Scientific Investigations Report 2006–5236
U.S. GEOLOGICAL SURVEY
Scientific Investigations Report 2006–5236
Historically, the NWQL used a minimum reporting level (MRL) to report nondetected concentrations or concentrations less than the MRL. The MRL for chemical constituents is the lowest measured constituent concentration that may be reliably reported using a given analytical method (Timme, 1995). This was the “less than” value reported by the NWQL. However, the NWQL determined that establishment of MRLs often was inconsistent, undefined, undocumented, and subjective (Childress and others, 1999). In 1998, the NWQL began implementing new reporting procedures for some analytical methods based on long-term method detection levels. Childress and others (1999, p. 16) explained the new reporting procedures used by the NWQL:
“The USGS National Water Quality Laboratory collects quality-control data on a continuing basis to evaluate selected analytical methods to determine long-term method detection levels (LT–MDLs) and laboratory reporting levels (LRLs). These values are re-evaluated each year on the basis of the most recent quality control data and, consequently, may change from year to year.
This reporting procedure limits the occurrence of false positive error. The chance of falsely reporting a concentration greater than the LT–MDL for a sample in which the analyte is not present is 1 percent or less. Application of the LRL limits the occurrence of false negative error. The chance of falsely reporting a non-detection for a sample in which the analyte is present at a concentration equal to or greater than the LRL is 1 percent or less.
Accordingly, concentrations are reported as <LRL for samples in which the analyte was either not detected or did not pass identification. Analytes detected at concentrations between the LT‑MDL and LRL and that pass identification criteria are estimated. Estimated concentrations will be noted with a remark code of “E.” These data should be used with the understanding that their uncertainty is greater than that of data reported without the “E” remark code.”
New LRLs were established for some analytical methods during 1999–2001. In this report, concentrations determined using these methods are reported as greater than the LRL; concentrations determined using other methods are reported as greater than the MRL. Estimated concentrations less than the LRLs are treated as nondetected concentrations for consistency with treatment in previous publications, and because an estimated concentration is considered a “qualitatively detected analyte” (Childress and others, 1999, p. 7).
U.S.
Department of the Interior | U.S. Geological
Survey
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