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Concentrations and annual fluxes for selected water-quality constituents from the USGS National Stream Water Quality Accounting Network (NASQAN)

By Valerie J. Kelly, Richard P. Hooper, Brent T. Aulenbach, and Mary Janet

Summary Statistics--Rio Grande Basin, Water Years 1996-2000

Rio Grande at Foster Ranch near Langtry, Texas (08377200)

Daily Mean Streamflow

Units                               N             Min     5th       25th     Median    75th      95th      Max

Cubic feet per second             1,827           130       249       371       494       646     1,840    14,800
Cubic meters per second           1,827             4         7        11        14        18        52       419

Field Parameters, Turbidity, and Suspended Sediment

Units in milligrams per liter, except where noted

Parameter                             N               Min      5th     25th    Median     75th     95th     Max

00010 Temperature (C)                52                 9.5    12.0     18.0      25.6     27.2     28.0     29.0
00076 Turbidity (NTU)                52                 0.1     6.2     38.5      85.0    705.0   7500.0  10400.0
00095 Conductance (uS/cm)            52               506.0   628.0    897.0    1225.0   1520.0   1850.0   2069.0
00300 Dissolved oxygen               52                 2.6     4.1      6.7       7.7      9.3     11.0     12.1
00400 pH (standard units)            52                 7.4     7.5      7.7       7.9      8.1      8.3      8.5
00452 CO3 (filtered)                 52                 0.0     0.0      0.0       0.0      0.0      6.0      8.0
00453 HCO3 (filtered)                52               102.0   107.0    138.5     167.5    179.0    205.0    255.0
39086 Alk (filtered, as CaCO3)       52                84.0    88.0    113.5     140.0    147.5    168.0    209.0
70331 % finer than 62 microns        41                93.0    98.0     99.1      99.8    100.0    100.0    100.0
80154 Suspended sediment             52                25.0    47.0    117.5     233.0   3824.0  17000.0  25119.0

Nutrients and Organic Carbon, dissolved (filtered at 0.45 microns) and whole-water (unfiltered)

Units in milligrams per liter

Note: because of changes in reporting levels (RL), all censored data in this summary are converted to the highest RL reported for this station

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

00608 NH3-N                   .015  52       69      < 0.015  < 0.015  < 0.015    0.011    0.019    0.035    0.208
00613 NO2-N                   .010  52       90      < 0.010  < 0.010    0.003    0.004    0.010    0.115    0.167
00623 Org+NH3-N (filtered)    .200  52       58      < 0.200  < 0.200  < 0.200    0.200    0.206    0.300    0.627
00625 Org+NH3-N (whole-water) .200  51       96      < 0.200    0.200    0.399    0.520    1.013    14.27    20.03
00631 NO2+NO3-N               .005  52       98      < 0.005    0.210    0.423    0.695    1.051    1.464    1.655
00665 Total P (whole-water)   .050  51       92      < 0.050  < 0.050    0.060    0.105    0.370    8.247    14.25
00666 Total P (filtered)      .050  52       42      < 0.050  < 0.050  < 0.050  < 0.050    0.013    0.050    0.050
00671 PO4-P                   .010  52       67      < 0.010  < 0.010  < 0.010    0.002    0.007    0.013    0.037
00681 DOC                     .300  52      100        1.100    1.300    1.700    2.536    3.294    4.500    5.500
00689 SOC                     .200  51       63        0.400    0.700    1.500    4.000  > 6.300  > 20.00  > 25.00

Major Ions, dissolved (filtered at 0.45 microns)

Units in milligrams per liter, except where noted

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

00915 Calcium                 .020  52      100        51.00    55.00    78.37    85.85    96.00    117.0    165.9
00925 Magnesium               .010  52      100        6.542    7.066    11.43    19.68    27.76    30.58    34.21
00930 Sodium                  .200  52      100        51.00    54.03    77.26    119.3    187.8    232.1    268.2
00935 Potassium               .010  52      100        3.660    4.150    5.095    5.955    6.665    7.500    8.120
00940 Chloride                .010  52      100        18.52    28.19    48.89    111.8    212.3    265.7    300.0
00945 Sulfate                 .010  52      100        120.0    129.4    221.3    293.0    346.2    415.9    520.5
00950 Fluoride                .100  52      100        0.462    0.598    0.882    1.100    1.203    1.357    1.400
00955 Silica                  .010  52      100        0.570    7.300    12.06    15.40    17.52    21.00    22.56

Trace Elements, dissolved (filtered at 0.45 microns)

Units in micrograms per liter

Note: because of changes in reporting levels (RL), all censored data in this summary are converted to the highest RL reported for this station

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

01000 Arsenic                  2.0  51       96      <   2.0      1.0      1.7      2.6      3.0      4.0      4.2
01005 Barium                   1.0  43      100         55.0     66.2     83.0     92.9    103.9    126.8    194.4
01010 Beryllium                1.0  42        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01020 Boron                   16.0  51      100         89.0    104.8    147.5    207.1    270.0    320.0    330.8
01025 Cadmium                  1.0  42        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01030 Chromium                 1.0  42       69      <   1.0  <   1.0  <   1.0      1.8      2.0      3.0      8.0
01035 Cobalt                   3.0  43        0      <   3.0  <   3.0  <   3.0  <   3.0  <   3.0  <   3.0  <   3.0
01040 Copper                   1.0  42       81      <   1.0  <   1.0      1.1      1.7      2.1      3.0      4.0
01046 Iron                    30.0  52        2      <  30.0  <  30.0  <  30.0  <  30.0  <  30.0  <  30.0     30.0
01049 Lead                     1.0  42        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01056 Manganese                1.0  43       33      <   1.0  <   1.0  <   1.0  <   1.0      1.6      3.0      5.6
01060 Molybdenum               1.0  43      100          5.2      6.1      7.0      9.6     10.0     11.1     11.9
01065 Nickel                   1.0  43       86      <   1.0  <   1.0      1.2      1.9      2.0      3.0      5.0
01075 Silver                   1.0  43        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01080 Strontium                0.5  52      100        814.9    912.2     1489     1871     2113     2499     2742
01085 Vanadium                10.0  52       42      <  10.0  <  10.0  <  10.0  <  10.0     10.0     10.9     19.0
01090 Zinc                     1.0  41       71      <   1.0  <   1.0  <   1.0      1.4      2.0      5.0      6.0
01095 Antimony                 1.0  42        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01106 Aluminum                10.0  43       70      <  10.0  <  10.0  <  10.0      1.8      2.7     10.0     15.0
01130 Lithium                  4.0  52      100         18.3     24.0     45.7     65.7    106.9    130.0    130.5
01145 Selenium                 2.4  52       56      <   2.4  <   2.4  <   2.4      1.0      1.5      2.4      2.7
22703 Uranium                  1.0  42      100          2.8      3.0      3.5      4.0      5.0      5.5      5.8

Pesticides, dissolved (filtered at 0.7 microns)

Units in micrograms per liter, except where noted

Note: concentrations sometimes are estimated below the reporting level (RL); in this summary, all censored and estimated concentrations are converted to highest RL reported for this station; the percent detections described in the table include estimated concentrations, when appropriate

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

04024 Propachlor              .007  52        0      < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007
04028 Butylate                .002  52        2      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.007
04035 Simazine                .005  52        4      < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005    0.005
04037 Prometon                .018  52        8      < 0.018  < 0.018  < 0.018  < 0.018  < 0.018    0.018    0.021
04040 Desethyl atrazine       .002  52        4      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.003
04041 Cyanazine               .004  52        4      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004    0.464
04095 Fonofos                 .003  52        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
34253 alpha-HCH               .002  52        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
34653 p,p DDE                 .006  52        6      < 0.006  < 0.006  < 0.006  < 0.006  < 0.006    0.006    0.006
38933 Chlorpyrifos            .004  52        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
39341 gamma-HCH               .004  51        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
39381 Dieldrin                .015  52        0      < 0.015  < 0.015  < 0.015  < 0.015  < 0.015  < 0.015  < 0.015
39415 Metolachlor             .002  52        6      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.004    0.006
39532 Malathion               .005  52        2      < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005    0.005
39542 Parathion               .004  52        2      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004    0.012
39572 Diazinon                .005  52       25      < 0.005  < 0.005  < 0.005  < 0.005  < 0.005    0.008    0.160
39632 Atrazine                .004  52       23      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004    0.005    0.020
46342 Alachlor                .002  52        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
49260 Acetochlor              .002  52        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
82630 Metribuzin              .021  52        0      < 0.021  < 0.021  < 0.021  < 0.021  < 0.021  < 0.021  < 0.021
82660 Diethylanaline          .003  52        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
82661 Trifluralin             .002  52        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
82663 Ethalfluralin           .004  52        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82664 Phorate                 .002  52        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
82665 Terbacil                .010  52        6      < 0.010  < 0.010  < 0.010  < 0.010  < 0.010    0.010    0.012
82666 Linuron                 .049  51        0      < 0.049  < 0.049  < 0.049  < 0.049  < 0.049  < 0.049  < 0.049
82667 Methyl parathion        .006  51        0      < 0.006  < 0.006  < 0.006  < 0.006  < 0.006  < 0.006  < 0.006
82668 EPTC                    .010  51        0      < 0.010  < 0.010  < 0.010  < 0.010  < 0.010  < 0.010  < 0.010
82669 Pebulate                .004  51        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82670 Tebuthiuron             .010  51        0      < 0.010  < 0.010  < 0.010  < 0.010  < 0.010  < 0.010  < 0.010
82671 Molinate                .004  52        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82672 Ethoprop                .003  52        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
82673 Benfluralin             .002  52        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
82674 Carbofuran              .017  52        0      < 0.017  < 0.017  < 0.017  < 0.017  < 0.017  < 0.017  < 0.017
82675 Terbufos                .013  52        0      < 0.013  < 0.013  < 0.013  < 0.013  < 0.013  < 0.013  < 0.013
82676 Pronamide               .005  52        4      < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005    0.012
82677 Disulfoton              .017  52        0      < 0.017  < 0.017  < 0.017  < 0.017  < 0.017  < 0.017  < 0.017
82678 Triallate               .001  52        0      < 0.001  < 0.001  < 0.001  < 0.001  < 0.001  < 0.001  < 0.001
82679 Propanil                .004  52        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82680 Carbaryl                .003  52        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
82681 Thiobencarb             .002  52        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
82682 Dachthal (DCPA)         .002  52       10      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.002    0.003
82683 Pendimethalin           .004  52        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82684 Napropamide             .003  52        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
82685 Propargite              .160  51        0      < 0.160  < 0.160  < 0.160  < 0.160  < 0.160  < 0.160  < 0.160
82686 Azinphos methyl         .001  52        0      < 0.001  < 0.001  < 0.001  < 0.001  < 0.001  < 0.001  < 0.001
82687 Permethrin              .005  52        0      < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005
91063 Diazinon-d10 (%)        .100  52      100        70.40    80.00    92.01    99.85    112.9    123.6    205.0
91064 Terbuthylazin (%)       .100  37      100        92.59    94.00    103.3    110.9    115.4    127.0    191.0
91065 HCH alpha-D6 (%)        .100  52      100        74.60    77.30    89.20    95.75    102.4    115.0    180.0

Suspended Sediment Chemistry

Units in parts per million (ppm) or parts per hundred (%)

Values censored higher than the reporting level (RL) indicate samples with insufficient sediment mass to quantify concentration above the RL

                                          Percent
Parameter                    RL       N  Detections    Min      5th      25th    Median    75th     95th     Max

29816 Antimony (ppm)        0.10     44     100       0.60     0.60     0.80     1.00      1.35     5.90     18.30
29818 Arsenic (ppm)         0.10     44     100       6.30     6.70     7.35     7.90      8.70    10.40     11.60
29820 Barium (ppm)          1.00     44     100      120.0    210.0    250.0    285.0     315.0    360.0     390.0
29822 Beryllium (ppm)       0.10     44     100       0.60     1.00     1.20     1.60      1.80     2.20      2.50
29826 Cadmium (ppm)         0.10     44      95    <  0.10     0.20     0.20     0.40      0.40     0.50      0.60
29829 Chromium (ppm)        1.00     43      98    <  1.00    29.00    36.00    40.00     48.00    59.00     150.0
29832 Copper (ppm)          1.00     44     100       7.00    11.00    12.50    14.50     17.00    19.00     21.00
29836 Lead (ppm)            1.00     44     100      11.00    12.00    14.00    16.00     19.50    35.00     52.00
29839 Manganese (ppm)       10.0     44     100      250.0    320.0    395.0    450.0     500.0    660.0      1200
29841 Mercury (ppm)         0.01     44     100       0.02     0.03     0.04     0.05      0.06     0.18      2.76
29843 Molybdenum (ppm)      5.00     43      14    <  2.00  <  5.00  <  5.00  <  5.00   < 19.00    25.00     25.00
29845 Nickel (ppm)          1.00     43      98    <  1.00    15.00    18.00    21.00     24.00    36.00     110.0
29847 Selenium (ppm)        0.10     44     100       0.40     0.40     0.60     0.70      0.75     1.10      2.20
29850 Silver (ppm)          0.50     44       5    <  0.50  <  0.50  <  0.50  <  0.50   <  2.50  <  2.50      5.00
29853 Vanadium (ppm)        1.00     44     100      31.00    53.00    69.50    86.00     100.0    120.0     140.0
29855 Zinc (ppm)            1.00     44     100      30.00    60.00    75.00    90.00     100.0    110.0     120.0
30221 Aluminum (%)          0.10     44     100       2.90     3.80     4.50     5.90      6.65     7.50      7.90
30244 Total carbon (%)      0.10     44      91    <  0.10  <  0.10     3.15     3.80      4.45     5.40      6.30
30269 Iron (%)              0.10     44     100       0.90     1.50     1.95     2.40      2.85     3.20      3.30
30292 Phosphorus (%)        0.01     44     100       0.03     0.05     0.06     0.08      0.09     0.09      0.12
30308 Sulfur (%)            0.10     38      71    <  0.10  <  0.10  <  0.10     0.50      1.10     3.30      3.50
30317 Titanium (%)          0.01     44     100       0.10     0.20     0.23     0.29      0.30     0.40      0.40
35031 Cobalt (ppm)          1.00     44     100       3.00     5.00     7.00     8.00      9.00    11.00     11.00
35040 Strontium (ppm)       0.01     44     100      370.0    400.0    465.0    770.0     920.0     1200      1300
35046 Uranium (ppm)         50.0     44       0    < 50.00  < 50.00  < 50.00  < 50.00   < 250.0  < 250.0   < 500.0
35050 Lithium (ppm)         1.00     44     100      28.00    33.00    37.00    41.00     48.50    62.00     69.00
49955 Thallium (ppm)        50.0     44       0    < 50.00  < 50.00  < 50.00  < 50.00   < 250.0  < 250.0   < 500.0
50279 Sediment (mg/L)       1.00     44     100      21.00    29.00    119.5    196.5      2775    22387     26042
50465 Organic carbon (%)    0.10     44      91    <  0.10  <  0.10     0.80     1.00      1.45     2.40      4.20

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