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Concentrations and annual fluxes for selected water-quality constituents from the USGS National Stream Water Quality Accounting Network (NASQAN)

By Valerie J. Kelly, Richard P. Hooper, Brent T. Aulenbach, and Mary Janet

Summary Statistics--Mississippi Basin, Water Years 1996-2000

Missouri River at Hermann, Missouri (06934500)

Daily Mean Streamflow

Units                               N             Min     5th       25th     Median    75th      95th      Max

Cubic feet per second             1,827        34,700    46,200    64,800    91,300   132,000   226,000   353,000
Cubic meters per second           1,827           983     1,308     1,835     2,585     3,738     6,400     9,996

Field Parameters, Turbidity, and Suspended Sediment

Units in milligrams per liter, except where noted

Parameter                             N               Min      5th     25th    Median     75th     95th     Max

00010 Temperature (C)                75                 1.7     3.1      7.0      15.3     23.8     28.6     29.6
00076 Turbidity (NTU)                75                 0.2     1.6     26.0      54.0    130.0    300.0    600.0
00095 Conductance (uS/cm)            75               301.0   380.0    500.0     630.0    721.0    790.0    858.0
00300 Dissolved oxygen               75                 3.8     5.5      7.1       9.0     11.6     13.3     14.5
00400 pH (standard units)            75                 7.4     7.5      7.8       7.9      8.0      8.2      8.7
00452 CO3 (filtered)                 75                 0.0     0.0      0.0       0.0      0.0      0.0     14.0
00453 HCO3 (filtered)                75               121.0   141.0    169.0     189.0    203.0    269.0    486.0
39086 Alk (filtered, as CaCO3)       74               100.0   115.0    139.0     156.0    166.0    221.0    398.0
70331 % finer than 62 microns        73                32.0    35.0     54.3      72.4     82.0     89.7     93.0
80154 Suspended sediment             74                86.6   135.0    224.0     427.0    740.0   2000.0   3097.0

Nutrients and Organic Carbon, dissolved (filtered at 0.45 microns) and whole-water (unfiltered)

Units in milligrams per liter

Note: because of changes in reporting levels (RL), all censored data in this summary are converted to the highest RL reported for this station

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

00608 NH3-N                   .020  74       55      < 0.020  < 0.020  < 0.020    0.020    0.047    0.110    0.340
00613 NO2-N                   .010  74       72      < 0.010  < 0.010  < 0.010    0.015    0.027    0.060    0.119
00623 Org+NH3-N (filtered)    .100  74       99      < 0.100    0.228    0.300    0.350    0.419    0.578    0.766
00625 Org+NH3-N (whole-water) .200  74      100        0.097    0.375    0.600    0.834    1.341    2.200    5.841
00631 NO2+NO3-N               .050  74       99      < 0.050    0.314    0.930    1.300    1.700    2.339    3.170
00665 Total P (whole-water)   .050  74       99      < 0.050    0.090    0.171    0.240    0.429    0.933    2.152
00666 Total P (filtered)      .010  74      100        0.029    0.040    0.060    0.080    0.100    0.135    0.205
00671 PO4-P                   .010  74      100        0.004    0.043    0.060    0.071    0.091    0.130    0.155
00681 DOC                     .300  73      100        3.000    3.221    3.600    4.200    4.700    6.000    9.600
00689 SOC                     .200  75       88        0.300    0.500    1.400    2.297    4.100  > 10.00  > 10.00

Major Ions, dissolved (filtered at 0.45 microns)

Units in milligrams per liter, except where noted

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

00915 Calcium                 .020  74      100        36.00    43.55    51.35    57.97    62.50    68.00    75.00
00925 Magnesium               .010  74      100        10.88    13.18    15.81    18.57    21.00    23.32    24.70
00930 Sodium                  .200  74      100        17.30    24.00    34.58    45.83    57.00    69.18    75.33
00935 Potassium               .010  74      100        3.530    4.140    5.210    5.870    6.170    6.900    7.900
00940 Chloride                .010  75      100        9.606    11.32    14.36    17.63    21.00    26.14    30.79
00945 Sulfate                 .010  75      100        53.03    71.35    101.7    129.7    170.0    200.1    219.9
00950 Fluoride                .100  75      100        0.200    0.258    0.300    0.358    0.400    0.495    0.504
00955 Silica                  .010  74      100        4.860    7.226    8.699    10.04    11.58    14.13    15.00

Trace Elements, dissolved (filtered at 0.45 microns)

Units in micrograms per liter

Note: because of changes in reporting levels (RL), all censored data in this summary are converted to the highest RL reported for this station

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

01000 Arsenic                  1.0  74       96      <   1.0      1.0      2.0      2.0      2.7      3.6      4.0
01005 Barium                   1.0  51      100         66.2     72.6     85.0     91.1    110.9    385.8    818.1
01010 Beryllium                1.0  51        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01020 Boron                   16.0  70      100         40.4     45.1     66.0     83.3    109.9    147.2    201.6
01025 Cadmium                  1.0  51        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01030 Chromium                 5.0  51       75      <   5.0  <   5.0  <   5.0      2.0      2.4      5.0      5.0
01035 Cobalt                   3.0  51        0      <   3.0  <   3.0  <   3.0  <   3.0  <   3.0  <   3.0  <   3.0
01040 Copper                   1.0  51       98      <   1.0      1.0      1.8      2.1      2.5      3.0      4.2
01046 Iron                    10.0  74       61      <  10.0  <  10.0  <  10.0     12.0     41.2    171.0     1111
01049 Lead                     1.0  51        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01056 Manganese                1.0  51       65      <   1.0  <   1.0  <   1.0      2.0      3.0      9.0     12.0
01060 Molybdenum              10.0  51       94      <  10.0  <  10.0      2.1      3.0      3.6     10.0     10.0
01065 Nickel                   1.0  51      100          1.0      1.8      2.1      2.4      3.0      3.9      5.8
01075 Silver                   1.0  51        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01080 Strontium                0.5  74      100        210.0    268.2    339.3    411.3    480.8    546.7    596.3
01085 Vanadium                10.0  74       12      <  10.0  <  10.0  <  10.0  <  10.0  <  10.0     10.0     11.6
01090 Zinc                     3.0  51       63      <   3.0  <   3.0  <   3.0      1.3      3.0     14.7     43.4
01095 Antimony                 1.0  48        8      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0      1.3      4.9
01106 Aluminum                10.0  51       94      <  10.0  <  10.0      2.7      7.0     18.8     53.9     58.0
01130 Lithium                  4.0  74      100         10.6     13.3     21.0     29.4     38.0     46.0     50.0
01145 Selenium                 2.4  74       89      <   2.4  <   2.4      1.4      1.8      2.0      2.5      2.9
22703 Uranium                  1.0  48      100          2.0      2.4      3.3      4.0      4.7      5.0      5.1

Pesticides, dissolved (filtered at 0.7 microns)

Units in micrograms per liter, except where noted

Note: concentrations sometimes are estimated below the reporting level (RL); in this summary, all censored and estimated concentrations are converted to highest RL reported for this station; the percent detections described in the table include estimated concentrations, when appropriate

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

04024 Propachlor              .010  75        7      < 0.010  < 0.010  < 0.010  < 0.010  < 0.010    0.007    0.011
04028 Butylate                .002  75        1      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.013
04035 Simazine                .011  75       63      < 0.011  < 0.011  < 0.011    0.007    0.019    0.044    0.180
04037 Prometon                .018  75       77      < 0.018  < 0.018    0.006    0.010    0.015    0.018    0.018
04040 Desethyl atrazine       .002  75      100        0.004    0.005    0.012    0.027    0.068    0.180    0.273
04041 Cyanazine               .018  75       83      < 0.018  < 0.018    0.010    0.021    0.106    1.000    1.500
04095 Fonofos                 .003  75        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
34253 alpha-HCH               .005  75        0      < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005
34653 p,p DDE                 .006  75        3      < 0.006  < 0.006  < 0.006  < 0.006  < 0.006  < 0.006    0.006
38933 Chlorpyrifos            .020  74        4      < 0.020  < 0.020  < 0.020  < 0.020  < 0.020  < 0.020    0.046
39341 gamma-HCH               .004  75        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
39381 Dieldrin                .005  75        1      < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005    0.005
39415 Metolachlor             .002  75      100        0.023    0.032    0.068    0.177    0.663    1.690    3.010
39532 Malathion               .027  75        0      < 0.027  < 0.027  < 0.027  < 0.027  < 0.027  < 0.027  < 0.027
39542 Parathion               .007  75        0      < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007
39572 Diazinon                .005  75       33      < 0.005  < 0.005  < 0.005  < 0.005    0.003    0.007    0.016
39632 Atrazine                .001  75      100        0.064    0.074    0.134    0.265    1.240    4.500    7.400
46342 Alachlor                .010  75       77      < 0.010  < 0.010    0.004    0.009    0.059    0.230    0.298
49260 Acetochlor              .010  75       81      < 0.010  < 0.010    0.006    0.021    0.152    0.615    1.320
82630 Metribuzin              .020  75       43      < 0.020  < 0.020  < 0.020  < 0.020    0.015    0.039    0.052
82660 Diethylanaline          .003  75        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
82661 Trifluralin             .009  75       19      < 0.009  < 0.009  < 0.009  < 0.009  < 0.009    0.006    0.013
82663 Ethalfluralin           .009  75        0      < 0.009  < 0.009  < 0.009  < 0.009  < 0.009  < 0.009  < 0.009
82664 Phorate                 .011  75        0      < 0.011  < 0.011  < 0.011  < 0.011  < 0.011  < 0.011  < 0.011
82665 Terbacil                .034  75        0      < 0.034  < 0.034  < 0.034  < 0.034  < 0.034  < 0.034  < 0.034
82666 Linuron                 .035  74        3      < 0.035  < 0.035  < 0.035  < 0.035  < 0.035  < 0.035    0.035
82667 Methyl parathion        .020  75        4      < 0.020  < 0.020  < 0.020  < 0.020  < 0.020  < 0.020    0.072
82668 EPTC                    .002  75       19      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.004    0.009
82669 Pebulate                .004  75        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82670 Tebuthiuron             .016  75        5      < 0.016  < 0.016  < 0.016  < 0.016  < 0.016    0.010    0.016
82671 Molinate                .004  75        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82672 Ethoprop                .005  74        0      < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005
82673 Benfluralin             .010  75        0      < 0.010  < 0.010  < 0.010  < 0.010  < 0.010  < 0.010  < 0.010
82674 Carbofuran              .020  75        8      < 0.020  < 0.020  < 0.020  < 0.020  < 0.020    0.012    0.032
82675 Terbufos                .017  75        0      < 0.017  < 0.017  < 0.017  < 0.017  < 0.017  < 0.017  < 0.017
82676 Pronamide               .004  75        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82677 Disulfoton              .021  75        1      < 0.021  < 0.021  < 0.021  < 0.021  < 0.021  < 0.021    0.021
82678 Triallate               .002  75        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
82679 Propanil                .011  75        0      < 0.011  < 0.011  < 0.011  < 0.011  < 0.011  < 0.011  < 0.011
82680 Carbaryl                .041  75        3      < 0.041  < 0.041  < 0.041  < 0.041  < 0.041  < 0.041    0.041
82681 Thiobencarb             .010  75        0      < 0.010  < 0.010  < 0.010  < 0.010  < 0.010  < 0.010  < 0.010
82682 Dachthal (DCPA)         .003  75        9      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003    0.002    0.003
82683 Pendimethalin           .010  75        3      < 0.010  < 0.010  < 0.010  < 0.010  < 0.010  < 0.010    0.023
82684 Napropamide             .007  75        0      < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007
82685 Propargite              .023  75        0      < 0.023  < 0.023  < 0.023  < 0.023  < 0.023  < 0.023  < 0.023
82686 Azinphos methyl         .050  73        0      < 0.050  < 0.050  < 0.050  < 0.050  < 0.050  < 0.050  < 0.050
82687 Permethrin              .006  75        0      < 0.006  < 0.006  < 0.006  < 0.006  < 0.006  < 0.006  < 0.006
91063 Diazinon-d10 (%)        .100  74      100        3.760    46.57    87.65    95.60    104.8    133.2    143.8
91064 Terbuthylazin (%)       .100  58      100        0.074    0.086    85.68    105.0    114.0    127.8    150.0
91065 HCH alpha-D6 (%)        .100  74      100        3.200    54.04    81.41    93.45    102.0    124.0    157.0

Suspended Sediment Chemistry

Units in parts per million (ppm) or parts per hundred (%)

Values censored higher than the reporting level (RL) indicate samples with insufficient sediment mass to quantify concentration above the RL

                                          Percent
Parameter                    RL       N  Detections    Min      5th      25th    Median    75th     95th     Max

29816 Antimony (ppm)        0.10     53     100       0.50     0.70     1.00     1.10      1.40     3.00      4.00
29818 Arsenic (ppm)         0.10     53     100       5.90     6.00     7.50     8.70      9.80    12.90     15.50
29820 Barium (ppm)          1.00     53     100      230.0    530.0    650.0    680.0     700.0    730.0     760.0
29822 Beryllium (ppm)       0.10     53     100       0.80     0.90     1.10     1.30      1.50     1.80      1.80
29826 Cadmium (ppm)         0.10     53      96    <  0.10     0.20     0.40     0.40      0.60     0.70      1.30
29829 Chromium (ppm)        1.00     53      94    <  1.00  <  1.00    50.00    56.00     62.00    76.00     82.00
29832 Copper (ppm)          1.00     53     100       6.00     9.00    14.00    17.00     22.00    28.00     30.00
29836 Lead (ppm)            1.00     53     100      13.00    14.00    17.00    19.00     23.00    36.00     46.00
29839 Manganese (ppm)       10.0     53     100      210.0    230.0    600.0    780.0     940.0     1300      1600
29841 Mercury (ppm)         0.01     53      83    <  0.01  <  0.01     0.02     0.03      0.04     0.12      0.23
29843 Molybdenum (ppm)      5.00     53       2    <  5.00  <  5.00  <  5.00  <  5.00   < 25.00  < 25.00     25.00
29845 Nickel (ppm)          1.00     53      94    <  1.00  <  1.00    30.00    33.00     37.00    47.00     51.00
29847 Selenium (ppm)        0.10     53     100       0.30     0.40     0.60     0.80      1.00     2.40      3.60
29850 Silver (ppm)          0.50     53       4    <  0.50  <  0.50  <  0.50  <  0.50   <  2.50  <  2.50      2.50
29853 Vanadium (ppm)        1.00     53     100      34.00    41.00    63.00    80.00     94.00    110.0     120.0
29855 Zinc (ppm)            1.00     53     100      40.00    50.00    70.00    80.00     90.00    110.0     120.0
30221 Aluminum (%)          0.10     53     100       4.20     4.20     4.70     5.30      6.00     6.80      7.10
30244 Total carbon (%)      0.10     53      94    <  0.10  <  0.10     1.40     1.80      2.10     3.40      3.70
30269 Iron (%)              0.10     53     100       1.20     1.30     1.90     2.30      2.60     3.30      3.70
30292 Phosphorus (%)        0.01     53     100       0.05     0.05     0.06     0.08      0.09     0.11      0.13
30308 Sulfur (%)            0.10     48      83    <  0.10  <  0.10     0.10     0.30      0.60     1.20      1.60
30317 Titanium (%)          0.01     53     100       0.10     0.15     0.20     0.29      0.30     0.33      0.40
35031 Cobalt (ppm)          1.00     53     100       6.00     7.00     8.00    10.00     11.00    14.00     16.00
35040 Strontium (ppm)       0.01     53     100      150.0    160.0    190.0    210.0     240.0    300.0     330.0
35046 Uranium (ppm)         50.0     53       0    < 50.00  < 50.00  < 50.00  < 50.00   < 250.0  < 250.0   < 250.0
35050 Lithium (ppm)         1.00     53     100      11.00    14.00    24.00    28.00     33.00    39.00     41.00
49955 Thallium (ppm)        50.0     53       0    < 50.00  < 50.00  < 50.00  < 50.00   < 250.0  < 250.0   < 250.0
50279 Sediment (mg/L)       1.00     53     100      43.00    86.00    183.0    380.0     705.0     1423      2956
50465 Organic carbon (%)    0.10     53      96    <  0.10     0.50     1.10     1.40      1.80     3.60      3.60

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