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Concentrations and annual fluxes for selected water-quality constituents from the USGS National Stream Water Quality Accounting Network (NASQAN)

By Valerie J. Kelly, Richard P. Hooper, Brent T. Aulenbach, and Mary Janet

Summary Statistics--Mississippi Basin, Water Years 1997-2000

Ohio River at Greenup Dam near Greenup, Kentucky (03216600)

Daily Mean Streamflow

Units                               N             Min     5th       25th     Median    75th      95th      Max

Cubic feet per second             1,827         3,920     9,970    23,800    57,900   119,000   268,000   520,000
Cubic meters per second           1,827           111       282       674     1,640     3,370     7,589    14,725

Field Parameters, Turbidity, and Suspended Sediment

Units in milligrams per liter, except where noted

Parameter                             N               Min      5th     25th    Median     75th     95th     Max

00010 Temperature (C)                51                 2.5     4.0      9.2      15.0     24.3     28.9     30.0
00076 Turbidity (NTU)                51                 1.0     1.5      3.1      13.0     23.0     72.0    340.0
00095 Conductance (uS/cm)            51               153.0   206.0    273.0     304.0    395.0    529.0    567.0
00300 Dissolved oxygen               49                 5.6     6.0      7.6       9.1     11.3     13.8     18.8
00400 pH (standard units)            51                 6.9     7.1      7.2       7.3      7.6      7.7      8.1
00453 HCO3 (filtered)                49                25.0    34.0     48.0      56.0     64.0     85.0     99.0
39086 Alk (filtered, as CaCO3)       48                20.0    28.0     39.0      45.5     52.0     70.0     81.0
70331 % finer than 62 microns        49                20.0    77.0     92.8      97.4     98.4     99.6     99.8
80154 Suspended sediment             49                 5.0     6.0     10.0      35.0     61.0    259.0    617.0

Nutrients and Organic Carbon, dissolved (filtered at 0.45 microns) and whole-water (unfiltered)

Units in milligrams per liter

Note: because of changes in reporting levels (RL), all censored data in this summary are converted to the highest RL reported for this station

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

00608 NH3-N                   .020  51       80      < 0.020  < 0.020    0.029    0.045    0.083    0.127    0.239
00613 NO2-N                   .010  51       86      < 0.010  < 0.010    0.012    0.020    0.030    0.073    0.108
00623 Org+NH3-N (filtered)    .200  51       80      < 0.200  < 0.200    0.200    0.217    0.282    0.376    0.667
00625 Org+NH3-N (whole-water) .200  51       98      < 0.200    0.200    0.275    0.368    0.433    0.845    0.903
00631 NO2+NO3-N               .050  51       98      < 0.050    0.554    0.708    0.851    1.020    1.410    5.174
00665 Total P (whole-water)   .010  51       94      < 0.010  < 0.010    0.023    0.052    0.080    0.229    0.307
00666 Total P (filtered)      .050  51       65      < 0.050  < 0.050  < 0.050    0.013    0.020    0.050    0.064
00671 PO4-P                   .001  51       90      < 0.001  < 0.001    0.001    0.007    0.013    0.034    0.048
00681 DOC                     .300  50      100        1.600    1.900    2.165    2.650    3.200    4.900    5.300
00689 SOC                     .200  50       98        0.300    0.300    0.400    0.700    1.000    3.600  > 5.000

Major Ions, dissolved (filtered at 0.45 microns)

Units in milligrams per liter, except where noted

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

00915 Calcium                 .020  51      100        16.00    20.00    25.76    29.41    34.48    41.84    45.89
00925 Magnesium               .010  51      100        4.100    5.607    7.700    8.631    10.62    14.04    15.21
00930 Sodium                  .200  51      100        7.000    8.551    12.33    16.81    23.96    38.90    47.33
00935 Potassium               .010  51      100        1.600    1.680    1.810    2.240    2.770    3.800    4.350
00940 Chloride                .010  51      100        8.200    9.500    14.00    18.98    25.60    41.34    60.24
00945 Sulfate                 .010  51      100        30.00    40.00    54.88    64.78    83.76    113.2    131.2
00950 Fluoride                .100  51       82      < 0.100  < 0.100    0.102    0.136    0.193    0.294    0.368
00955 Silica                  .010  51      100        1.618    2.207    3.423    4.864    5.600    5.961    6.335

Trace Elements, dissolved (filtered at 0.45 microns)

Units in micrograms per liter

Note: because of changes in reporting levels (RL), all censored data in this summary are converted to the highest RL reported for this station

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

01000 Arsenic                  2.0  51        8      <   2.0  <   2.0  <   2.0  <   2.0  <   2.0      2.0      2.2
01005 Barium                   1.0  36      100         28.0     30.1     33.7     37.6     45.7     56.0     57.1
01010 Beryllium                1.0  36        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01020 Boron                   16.0  51      100         19.0     20.9     24.0     33.5     51.3     74.5    111.9
01025 Cadmium                  1.0  36        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01030 Chromium                 1.0  36       17      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0      1.2      1.4
01035 Cobalt                   1.0  36        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01040 Copper                   1.0  36       97      <   1.0      1.0      1.2      1.7      2.1      2.8      3.1
01046 Iron                    10.0  51       65      <  10.0  <  10.0  <  10.0     10.0     16.8     28.2     77.0
01049 Lead                     1.0  36        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01056 Manganese                1.0  36      100          1.4      1.8      3.9     13.3     28.4     57.9     64.0
01060 Molybdenum               1.0  36       81      <   1.0  <   1.0      1.0      1.7      2.9      6.4      7.8
01065 Nickel                   1.0  36       97      <   1.0      1.0      1.5      1.7      2.2      2.8      3.0
01075 Silver                   1.0  36        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01080 Strontium                0.5  51      100         85.0    110.0    150.0    171.1    218.9    286.7    309.2
01085 Vanadium                10.0  51        2      <  10.0  <  10.0  <  10.0  <  10.0  <  10.0  <  10.0     10.0
01090 Zinc                     1.0  36       86      <   1.0  <   1.0      1.2      1.7      3.6      6.0      7.6
01095 Antimony                 1.0  36        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01106 Aluminum                 1.0  36      100          4.5      6.7      8.8     10.8     13.4     19.8     20.8
01130 Lithium                  4.0  51       90      <   4.0  <   4.0      5.4      6.0      8.2     12.2     15.2
01145 Selenium                 2.4  51        2      <   2.4  <   2.4  <   2.4  <   2.4  <   2.4  <   2.4      2.4
22703 Uranium                  1.0  36        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0

Pesticides, dissolved (filtered at 0.7 microns)

Units in micrograms per liter, except where noted

Note: concentrations sometimes are estimated below the reporting level (RL); in this summary, all censored and estimated concentrations are converted to highest RL reported for this station; the percent detections described in the table include estimated concentrations, when appropriate

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

04024 Propachlor              .007  51        0      < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007
04028 Butylate                .002  51        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
04035 Simazine                .005  51       88      < 0.005  < 0.005    0.007    0.014    0.028    0.154    0.285
04037 Prometon                .018  51       67      < 0.018  < 0.018  < 0.018    0.018    0.018    0.021    0.028
04040 Desethyl atrazine       .002  51       98      < 0.002    0.004    0.007    0.010    0.021    0.073    0.100
04041 Cyanazine               .010  51       39      < 0.010  < 0.010  < 0.010  < 0.010    0.010    0.131    0.236
04095 Fonofos                 .003  51        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
34253 alpha-HCH               .023  51        2      < 0.023  < 0.023  < 0.023  < 0.023  < 0.023  < 0.023    0.023
34653 p,p DDE                 .006  51        2      < 0.006  < 0.006  < 0.006  < 0.006  < 0.006  < 0.006    0.006
38933 Chlorpyrifos            .090  51       20      < 0.090  < 0.090  < 0.090  < 0.090  < 0.090    0.005    0.090
39341 gamma-HCH               .004  51        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
39381 Dieldrin                .001  51        0      < 0.001  < 0.001  < 0.001  < 0.001  < 0.001  < 0.001  < 0.001
39415 Metolachlor             .002  51       98      < 0.002    0.005    0.009    0.015    0.046    0.440    0.903
39532 Malathion               .005  51        0      < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005
39542 Parathion               .004  51        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
39572 Diazinon                .002  51       35      < 0.002  < 0.002  < 0.002  < 0.002    0.004    0.007    0.010
39632 Atrazine                .001  51       98      < 0.001    0.010    0.018    0.039    0.128    1.180    1.480
46342 Alachlor                .002  51       18      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.020    0.039
49260 Acetochlor              .010  51       39      < 0.010  < 0.010  < 0.010  < 0.010    0.010    0.130    0.276
82630 Metribuzin              .004  51       20      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004    0.030    0.062
82660 Diethylanaline          .003  51        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
82661 Trifluralin             .002  51        6      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.002    0.005
82663 Ethalfluralin           .004  51        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82664 Phorate                 .002  51        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
82665 Terbacil                .007  51        0      < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007
82666 Linuron                 .015  51        0      < 0.015  < 0.015  < 0.015  < 0.015  < 0.015  < 0.015  < 0.015
82667 Methyl parathion        .006  51        0      < 0.006  < 0.006  < 0.006  < 0.006  < 0.006  < 0.006  < 0.006
82668 EPTC                    .015  51        4      < 0.015  < 0.015  < 0.015  < 0.015  < 0.015  < 0.015    0.024
82669 Pebulate                .004  51        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82670 Tebuthiuron             .010  51       35      < 0.010  < 0.010  < 0.010  < 0.010    0.010    0.014    0.022
82671 Molinate                .004  51        2      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004    0.004
82672 Ethoprop                .003  51        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
82673 Benfluralin             .002  51        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
82674 Carbofuran              .030  51        4      < 0.030  < 0.030  < 0.030  < 0.030  < 0.030  < 0.030    0.030
82675 Terbufos                .013  51        0      < 0.013  < 0.013  < 0.013  < 0.013  < 0.013  < 0.013  < 0.013
82676 Pronamide               .003  51        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
82677 Disulfoton              .017  51        0      < 0.017  < 0.017  < 0.017  < 0.017  < 0.017  < 0.017  < 0.017
82678 Triallate               .001  51        0      < 0.001  < 0.001  < 0.001  < 0.001  < 0.001  < 0.001  < 0.001
82679 Propanil                .004  51        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82680 Carbaryl                .003  51       39      < 0.003  < 0.003  < 0.003  < 0.003    0.007    0.017    0.035
82681 Thiobencarb             .002  51        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
82682 Dachthal (DCPA)         .002  51        4      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.002
82683 Pendimethalin           .004  51        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82684 Napropamide             .003  51        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
82685 Propargite              .100  50        0      < 0.100  < 0.100  < 0.100  < 0.100  < 0.100  < 0.100  < 0.100
82686 Azinphos methyl         .500  51        2      < 0.500  < 0.500  < 0.500  < 0.500  < 0.500  < 0.500    0.500
82687 Permethrin              .005  51        0      < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005
91063 Diazinon-d10 (%)        .100  51      100        78.72    83.91    92.66    100.9    109.2    122.3    149.6
91064 Terbuthylazin (%)       .100  37      100        0.007    0.034    104.4    112.2    121.9    176.4    178.9
91065 HCH alpha-D6 (%)        .100  51      100        70.72    73.40    86.90    92.55    100.8    112.2    126.3

Suspended Sediment Chemistry

Units in parts per million (ppm) or parts per hundred (%)

Values censored higher than the reporting level (RL) indicate samples with insufficient sediment mass to quantify concentration above the RL

                                          Percent
Parameter                    RL       N  Detections    Min      5th      25th    Median    75th     95th     Max

29816 Antimony (ppm)        0.10     34     100       0.80     0.90     1.10     1.30      1.90     3.40      5.90
29818 Arsenic (ppm)         0.10     34     100       5.80     6.40    12.90    14.05     18.00    21.00     21.00
29820 Barium (ppm)          1.00     34     100      260.0    280.0    460.0    530.0     560.0    640.0     720.0
29822 Beryllium (ppm)       0.10     34     100       0.70     0.80     2.40     2.75      3.00     3.40      3.60
29826 Cadmium (ppm)         0.10     34      97    <  0.30     0.30     0.50     0.70      1.00     1.50      1.50
29829 Chromium (ppm)        1.00     34     100      48.00    51.00    85.00    92.50     100.0    160.0     170.0
29832 Copper (ppm)          1.00     34     100      20.00    21.00    34.00    39.00     46.00    66.00     66.00
29836 Lead (ppm)            1.00     34     100      19.00    25.00    37.00    42.50     49.00    58.00     62.00
29839 Manganese (ppm)       10.0     34     100      860.0     1100     1900     2450      3300     4200      4900
29841 Mercury (ppm)         0.01     24      88    <  0.01  <  0.01     0.05     0.09      0.12     0.17      0.23
29843 Molybdenum (ppm)      5.00     34      24    <  5.00  <  5.00  <  5.00  < 10.00   < 12.00    28.00     50.00
29845 Nickel (ppm)          1.00     34     100      31.00    46.00    69.00    80.50     91.00    120.0     130.0
29847 Selenium (ppm)        0.10     34     100       0.40     0.70     1.00     1.20      1.60     2.40      2.60
29850 Silver (ppm)          0.50     34       6    <  0.50  <  0.50  <  0.50  <  1.00   <  1.00     2.50      5.00
29853 Vanadium (ppm)        1.00     34     100      31.00    37.00    90.00    100.0     110.0    130.0     140.0
29855 Zinc (ppm)            1.00     34     100      100.0    140.0    200.0    240.0     300.0    380.0     450.0
30221 Aluminum (%)          0.10     34     100       2.30     2.80     6.70     7.75      8.10    10.00     10.30
30244 Total carbon (%)      0.10     24     100       2.90     3.20     3.35     3.75      4.15     5.20      6.00
30269 Iron (%)              0.10     34     100       1.20     1.30     4.00     4.35      4.80     5.30      5.60
30292 Phosphorus (%)        0.01     34     100       0.06     0.07     0.10     0.12      0.14     0.17      0.21
30308 Sulfur (%)            0.10     21     100       0.10     0.10     0.30     0.70      1.40     1.90      2.00
30317 Titanium (%)          0.01     34     100       0.12     0.13     0.40     0.43      0.50     0.59      0.60
35031 Cobalt (ppm)          1.00     34     100       7.00     9.00    22.00    30.50     36.00    44.00     51.00
35040 Strontium (ppm)       0.01     34     100      110.0    110.0    140.0    180.0     280.0    510.0     660.0
35046 Uranium (ppm)         50.0     34       3    < 50.00  < 50.00  < 50.00  < 100.0   < 100.0  < 250.0     500.0
35050 Lithium (ppm)         1.00     34     100      36.00    39.00    54.00    63.50     69.00    75.00     79.00
49955 Thallium (ppm)        50.0     34       0    < 50.00  < 50.00  < 50.00  < 100.0   < 100.0  < 250.0   < 500.0
50279 Sediment (mg/L)       1.00     34     100       5.00     7.00    12.00    33.00     70.00    284.0     693.0
50465 Organic carbon (%)    0.10     17     100       0.90     0.90     3.30     3.60      3.80     4.90      4.90

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