USGS

Quality Assurance Practices For the Chemical and Biological Analyses of Water and Fluvial Sediments

U.S. Geological Survey, Techniques of Water-Resources Investigations, Book 5, Chapter A6

By Linda C. Friedman and David E. Erdmann


Table of Contents

Preface

Contributors

Abstract

Introduction

Purpose

Scope

Definitions

References

Analytical methods development procedures

Single operator precision

Bias

Chemical interferences

Intralaboratory precision and bias

Interlaboratory precision

Acceptance or rejection of a new method

Standard quantitative analysis techniques

Cleaning glassware

Correction for color interference

Gravimetry

Reagents and gases

Standard-addition technique

Titrimetry

Instrumental techniques

Instrument maintenance

Analytical balances

Atomic absorption spectrometers

Automated analyzers

Calorimetric spectrometers

Conductivity meters

Gas chromatographs

Potentiometers

Reference material

Preparation of ampouled concentrates

Preparation of natural water reference material

Development of statistical data for standard reference water samples

Laboratory quality control

Biological quality control

Analysis of aquatic organisms (benthic invertebrates, phytoplankton, and periphyton)

Bacteriological analysis

Inorganic quality control

Atomic absorption analysis

Automated calorimetric or potentiometric analysis

Automated measurement of specific conductance and pH

Calorimetric analysis

Determination of color or turbidity

Determination of pH

Determination of solids concentration

Determination of specific conductance

Electrometric titration (alkalinity and acidity)

Organic quality control

Gas chromatographic analysis

Quality control charts

Quality control duties and responsibilities of section leader

Quality assurance monitoring

Analytical data review and quality assurance

Reference material submitted by laboratory management

Reference material submitted from outside the laboratory

Reference material submitted to cooperator and contractor laboratories

Reference material use in monitoring field pH and specific conductance measurements

Quality assurance and quality control personnel

Documentation, summary, and evaluation of data

Required documentation and review of data

Evaluation of field reference material data

Initial evaluation of cooperator and contractor laboratories

Methods for data summation and evaluations: tabular presentations

Methods used for data evaluation: graphical presentations

Methods used for data evaluation: t-test

Methods used for data evaluation: a test of laboratory variance

Materials evaluation

Selection of sample

Single sampling with operating characteristic curves

Single sampling plans, to obtain lots of acceptable quality

Double sampling plans, to obtain lots of acceptable quality

Sequential sampling plans, to obtain lots of acceptable quality

Reducing sample inspection

Appendix

 


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