":[{"id":479493,"rank":1,"type":{"id":40,"text":"Open Access Publisher Index Page"},"url":"https://doi.org/10.1016/0016-7037(93)90567-g","text":"Publisher Index Page"},{"id":227064,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"volume":"57","issue":"10","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"505b9f98e4b08c986b31e6cc","contributors":{"authors":[{"text":"Waychunas, G.A.","contributorId":90888,"corporation":false,"usgs":true,"family":"Waychunas","given":"G.A.","email":"","affiliations":[],"preferred":false,"id":379241,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Rea, B.A.","contributorId":39008,"corporation":false,"usgs":true,"family":"Rea","given":"B.A.","email":"","affiliations":[],"preferred":false,"id":379239,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Fuller, C. C.","contributorId":29858,"corporation":false,"usgs":true,"family":"Fuller","given":"C.","email":"","middleInitial":"C.","affiliations":[],"preferred":false,"id":379238,"contributorType":{"id":1,"text":"Authors"},"rank":3},{"text":"Davis, J.A.","contributorId":71694,"corporation":false,"usgs":true,"family":"Davis","given":"J.A.","email":"","affiliations":[],"preferred":false,"id":379240,"contributorType":{"id":1,"text":"Authors"},"rank":4}]}}
,{"id":70018327,"text":"70018327 - 1993 - Surface chemistry of ferrihydrite: Part 2. Kinetics of arsenate adsorption and coprecipitation","interactions":[],"lastModifiedDate":"2019-03-04T19:05:12","indexId":"70018327","displayToPublicDate":"1993-01-01T00:00:00","publicationYear":"1993","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":1759,"text":"Geochimica et Cosmochimica Acta","active":true,"publicationSubtype":{"id":10}},"title":"Surface chemistry of ferrihydrite: Part 2. Kinetics of arsenate adsorption and coprecipitation","docAbstract":"<p>The kinetics of As(V) adsorption by ferrihydrite was investigated in coprecipitation and postsynthesis adsorption experiments conducted in the pH range 7.5-9.0. In coprecipitation experiments, As(V) was present in solution during the hydrolysis and precipitation of iron. In adsorption experiments, a period of rapid (&lt;5 min) As(V) uptake from solution was followed by continued uptake for at least eight days, as As(V) diffused to adsorption sites on ferrihydrite surfaces within aggregates of colloidal particles. The time dependence of As(V) adsorption is well described by a general model for diffusion into a sphere if a subset of surface sites located near the exterior of aggregates is assumed to attain adsorptive equilibrium rapidly. The kinetics of As(V) desorption after an increase in pH were also consistent with diffusion as a rate-limiting process. Aging of pure ferrihydrite prior to As(V) adsorption caused a decrease in adsorption sites on the precipitate owing to crystallite growth. In coprecipitation experiments, the initial As(V) uptake was significantly greater than in post-synthesis adsorption experiments, and the rate of uptake was not diffusion limited because As(V) was coordinated by surface sites before crystallite growth and coagulation processes could proceed. After the initial adsorption, As(V) was slowly released from coprecipitates for at least one month, as crystallite growth caused desorption of As(V). Adsorption densities as high as 0.7 mole As(V) per mole of Fe were measured in coprecipitates, in comparison to 0.25 mole As(V) per mole of Fe in post-synthesis adsorption experiments. Despite the high Concentration of As(V) in the precipitates, EXAFS spectroscopy (Waychunas et al., 1993) showed that neither ferric arsenate nor any other As-bearing surface precipitate or solid solution was formed. The high adsorption densities are possible because the ferrihydrite particles are extremely small, approaching the size of small dioctahedral chains at the highest As(V) adsorption density. The results suggest that the solid solution model proposed by Fox (1989, 1992) for control of arsenate and phosphate concentrations in natural waters may be invalid.&nbsp;</p>","language":"English","publisher":"Elsevier","doi":"10.1016/0016-7037(93)90568-H","issn":"00167037","usgsCitation":"Fuller, C.C., Dadis, J., and Waychunas, G., 1993, Surface chemistry of ferrihydrite: Part 2. Kinetics of arsenate adsorption and coprecipitation: Geochimica et Cosmochimica Acta, v. 57, no. 10, p. 2271-2282, https://doi.org/10.1016/0016-7037(93)90568-H.","productDescription":"12 p.","startPage":"2271","endPage":"2282","costCenters":[{"id":589,"text":"Toxic Substances Hydrology Program","active":true,"usgs":true}],"links":[{"id":227065,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"volume":"57","issue":"10","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"505b9f98e4b08c986b31e6d2","contributors":{"authors":[{"text":"Fuller, C. C.","contributorId":29858,"corporation":false,"usgs":true,"family":"Fuller","given":"C.","email":"","middleInitial":"C.","affiliations":[],"preferred":false,"id":379242,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Dadis, J.A.","contributorId":75288,"corporation":false,"usgs":true,"family":"Dadis","given":"J.A.","email":"","affiliations":[],"preferred":false,"id":379243,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Waychunas, G.A.","contributorId":90888,"corporation":false,"usgs":true,"family":"Waychunas","given":"G.A.","email":"","affiliations":[],"preferred":false,"id":379244,"contributorType":{"id":1,"text":"Authors"},"rank":3}]}}
,{"id":70018339,"text":"70018339 - 1993 - Tectonic characterization of a potential high-level nuclear waste repository at Yucca Mountain, Nevada","interactions":[],"lastModifiedDate":"2012-03-12T17:19:24","indexId":"70018339","displayToPublicDate":"1993-01-01T00:00:00","publicationYear":"1993","noYear":false,"publicationType":{"id":24,"text":"Conference Paper"},"publicationSubtype":{"id":19,"text":"Conference Paper"},"title":"Tectonic characterization of a potential high-level nuclear waste repository at Yucca Mountain, Nevada","docAbstract":"Tectonic characterization of a potential high-level nuclear waste repository at Yucca Mountain, Nevada, is needed to assess seismic and possible volcanic hazards that could affect the site during the preclosure (next 100 years) and the behavior of the hydrologic system during the postclosure (the following 10,000 years) periods. Tectonic characterization is based on assembling mapped geological structures in their chronological order of development and activity, and interpreting their dynamic interrelationships. Addition of mechanistic models and kinematic explanations for the identified tectonic processes provides one or more tectonic models having predictive power. Proper evaluation and application of tectonic models can aid in seismic design and help anticipate probable occurrence of future geologic events of significance to the repository and its design.","largerWorkTitle":"Dynamic Analysis and Design Considerations for High-Level Nuclear Waste Repositories","conferenceTitle":"Proceedings of the Dynamic Analysis and Design Considerations for High-Level Nuclear Waste Repositories","conferenceDate":"19 August 1992 through 20 August 1992","conferenceLocation":"San Francisco, CA, USA","language":"English","publisher":"Publ by ASCE","publisherLocation":"New York, NY, United States","isbn":"0872629457","usgsCitation":"Whitney, J.W., and O’Leary, D.W., 1993, Tectonic characterization of a potential high-level nuclear waste repository at Yucca Mountain, Nevada, <i>in</i> Dynamic Analysis and Design Considerations for High-Level Nuclear Waste Repositories, San Francisco, CA, USA, 19 August 1992 through 20 August 1992, p. 85-96.","startPage":"85","endPage":"96","numberOfPages":"12","costCenters":[],"links":[{"id":227245,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"505ba454e4b08c986b320268","contributors":{"authors":[{"text":"Whitney, John W. 0000-0003-3824-3692 jwhitney@usgs.gov","orcid":"https://orcid.org/0000-0003-3824-3692","contributorId":804,"corporation":false,"usgs":true,"family":"Whitney","given":"John","email":"jwhitney@usgs.gov","middleInitial":"W.","affiliations":[{"id":318,"text":"Geosciences and Environmental Change Science Center","active":true,"usgs":true}],"preferred":true,"id":379270,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"O’Leary, Dennis W.","contributorId":63396,"corporation":false,"usgs":true,"family":"O’Leary","given":"Dennis","email":"","middleInitial":"W.","affiliations":[],"preferred":false,"id":379271,"contributorType":{"id":1,"text":"Authors"},"rank":2}]}}
,{"id":70018340,"text":"70018340 - 1993 - Selected precipitation characteristics in Antelope Valley, Mojave Desert, CA","interactions":[],"lastModifiedDate":"2012-03-12T17:19:23","indexId":"70018340","displayToPublicDate":"1993-01-01T00:00:00","publicationYear":"1993","noYear":false,"publicationType":{"id":24,"text":"Conference Paper"},"publicationSubtype":{"id":19,"text":"Conference Paper"},"title":"Selected precipitation characteristics in Antelope Valley, Mojave Desert, CA","docAbstract":"An urban hydrology study currently in progress in Antelope Valley, California, includes the collection and analyses of precipitation and runoff data. Storms in Antelope Valley are most prevalent during the months of December, January, February, and March, but major storms have occurred during all months of the year except April, June, and July. The areal distribution of precipitation in the valley is influenced by the San Gabriel and Tehachapi Mountains. The rapid change in precipitation intensity with altitude causes large variations in precipitation amounts in basins of close proximity. An analysis of storm-precipitation intensity-duration data for 6 storms during 1938-92 indicates that duration of storm activity ranges from 1 to 4 days, depending on the intensity of the storm. Runoff from a completely urbanized basin averaged 27 percent of precipitation volume for 13 storms from 1989 to 1992. Significant valley-wide storms were recorded in 1943 and 1983 with 1-day precipitation amounts of as much as 5.00 inches; recurrence intervals for storms in those 2 years ranged from 11 to more than 100 years. The February 1992 storm, with 1-day precipitation of 1.51 inches at Palmdale, has a recurrence interval of 3 years. The February 1992 storm produced flooding in Palmdale and Lancaster.","largerWorkTitle":"Proceedings of the Symposium on Engineering Hydrology","conferenceTitle":"Proceedings of the Symposium on Engineering Hydrology","conferenceDate":"25 July 1993 through 30 July 1993","conferenceLocation":"San Francisco, CA, USA","language":"English","publisher":"Publ by ASCE","publisherLocation":"New York, NY, United States","isbn":"087262921X","usgsCitation":"Blodgett, J.C., and Nasseri, I., 1993, Selected precipitation characteristics in Antelope Valley, Mojave Desert, CA, <i>in</i> Proceedings of the Symposium on Engineering Hydrology, San Francisco, CA, USA, 25 July 1993 through 30 July 1993, p. 7-12.","startPage":"7","endPage":"12","numberOfPages":"6","costCenters":[],"links":[{"id":227289,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"505b8c87e4b08c986b317f6f","contributors":{"authors":[{"text":"Blodgett, James C.","contributorId":82348,"corporation":false,"usgs":true,"family":"Blodgett","given":"James","email":"","middleInitial":"C.","affiliations":[],"preferred":false,"id":379272,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Nasseri, Iraj","contributorId":85333,"corporation":false,"usgs":true,"family":"Nasseri","given":"Iraj","email":"","affiliations":[],"preferred":false,"id":379273,"contributorType":{"id":1,"text":"Authors"},"rank":2}]}}
,{"id":70018353,"text":"70018353 - 1993 - Flood elevation limits in the rocky mountains","interactions":[],"lastModifiedDate":"2012-03-12T17:19:23","indexId":"70018353","displayToPublicDate":"1993-01-01T00:00:00","publicationYear":"1993","noYear":false,"publicationType":{"id":24,"text":"Conference Paper"},"publicationSubtype":{"id":19,"text":"Conference Paper"},"title":"Flood elevation limits in the rocky mountains","docAbstract":"An analysis of 77,987 station-years of streamflow-gaging station data from 3,748 stations in the Rocky Mountains indicates that there is a latitude-dependent elevation limit to substantial rainfall-produced flooding. The elevation limit ranges from about 1,650 m in Montana to about 2,350 m in New Mexico. Above this elevation limit, large rainfall-produced floods occur very infrequently and maximum unit discharge is 1.7 m3/s/km2 or less. Below this elevation limit, large-magnitude flooding is more common and maximum unit discharge ranges from to 30 m3/s/km2 in Idaho and Montana to 59 m3/s/km2 in New Mexico. These results emphasize the critical need for additional research to increase our knowledge of floods, and have important implications in water-resources investigations in the Rocky Mountains.","largerWorkTitle":"Proceedings of the Symposium on Engineering Hydrology","conferenceTitle":"Proceedings of the Symposium on Engineering Hydrology","conferenceDate":"25 July 1993 through 30 July 1993","conferenceLocation":"San Francisco, CA, USA","language":"English","publisher":"Publ by ASCE","publisherLocation":"New York, NY, United States","isbn":"087262921X","usgsCitation":"Jarrett, R.D., 1993, Flood elevation limits in the rocky mountains, <i>in</i> Proceedings of the Symposium on Engineering Hydrology, San Francisco, CA, USA, 25 July 1993 through 30 July 1993, p. 180-185.","startPage":"180","endPage":"185","numberOfPages":"6","costCenters":[],"links":[{"id":227467,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"505a10e9e4b0c8380cd53e5a","contributors":{"authors":[{"text":"Jarrett, Robert D. rjarrett@usgs.gov","contributorId":2260,"corporation":false,"usgs":true,"family":"Jarrett","given":"Robert","email":"rjarrett@usgs.gov","middleInitial":"D.","affiliations":[],"preferred":true,"id":379309,"contributorType":{"id":1,"text":"Authors"},"rank":1}]}}
,{"id":70018357,"text":"70018357 - 1993 - Tidal, Residual, Intertidal Mudflat (TRIM) Model and its Applications to San Francisco Bay, California","interactions":[],"lastModifiedDate":"2019-03-06T07:08:13","indexId":"70018357","displayToPublicDate":"1993-01-01T00:00:00","publicationYear":"1993","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":1587,"text":"Estuarine, Coastal and Shelf Science","active":true,"publicationSubtype":{"id":10}},"title":"Tidal, Residual, Intertidal Mudflat (TRIM) Model and its Applications to San Francisco Bay, California","docAbstract":"<p>A numerical model using a semi-implicit finite-difference method for solving the two-dimensional shallow-water equations is presented. The gradient of the water surface elevation in the momentum equations and the velocity divergence in the continuity equation are finite-differenced implicitly, the remaining terms are finite-differenced explicitly. The convective terms are treated using an Eulerian-Lagrangian method. The combination of the semi-implicit finite-difference solution for the gravity wave propagation, and the Eulerian-Lagrangian treatment of the convective terms renders the numerical model unconditionally stable. When the baroclinic forcing is included, a salt transport equation is coupled to the momentum equations, and the numerical method is subject to a weak stability condition. The method of solution and the properties of the numerical model are given. This numerical model is particularly suitable for applications to coastal plain estuaries and tidal embayments in which tidal currents are dominant, and tidally generated residual currents are important. The model is applied to San Francisco Bay, California where extensive historical tides and current-meter data are available. The model calibration is considered by comparing time-series of the field data and of the model results. Alternatively, and perhaps more meaningfully, the model is calibrated by comparing the harmonic constants of tides and tidal currents derived from field data with those derived from the model. The model is further verified by comparing the model results with an independent data set representing the wet season. The strengths and the weaknesses of the model are assessed based on the results of model calibration and verification. Using the model results, the properties of tides and tidal currents in San Francisco Bay are characterized and discussed. Furthermore, using the numerical model, estimates of San Francisco Bay's volume, surface area, mean water depth, tidal prisms, and tidal excursions at spring and neap tides are computed. Additional applications of the model reveal, qualitatively the spatial distribution of residual variables.&nbsp;</p>","language":"English","publisher":"Elsevier","doi":"10.1006/ecss.1993.1016","issn":"02727714","usgsCitation":"Cheng, R.T., Casulli, V., and Gartner, J.W., 1993, Tidal, Residual, Intertidal Mudflat (TRIM) Model and its Applications to San Francisco Bay, California: Estuarine, Coastal and Shelf Science, v. 36, no. 3, p. 235-280, https://doi.org/10.1006/ecss.1993.1016.","productDescription":"46 p.","startPage":"235","endPage":"280","onlineOnly":"N","additionalOnlineFiles":"N","costCenters":[{"id":154,"text":"California Water Science Center","active":true,"usgs":true},{"id":552,"text":"San Francisco Bay-Delta","active":false,"usgs":true},{"id":589,"text":"Toxic Substances Hydrology Program","active":true,"usgs":true},{"id":5079,"text":"Pacific Regional Director's Office","active":true,"usgs":true}],"links":[{"id":227557,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"},{"id":205946,"rank":9999,"type":{"id":10,"text":"Digital Object Identifier"},"url":"https://dx.doi.org/10.1006/ecss.1993.1016"}],"country":"United States","state":"Califoronia","otherGeospatial":"San Francisco Bay","volume":"36","issue":"3","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"505bb37de4b08c986b325dfc","contributors":{"authors":[{"text":"Cheng, R. T.","contributorId":23138,"corporation":false,"usgs":false,"family":"Cheng","given":"R.","email":"","middleInitial":"T.","affiliations":[],"preferred":false,"id":379318,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Casulli, V.","contributorId":65994,"corporation":false,"usgs":true,"family":"Casulli","given":"V.","affiliations":[],"preferred":false,"id":379319,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Gartner, J. W.","contributorId":81903,"corporation":false,"usgs":false,"family":"Gartner","given":"J.","email":"","middleInitial":"W.","affiliations":[],"preferred":false,"id":379320,"contributorType":{"id":1,"text":"Authors"},"rank":3}]}}
]}