Table 13. Halogenated compounds detected in solids filtered from wastewater-treatment-plant effluent, Columbia River Basin, Washington and Oregon, 2008–09.
[Station names are shown in table 2. Concentrations reported in nanograms per liter. See table A1 for a listing of halogenated compounds analyzed and their reporting limits. Present, presence is verified, but concentration is not quantified; sometimes the reporting limit for an individual sample is raised because of matrix interference, these instances of non-detection are shown as less than (<) the raised reporting limit. Abbreviations: L, liter; –, not detected; ND, not determined because of poor compound recoveries]
| Analyte |
Wenatchee |
Richland |
Umatilla |
The Dalles |
Hood River |
Portland |
Vancouver |
St. Helens |
Longview |
| (a.m.) |
(noon) |
(p.m.) |
| Volume filtered (L) |
21 |
19 |
18 |
18 |
19 |
20 |
10 |
9 |
18 |
12 |
20 |
| Polybrominated diphenyl ethers (PBDEs) or brominated flame retardants |
| Dechlorane plus |
Present |
Present |
– |
– |
– |
– |
– |
– |
– |
Present |
– |
| Firemaster 680 |
0.02 |
0.07 |
0.02 |
0.04 |
0.13 |
0.05 |
0.03 |
0.08 |
0.06 |
0.05 |
– |
| PBDE-47 |
Present |
Present |
Present |
Present |
Present |
Present |
Present |
Present |
Present |
Present |
Present |
| PBDE-66 |
0.07 |
0.22 |
0.14 |
0.15 |
0.09 |
0.10 |
0.02 |
0.11 |
0.45 |
0.04 |
0.05 |
| PBDE-85 |
0.07 |
0.28 |
0.09 |
0.09 |
0.08 |
0.17 |
0.09 |
0.21 |
0.21 |
0.08 |
0.12 |
| PBDE-99 |
Present |
Present |
Present |
Present |
Present |
Present |
Present |
4.8 |
Present |
Present |
Present |
| PBDE-100 |
Present |
1.6 |
Present |
Present |
Present |
Present |
Present |
Present |
Present |
Present |
Present |
| PBDE-138 |
0.02 |
0.06 |
0.04 |
0.03 |
0.03 |
0.05 |
0.02 |
0.08 |
0.06 |
0.03 |
– |
| PBDE-153 |
0.12 |
0.40 |
0.25 |
0.14 |
0.15 |
0.06 |
0.11 |
0.36 |
0.27 |
0.16 |
0.16 |
| PBDE-154 |
0.12 |
0.38 |
0.27 |
0.15 |
0.15 |
0.25 |
0.08 |
0.31 |
0.28 |
0.15 |
0.16 |
| PBDE-183 |
– |
0.05 |
0.03 |
0.03 |
0.04 |
0.04 |
0.02 |
0.04 |
0.04 |
– |
– |
| Polychlorinated biphenyls (PCBs) |
| PCB-101 |
– |
– |
– |
– |
– |
– |
– |
– |
– |
– |
Present |
| PCB-146 |
0.01 |
– |
– |
– |
– |
– |
– |
– |
– |
– |
– |
| PCB-170 |
0.01 |
– |
– |
– |
– |
– |
– |
– |
– |
– |
– |
| PCB-174 |
0.01 |
– |
– |
– |
– |
– |
– |
– |
– |
– |
– |
| PCB-177 |
0.01 |
– |
– |
– |
– |
– |
– |
– |
– |
– |
– |
| PCB-180 |
0.02 |
– |
– |
– |
– |
– |
– |
– |
– |
0.02 |
0.01 |
| PCB-183 |
Present |
– |
– |
– |
– |
– |
– |
– |
– |
– |
– |
| PCB-187 |
0.01 |
– |
– |
– |
– |
– |
– |
– |
– |
– |
– |
| PCB-194 |
Present |
– |
– |
– |
– |
– |
– |
– |
– |
– |
– |
| Herbicides and insecticides |
| cis-Chlordane |
0.03 |
0.19 |
0.02 |
0.08 |
0.05 |
0.10 |
– |
0.05 |
0.05 |
0.07 |
0.09 |
| trans-Chlordane |
0.02 |
0.19 |
0.01 |
0.05 |
0.03 |
0.08 |
0.02 |
0.06 |
0.03 |
0.01 |
0.05 |
| Chlorpyrifos |
– |
– |
– |
– |
– |
0.18 |
0.18 |
0.43 |
– |
0.04 |
0.03 |
| Cyfluthrin |
– |
0.26 |
– |
0.18 |
– |
0.26 |
0.07 |
0.41 |
– |
– |
– |
| lambda-Cyhalothrin |
0.02 |
Present |
– |
– |
– |
Present |
– |
Present |
– |
– |
– |
| Desulfinylfipronil |
– |
Present |
Present |
0.02 |
0.02 |
Present |
– |
Present |
0.07 |
– |
– |
| Dieldrin |
0.01 |
0.17 |
– |
– |
0.05 |
0.14 |
– |
0.09 |
0.08 |
– |
< 0.04 |
| alpha-Endosulfan |
0.01 |
– |
– |
– |
– |
– |
– |
– |
– |
– |
– |
| Fipronil |
ND |
0.22 |
0.06 |
0.17 |
0.20 |
0.99 |
0.35 |
0.77 |
1.4 |
ND |
0.05 |
| Fipronil Sulfide |
– |
0.03 |
0.02 |
Present |
0.02 |
0.06 |
0.02 |
0.06 |
0.08 |
0.04 |
0.01 |
| cis-Nonachlor |
Present |
– |
– |
– |
– |
– |
– |
– |
– |
– |
0.01 |
| trans-Nonachlor |
0.01 |
0.10 |
Present |
0.03 |
– |
0.04 |
– |
0.04 |
– |
0.01 |
0.03 |
| Pentachloroanisole |
Present |
Present |
– |
– |
Present |
– |
– |
– |
0.85 |
– |
Present |
| Trifluralin |
Present |
– |
– |
– |
– |
0.02 |
– |
0.02 |
– |
– |
– |
| Other compounds |
| Hexachlorobenzene (HCB) |
– |
– |
Present |
– |
– |
– |
– |
– |
– |
– |
– |
| Methoxy triclosan |
1.2 |
3.7 |
– |
– |
4.6 |
1.7 |
– |
– |
13 |
Present |
1.1 |
| Triclosan |
Present |
Present |
– |
Present |
Present |
55 |
Present |
57 |
86 |
– |
ND |
|
First posted April 25, 2012
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