The U.S. Geological Survey (USGS) has compiled a national retrospective data set of analyses of volatile organic compounds (VOCs) in ground water of the United States. The data are from Federal, State, and local nonpoint-source monitoring programs, collected between 1985–95. This data set is being used to augment data collected by the USGS National Water-Quality Assessment (NAWQA) Program to ascertain the occurrence of VOCs in ground water nationwide. Eleven attributes of the retrospective data set were evaluated to determine the suitability of the data to augment NAWQA data in answering occurrence questions of varying complexity. These 11 attributes are the VOC analyte list and the associated reporting levels for each VOC, well type, well-casing material, type of openings in the interval (screened interval or open hole), well depth, depth to the top and bottom of the open interval(s), depth to water level in the well, aquifer type (confined or unconfined), and aquifer lithology. VOCs frequently analyzed included solvents, industrial reagents, and refrigerants, but other VOCs of current interest were not frequently analyzed.
\nAbout 70 percent of the sampled wells have the type of well documented in the data set, and about 74 percent have well depth documented. However, the data set generally lacks documentation of other characteristics, such as well-casing material, information about the screened or open interval(s), depth to water level in the well, and aquifer type and lithology. For example, only about 20 percent of the wells include information on depth to water level in the well and only about 14 percent of the wells include information about aquifer type.
\nThe three most important enhancements to VOC data collected in nonpoint-source monitoring programs for use in a national assessment of VOC occurrence in ground water would be an expanded VOC analyte list, recording the reporting level for each analyte for every analysis, and recording key ancillary information about each well. These enhancements would greatly increase the usefulness of VOC data in addressing complex occurrence questions, such as those that seek to explain the reasons for VOC occurrence and nonoccurrence in ground water of the United States.
\nA mass balance approach was used to determine the most important nonpoint source of volatile organic compounds (VOCs) in storm water from an asphalt parking lot without obvious point sources (e.g., gasoline stations). The parking lot surface and atmosphere are important nonpoint sources of VOCs, with each being important for different VOCs. The atmosphere is an important source of soluble, oxygenated VOCs (e.g., acetone), and the parking lot surface is an important source for the more hydrophobic VOCs (e.g., benzene). VOCs on the parking lot surface appear to be concentrated in oil and grease and organic material in urban particles (e.g., vehicle soot). Except in the case of spills, asphalt does not appear to be an important source of VOCs. The uptake isotherm of gaseous methyl tert-butyl ether on urban particles indicates a mechanism for dry deposition of VOCs from the atmosphere. This study demonstrated that a mass balance approach is a useful means of understanding non-point-source pollution, even for compounds such as VOCs, which are difficult to sample.
","largerWorkType":{"id":2,"text":"Article"},"largerWorkTitle":"Journal of Environmental Engineering","largerWorkSubtype":{"id":10,"text":"Journal Article"},"language":"English","publisher":"ASCE","publisherLocation":"Reston, VA, United States","doi":"10.1061/(ASCE)0733-9372(2000)126:12(1137)","issn":"07339372","usgsCitation":"Lopes, T.J., Fallon, J.D., Rutherford, D., and Hiatt, M., 2000, Volatile organic compounds in storm water from a parking lot: Journal of Environmental Engineering, v. 126, no. 12, p. 1137-1143, https://doi.org/10.1061/(ASCE)0733-9372(2000)126:12(1137).","productDescription":"7 p.","startPage":"1137","endPage":"1143","onlineOnly":"N","additionalOnlineFiles":"N","costCenters":[{"id":392,"text":"Minnesota Water Science Center","active":true,"usgs":true}],"links":[{"id":206733,"rank":9999,"type":{"id":10,"text":"Digital Object Identifier"},"url":"https://dx.doi.org/10.1061/(ASCE)0733-9372(2000)126:12(1137)"},{"id":230661,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"volume":"126","issue":"12","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"505bc2c5e4b08c986b32ad57","contributors":{"authors":[{"text":"Lopes, T. J.","contributorId":9631,"corporation":false,"usgs":true,"family":"Lopes","given":"T.","email":"","middleInitial":"J.","affiliations":[],"preferred":false,"id":392326,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Fallon, J. D.","contributorId":57478,"corporation":false,"usgs":true,"family":"Fallon","given":"J.","email":"","middleInitial":"D.","affiliations":[],"preferred":false,"id":392328,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Rutherford, D.W.","contributorId":21244,"corporation":false,"usgs":true,"family":"Rutherford","given":"D.W.","email":"","affiliations":[],"preferred":false,"id":392327,"contributorType":{"id":1,"text":"Authors"},"rank":3},{"text":"Hiatt, M.H.","contributorId":80449,"corporation":false,"usgs":true,"family":"Hiatt","given":"M.H.","email":"","affiliations":[],"preferred":false,"id":392329,"contributorType":{"id":1,"text":"Authors"},"rank":4}]}} ,{"id":1015328,"text":"1015328 - 2000 - Ecosystem responses to nitrogen deposition in the Colorado Front Range","interactions":[],"lastModifiedDate":"2018-02-21T17:27:32","indexId":"1015328","displayToPublicDate":"2000-01-01T00:00:00","publicationYear":"2000","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":1478,"text":"Ecosystems","active":true,"publicationSubtype":{"id":10}},"title":"Ecosystem responses to nitrogen deposition in the Colorado Front Range","docAbstract":"We asked whether 3–5 kg N y−1 atmospheric N deposition was sufficient to have influenced natural, otherwise undisturbed, terrestrial and aquatic ecosystems of the Colorado Front Range by comparing ecosystem processes and properties east and west of the Continental Divide. The eastern side receives elevated N deposition from urban, agricultural, and industrial sources, compared with 1–2 kg N y−1 on the western side. Foliage of east side old-growth Englemann spruce forests have significantly lower C:N and lignin:N ratios and greater N:Mg and N:P ratios. Soil % N is higher, and C:N ratios lower in the east side stands, and potential net N mineralization rates are greater. Lake NO3 concentrations are significantly higher in eastern lakes than western lakes. Two east side lakes studied paleolimnologically revealed rapid changes in diatom community composition and increased biovolumes and cell concentrations. The diatom flora is now representative of increased disturbance or eutrophication. Sediment nitrogen isotopic ratios have become progressively lighter over the past 50 years, coincident with the change in algal flora, possibly from an influx of isotopically light N volatilized from agricultural fields and feedlots. Seventy-five percent of the increased east side soil N pool can be accounted for by increased N deposition commensurate with human settlement. Nitrogen emissions from fixed, mobile, and agricultural sources have increased dramatically since approximately 1950 to the east of the Colorado Front Range, as they have in many parts of the world. Our findings indicate even slight increases in atmospheric deposition lead to measurable changes in ecosystem properties.
","language":"English","publisher":"Springer","doi":"10.1007/s100210000032","usgsCitation":"Baron, J., Rueth, H., Wolfe, A., Nydick, K., Allstott, E., Minear, J., and Moraska, B., 2000, Ecosystem responses to nitrogen deposition in the Colorado Front Range: Ecosystems, v. 3, no. 4, p. 352-368, https://doi.org/10.1007/s100210000032.","productDescription":"17 p.","startPage":"352","endPage":"368","costCenters":[{"id":291,"text":"Fort Collins Science Center","active":true,"usgs":true}],"links":[{"id":133170,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"country":"United States","state":"Colorado","otherGeospatial":"Colorado Front Range","volume":"3","issue":"4","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"4f4e4a4be4b07f02db6259b4","contributors":{"authors":[{"text":"Baron, Jill 0000-0002-5902-6251 jill_baron@usgs.gov","orcid":"https://orcid.org/0000-0002-5902-6251","contributorId":194124,"corporation":false,"usgs":true,"family":"Baron","given":"Jill","email":"jill_baron@usgs.gov","affiliations":[{"id":291,"text":"Fort Collins Science Center","active":true,"usgs":true}],"preferred":true,"id":322898,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Rueth, H.M.","contributorId":103611,"corporation":false,"usgs":true,"family":"Rueth","given":"H.M.","email":"","affiliations":[],"preferred":false,"id":322902,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Wolfe, A.M.","contributorId":106452,"corporation":false,"usgs":true,"family":"Wolfe","given":"A.M.","email":"","affiliations":[],"preferred":false,"id":322903,"contributorType":{"id":1,"text":"Authors"},"rank":3},{"text":"Nydick, K. R.","contributorId":9991,"corporation":false,"usgs":false,"family":"Nydick","given":"K. R.","affiliations":[],"preferred":false,"id":322897,"contributorType":{"id":1,"text":"Authors"},"rank":4},{"text":"Allstott, E.J.","contributorId":25102,"corporation":false,"usgs":true,"family":"Allstott","given":"E.J.","email":"","affiliations":[],"preferred":false,"id":322899,"contributorType":{"id":1,"text":"Authors"},"rank":5},{"text":"Minear, J.T.","contributorId":38519,"corporation":false,"usgs":true,"family":"Minear","given":"J.T.","email":"","affiliations":[],"preferred":false,"id":322900,"contributorType":{"id":1,"text":"Authors"},"rank":6},{"text":"Moraska, B.","contributorId":84713,"corporation":false,"usgs":true,"family":"Moraska","given":"B.","email":"","affiliations":[],"preferred":false,"id":322901,"contributorType":{"id":1,"text":"Authors"},"rank":7}]}} ,{"id":70023137,"text":"70023137 - 2000 - Intra- and inter-unit variation in fly ash petrography and mercury adsorption: Examples from a western Kentucky power station","interactions":[],"lastModifiedDate":"2012-03-12T17:20:38","indexId":"70023137","displayToPublicDate":"2000-01-01T00:00:00","publicationYear":"2000","noYear":false,"publicationType":{"id":2,"text":"Article"},"publicationSubtype":{"id":10,"text":"Journal Article"},"seriesTitle":{"id":1513,"text":"Energy and Fuels","active":true,"publicationSubtype":{"id":10}},"title":"Intra- and inter-unit variation in fly ash petrography and mercury adsorption: Examples from a western Kentucky power station","docAbstract":"Fly ash was collected from eight mechanical and 10 baghouse hoppers at each of the twin 150-MW wall-fired units in a western Kentucky power station. The fuel burned at that time was a blend of many low-sulfur, high-volatile bituminous Central Appalachian coals. The baghouse ash showed less variation between units than the mechanical hoppers. The mechanical fly ash, coarser than the baghouse ash, showed significant differences in the amount of total carbon and in the ratio of isotropic coke to both total carbon and total coke - the latter excluding inertinite and other unburned, uncoked coal. There was no significant variation in proportions of inorganic fly ash constituents. The inter-unit differences in the amount and forms of mechanical fly ash carbon appear to be related to differences in pulverizer efficiency, leading to greater amounts of coarse coal, therefore unburned carbon, in one of the units. Mercury capture is a function of both the total carbon content and the gas temperature at the point of fly ash separation, mercury content increasing with an increase in carbon for a specific collection system. Mercury adsorption on fly ash carbon increases at lower flue-gas temperatures. Baghouse fly ash, collected at a lower temperature than the higher-carbon mechanically separated fly ash, contains a significantly greater amount of Hg.","largerWorkType":{"id":2,"text":"Article"},"largerWorkTitle":"Energy and Fuels","largerWorkSubtype":{"id":10,"text":"Journal Article"},"language":"English","publisher":"ACS","publisherLocation":"Washington, DC, United States","doi":"10.1021/ef9901488","issn":"08870624","usgsCitation":"Hower, J., Finkelman, R.B., Rathbone, R., and Goodman, J., 2000, Intra- and inter-unit variation in fly ash petrography and mercury adsorption: Examples from a western Kentucky power station: Energy and Fuels, v. 14, no. 1, p. 212-216, https://doi.org/10.1021/ef9901488.","startPage":"212","endPage":"216","numberOfPages":"5","costCenters":[],"links":[{"id":208124,"rank":9999,"type":{"id":10,"text":"Digital Object Identifier"},"url":"https://dx.doi.org/10.1021/ef9901488"},{"id":233590,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/outside_thumb.jpg"}],"volume":"14","issue":"1","noUsgsAuthors":false,"publicationDate":"1999-12-07","publicationStatus":"PW","scienceBaseUri":"505a3db9e4b0c8380cd637b4","contributors":{"authors":[{"text":"Hower, J.C.","contributorId":100541,"corporation":false,"usgs":true,"family":"Hower","given":"J.C.","email":"","affiliations":[],"preferred":false,"id":396444,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Finkelman, R. B.","contributorId":20341,"corporation":false,"usgs":true,"family":"Finkelman","given":"R.","email":"","middleInitial":"B.","affiliations":[],"preferred":false,"id":396441,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Rathbone, R.F.","contributorId":51924,"corporation":false,"usgs":true,"family":"Rathbone","given":"R.F.","email":"","affiliations":[],"preferred":false,"id":396443,"contributorType":{"id":1,"text":"Authors"},"rank":3},{"text":"Goodman, J.","contributorId":21417,"corporation":false,"usgs":true,"family":"Goodman","given":"J.","email":"","affiliations":[],"preferred":false,"id":396442,"contributorType":{"id":1,"text":"Authors"},"rank":4}]}} ,{"id":29691,"text":"wri994269 - 2000 - Ground-water quality in the Appalachian Plateaus, Kanawha River basin, West Virginia","interactions":[],"lastModifiedDate":"2012-02-02T00:08:57","indexId":"wri994269","displayToPublicDate":"1994-01-01T00:00:00","publicationYear":"2000","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":342,"text":"Water-Resources Investigations Report","code":"WRI","active":false,"publicationSubtype":{"id":5}},"seriesNumber":"99-4269","title":"Ground-water quality in the Appalachian Plateaus, Kanawha River basin, West Virginia","docAbstract":"Water samples collected from 30 privately-owned and small public-supply wells in the Appalachian Plateaus of the Kanawha River Basin were analyzed for a wide range of constituents, including bacteria, major ions, nutrients, trace elements, radon, pesticides, and volatile organic compounds. Concentrations of most constituents from samples analyzed did not exceed U.S. Environmental Protection Agency (USEPA) standards.\r\n\r\nConstituents that exceeded drinking-water standards in at least one sample were total coliform bacteria, Escherichia coli (E. coli), iron, manganese, and sulfate. Total coliform bacteria were present in samples from five sites, and E. coli were present at only one site. USEPA secondary maximum contaminant levels (SMCLs) were exceeded for three constituents -- sulfate exceeded the SMCL of 250 mg/L (milligrams per liter) in samples from 2 of 30 wells; iron exceeded the SMCL of 300 ?g/L (micrograms per liter) in samples from 12 of the wells, and manganese exceeded the SMCL of 50 ?g/L in samples from 17 of the wells sampled.\r\n\r\nNone of the samples contained concentrations of nutrients that exceeded the USEPA maximum contaminant levels (MCLs) for these constituents. The maximum concentration of nitrate detected was only 4.1 mg/L, which is below the MCL of 10 mg/L. Concentrations of nitrate in precipitation and shallow ground water are similar, potentially indicating that precipitation may be a source of nitrate in shallow ground water in the study area.\r\n\r\nRadon concentrations exceeded the recently proposed maximum contaminant level of 300 pCi/L at 50 percent of the sites sampled. The median concentration of radon was only 290 pCi/L. Radon-222 is a naturally occurring, carcinogenic, radioactive decay product of uranium. Concentrations, however, did not exceed the alternate maximum contaminant level (AMCL) for radon of 4,000 pCi/L in any of the 30 samples.\r\n\r\nArsenic concentrations exceeded the proposed MCL of 5?g/L at 4 of the 30 sites. No samples exceeded the current MCL of 50 ?g/L. \r\n\r\nNeither pesticides nor volatile organic compounds (VOCs) were prevalent in the study area, and the concentrations of the compounds that were detected did not exceed any USEPA MCLs. Pesticides were detected in only two of the 30 wells sampled, but four pesticides -- atrazine, carbofuran, DCPA, and deethylatrazine -- were detected in one well; molinate was detected in the other well. All of the pesticides detected were at estimated concentrations of only 0.002 ?g/L. Of the VOCs detected, trihalomethane compounds (THMs), which can result from chlorination of a well, were the most common. THMs were detected in 13 of the 30 wells sampled. Gasoline by-products, such as benzene, toluene, ethylbenzene and xylene (BTEX compounds) were detected in 10 of the 30 wells sampled. The maximum concentration of any of the VOCs detected in this study, however, was only 1.040 ?g/L, for the THM dichlorofluoromethane.\r\n\r\nWater samples from 25 of the wells were analyzed for chlorofluorocarbons (CFCs) to estimate the apparent age of ground water. The analyses indicated that age of water ranged from 10 to greater than 57 years, and that the age of ground water could be correlated with the topographic setting of the wells sampled. Thus the apparent age of water in wells on hilltops was youngest (median of 13 years) and that of water in wells in valleys was oldest (median of 42 years). Water from wells on hillsides was intermediate in age (median of 29 years). These data can be used to define contributing areas to wells, corroborate or revise conceptual ground-water flow models, estimate contaminant travel times from spills to other sources such as nearby domestic or public supply wells, and to manage point and nonpoint source activities that may affect critical aquifers.","language":"ENGLISH","publisher":"U.S. Department of the Interior, U.S. Geological Survey ;\r\nBranch of Information Services [distributor],","doi":"10.3133/wri994269","usgsCitation":"Sheets, C.J., and Kozar, M.D., 2000, Ground-water quality in the Appalachian Plateaus, Kanawha River basin, West Virginia: U.S. Geological Survey Water-Resources Investigations Report 99-4269, v, 25 p. :ill., maps (some col.) ;28 cm., https://doi.org/10.3133/wri994269.","productDescription":"v, 25 p. :ill., maps (some col.) ;28 cm.","costCenters":[],"links":[{"id":2445,"rank":100,"type":{"id":15,"text":"Index Page"},"url":"https://pubs.water.usgs.gov/wri99-4269/","linkFileType":{"id":5,"text":"html"}},{"id":159681,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/usgs_thumb.jpg"}],"noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"4f4e4aa7e4b07f02db667225","contributors":{"authors":[{"text":"Sheets, Charlynn J.","contributorId":43392,"corporation":false,"usgs":true,"family":"Sheets","given":"Charlynn","email":"","middleInitial":"J.","affiliations":[],"preferred":false,"id":201959,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Kozar, Mark D. 0000-0001-7755-7657 mdkozar@usgs.gov","orcid":"https://orcid.org/0000-0001-7755-7657","contributorId":1963,"corporation":false,"usgs":true,"family":"Kozar","given":"Mark","email":"mdkozar@usgs.gov","middleInitial":"D.","affiliations":[{"id":37280,"text":"Virginia and West Virginia Water Science Center ","active":true,"usgs":true}],"preferred":true,"id":201958,"contributorType":{"id":1,"text":"Authors"},"rank":2}]}} ,{"id":30312,"text":"wri20004182 - 2000 - Diffusion sampler testing at Naval Air Station North Island, San Diego County, California, November 1999 to January 2000","interactions":[],"lastModifiedDate":"2018-05-08T14:04:34","indexId":"wri20004182","displayToPublicDate":"1994-01-01T00:00:00","publicationYear":"2000","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":342,"text":"Water-Resources Investigations Report","code":"WRI","active":false,"publicationSubtype":{"id":5}},"seriesNumber":"2000-4182","title":"Diffusion sampler testing at Naval Air Station North Island, San Diego County, California, November 1999 to January 2000","docAbstract":"Volatile organic compound concentrations in water from diffusion samplers were compared to concentrations in water obtained by low-flow purging at 15 observation wells at the Naval Air Station North Island, San Diego, California. Multiple diffusion samplers were installed in the wells. In general, comparisons using bladder pumps and diffusion samplers showed similar volatile organic carbon concentrations. In some wells, sharp concentration gradients were observed, such as an increase in cis-1,2-dichloroethene concentration from 100 to 2,600 micrograms per liter over a vertical distance of only 3.4 feet. In areas where such sharp gradients were observed, concentrations in water obtained by low-flow sampling at times reflected an average concentration over the area of influence; however, concentrations obtained by using the diffusion sampler seemed to represent the immediate vicinity of the sampler. When peristaltic pumps were used to collect ground-water samples by low-flow purging, the volatile organic compound concentrations commonly were lower than concentrations obtained by using diffusion samplers. This difference may be due to loss of volatiles by degassing under negative pressures in the sampling lines induced while using the peristaltic pump, mixing in the well screen, or possible short-circuiting of water from an adjacent depth. Diffusion samplers placed in buckets of freephase jet fuel (JP-5) and Stoddard solvent from observation wells did not show evidence of structural integrity loss during the 2 months of equilibration, and volatile organic compounds detected in the free-phase fuel also were detected in the water from the diffusion samplers.","language":"English","publisher":"U.S. Geological Survey","publisherLocation":"Reston, VA","doi":"10.3133/wri20004182","collaboration":"Prepared in cooperation with the Southwestern Division Naval Facilities Engineering Command","usgsCitation":"Vroblesky, D.A., and Peters, B.C., 2000, Diffusion sampler testing at Naval Air Station North Island, San Diego County, California, November 1999 to January 2000: U.S. Geological Survey Water-Resources Investigations Report 2000-4182, iv, 27 p., https://doi.org/10.3133/wri20004182.","productDescription":"iv, 27 p.","numberOfPages":"34","costCenters":[{"id":595,"text":"U.S. Geological Survey","active":false,"usgs":true},{"id":13634,"text":"South Atlantic Water Science Center","active":true,"usgs":true}],"links":[{"id":160506,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/wri/2000/4182/coverthb.jpg"},{"id":353624,"rank":3,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/wri/2000/4182/wri20004182.pdf","text":"Report","size":"598 KB","linkFileType":{"id":1,"text":"pdf"}}],"country":"United States","state":"California","county":"San Diego County","otherGeospatial":"Naval Air Station North Island","geographicExtents":"{\n \"type\": \"FeatureCollection\",\n \"features\": [\n {\n \"type\": \"Feature\",\n \"properties\": {},\n \"geometry\": {\n \"type\": \"Polygon\",\n \"coordinates\": [\n [\n [\n -117.24523544311523,\n 32.6656796405623\n ],\n [\n -117.158203125,\n 32.6656796405623\n ],\n [\n -117.158203125,\n 32.733140517450266\n ],\n [\n -117.24523544311523,\n 32.733140517450266\n ],\n [\n -117.24523544311523,\n 32.6656796405623\n ]\n ]\n ]\n }\n }\n ]\n}","contact":"Director, South Atlantic Water Science Center
U.S. Geological Survey
720 Gracern Road
Columbia, SC 29210
The U.S. Geological Survey, in cooperation with the Wisconsin Department of Natural Resources, collected water samples during the September 1 - December 15, 1999 removal of sediment contaminated with polychlorinated biphenyls (PCBs) from a reach of the Lower Fox River designated Sediment Management Unit (SMU) 56/57. Results of analyses of the samples, along with monitoring activities of several other organizations, were used to delineate and compare PCB mass pathways during the cleanup effort (fig. 1). Results indicate that the cleanup at SMU 56/57 had the following effect on PCB mass: dredging permanently removed more than 650 kg (1441 lb) of PCBs, transported 14.5 kg (32 lb) downstream, and volatilized 2.6 kg (5.7 lb) to the atmosphere; associated activities on the shore returned 0.1 kg (0.3 lb) to the river. This report documents the USGS data-collection efforts and details the mass-balance approach for PCB pathway delineation.
","language":"English","publisher":"U.S. Geological Survey","doi":"10.3133/wri004245","usgsCitation":"Steuer, J.J., 2000, A mass-balance approach for assessing PCB movement during remediation of a PCB-contaminated deposit on the Fox River, Wisconsin: U.S. Geological Survey Water-Resources Investigations Report 2000-4245, 8 p., https://doi.org/10.3133/wri004245.","productDescription":"8 p.","numberOfPages":"8","onlineOnly":"N","additionalOnlineFiles":"N","costCenters":[{"id":677,"text":"Wisconsin Water Science Center","active":true,"usgs":true}],"links":[{"id":2421,"rank":100,"type":{"id":15,"text":"Index Page"},"url":"https://wi.water.usgs.gov/pubs/wrir-00-4245/","linkFileType":{"id":5,"text":"html"}},{"id":124804,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/wri/2000/4245/report-thumb.jpg"},{"id":58771,"rank":300,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/wri/2000/4245/report.pdf","linkFileType":{"id":1,"text":"pdf"}}],"country":"United States","state":"Wisconsin","otherGeospatial":"Green Bay, Fox River, Lake Winebago","geographicExtents":"{\n \"type\": \"FeatureCollection\",\n \"features\": [\n {\n \"type\": \"Feature\",\n \"properties\": {},\n \"geometry\": {\n \"type\": \"Polygon\",\n \"coordinates\": [\n [\n [\n -88.0609130859375,\n 44.64911632343077\n ],\n [\n -87.8521728515625,\n 44.54742015866829\n ],\n [\n -88.187255859375,\n 44.21174128124646\n ],\n [\n -88.29711914062499,\n 44.14476875978378\n ],\n [\n -88.47564697265625,\n 44.16447445668458\n ],\n [\n -88.23944091796875,\n 44.54154764174371\n ],\n [\n -88.16253662109375,\n 44.5924231071787\n ],\n [\n -88.0609130859375,\n 44.64911632343077\n ]\n ]\n ]\n }\n }\n ]\n}","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"4f4e4b23e4b07f02db6ae190","contributors":{"authors":[{"text":"Steuer, Jeffrey J.","contributorId":75136,"corporation":false,"usgs":true,"family":"Steuer","given":"Jeffrey","email":"","middleInitial":"J.","affiliations":[],"preferred":false,"id":202413,"contributorType":{"id":1,"text":"Authors"},"rank":1}]}} ,{"id":22478,"text":"ofr99195 - 1999 - Summary of water-quality data for City of Albuquerque drinking-water supply wells, 1988-97","interactions":[],"lastModifiedDate":"2012-02-02T00:08:08","indexId":"ofr99195","displayToPublicDate":"2003-04-01T00:00:00","publicationYear":"1999","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":330,"text":"Open-File Report","code":"OFR","onlineIssn":"2331-1258","printIssn":"0196-1497","active":true,"publicationSubtype":{"id":5}},"seriesNumber":"99-195","title":"Summary of water-quality data for City of Albuquerque drinking-water supply wells, 1988-97","docAbstract":"The City of Albuquerque has collected and analyzed more than 5,000 \r\nwater-quality samples from 113 water-supply wells in the Albuquerque \r\narea, including many drinking-water supply wells, since May of 1988. \r\nAs a result, a large water-quality data base has been compiled that \r\nincludes data for major ions, nutrients, trace elements, carbon, \r\nvolatile organic compounds, radiological constituents, and bacteria. \r\nThese data are intended to improve the understanding and management of \r\nthe ground-water resources of the region, rather than demonstrate \r\ncompliance with Federal and State drinking-water standards. This \r\nreport gives summary statistics for selected physical properties \r\nand chemical constituents for ground water from wells used by the \r\nCity of Albuquerque for drinking-water supply between 1988 and 1997. \r\nMaps are provided to show the general spatial distribution of selected \r\nparameters and water types around the region. Although the values of \r\nsome parameters vary substantially across the city, median values for \r\nall parameters included in this report are less than their respective \r\nmaximum contaminant levels in each drinking-water supply well. The \r\ndominant water types are sodium plus potassium / carbonate plus bicarbonate \r\nin the western part of the city and calcium / carbonate plus bicarbonate \r\nin the eastern part of the city.","language":"ENGLISH","publisher":"U.S. Geological Survey ;\r\nBranch of Information Services [distributor],","doi":"10.3133/ofr99195","issn":"0094-9140","usgsCitation":"Bexfield, L.M., Lindberg, W., and Anderholm, S.K., 1999, Summary of water-quality data for City of Albuquerque drinking-water supply wells, 1988-97: U.S. Geological Survey Open-File Report 99-195, vi, 138 p. :ill., maps ;28 cm., https://doi.org/10.3133/ofr99195.","productDescription":"vi, 138 p. :ill., maps ;28 cm.","costCenters":[],"links":[{"id":156464,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/of/1999/0195/report-thumb.jpg"},{"id":51995,"rank":400,"type":{"id":17,"text":"Plate"},"url":"https://pubs.usgs.gov/of/1999/0195/plate-1.pdf","linkFileType":{"id":1,"text":"pdf"}},{"id":51996,"rank":300,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/of/1999/0195/report.pdf","linkFileType":{"id":1,"text":"pdf"}}],"noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"4f4e4affe4b07f02db697dee","contributors":{"authors":[{"text":"Bexfield, Laura M. 0000-0002-1789-654X bexfield@usgs.gov","orcid":"https://orcid.org/0000-0002-1789-654X","contributorId":1273,"corporation":false,"usgs":true,"family":"Bexfield","given":"Laura","email":"bexfield@usgs.gov","middleInitial":"M.","affiliations":[{"id":472,"text":"New Mexico Water Science Center","active":true,"usgs":true}],"preferred":true,"id":188325,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Lindberg, William E.","contributorId":27091,"corporation":false,"usgs":true,"family":"Lindberg","given":"William E.","affiliations":[],"preferred":false,"id":188326,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Anderholm, Scott K.","contributorId":94270,"corporation":false,"usgs":true,"family":"Anderholm","given":"Scott","email":"","middleInitial":"K.","affiliations":[],"preferred":false,"id":188327,"contributorType":{"id":1,"text":"Authors"},"rank":3}]}} ,{"id":28503,"text":"wri994257 - 1999 - Occurrence, distribution, and trends of volatile organic compounds in the Ohio River and its major tributaries, 1987-96","interactions":[],"lastModifiedDate":"2018-03-12T14:11:57","indexId":"wri994257","displayToPublicDate":"2001-05-01T00:00:00","publicationYear":"1999","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":342,"text":"Water-Resources Investigations Report","code":"WRI","active":false,"publicationSubtype":{"id":5}},"seriesNumber":"99-4257","title":"Occurrence, distribution, and trends of volatile organic compounds in the Ohio River and its major tributaries, 1987-96","docAbstract":"The Ohio River is a source of drinking water for more than 3 million people. Thus, it is important to monitor the water quality of this river to determine if contaminants are present, their concentrations, and if water quality is changing with time. This report presents an analysis of the occurrence, distribution, and trends of 21 volatile organic compounds (VOCs) along the main stem of the Ohio River and its major tributaries from 1987 through 1996. The data were collected by the Ohio River Valley Water Sanitation Commission's Organics Detection System, which monitors daily for VOCs at 15 stations. Various statistical methods were applied to basinwide data from all monitoring stations and to data from individual monitoring stations. For the basinwide data, one or more VOCs were detected in 45 percent of the 44,837 river-water samples. Trichloromethane, detected in 26 percent of the samples, was the most frequently detected VOC followed by benzene (11 percent), methylbenzene (6.4 percent), and the other 18 VOCs, which were detected in less than 4 percent of the samples. In samples from 8 of the 15 monitoring stations, trichloromethane was also the most frequently detected VOC. These stations were generally near large cities along the Ohio River. The median trichloromethane concentration was 0.3 microgram per liter (μg/L), and concentrations ranged from less than 0.1 to 125.3 μg/L. Most of the VOCs had median detected concentrations that ranged from 0.1 to 0.4 μg/L for the basinwide data and for samples from individual stations. Samples from stations in the upstream part of the basin and from the Kanawha River had the highest median concentrations. Ninety-nine percent of the detected VOC concentrations were within U.S. Environmental Protection Agency drinking-water regulations. Of the 268 exceedances of drinking-water regulations, 188 were due to the detection of 1,2-dichloroethane prior to 1993 in samples from the monitoring station near Paducah, Ky. Time trend analyses indicated that most VOCs had no trend in samples at most monitoring stations because they were detected infrequently. At one or more stations, 14 VOCs had decreasing trends in monthly mean concentrations that ranged from -0.01 to -0.42 μ/L per year. Nine VOCs had significant decreasing trends in percentage detection that ranged from -1.08 to -12.90 percent per year. These trends suggest that source-control efforts are working and that water quality is improving.","language":"English","publisher":"U.S. Geological Survey","publisherLocation":"Rapid City, SD","doi":"10.3133/wri994257","usgsCitation":"Lundgren, R.F., and Lopes, T.J., 1999, Occurrence, distribution, and trends of volatile organic compounds in the Ohio River and its major tributaries, 1987-96: U.S. Geological Survey Water-Resources Investigations Report 99-4257, x, 89 p., https://doi.org/10.3133/wri994257.","productDescription":"x, 89 p.","additionalOnlineFiles":"N","costCenters":[{"id":478,"text":"North Dakota Water Science Center","active":true,"usgs":true},{"id":34685,"text":"Dakota Water Science Center","active":true,"usgs":true}],"links":[{"id":159618,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/wri994257.jpg"},{"id":286070,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/wri/1999/4257/report.pdf"}],"scale":"2000000","projection":"Albers Equal-Area Conic","country":"United States","otherGeospatial":"Ohio River","geographicExtents":"{ \"type\": \"FeatureCollection\", \"features\": [ { \"type\": \"Feature\", \"properties\": {}, \"geometry\": { \"type\": \"Polygon\", \"coordinates\": [ [ [ -89.183,36.4204 ], [ -89.183,42.3272 ], [ -78.6509,42.3272 ], [ -78.6509,36.4204 ], [ -89.183,36.4204 ] ] ] } } ] }","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"4f4e49f9e4b07f02db5f3988","contributors":{"authors":[{"text":"Lundgren, Robert F. 0000-0001-7669-0552 rflundgr@usgs.gov","orcid":"https://orcid.org/0000-0001-7669-0552","contributorId":1657,"corporation":false,"usgs":true,"family":"Lundgren","given":"Robert","email":"rflundgr@usgs.gov","middleInitial":"F.","affiliations":[{"id":34685,"text":"Dakota Water Science Center","active":true,"usgs":true}],"preferred":true,"id":199922,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Lopes, Thomas J. tjlopes@usgs.gov","contributorId":2302,"corporation":false,"usgs":true,"family":"Lopes","given":"Thomas","email":"tjlopes@usgs.gov","middleInitial":"J.","affiliations":[],"preferred":true,"id":199923,"contributorType":{"id":1,"text":"Authors"},"rank":2}]}} ,{"id":26040,"text":"wri994180 - 1999 - Relation of Land Use to Streamflow and Water Quality at Selected Sites in the City of Charlotte and Mecklenburg County, North Carolina, 1993-98","interactions":[],"lastModifiedDate":"2018-05-08T14:02:00","indexId":"wri994180","displayToPublicDate":"2001-05-01T00:00:00","publicationYear":"1999","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":342,"text":"Water-Resources Investigations Report","code":"WRI","active":false,"publicationSubtype":{"id":5}},"seriesNumber":"99-4180","title":"Relation of Land Use to Streamflow and Water Quality at Selected Sites in the City of Charlotte and Mecklenburg County, North Carolina, 1993-98","docAbstract":"Streamflow and water-quality data were collected at nine sites in the city of Charlotte and Mecklenburg County, North Carolina, during 1993–97. Six of the basins drained areas having relatively homogeneous land use and were less than 0.3 square mile in size; the other three basins had mixed land use. Atmospheric wet-deposition data were collected in three of the basins during 1997–98.
Streamflow yield varied by a factor of six among the sites, despite the fact that sites were in close proximity to one another. The lowest yield occurred in a residential basin having no curbs and gutters. The variability in mean flow from these small, relatively homogeneous basins is much greater than is found in streams draining basins that are 10 square miles in size or larger. The ratio of runoff to rainfall in the developing basin appears to have increased during the study period.
Low-flow suspended-sediment concentrations in the study basins were about the same magnitude as median stormflow concentrations in Piedmont agricultural basins. Sediment concentrations were higher in the mixed land-use basins and in the developing basin. Median suspended-sediment concentrations in these basins generally were an order of magnitude greater than median concentrations in the other five basins, which had stable land use.
Some of the highest total nitrogen concentrations occurred in residential basins. Total nitrogen concentrations detected in this study were about twice as high as concentrations in small Piedmont streams affected by agriculture and urbanization. Most of the total nitrogen consisted of organic nitrogen at all of the sites except in two residential land- use basins. The high ammonia content of lawn fertilizer may explain the higher ammonia concentration in stormflow from residential basins.
The two basins with the highest median suspended-sediment concentrations also had the highest total phosphorus concentrations. Median total phosphorus concentrations measured in this study were several times greater than median concentrations in small Piedmont streams but almost an order of magnitude less than total phosphorus concentrations in Charlotte streams during the late 1970's.
Bacteria concentrations are not correlated to streamflow. The highest bacteria levels were found in 'first-flush' samples. Higher fecal coliform concentrations were associated with residential land use.
Chromium, copper, lead, and zinc occurred at all sites in concentrations that exceeded the North Carolina ambient water-quality standards. The median chromium concentration in the developing basin was more than double the median concentration at any other site. As with chromium, the maximum copper concentration in the developing basin was almost an order of magnitude greater than maximum concentrations at other sites. The highest zinc concentration also occurred in the developing basin. Samples were analyzed for 121 organic compounds and 57 volatile organic compounds. Forty-five organic compounds and seven volatile organic compounds were detected. At least five compounds were detected at all sites, and 15 or more compounds were detected at all sites except two mixed land-use basins. Atrazine, carbaryl, and metolachlor were detected at eight sites, and 90 percent of all samples had measurable amounts of atrazine. About 60 percent of the samples had detectable levels of carbaryl and metolachlor. Diazinon and malathion were measured in samples from seven sites, and methyl parathion, chlorpyrifos, alachlor, and 2,4-D were detected at four or more sites. The fewest compounds were detected in the larger, mixed land-use basins. Residential basins and the developing basin had the greatest number of detections of organic compounds.
The pH of wet atmospheric deposition in three Charlotte basins was more variable than the pH measured at a National Atmospheric Deposition Program (NADP)site in Rowan County. Summer pH values were significantly lower than pH measured during the remainder of the year, probably as a result of poorer air quality and different weather patterns during the summer.
Concentrations of ammonia and nitrate at the Charlotte sites generally were lower than those measured at the NADP site. Summer concentrations of ammonia and nitrate at both the Charlotte and the NADP sites were significantly greater than concentrations measured during the remainder of the year, again probably reflecting poorer summertime air-quality conditions.
Sediment yields at the nine sites ranged from 77 tons per square mile per year in a residential basin to 4,700 tons per square mile per year at the developing basin. Residential areas that have been built-out for several years and industrial areas appear, in general, to have the lowest sediment yields for the Charlotte study sites.
Average annual yields of total nitrogen loads ranged from about 1.7 tons per square mile to 6.6 tons per square mile. Average annual total phosphorus yields for all sites except the developing basin were less than 1.4 tons per square mile. Phosphorus yield at the developing basin was 13 .4 tons per square mile per year.
Biochemical oxygen demand loading in 1993 from all of the permitted wastewater-treatment facilities in Charlotte and Mecklenburg County was about 1.5 tons per day or 548 tons per year. Converting this point-source loading to an annual yield for the 528 square-mile area of Mecklenburg County is equivalent to 1.03 tons per square mile per year, or a yield much lower than any of the yields measured at the nine study sites. In other words, biochemical oxygen demand loading from nonpoint sources in Mecklenburg County probably exceeds loading from all point sources by a large amount.
Loads and average annual yields were computed for five metals-chromium, copper, lead, nickel, and zinc. The highest annual average yields for all five of these metals were in the developing basin, which also had the highest annual average suspended-sediment yield of all the sites. Estimated wet-deposition watershed loadings suggest that atmospheric deposition may be an important source of some metals, including chromium, copper, lead, and zinc, in Charlotte storm water.
Storm water from residential land-use basins has higher concentrations of total nitrogen, fecal coliform bacteria, and organic compounds than do other land-use types. Reductions in suspended-sediment concentrations should generally result in reduced export of phosphorus and metals. Stable land uses, such as industrial areas and built-out residential basins, have lower sediment concentrations in stormwater than do mixed land use and developing basins. Finally, atmospheric deposition may be an important source of nitrogen and some metals in Charlotte stormwater.
","language":"English","publisher":"U.S. Geological Survey","publisherLocation":"Reston, VA","doi":"10.3133/wri994180","collaboration":"Prepared in cooperation with the city of Charlotte and Mecklenburg County, North Carolina","usgsCitation":"Bales, J.D., Weaver, J., and Robinson, J.B., 1999, Relation of Land Use to Streamflow and Water Quality at Selected Sites in the City of Charlotte and Mecklenburg County, North Carolina, 1993-98: U.S. Geological Survey Water-Resources Investigations Report 99-4180, vi, 95 p., https://doi.org/10.3133/wri994180.","productDescription":"vi, 95 p.","temporalStart":"1993-01-01","temporalEnd":"1998-12-31","costCenters":[{"id":13634,"text":"South Atlantic Water Science 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Carolina\",\"nation\":\"USA \"}}]}","contact":"Director, South Atlantic Water Science Center
U.S. Geological Survey
720 Gracern Road
Columbia, SC 29210
To investigate the feasbility of artificial recharge as a method of meeting future water-supply needs and to protect the Equus Beds aquifer from saltwater intrusion from natural and anthropogenic sources to the west, the Equus Beds Ground-Water Recharge from Demonstration Project was begun in 1995. The project is a cooperative effort between the city of Wichita and the Bureau of Reclamation, U.S. Department of the Interior. During the project, high flows from the Little Arkansas River are captured and recharged into the Equus Beds aquifer through recharge basins, a trench, or a recharge well, located at two recharge sites near Halstead and Sedgwick, Kansas. To document baseline concentrations and compatibility of stream (recharge) and aquifer water, the U.S. Geological Survey collected water samples from February 1995 through August 1998. These samples were analyzed for dissolved solids, total and dissolved inorganic constituents, nutrients, organic and volatile organic compounds, radionuclides, and bacteria. Results of baseline sampling indicated that the primary constituents of concern for recharge were sodium, chloride, nitrite plus nitrate, iron and manganese, total coliform bacteria, and atrazine. Chloride and atrazine were of particular concern because concentrations of these constituents in water from the Little Arkansas River frequently exceeded regulatory criteria. The Little Arkansas River is used as the source water for recharge. The U.S. Environmental Protection Agency Secondary Maximum Contaminant Level for chloride is 250 mg/L (milligrams per liter), and the Maximum Contaminant Level for atrazine is 3.0 μg/L (micrograms per liter) as an annual mean. Baseline concentrations of chloride in surface water ranged from 8.0 to 400 μg/L. Baseline concentrations of atrazine in surface water ranged from less than 0.10 to 46 μg/L.
Concentrations of chloride and atrazine have increased in water from some of the wells at both the Halstead and Sedgwick recharge sites after recharge began, although concentrations remained within the range of baseline values in the Equus Beds aquifer and are considerably less than U.S. Environmental Protection Agency drinking-water criteria. However, a substantial quantity of water has not been recharged at the Sedgwick site to determine the overall effects of artificial recharge on aquifer quality. Continued monitoring is necessary to determine long-term effects at both sites.
Major ion and trace element concentrations in source water and receiving water were analyzed to determine the compatibility of recharge and receiving ground water for artificial recharge. Stiff diagrams of major ions were used to show the similarity or differences between source surface water and receiving ground water. The water from both sources, for the most part, was chemically compatible to the receiving aquifer water at both recharge sites.
It may be possible to decrease the monitoring frequency at the Halstead recharge site because water-quality changes in receiving water at this site are very gradual. However, real-time water-quality monitoring of surrogates needs to be site specific for the determination of chloride and atrazine. Real-time water-quality monitoring potentially can be used to more effectively manage the artificial recharge process, enabling project officials to respond more rapidly to changes in water quality.
","language":"English","publisher":"U.S. Geological Survey","publisherLocation":"Reston, VA","doi":"10.3133/wri994250","usgsCitation":"Ziegler, A., Christensen, V.G., and Ross, H.C., 1999, Baseline water quality and preliminary effects of artificial recharge on ground water, south-central Kansas, 1995–98: U.S. Geological Survey Water-Resources Investigations Report 99-4250, Report: vi, 74 p.; 2 Additional pieces: Figures, Tables, https://doi.org/10.3133/wri994250.","productDescription":"Report: vi, 74 p.; 2 Additional pieces: Figures, Tables","costCenters":[{"id":353,"text":"Kansas Water Science Center","active":false,"usgs":true}],"links":[{"id":159971,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/usgs_thumb.jpg"},{"id":362199,"rank":3,"type":{"id":2,"text":"Additional Report Piece"},"url":"https://pubs.usgs.gov/wri/1999/4250/figures/","text":"Figures","description":"WRIR 1999–4250 Figures"},{"id":3006,"rank":199,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/wri/1999/4250/wrir19994250.pdf","text":"Report ","size":"143 kB","linkFileType":{"id":1,"text":"pdf"},"description":"WRIR 1999–4250"},{"id":362200,"rank":4,"type":{"id":2,"text":"Additional Report Piece"},"url":"https://pubs.usgs.gov/wri/1999/4250/tables/","text":"Tables","description":"WRIR 1999–4250 Tables"}],"contact":"Director, Kansas Water Science Center
U.S. Geological Survey
1217 Biltmore Drive
Lawrence, KS 66049
Irondequoit Creek, which drains 169 square miles in the eastern part of Monroe County, has been recognized as a source of contaminants that contribute to the eutrophication of Irondequoit Bay on Lake Ontario. The discharge from sewage-treatment plants to the creek and its tributaries was eliminated in 1979 by diversion to another wastewater-treatment facility, but sediment and nonpoint-source pollution remain a concern. This report presents data from five surface-water sites in the Irondequoit Creek basin. Irondequoit Creek at Railroad Mills, East Branch Allen Creek, Allen Creek near Rochester, Irondequoit Creek at Blossom Road, and Irondequoit Creek at Empire Boulevard, to supplement published data from 1984-88. Data from Northrup Creek, which drains 11.7 square miles in western Monroe County, provide information on surface-water quality west of the Genesee River. Also presented are water-level and water-quality data from 12 observation-well sites in Ellison and Powdermill Parks and atmospheric-deposition data from 1 site (Mendon Ponds).
Concentrations of several chemical constituents in streams of the Irondequoit Creek basin showed statistically significant trends during 1989-93. Concentrations of total suspended-solids and volatile suspended-solids in Irondequoit Creek at Blossom Road decreased 13.5 and 12.5 percent per year, respectively, and those at Empire Boulevard decreased 33.5 and 22 percent per year, respectively.
Concentrations of ammonia plus organic nitrogen increased 17.6 percent per year at one site in the basin, but decreased 8.5 and 22.3 percent per year at two sites. Nitrite plus nitrate decreased at only one site (3.5 percent per year). Concentrations of total phosphorus increased at two sites (about 7 percent per year) and decreased at two other sites (7.6 and 29.9 percent per year), and orthophosphate concentrations increased at one site (10.8 percent per year). Dissolved chloride increased at three sites (1.7 to 10.9 percent per year), and dissolved sulfate decreased at one site (2.1 percent per year) and increased at one site (6.8 percent per year).
Median concentrations of constituents were significantly lower in atmospheric deposition than in streamflow, although annual deposition of ammonia nitrogen, nitrite plus nitrate, total phosphorus, and orthophosphate in the basin exceeded the amounts removed by streamflow. Atmospheric deposition of chloride and sulfate, by contrast, represented only 1 and 12 percent, respectively, of the loads transported by Irondequoit Creek (Blossom Road site).
Comparison of water-quality data from the Allen Creek site and Irondequoit Creek at Blossom Road from water years 1989-93 with corresponding data from 1984-88 indicates significant changes in median concentrations of several constituents. The concentration of dissolved chloride increased at Blossom Road and was unchanged at Allen Creek, whereas sulfate decreased at both sites. Concentrations of ammonia plus organic nitrogen, and nitrite plus nitrate, were significantly lower during 1989-93 than during 1984-88 at both sites. Total phosphorus concentration was lower during 1984-88 than during 1989-93 at Blossom Road but showed no change at Allen Creek, and orthophosphate concentration for 1989-93 was lower than in 1984-88 at both sites. Comparison of chemical loads in atmospheric deposition also indicates significant changes in many constituents. Five-year-mean loads of sodium, sulfate, and lead in atmospheric deposition for 1989-93 exceeded those for 1984-88, whereas 5-year-mean loads of calcium, magnesium, potassium, chloride, nitrite plus nitrate, ammonia nitrogen, and orthophosphate for 1989-93 were lower than in 1984-88.
The changes in surface-water quality resulted from several factors within the basin, including land-use changes, annual and seasonal variations in streamflow, and year-to-year variations in the application of deicing salts on area roads. Statistical analyses of long-term (9 years or more) flow records of three unregulated streams in Monroe County indicate that annual mean flows for water years 1989- 93 were in the normal range (20th- to 80th-percentile). The greatest mean annual flow in this period-about 140 percent of normal at Irondequoit Creek and Black Creek-occurred in 1993, but the annual mean flow for that water year at Allen Creek was only 98 percent of normal. The lowest annual mean flows of these streams-ranging from 75 percent of normal to 93 percent of normal-occurred in 1989. The average annual mean flows for these streams for 1989-93 was 104 percent of normal, and that for 1984-88 was normal.
","language":"English","publisher":"U.S. Geological Survey","doi":"10.3133/wri994084","usgsCitation":"Sherwood, D.A., 1999, Water resources of Monroe County, New York, water years 1989-93, with emphasis on water quality in the Irondequoit Creek basin: Part 2. Atmospheric deposition, ground water, streamflow, trends in water quality, and chemical loads to Irondequoit Bay: U.S. Geological Survey Water-Resources Investigations Report 99-4084, v, 50 p., https://doi.org/10.3133/wri994084.","productDescription":"v, 50 p.","costCenters":[],"links":[{"id":410243,"rank":3,"type":{"id":36,"text":"NGMDB Index Page"},"url":"https://ngmdb.usgs.gov/Prodesc/proddesc_22770.htm","linkFileType":{"id":5,"text":"html"}},{"id":274647,"rank":1,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/wri/1999/4084/report.pdf","linkFileType":{"id":1,"text":"pdf"}},{"id":159511,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/wri/1999/4084/report-thumb.jpg"}],"country":"United States","state":"New York","county":"Monroe County","otherGeospatial":"Irondequoit Creek basin","geographicExtents":"{\n \"type\": \"FeatureCollection\",\n \"features\": [\n {\n \"type\": \"Feature\",\n \"properties\": {},\n \"geometry\": {\n \"coordinates\": [\n [\n [\n -77.625,\n 43.25\n ],\n [\n -77.625,\n 43\n ],\n [\n -77.375,\n 43\n ],\n [\n -77.375,\n 43.25\n ],\n [\n -77.625,\n 43.25\n ]\n ]\n ],\n \"type\": \"Polygon\"\n }\n }\n ]\n}","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"4f4e49b4e4b07f02db5ca5c0","contributors":{"authors":[{"text":"Sherwood, Donald A.","contributorId":103267,"corporation":false,"usgs":true,"family":"Sherwood","given":"Donald","email":"","middleInitial":"A.","affiliations":[],"preferred":false,"id":201975,"contributorType":{"id":1,"text":"Authors"},"rank":1}]}} ,{"id":25560,"text":"wri994070 - 1999 - Ground-water resources in Kaloko-Honokohau National Historical Park, Island of Hawaii, and numerical simulation of the effects of ground-water withdrawals","interactions":[],"lastModifiedDate":"2023-03-13T20:46:52.570508","indexId":"wri994070","displayToPublicDate":"2001-03-01T00:00:00","publicationYear":"1999","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":342,"text":"Water-Resources Investigations Report","code":"WRI","active":false,"publicationSubtype":{"id":5}},"seriesNumber":"99-4070","title":"Ground-water resources in Kaloko-Honokohau National Historical Park, Island of Hawaii, and numerical simulation of the effects of ground-water withdrawals","docAbstract":"Within the Kaloko-Honokohau National Historical Park, which was established in 1978, the ground-water flow system is composed of brackish water overlying saltwater. Ground-water levels measured in the Park range from about 1 to 2 feet above mean sea level, and fluctuate daily by about 0.5 to 1.5 feet in response to ocean tides. The brackish water is formed by mixing of seaward flowing fresh ground water with underlying saltwater from the ocean. The major source of fresh ground water is from subsurface flow originating from inland areas to the east of the Park. Ground-water recharge from the direct infiltration of precipitation within the Park area, which has land-surface altitudes less than 100 feet, is small because of low rainfall and high rates of evaporation. Brackish water flowing through the Park ultimately discharges to the fishponds in the Park or to the ocean. The ground water, fishponds, and anchialine ponds in the Park are hydrologically connected; thus, the water levels in the ponds mark the local position of the water table. \r\n\r\nWithin the Park, ground water near the water table is brackish; measured chloride concentrations of water samples from three exploratory wells in the Park range from 2,610 to 5,910 milligrams per liter. Chromium and copper were detected in water samples from the three wells in the Park and one well upgradient of the Park at concentrations of 1 to 5 micrograms per liter. One semi-volatile organic compound, phenol, was detected in water samples from the three wells in the Park at concentrations between 4 and 10 micrograms per liter. \r\n\r\nA regional, two-dimensional (areal), freshwater-saltwater, sharp-interface ground-water flow model was used to simulate the effects of regional withdrawals on ground-water flow within the Park. For average 1978 withdrawal rates, the estimated rate of fresh ground-water discharge to the ocean within the Park is about 6.48 million gallons per day, or about 3 million gallons per day per mile of coastline. Although the coastal discharge within the Park is actually brackish water, the model assumes that freshwater and saltwater do not mix and therefore the model-calculated coastal discharge within the Park is in the form of freshwater discharge.\r\n\r\nModel results indicate that ground-water withdrawals in excess of average 1978 withdrawal rates will reduce the rate of freshwater coastal discharge within the Park. Withdrawals from wells directly upgradient of the Park had the greatest effect on the model-calculated freshwater coastal discharge within the Park, whereas withdrawals from wells south of Papa Bay had little effect on the freshwater discharge within the Park. For an increased ground-water withdrawal rate of 56.8 million gallons per day, relative to average 1978 withdrawal rates in the Kona area, model-calculated freshwater coastal discharge within the Park was reduced by about 47 percent.","language":"English","publisher":"U.S. Geological Survey","doi":"10.3133/wri994070","usgsCitation":"Oki, D.S., Tribble, G.W., Souza, W.R., and Bolke, E.L., 1999, Ground-water resources in Kaloko-Honokohau National Historical Park, Island of Hawaii, and numerical simulation of the effects of ground-water withdrawals: U.S. Geological Survey Water-Resources Investigations Report 99-4070, vi, 49 p., https://doi.org/10.3133/wri994070.","productDescription":"vi, 49 p.","costCenters":[{"id":525,"text":"Pacific Islands Water Science Center","active":true,"usgs":true}],"links":[{"id":157732,"rank":1,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/wri/1999/4070/report-thumb.jpg"},{"id":95537,"rank":2,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/wri/1999/4070/report.pdf","linkFileType":{"id":1,"text":"pdf"}},{"id":414047,"rank":3,"type":{"id":36,"text":"NGMDB Index Page"},"url":"https://ngmdb.usgs.gov/Prodesc/proddesc_23011.htm","linkFileType":{"id":5,"text":"html"}}],"country":"United States","state":"Hawaii","otherGeospatial":"Kaloko-Honokohau National Historical Park","geographicExtents":"{\n \"type\": \"FeatureCollection\",\n \"features\": [\n {\n \"type\": \"Feature\",\n \"properties\": {},\n \"geometry\": {\n \"coordinates\": [\n [\n [\n -156.05,\n 19.7\n ],\n [\n -156.05,\n 19.667\n ],\n [\n -156.017,\n 19.667\n ],\n [\n -156.017,\n 19.7\n ],\n [\n -156.05,\n 19.7\n ]\n ]\n ],\n \"type\": \"Polygon\"\n }\n }\n ]\n}","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"4f4e4b01e4b07f02db6986e2","contributors":{"authors":[{"text":"Oki, Delwyn S. 0000-0002-6913-8804 dsoki@usgs.gov","orcid":"https://orcid.org/0000-0002-6913-8804","contributorId":1901,"corporation":false,"usgs":true,"family":"Oki","given":"Delwyn","email":"dsoki@usgs.gov","middleInitial":"S.","affiliations":[{"id":525,"text":"Pacific Islands Water Science Center","active":true,"usgs":true}],"preferred":true,"id":194194,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Tribble, Gordon W. gtribble@usgs.gov","contributorId":2643,"corporation":false,"usgs":true,"family":"Tribble","given":"Gordon","email":"gtribble@usgs.gov","middleInitial":"W.","affiliations":[],"preferred":true,"id":194195,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Souza, William R.","contributorId":90295,"corporation":false,"usgs":true,"family":"Souza","given":"William","email":"","middleInitial":"R.","affiliations":[],"preferred":false,"id":194197,"contributorType":{"id":1,"text":"Authors"},"rank":3},{"text":"Bolke, Edward L.","contributorId":44957,"corporation":false,"usgs":true,"family":"Bolke","given":"Edward","email":"","middleInitial":"L.","affiliations":[],"preferred":false,"id":194196,"contributorType":{"id":1,"text":"Authors"},"rank":4}]}} ,{"id":28774,"text":"wri994229 - 1999 - Volatile organic compounds in ground water of the lower Illinois River basin","interactions":[],"lastModifiedDate":"2012-02-02T00:08:52","indexId":"wri994229","displayToPublicDate":"2001-03-01T00:00:00","publicationYear":"1999","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":342,"text":"Water-Resources Investigations Report","code":"WRI","active":false,"publicationSubtype":{"id":5}},"seriesNumber":"99-4229","title":"Volatile organic compounds in ground water of the lower Illinois River basin","docAbstract":"Water samples collected from 60 wells in the lower Illinois River Basin (LIRB) in 1996 were sampled and analyzed for 73 volatile organic compounds (VOC?s). There were only six VOC detections in more than 4,300 analyses of the ground-water samples: three detections of chloroform, one detection of carbon tetrachloride, one detection of methyl tert-butyl ether (MTBE), and one detection of 1,2,3,4-tetramethyl benzene (TeMB). VOC concentrations ranged from 0.22 to 4.7 micrograms per liter (?g/L), with only one VOC concentration greater than 1 ?g/L. A VOC was detected in one sample from the deep glacial drift aquifer, indicating that shallow aquifers may be more susceptible to VOC contamination than deep aquifers.","language":"ENGLISH","publisher":"U.S. Dept. of the Interior, U.S. Geological Survey,","doi":"10.3133/wri994229","usgsCitation":"Morrow, W.S., 1999, Volatile organic compounds in ground water of the lower Illinois River basin: U.S. Geological Survey Water-Resources Investigations Report 99-4229, 1 folded sheet; 6 p. :col. maps ;28 cm., https://doi.org/10.3133/wri994229.","productDescription":"1 folded sheet; 6 p. :col. maps ;28 cm.","costCenters":[],"links":[{"id":2312,"rank":100,"type":{"id":15,"text":"Index Page"},"url":"https://il.water.usgs.gov/pubsearch/reports.cgi/view?series=WRIR&number=99-4229","linkFileType":{"id":5,"text":"html"}},{"id":159629,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/wri/1999/4229/report-thumb.jpg"},{"id":57648,"rank":300,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/wri/1999/4229/report.pdf","linkFileType":{"id":1,"text":"pdf"}}],"noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"4f4e4a0de4b07f02db5fd9c3","contributors":{"authors":[{"text":"Morrow, William S. 0000-0002-2250-3165 wsmorrow@usgs.gov","orcid":"https://orcid.org/0000-0002-2250-3165","contributorId":1886,"corporation":false,"usgs":true,"family":"Morrow","given":"William","email":"wsmorrow@usgs.gov","middleInitial":"S.","affiliations":[{"id":344,"text":"Illinois Water Science Center","active":true,"usgs":true}],"preferred":true,"id":200375,"contributorType":{"id":1,"text":"Authors"},"rank":1}]}} ,{"id":28460,"text":"wri994108 - 1999 - Summary of hydrogeologic and ground-water-quality data and hydrogeologic framework at selected well sites, Adams County, Pennsylvania","interactions":[],"lastModifiedDate":"2018-02-12T09:41:37","indexId":"wri994108","displayToPublicDate":"2001-03-01T00:00:00","publicationYear":"1999","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":342,"text":"Water-Resources Investigations Report","code":"WRI","active":false,"publicationSubtype":{"id":5}},"seriesNumber":"99-4108","title":"Summary of hydrogeologic and ground-water-quality data and hydrogeologic framework at selected well sites, Adams County, Pennsylvania","docAbstract":"Rapid population growth in Adams County has increased the demand for ground water and led Adams County planning officials to undertake an effort to evaluate the capabilities of existing community water systems to meet future, projected growth and to begin wellhead-protection programs for public-supply wells. As part of this effort, this report summarizes ground-water data on a countywide scale and provides hydrogeologic information needed to delineate wellheadprotection areas in three hydrogeologic units (Gettysburg Lowland, Blue Ridge, and Piedmont Lowland).
Reported yields, specific capacities, well depths, and reported overburden thickness can vary by hydrogeologic unit, geologic formation, water use (domestic and nondomestic), and topographic setting. The reported yields of domestic wells drilled in the Gettysburg Lowland (median reported yield of 10 gallons per minute) are significantly greater than the reported yields from the Blue Ridge, Piedmont Lowland, and Piedmont Upland (median reported yields of 7.0, 8.0, and 7.0 gallons per minute, respectively). Reported yields of domestic wells completed in the diabase and the New Oxford Formation of the Gettysburg Lowland, and in the metarhyolite and metabasalt of the Blue Ridge, are significantly lower than reported yields of wells completed in the Gettysburg Formation. For nondomestic wells, reported yields from the Conestoga Formation of the Piedmont Lowland are significantly greater than in the diabase. Reported yields of nondomestic wells drilled in the Gettysburg, New Oxford, and Conestoga Formations, and the metarhyolite are significantly greater than those for domestic wells drilled in the respective geologic formations. Specific capacities of nondomestic wells in the Conestoga and Gettysburg Formations are significantly greater than their domestic counterparts. Specific capacities of nondomestic wells in the Conestoga Formation are significantly greater than the specific capacities of nondomestic wells in the metarhyolite, diabase, and Gettysburg and New Oxford Formations.Well depths do not vary considerably by hydrogeologic unit; instead, the greatest variability is by water use. Nondomestic wells drilled in the metarhyolite, Kinzers, Conestoga, Gettysburg, and New Oxford Formations are completed at significantly greater depths than their domestic counterparts. The reported thickness of overburden varies significantly by geologic formation and water use, but not by topographic setting. The median overburden thickness of the Blue Ridge (35 feet) is greater than in any other hydrologic unit.
Except where adversely affected by human activities, ground water in Adams County is suitable for most purposes. Calcium and magnesium are the dominant cations, and bicarbonate is the dominant anion. In general, the pH and hardness of ground water is lower in areas that are underlain by crystalline rocks (Blue Ridge and Piedmont Upland) than in areas underlain by sedimentary rocks, especially where limestone or dolomite is dominant (Piedmont Lowland). Dissolved nitrate (as N) and dissolved nitrite (as N) concentrations in the water from 9 of 69 wells and 3 of 80 wells sampled exceeded the U.S. Environmental Protection Agency (USEPA) maximum contaminant levels (MCL) of 10 and 1.0 mg/L (milligrams per liter), respectively. Sulfate concentrations greater than the proposed USEPA MCL of 500 mg/L were reported from the water in 3 of 110 wells sampled. Iron concentrations in the water from 13 of 67 wells sampled and manganese in the water from 9 of 64 wells sampled exceeded the USEPA secondary maximum contaminant level (SMCL) of 300 and 50 mg/L (micrograms per liter), respectively. Aluminum concentrations in the water from 16 of 22 wells sampled exceeded the lower USEPA SMCL threshold of 50 µg/L. Pesticides were detected in the water from seven wells but at concentrations that did not exceed USEPA MCL's. Most volatile organic compounds detected in the ground water were confined to USEPA Superfund sites or the immediate area around the sites.
The hydrogeologic framework in the vicinity of four public-supply well fields (Gettysburg, Abbottstown, Fairfield, and Littlestown) consists of two zones—an upper zone and a lower zone. In general, the upper zone is thin (5 to 60 feet or more) and dominated by saturated regolith and deeply weathered bedrock. The upper zone is bounded at the top by the water table and below by bedrock in which secondary porosity and permeability are considerably lower. Ground water is generally unconfined, and recharge rates are rapid. Ground-water flow is influenced more strongly by the topography of the ground surface and bedrock surface than by geologic structure. The lower zone is relatively thick (400 to 1,000 feet) and consists of slightly weathered to highly competent bedrock. Ground-water flow paths in the lower zone are generally greater and recharge rates are longer than in the upper zone; confined conditions are common, especially at depth.
","language":"English","publisher":"U.S. Geological Survey","publisherLocation":"Reston, VA","doi":"10.3133/wri994108","collaboration":"Adams County Office of Planning and Development","usgsCitation":"Low, D.J., and Dugas, D.L., 1999, Summary of hydrogeologic and ground-water-quality data and hydrogeologic framework at selected well sites, Adams County, Pennsylvania: U.S. Geological Survey Water-Resources Investigations Report 99-4108, viii, 86 p., https://doi.org/10.3133/wri994108.","productDescription":"viii, 86 p.","costCenters":[{"id":532,"text":"Pennsylvania Water Science Center","active":true,"usgs":true}],"links":[{"id":2311,"rank":300,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/wri/1999/4108/wri19994108.pdf","text":"Report","size":"6.97 MB","linkFileType":{"id":1,"text":"pdf"},"description":"WRI 1999-4108"},{"id":159423,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/wri/1999/4108/coverthb.jpg"}],"contact":"Director, Pennsylvania Water Science Center
U.S. Geological Survey
Pennsylvania Water Science Center
215 Limekiln Road
New Cumberland, PA 17070
Water-quality samples were collected during April 1996-April 1998 at three intensive fixed sites in the San Antonio region of the South-Central Texas study unit as part of the U.S. Geological Survey National Water-Quality Assessment Program. The sampling strategy for the intensive fixed-site assessment is centered on obtaining information about the occurrence and seasonal patterns of selected constituents including nutrients, pesticides, and volatile organic compounds. The three sites selected to determine the effects of agriculture and urbanization on surface-water quality in the study unit are Medina River at LaCoste (agriculture indicator site), Salado Creek (lower station) at San Antonio (urban indicator site), and San Antonio River near Elmendorf (integrator site).Concentrations of two nutrients, dissolved nitrite plus nitrate nitrogen and total phosphorus, were largest at the integrator site, which is downstream of municipal wastewater treatment plants. Nitrite plus nitrate nitrogen concentrations at this site often exceeded the U.S. Environmental Protection Agency (EPA) maximum contaminant level (MCL) for drinking water. All total phosphorus concentrations at the site exceeded the EPA recommended maximum concentration for streams not discharging directly into reservoirs. Nitrite plus nitrate nitrogen concentrations at the integrator site tended to be smaller, and total phosphorus concentrations at the urban site tended to be larger in samples collected during stormflow than during base flow. The most detections and largest concentrations of three pesticides (atrazine, diazinon, and prometon) were in samples collected at the urban site. Some pesticide concentrations at the agriculture site showed a seasonal pattern of increasing concentrations during spring, the peak application season. Four pesticides (atrazine, deethylatrazine, diazinon, and prometon) were detected in at least 38 percent of samples collected at all three sites. The concentrations of all detected pesticides that have an MCL were less than the MCL at the three sites. More volatile organic compounds (VOC) were detected at the urban indicator site than at the agriculture indicator site, mostly likely because more sources are located in urbanized areas. The most VOCs detected and the largest concentrations of two VOCs (chloroform and tetrahydrofuran) were in samples from the integrator site. More VOCs were detected in samples collected at the integrator site during stormflow than during base flow. The concentrations of all detected VOCs that have an MCL were less than the MCL at the three sites.
","language":"English","publisher":"U.S. Geological Survey","publisherLocation":"Reston, VA","doi":"10.3133/wri994155","usgsCitation":"Ging, P.B., 1999, Water-quality assessment of south-central Texas — Descriptions and comparisons of nutrients, pesticides, and volatile organic compounds at three intensive fixed sites, 1996-98: U.S. Geological Survey Water-Resources Investigations Report 99-4155, vi, 24 p., https://doi.org/10.3133/wri994155.","productDescription":"vi, 24 p.","onlineOnly":"N","additionalOnlineFiles":"N","costCenters":[{"id":583,"text":"Texas Water Science Center","active":true,"usgs":true}],"links":[{"id":159017,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/wri994155.PNG"},{"id":393468,"rank":4,"type":{"id":36,"text":"NGMDB Index Page"},"url":"https://ngmdb.usgs.gov/Prodesc/proddesc_22938.htm"},{"id":327296,"rank":101,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/wri/wri994155/99-4155.pdf"},{"id":2191,"rank":100,"type":{"id":15,"text":"Index Page"},"url":"https://pubs.water.usgs.gov/wri994155","linkFileType":{"id":5,"text":"html"}}],"country":"United States","state":"Texas","geographicExtents":"{\n \"type\": \"FeatureCollection\",\n \"features\": [\n {\n \"type\": \"Feature\",\n \"properties\": {},\n \"geometry\": {\n \"type\": \"Polygon\",\n \"coordinates\": [\n [\n [\n -100.546,\n 29\n ],\n [\n -97.694,\n 29\n ],\n [\n -97.694,\n 30.233\n ],\n [\n -100.546,\n 30.233\n ],\n [\n -100.546,\n 29\n ]\n ]\n ]\n }\n }\n ]\n}","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"4f4e49e6e4b07f02db5e7155","contributors":{"authors":[{"text":"Ging, Patricia B. 0000-0001-5491-8448 pbging@usgs.gov","orcid":"https://orcid.org/0000-0001-5491-8448","contributorId":1788,"corporation":false,"usgs":true,"family":"Ging","given":"Patricia","email":"pbging@usgs.gov","middleInitial":"B.","affiliations":[{"id":583,"text":"Texas Water Science Center","active":true,"usgs":true}],"preferred":true,"id":197909,"contributorType":{"id":1,"text":"Authors"},"rank":1}]}} ,{"id":25822,"text":"wri994135 - 1999 - Water-quality assessment of part of the upper Mississippi River basin, Minnesota and Wisconsin — Design and implementation of water-quality studies, 1995-98","interactions":[],"lastModifiedDate":"2021-12-15T22:41:44.97828","indexId":"wri994135","displayToPublicDate":"2001-02-01T00:00:00","publicationYear":"1999","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":342,"text":"Water-Resources Investigations Report","code":"WRI","active":false,"publicationSubtype":{"id":5}},"seriesNumber":"99-4135","title":"Water-quality assessment of part of the upper Mississippi River basin, Minnesota and Wisconsin — Design and implementation of water-quality studies, 1995-98","docAbstract":"From 1995 through 1998, water-quality and aquatic-biological samples were collected, processed, and analyzed for the U.S. Geological Survey's National Water-Quality Assessment Program in the Upper Mississippi River Basin in Minnesota and Wisconsin. Sites were selected and samples collected for integrated studies designed to provide a comprehensive description of water-quality conditions, to identify trends, and to determine the factors that affect existing conditions.
\nThis report describes the design, site-selection, and implementation of the study. Methods used to collect, process, and analyze samples; characterize sites; and assess habitat are described. A comprehensive list of sample sites is provided. Sample analyses for water-quality studies included chlorophyll a, major inorganic constituents, nutrients, trace elements, tritium, radon, environmental isotopes, organic carbon, pesticides, volatile organic compounds, and other synthetic and naturallyoccurring organic compounds. Aquatic-biological samples included fish, benthic macroinvertebrates, and algal enumeration and identification, as well as synthetic-organic compounds and trace elements in fish tissue.
","language":"English","publisher":"U.S. Geological Survey","publisherLocation":"Mounds View, MN","doi":"10.3133/wri994135","usgsCitation":"Stark, J.R., Fallon, J.D., Fong, A.L., Goldstein, R.M., Hanson, P.E., Kroening, S., and Lee, K.E., 1999, Water-quality assessment of part of the upper Mississippi River basin, Minnesota and Wisconsin — Design and implementation of water-quality studies, 1995-98: U.S. Geological Survey Water-Resources Investigations Report 99-4135, vii, 85 p., https://doi.org/10.3133/wri994135.","productDescription":"vii, 85 p.","onlineOnly":"N","additionalOnlineFiles":"N","costCenters":[{"id":392,"text":"Minnesota Water Science 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E.","contributorId":100014,"corporation":false,"usgs":true,"family":"Lee","given":"K.","email":"","middleInitial":"E.","affiliations":[],"preferred":false,"id":195214,"contributorType":{"id":1,"text":"Authors"},"rank":7}]}} ,{"id":25712,"text":"wri984220 - 1999 - Potentiometric levels and water quality in the aquifers underlying Belvidere, Illinois, 1993–96","interactions":[],"lastModifiedDate":"2024-10-30T18:36:47.762909","indexId":"wri984220","displayToPublicDate":"2001-02-01T00:00:00","publicationYear":"1999","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":342,"text":"Water-Resources Investigations Report","code":"WRI","active":false,"publicationSubtype":{"id":5}},"seriesNumber":"98-4220","displayTitle":"Potentiometric Levels and Water Quality in the Aquifers Underlying Belvidere, Illinois, 1993–96","title":"Potentiometric levels and water quality in the aquifers underlying Belvidere, Illinois, 1993–96","docAbstract":"In 1992, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency (USEPA), began a study of the hydrogeology and water quality of the aquifers underlying the vicinity of Belvidere, Boone County, Ill. Previously, volatile organic compounds (VOC's) and other constituents of industrial origin were detected in one or more ground-water samples from about 100 of the approximately 700 monitoring and water-supply wells in the area, including the 8 municipal wells in Belvidere. A glacial drift aquifer underlies at least 50 percent of the 80-square-mile study area; bedrock aquifers that underlie virtually all of the study area include the Galena-Platteville, St. Peter Sandstone, Ordovician, and Cambrian-Ordovician aquifers.
During 1993, water levels were measured in 152 wells and water-quality samples were collected from 97 wells distributed throughout the study area. During 1994–96, similar data were collected from 31 wells. Potentiometric levels in the glacial drift and Galena-Platteville aquifers are similar and range from about 750 to 900 feet above sea level. The potentiometric surfaces of the aquifers are subdued representations of the land surface. Horizontal ground-water flow in the aquifers primarily is towards the Kishwaukee River, which flows through the central part of the study area, and its principal tributaries. Vertical ground-water flow appears to be downward at most locations in the study area, particularly in the urbanized areas affected by pumping of the Belvidere municipal wells and upland areas remote from the principal surface-water drainages. Flow appears to be upward between the Galena-Platteville and glacial drift aquifers where ground water discharges to the Kishwaukee River and its principal tributaries.
All water samples were analyzed for VOC's. Selected samples also were analyzed for trace metals, cyanide, semivolatile organic compounds, or other constituents. VOC's were detected in samples from 50 wells (52 percent of total wells sampled). Twenty-seven specific VOC's were identified in the samples. Samples were collected from six municipal wells in use during the study; two wells were not in use because one or more VOC's exceeded maximum contaminant levels (MCL's). Two VOC's were detected in one of the samples at concentrations below MCL's established by the USEPA for protection of public-water supplies. Samples from 21 wells had at least one VOC detected at a concentration above MCL's. The VOC's detected above MCL's and their maximum concentrations were 1,2-dichloroethene (total), 470 micrograms per liter; trichloroethene (TCE), 360 micrograms per liter; tetrachloroethene (PCE), 82 micrograms per liter; benzene, 53 micrograms per liter; and vinyl chloride, 11 micrograms per liter. TCE and PCE were the most frequently detected VOC's and generally had the highest concentrations. VOC's with concentrations above MCL's were detected in samples from 15 wells open to the glacial drift aquifer and 6 wells open to the Galena-Platteville aquifer.
Generally, the concentrations of VOC's were higher, and number and type of VOC's detected were greater in the glacial drift aquifer than in the Galena-Platteville aquifer and the deeper bedrock aquifers. The high concentrations and spatial distribution of VOC's in the glacial drift aquifer usually were related to nearby sources of contamination. Except in the immediate vicinity of a known hazardous-waste site, possible sources of VOC's in the bedrock aquifers were difficult to identify in the study area; VOC concentrations at most locations in the bedrock aquifers were below 5 micrograms per liter. Most locations where VOC's were detected in the glacial and bedrock aquifers were within about 1,000 feet of the Kishwaukee River. Hydrogeologic factors that affect the distribution of VOC's in the aquifers include ground-water flow through (1) the glacial drift aquifer with discharge to the nearby Kishwaukee River; and (2) the weathered-surface deposits, bedding-plane partings, and fractures in the Galena-Platteville aquifer. One bedding-plane parting intersecting wells that represent an area of about 1.5 square miles has a horizontal hydraulic conductivity as high as 220 feet per day. Pumping of high-capacity wells may contribute to the widespread distribution of VOC’s at low concentrations in the bedrock aquifers.
","language":"English","publisher":"U.S. Geological Survey","publisherLocation":"Reston, VA","doi":"10.3133/wri984220","collaboration":"Prepared in cooperation with the U.S. Environmental Protection Agency","usgsCitation":"Mills, P., Thomas, C., Brown, T., Yeskis, D., and Kay, R., 1999, Potentiometric levels and water quality in the aquifers underlying Belvidere, Illinois, 1993–96: U.S. Geological Survey Water-Resources Investigations Report 98-4220, Report: v, 106 p.; 2 Plates: 31.33 x 34.65 inches and 29.39 x 34.79 inches, https://doi.org/10.3133/wri984220.","productDescription":"Report: v, 106 p.; 2 Plates: 31.33 x 34.65 inches and 29.39 x 34.79 inches","costCenters":[{"id":344,"text":"Illinois Water Science Center","active":true,"usgs":true}],"links":[{"id":95555,"rank":4,"type":{"id":17,"text":"Plate"},"url":"https://pubs.usgs.gov/wri/1998/4220/plate-2.pdf","text":"Plate 2","linkFileType":{"id":1,"text":"pdf"},"description":"WRI 98–4220 Plate 2"},{"id":95554,"rank":3,"type":{"id":17,"text":"Plate"},"url":"https://pubs.usgs.gov/wri/1998/4220/plate-1.pdf","text":"Plate 1","linkFileType":{"id":1,"text":"pdf"},"description":"WRI 98–4220 Plate 1"},{"id":156887,"rank":1,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/wri/1998/4220/coverthb.jpg"},{"id":361757,"rank":2,"type":{"id":11,"text":"Document"},"url":"https://pubs.usgs.gov/wri/1998/4220/wrir98_4220.pdf","text":"Report","linkFileType":{"id":1,"text":"pdf"},"description":"WRI 98–4220"},{"id":463438,"rank":5,"type":{"id":36,"text":"NGMDB Index Page"},"url":"https://ngmdb.usgs.gov/Prodesc/proddesc_19292.htm","linkFileType":{"id":5,"text":"html"}}],"country":"United States","state":"Illinois","city":"Belvidere","geographicExtents":"{\n \"type\": \"FeatureCollection\",\n \"features\": [\n {\n \"type\": \"Feature\",\n \"properties\": {},\n \"geometry\": {\n \"type\": \"Polygon\",\n \"coordinates\": [\n [\n [\n -88.97003173828125,\n 42.16340342422401\n ],\n [\n -88.758544921875,\n 42.16340342422401\n ],\n [\n -88.758544921875,\n 42.332153998913704\n ],\n [\n -88.97003173828125,\n 42.332153998913704\n ],\n [\n -88.97003173828125,\n 42.16340342422401\n ]\n ]\n ]\n }\n }\n ]\n}","contact":"Director, Central Midwest Water Science Center
U.S. Geological Survey
405 North Goodwin
Urbana, IL 61801
Ground-water samples were collected from 33 domestic wells to assess the water quality of the eastern part of the Silurian-Devonian and Upper Carbonate aquifers in the Eastern Iowa Basins National Water-Quality Assessment Program study unit. Samples were collected during June and July 1996 and analyzed for major ions, nutrients, pesticides and pesticide metabolites, volatile organic compounds, tritium, radon222, and environmental isotopes.
\nCalcium, magnesium, and bicarbonate were the dominant ions in most samples and were likely derived from the solution of carbonate minerals (calcite and dolomite) present in the aquifer materials. The dominance of sulfate in samples from several wells suggests the dissolution of evaporite minerals. Ammonia and orthophosphorus were the most commonly detected nutrients. Nitrate was detected in about half of the samples and exceeded the U.S. Environmental Protection Agency maximum contaminant level (10 milligrams per liter) in 6 percent of samples. Atrazine and metolachlor were the only pesticides detected and were present in 18 percent and 12 percent of samples, respectively. Alachlor ethanesulfonic acid and deethylatrazine were the most commonly detected pesticide metabolites and were present in 16 percent and 9 percent of samples, respectively. Radon-222 was detected in all samples, and 47 percent had concentrations in excess of the U.S. Environmental Protection Agency previously proposed maximum contaminant level (300 picocuries per liter). Radon-222 concentrations were significantly higher in samples from wells that produced recently recharged water. This relation suggests that uranium-bearing glacial deposits (Schumann, 1993) may be a source of radon-222 in the underlying aquifers.
\nThe presence of regional confining units and thick overlying Quaternary-age deposits have an effect on water quality in the Silurian-Devonian and Upper Carbonate aquifers in the study area. Tritium-based ground-water ages were significantly older, and dissolved-solids concentrations were significantly higher in relatively well protected areas (where the aquifers are overlain by a bedrock confining unit or more than 100 feet of Quaternary-age deposits). Ammonia concentrations were significantly higher in relatively well protected areas and in samples from wells that produced older water. Higher ammonia concentrations also were observed in ground water with dissolved-oxygen concentrations of 0.5 milligram per liter or less, allowing for the anaerobic reduction of nitrate to ammonia. Nitrate concentrations were significantly higher in relatively poorly protected areas (where the aquifers are not overlain by a bedrock confining unit or are overlain by less than 100 feet of Quaternaryage deposits) and in samples from wells that produced recently recharged water. Pesticide and metabolite concentrations were significantly higher in samples from wells that produced recently recharged water. Atrazine, metolachlor, and deethylatrazine were not detected in any samples from relatively well protected areas of the aquifers.
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1999 - Water-quality assessment of the New England coastal basins in Maine, Massachusetts, New Hampshire, and Rhode Island: Environmental settings and implications for water quality and aquatic biota","interactions":[],"lastModifiedDate":"2022-02-22T22:55:18.732039","indexId":"wri984249","displayToPublicDate":"2001-01-01T00:00:00","publicationYear":"1999","noYear":false,"publicationType":{"id":18,"text":"Report"},"publicationSubtype":{"id":5,"text":"USGS Numbered Series"},"seriesTitle":{"id":342,"text":"Water-Resources Investigations Report","code":"WRI","active":false,"publicationSubtype":{"id":5}},"seriesNumber":"98-4249","title":"Water-quality assessment of the New England coastal basins in Maine, Massachusetts, New Hampshire, and Rhode Island: Environmental settings and implications for water quality and aquatic biota","docAbstract":"The New England Coastal Basins in Maine, Massachusetts, New Hampshire, and Rhode Island constitute one of 59 study units selected for water-quality assessment as part of the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) program. England Coastal Basins study unit encompasses the fresh surface waters and ground waters in a 23,000 square-mile area that drains to the Atlantic Ocean. Major basins include those of the Kennebec, Androscoggin, Saco, Merrimack, Charles, Blackstone, Taunton, and Pawcatuck Rivers. Defining the environmental setting of the study unit is the first step in designing and conducting a multi-disciplinary regional water-quality assessment. The report describes the natural and human factors that affect water quality in the basins and includes descriptions of the physiography, climate, geology, soils, surface- and ground-water hydrology, land use, and the aquatic ecosystem. Although surface-water quality has greatly improved over the past 30 years as a result of improved wastewater treatment at municipal and industrial wastewater facilities, a number of water-quality problems remain. Industrial and municipal wastewater discharges, combined sewer overflows, hydrologic modifications from dams and water diversions, and runoff from urban land use are the major causes of water-quality degradation in 1998. The most frequently detected contaminants in ground water in the study area are volatile organic compounds, petroleum-related products, nitrates, and chloride and sodium. Sources of these contaminants include leaking storage tanks, accidental spills, landfills, road salting, and septic systems and lagoons. Elevated concentrations of mercury are found in fish tissue from streams and lakes throughout the study area.","language":"English","publisher":"U.S. Geological Survey","doi":"10.3133/wri984249","usgsCitation":"Flanagan, S., Nielsen, M.G., Robinson, K.W., and Coles, J.F., 1999, Water-quality assessment of the New England coastal basins in Maine, Massachusetts, New Hampshire, and Rhode Island: Environmental settings and implications for water quality and aquatic biota: U.S. Geological Survey Water-Resources Investigations Report 98-4249, vii, 62 p., https://doi.org/10.3133/wri984249.","productDescription":"vii, 62 p.","costCenters":[],"links":[{"id":158522,"rank":0,"type":{"id":24,"text":"Thumbnail"},"url":"https://pubs.usgs.gov/thumbnails/usgs_thumb.jpg"},{"id":396300,"rank":3,"type":{"id":36,"text":"NGMDB Index Page"},"url":"https://ngmdb.usgs.gov/Prodesc/proddesc_16456.htm"},{"id":2062,"rank":100,"type":{"id":15,"text":"Index Page"},"url":"https://pubs.water.usgs.gov/wri984249","linkFileType":{"id":5,"text":"html"}}],"country":"United States","state":"Maine, Massachusetts, New Hampshire, Rhode Island","otherGeospatial":"New England coastal basins","geographicExtents":"{\n \"type\": \"FeatureCollection\",\n \"features\": [\n {\n \"type\": \"Feature\",\n \"properties\": {},\n \"geometry\": {\n \"type\": \"Polygon\",\n \"coordinates\": [\n [\n [\n -72,\n 41.3\n ],\n [\n -69.183,\n 41.3\n ],\n [\n -69.183,\n 45.733\n ],\n [\n -72,\n 45.733\n ],\n [\n -72,\n 41.3\n ]\n ]\n ]\n }\n }\n ]\n}","noUsgsAuthors":false,"publicationStatus":"PW","scienceBaseUri":"4f4e4a0ae4b07f02db5fb5b3","contributors":{"authors":[{"text":"Flanagan, Sarah M.","contributorId":8492,"corporation":false,"usgs":true,"family":"Flanagan","given":"Sarah M.","affiliations":[],"preferred":false,"id":195271,"contributorType":{"id":1,"text":"Authors"},"rank":1},{"text":"Nielsen, Martha G. 0000-0003-3038-9400 mnielsen@usgs.gov","orcid":"https://orcid.org/0000-0003-3038-9400","contributorId":4169,"corporation":false,"usgs":true,"family":"Nielsen","given":"Martha","email":"mnielsen@usgs.gov","middleInitial":"G.","affiliations":[{"id":37947,"text":"Upper Midwest Water Science Center","active":true,"usgs":true}],"preferred":true,"id":195270,"contributorType":{"id":1,"text":"Authors"},"rank":2},{"text":"Robinson, Keith W. kwrobins@usgs.gov","contributorId":2969,"corporation":false,"usgs":true,"family":"Robinson","given":"Keith","email":"kwrobins@usgs.gov","middleInitial":"W.","affiliations":[],"preferred":true,"id":195269,"contributorType":{"id":1,"text":"Authors"},"rank":3},{"text":"Coles, James F. 0000-0002-1953-012X jcoles@usgs.gov","orcid":"https://orcid.org/0000-0002-1953-012X","contributorId":2239,"corporation":false,"usgs":true,"family":"Coles","given":"James","email":"jcoles@usgs.gov","middleInitial":"F.","affiliations":[{"id":466,"text":"New England Water Science Center","active":true,"usgs":true}],"preferred":true,"id":195268,"contributorType":{"id":1,"text":"Authors"},"rank":4}]}} ]}