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Concentrations and annual fluxes for selected water-quality constituents from the USGS National Stream Water Quality Accounting Network (NASQAN)

By Valerie J. Kelly, Richard P. Hooper, Brent T. Aulenbach, and Mary Janet

Summary Statistics--Mississippi Basin, Water Years 1996-2000

Mississippi River near St. Francisville, Louisiana (07373420)

Daily Mean Streamflow

Units                               N             Min     5th       25th     Median    75th      95th      Max

Cubic feet per second             1,827       138,000   170,000   277,000   453,000   732,000 1,010,000 1,480,000
Cubic meters per second           1,827         3,908     4,814     7,844    12,828    20,728    28,600    41,909

Field Parameters, Turbidity, and Suspended Sediment

Units in milligrams per liter, except where noted

Parameter                             N               Min      5th     25th    Median     75th     95th     Max

00010 Temperature (C)                72                 2.0     6.5     12.5      19.9     26.4     30.5     34.0
00076 Turbidity (NTU)                72                 1.0    16.0     26.5      46.5     63.5    106.0    290.0
00095 Conductance (uS/cm)            72               256.0   310.0    338.0     391.0    460.5    522.0    550.0
00300 Dissolved oxygen               71                 5.9     6.1      7.0       8.4     10.0     11.5     12.4
00400 pH (standard units)            72                 7.2     7.3      7.7       7.9      8.0      8.1      8.3
00452 CO3 (filtered)                 50                 0.0     0.0      0.0       0.0      0.0      0.0      4.0
00453 HCO3 (filtered)                54                85.0    96.0    117.0     127.0    143.0    170.0    176.0
39086 Alk (filtered, as CaCO3)       54                70.0    78.0     96.0     104.5    117.0    140.0    146.0
70331 % finer than 62 microns        69                55.0    60.0     75.0      88.5     96.2     98.9    100.0
80154 Suspended sediment             69                37.0    56.0    110.0     183.0    229.0    354.0    484.0

Nutrients and Organic Carbon, dissolved (filtered at 0.45 microns) and whole-water (unfiltered)

Units in milligrams per liter

Note: because of changes in reporting levels (RL), all censored data in this summary are converted to the highest RL reported for this station

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

00608 NH3-N                   .020  72       51      < 0.020  < 0.020  < 0.020    0.020    0.030    0.067    0.090
00613 NO2-N                   .010  72       46      < 0.010  < 0.010  < 0.010  < 0.010    0.020    0.032    0.114
00623 Org+NH3-N (filtered)    .200  68       90      < 0.200  < 0.200    0.209    0.251    0.293    0.346    0.400
00625 Org+NH3-N (whole-water) .200  71      100        0.300    0.334    0.442    0.577    0.673    0.845    1.145
00631 NO2+NO3-N               .050  71      100        0.500    0.664    1.054    1.281    1.640    2.644    2.901
00665 Total P (whole-water)   .010  71      100        0.060    0.080    0.141    0.180    0.234    0.351    0.420
00666 Total P (filtered)      .010  71       99      < 0.010    0.030    0.050    0.062    0.077    0.109    0.123
00671 PO4-P                   .010  66      100        0.029    0.038    0.051    0.060    0.080    0.107    0.114
00681 DOC                     .300  66      100        2.200    3.100    3.400    3.663    3.984    5.200    6.200
00689 SOC                     .200  67      100        0.400    0.500    1.100    1.688    2.700    5.000    7.400

Major Ions, dissolved (filtered at 0.45 microns)

Units in milligrams per liter, except where noted

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

00915 Calcium                 .020  70      100        27.35    30.00    35.24    38.11    43.00    46.88    49.51
00925 Magnesium               .010  72      100        7.214    8.473    10.27    12.03    14.36    16.58    18.09
00930 Sodium                  .200  72      100        9.371    10.00    14.96    18.79    25.40    34.00    41.32
00935 Potassium               .010  72      100        2.400    2.500    2.945    3.260    3.615    4.000    4.050
00940 Chloride                .010  72      100        10.40    12.00    16.36    20.35    23.98    30.55    37.13
00945 Sulfate                 .010  72      100        26.83    31.33    37.63    46.22    58.39    84.37    92.39
00950 Fluoride                .100  72       97      < 0.100    0.105    0.163    0.193    0.214    0.266    0.320
00955 Silica                  .010  72      100        2.600    4.142    5.717    6.265    7.012    8.190    9.120

Trace Elements, dissolved (filtered at 0.45 microns)

Units in micrograms per liter

Note: because of changes in reporting levels (RL), all censored data in this summary are converted to the highest RL reported for this station

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

01000 Arsenic                  2.0  69       70      <   2.0  <   2.0  <   2.0      1.2      1.8      2.0      3.0
01005 Barium                   1.0  50      100         41.8     43.0     49.3     57.0     63.2     74.0     77.5
01010 Beryllium                1.0  48        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01020 Boron                   16.0  69      100         21.6     25.5     33.2     40.0     48.4     72.9     77.7
01025 Cadmium                  1.0  48        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01030 Chromium                 1.0  48       48      <   1.0  <   1.0  <   1.0  <   1.0      1.5      2.2      9.6
01035 Cobalt                   3.0  50        0      <   3.0  <   3.0  <   3.0  <   3.0  <   3.0  <   3.0  <   3.0
01040 Copper                   1.0  47      100          1.1      1.5      1.7      2.0      2.1      2.8      6.5
01046 Iron                    10.0  70       34      <  10.0  <  10.0  <  10.0  <  10.0     10.0     19.0     33.0
01049 Lead                     1.0  48        4      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0      1.9
01056 Manganese                1.0  50       56      <   1.0  <   1.0  <   1.0      1.0      2.5      6.0      9.8
01060 Molybdenum              10.0  50       88      <  10.0  <  10.0      1.2      1.7      2.2      3.5     10.0
01065 Nickel                   1.0  49       98      <   1.0      1.0      1.5      1.7      2.0      3.0      3.0
01075 Silver                   1.0  50        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01080 Strontium                0.5  71      100        107.6    128.2    150.0    177.6    202.5    251.0    283.8
01085 Vanadium                10.0  72        4      <  10.0  <  10.0  <  10.0  <  10.0  <  10.0  <  10.0     10.0
01090 Zinc                     1.0  46       87      <   1.0  <   1.0      1.2      2.0      2.9      6.1      7.0
01095 Antimony                 1.0  48        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01106 Aluminum                10.0  48       98      <  10.0      1.6      2.9      4.0      5.0     10.0     21.0
01130 Lithium                  6.0  71       86      <   6.0  <   6.0      4.6      6.1      9.4     15.4     17.0
01145 Selenium                 2.4  71        4      <   2.4  <   2.4  <   2.4  <   2.4  <   2.4  <   2.4      2.4
22703 Uranium                  1.0  48       52      <   1.0  <   1.0  <   1.0      1.0      1.5      2.0      2.1

Pesticides, dissolved (filtered at 0.7 microns)

Units in micrograms per liter, except where noted

Note: concentrations sometimes are estimated below the reporting level (RL); in this summary, all censored and estimated concentrations are converted to highest RL reported for this station; the percent detections described in the table include estimated concentrations, when appropriate

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

04024 Propachlor              .007  71        0      < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007
04028 Butylate                .002  71        6      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.002    0.002
04035 Simazine                .050  71       99      < 0.050    0.014    0.020    0.031    0.088    0.250    0.408
04037 Prometon                .050  71       94      < 0.050  < 0.050    0.006    0.009    0.013    0.018    0.050
04040 Desethyl atrazine       .050  72       97      < 0.050    0.012    0.024    0.047    0.093    0.248    0.445
04041 Cyanazine               .200  72       90      < 0.200  < 0.200    0.015    0.028    0.094    0.850    0.915
04095 Fonofos                 .003  71        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
34253 alpha-HCH               .002  71        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
34653 p,p DDE                 .006  71        6      < 0.006  < 0.006  < 0.006  < 0.006  < 0.006    0.006    0.006
38933 Chlorpyrifos            .005  71        3      < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005    0.018
39341 gamma-HCH               .004  71        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
39381 Dieldrin                .001  71        7      < 0.001  < 0.001  < 0.001  < 0.001  < 0.001    0.004    0.007
39415 Metolachlor             .002  72      100        0.030    0.033    0.052    0.125    0.503    1.360    2.430
39532 Malathion               .005  71       15      < 0.005  < 0.005  < 0.005  < 0.005  < 0.005    0.011    0.022
39542 Parathion               .004  71        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
39572 Diazinon                .002  71       58      < 0.002  < 0.002  < 0.002    0.003    0.005    0.012    0.024
39632 Atrazine                .001  72      100        0.060    0.072    0.120    0.314    1.105    3.650    4.710
46342 Alachlor                .050  72       82      < 0.050  < 0.050    0.004    0.008    0.036    0.113    0.170
49260 Acetochlor              .002  71       94      < 0.002  < 0.002    0.008    0.016    0.148    0.370    0.558
82630 Metribuzin              .050  72       46      < 0.050  < 0.050  < 0.050  < 0.050    0.020    0.050    0.080
82660 Diethylanaline          .003  71        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
82661 Trifluralin             .002  71       37      < 0.002  < 0.002  < 0.002  < 0.002    0.003    0.006    0.008
82663 Ethalfluralin           .004  71        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82664 Phorate                 .002  71        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
82665 Terbacil                .007  71        0      < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007
82666 Linuron                 .002  71        4      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.008
82667 Methyl parathion        .006  71        0      < 0.006  < 0.006  < 0.006  < 0.006  < 0.006  < 0.006  < 0.006
82668 EPTC                    .002  71       10      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.002    0.005
82669 Pebulate                .004  71        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82670 Tebuthiuron             .020  71       87      < 0.020  < 0.020    0.008    0.010    0.012    0.016    0.020
82671 Molinate                .004  71       23      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004    0.033    0.129
82672 Ethoprop                .003  71        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
82673 Benfluralin             .002  71        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
82674 Carbofuran              .010  71       24      < 0.010  < 0.010  < 0.010  < 0.010  < 0.010    0.015    0.024
82675 Terbufos                .013  71        0      < 0.013  < 0.013  < 0.013  < 0.013  < 0.013  < 0.013  < 0.013
82676 Pronamide               .003  71        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
82677 Disulfoton              .017  71        0      < 0.017  < 0.017  < 0.017  < 0.017  < 0.017  < 0.017  < 0.017
82678 Triallate               .001  71        1      < 0.001  < 0.001  < 0.001  < 0.001  < 0.001  < 0.001    0.003
82679 Propanil                .004  71        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82680 Carbaryl                .020  71        3      < 0.020  < 0.020  < 0.020  < 0.020  < 0.020  < 0.020    0.020
82681 Thiobencarb             .002  71        6      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.002    0.007
82682 Dachthal (DCPA)         .002  69        3      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.002
82683 Pendimethalin           .011  71       15      < 0.011  < 0.011  < 0.011  < 0.011  < 0.011    0.010    0.012
82684 Napropamide             .003  71        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
82685 Propargite              .013  70        0      < 0.013  < 0.013  < 0.013  < 0.013  < 0.013  < 0.013  < 0.013
82686 Azinphos methyl         .020  71        0      < 0.020  < 0.020  < 0.020  < 0.020  < 0.020  < 0.020  < 0.020
82687 Permethrin              .005  71        0      < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005
91063 Diazinon-d10 (%)        .100  71      100        66.64    75.62    93.70    100.6    107.0    117.0    218.0
91064 Terbuthylazin (%)       .100  51      100        96.20    99.03    106.0    114.0    118.9    129.7    249.0
91065 HCH alpha-D6 (%)        .100  71      100        70.80    81.76    89.98    99.13    103.7    113.3    217.0

Suspended Sediment Chemistry

Units in parts per million (ppm) or parts per hundred (%)

Values censored higher than the reporting level (RL) indicate samples with insufficient sediment mass to quantify concentration above the RL

                                          Percent
Parameter                    RL       N  Detections    Min      5th      25th    Median    75th     95th     Max

29816 Antimony (ppm)        0.10     52     100       0.60     0.70     0.85     1.00      1.40     2.50      4.20
29818 Arsenic (ppm)         0.10     52     100       5.80     7.90     9.60    11.15     12.35    14.40     16.00
29820 Barium (ppm)          1.00     52     100      450.0    530.0    575.0    600.0     630.0    660.0     710.0
29822 Beryllium (ppm)       0.10     52     100       1.10     1.20     1.45     1.60      1.70     1.80      2.20
29826 Cadmium (ppm)         0.10     52      98    <  0.10     0.20     0.40     0.50      0.60     0.80      1.00
29829 Chromium (ppm)        1.00     52      96    <  1.00    48.00    58.00    63.00     68.00    80.00     100.0
29832 Copper (ppm)          1.00     52     100      13.00    15.00    20.00    22.50     25.00    28.00     31.00
29836 Lead (ppm)            1.00     52     100      17.00    20.00    22.00    24.00     27.00    37.00     71.00
29839 Manganese (ppm)       10.0     52     100      560.0    640.0    930.0     1150      1450     2300      2900
29841 Mercury (ppm)         0.01     52      96    <  0.01     0.02     0.03     0.04      0.06     0.10      0.26
29843 Molybdenum (ppm)      5.00     52       6    <  2.00  <  5.00  <  5.00  <  5.00   < 25.00    25.00     25.00
29845 Nickel (ppm)          1.00     52      96    <  1.00    29.00    35.00    39.00     41.00    50.00     52.00
29847 Selenium (ppm)        0.10     52     100       0.30     0.40     0.50     0.60      0.80     1.10      1.30
29850 Silver (ppm)          0.50     52       4    <  0.50  <  0.50  <  0.50  <  0.50   <  2.50  <  2.50      2.50
29853 Vanadium (ppm)        1.00     52     100      55.00    60.00    80.00    91.00     95.50    110.0     140.0
29855 Zinc (ppm)            1.00     52     100      70.00    90.00    100.0    110.0     130.0    150.0     180.0
30221 Aluminum (%)          0.10     52     100       4.50     4.90     5.75     6.10      6.50     7.30      7.80
30244 Total carbon (%)      0.10     52      98    <  0.10     1.20     1.65     1.90      2.20     2.80      3.10
30269 Iron (%)              0.10     52     100       1.90     2.10     2.70     3.00      3.20     3.80      4.30
30292 Phosphorus (%)        0.01     52     100       0.05     0.08     0.09     0.10      0.11     0.12      0.14
30308 Sulfur (%)            0.10     47      85    <  0.10  <  0.10     0.10     0.20      0.30     1.00      1.30
30317 Titanium (%)          0.01     52     100       0.20     0.24     0.30     0.33      0.40     0.40      0.41
35031 Cobalt (ppm)          1.00     52     100       9.00     9.00    12.00    13.00     15.00    16.00     16.00
35040 Strontium (ppm)       0.01     52     100      110.0    130.0    140.0    150.0     160.0    240.0     250.0
35046 Uranium (ppm)         50.0     52       0    < 50.00  < 50.00  < 50.00  < 50.00   < 250.0  < 250.0   < 250.0
35050 Lithium (ppm)         1.00     52     100      22.00    25.00    31.50    36.50     38.00    46.00     52.00
49955 Thallium (ppm)        50.0     52       0    < 50.00  < 50.00  < 50.00  < 50.00   < 250.0  < 250.0   < 250.0
50279 Sediment (mg/L)       1.00     52     100      43.00    46.00    94.50    149.5     203.5    319.0     371.0
50465 Organic carbon (%)    0.10     52      98    <  0.10     1.00     1.35     1.55      2.00     2.40      2.50

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