Tellurium (Te) is a rare metalloid, meaning this element has properties between those of a typical metal and nonmetal. It is used in alloys, mostly with copper (Cu) and stainless steel to improve their machinability. Tellurium is also used in the coloring of glass and ceramics, in thermoelectric devices, and as an ingredient in blasting caps. Tellurium has no known biological function and is considered to be mildly toxic.
The chemistry of Te is similar to that of sulfur (S), and Te frequently occurs as a replacement for S in common sulfide minerals such as pyrite (FeS2), chalcopyrite (CuFeS2), and molybdenite (MoS2). In soils, Te is associated with iron (Fe) and manganese (Mn) oxides and hydroxides.
The average abundance of Te in the Earth's upper continental crust is estimated to be about 0.027 milligrams per kilogram (mg/kg) (Hu and Gao, 2008), although data are somewhat lacking. Data are also sparse for the common rock types, but Te concentration averages about 0.009 mg/kg in shale, about 0.005 mg/kg in granite, and about 0.002 mg/kg in sandstone and limestone.
In our study, Te was determined by inductively coupled plasma–mass spectrometry following a near–total four–acid digestion of the <2–mm fraction of the soil samples. The lower limit of determination (LLD) for Te by this method is 0.1 mg/kg, which is high compared to the average crustal abundance of approximately 0.027 mg/kg. Therefore, relatively few of the analytical results for Te are above the LLD. Tellurium concentrations in only 157 of 4,841 samples analyzed (3.2 percent) are above the LLD for the top 0- to 5-cm layer; 158 of 4,813 samples (3.3 percent) for the soil A horizon; and 213 of 4,780 samples (4.5 percent) for the soil C horizon. Obviously, the median concentration for all three sample types collected in this study (top 0- to 5-cm layer, soil A horizon, and soil C horizon) can only be stated as less than 0.1 mg/kg (see the summary statistics [open in new window]). Because so few of the samples have Te concentrations above the LLD, the spatial distribution is shown as proportional symbol maps rather than interpolated and smoothed color surface maps. It is also important to note that even for samples having uncensored concentrations (concentrations above the LLD), most were less than 5 times the LLD. Data this close to the LLD are subject to considerable uncertainty and the map patterns generated from these data must be interpreted with caution.
The distribution of mineral resource deposits with Te as a commodity (major or minor) in the United States, extracted from the U.S. Geological Survey (USGS) Mineral Resource Data System (MRDS) website, can be seen by hovering the mouse here. Statistics and information on the worldwide supply of, demand for, and flow of Te–bearing materials are available through the U.S. Geological Survey (USGS) National Minerals Information Center (NMIC) website.
The distribution of Te in soils of the conterminous United States seems to be primarily controlled by the composition of the underlying soil parent material. Although only a small percentage of data are above the LLD, a few patterns of elevated Te are observed as follows:
Given the nature of the Te data and the resulting maps, it is impossible to observe any geochemical patterns relating to depleted Te concentrations.