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Scientific Investigations Report 2010–5070–J

A Deposit Model for Carbonatite and Peralkaline Intrusion-Related Rare Earth Element Deposits

By Philip L. Verplanck, Bradley S. Van Gosen, Robert R. Seal, and Anne E. McCafferty

Chapter J of
Mineral Deposit Models for Resource Assessment

Thumbnail of and link to report PDF (11.8 MB)Abstract

Carbonatite and alkaline intrusive complexes, as well as their weathering products, are the primary sources of rare earth elements. A wide variety of other commodities have been exploited from carbonatites and alkaline igneous rocks including niobium, phosphate, titanium, vermiculite, barite, fluorite, copper, calcite, and zirconium. Other elements enriched in these deposits include manganese, strontium, tantalum, thorium, vanadium, and uranium. Carbonatite and peralkaline intrusion-related rare earth element deposits are presented together in this report because of the spatial, and potentially genetic, association between carbonatite and alkaline rocks. Although these rock types occur together at many locations, carbonatite and peralkaline intrusion-related rare earth element deposits are not generally found together.

Carbonatite hosted rare earth element deposits are found throughout the world, but currently only five are being mined for rare earth elements: Bayan Obo, Daluxiang, Maoniuping, and Weishan deposits in China and the Mountain Pass deposit in California, United States. These deposits are enriched in light rare earth elements, including lanthanum, cerium, praseodynium, and neodynium. The principal rare earth element-minerals associated with carbonatites are fluocarbonates (bastnäsite, parisite, and synchysite), hydrated carbonates (ancylite), and phosphates (monazite) with bastnäsite being the primary ore mineral. Calcite and dolomite are the primary gangue minerals. At present, the only rare earth element production from a peralkaline intrusion-related deposit is as a byproduct commodity at the Lovozero deposit in Russia. Important rare earth element minerals found in various deposits include apatite, eudialyte, loparite, gittinsite, xenotime, gadolinite, monazite, bastnäsite, kainosite, mosandrite, britholite, allanite, fergusonite, and zircon, and these minerals tend to be enriched in heavy rare earth elements.

Carbonatite and alkaline intrusive complexes are derived from partial melts of mantle material, and neodymium isotopic data are consistent with the rare earth elements being derived from the parental magma. Deposits and these associated rock types tend to occur within stable continental tectonic units, in areas defined as shields, cratons, and crystalline blocks; they are generally associated with intracontinental rift and fault systems. Protracted fractional crystallization of the magma leads to enrichment in rare earth elements and other incompatible elements. Rare earth element mineralization associated with carbonatites can occur as either primary mineral phases or as mineralization associated with late stage orthomagmatic fluids. Rare earth element mineralization associated with alkaline intrusive complexes may occur as primary phases in magmatic layered complexes or as late-stage dikes and veins.

The greatest environmental challenges associated with carbonatite and peralkaline intrusion-related rare earth element deposits center on the associated uranium and thorium. Considerable uncertainty exists around the toxicity of rare earth elements and warrants further investigation. The acid-generating potential of carbonatites and peralkaline intrusion-related deposits is low due to the dominance of carbonate minerals in carbonatite deposits, the presence of feldspars and minor calcite within the alkaline intrusion deposits, and only minor quantities of potentially acid-generating sulfides. Therefore, acid-drainage issues are not likely to be a major concern associated with these deposits. Uranium has the potential to be recovered as a byproduct, which would mitigate some of its environmental effects. However, thorium will likely remain a waste-stream product that will require management since progress is not being made towards the development of thorium-based nuclear reactors in the United States or other large scale commercial uses. Because some deposits are rich in fluorine and beryllium, these elements may be of environmental concern in certain locations.

First posted March 3, 2014

For additional information, contact:
Director, Central Mineral and Environmental Resources Science Center
U.S. Geological Survey
Box 25046, MS 973
Denver, CO 80225

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Suggested citation:

Verplanck, P.L., Van Gosen, B.S., Seal, R.R, and McCafferty, A.E., 2014, A deposit model for carbonatite and peralkaline intrusion-related rare earth element deposits: U.S. Geological Survey Scientific Investigations Report 2010–5070–J, 58 p.,

ISSN 2328-0328 (online)




Deposit Type and Associated Commodities

Historical Evolution of Descriptive and Genetic Knowledge and Concepts

Regional Environment

Physical Description of Deposit

Geophysical Characteristics

Hypogene Ore Characteristics

Hypogene Gangue Characteristics

Hydrothermal Alteration

Weathering/Supergene Characteristics and Processes

Geochemical Characteristics

Petrology of Associated Igneous Rocks

Petrology of Associated Sedimentary Rocks

Petrology of Associated Metamorphic Rocks

Theory of Deposit Formation

Exploration/Resource Assessment Guides

Geoenvironmental Features

References Cited

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