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Concentrations and annual fluxes for selected water-quality constituents from the USGS National Stream Water Quality Accounting Network (NASQAN)

By Valerie J. Kelly, Richard P. Hooper, Brent T. Aulenbach, and Mary Janet

Summary Statistics--Mississippi Basin, Water Years 1997-2000

Tennessee River at Highway 60 near Paducah, Kentucky (03609750)

Daily Mean Streamflow

Units                               N             Min     5th       25th     Median    75th      95th      Max

Cubic feet per second             1,827        10,471    15,470    28,504    38,666    73,217   163,531   310,742
Cubic meters per second           1,827           297       438       807     1,095     2,073     4,631     8,799

Field Parameters, Turbidity, and Suspended Sediment

Units in milligrams per liter, except where noted

Parameter                             N               Min      5th     25th    Median     75th     95th     Max

00010 Temperature (C)                50                 4.0     7.0     10.9      17.0     26.5     29.5     30.0
00076 Turbidity (NTU)                50                 1.9     2.3      3.1       4.8     10.0     19.0     60.0
00095 Conductance (uS/cm)            50               124.0   130.0    146.0     152.0    173.0    205.0    218.0
00300 Dissolved oxygen               45                 5.3     5.5      7.4       9.6     11.6     13.9     16.3
00400 pH (standard units)            50                 6.7     7.0      7.3       7.5      7.7      8.3      8.6
00453 HCO3 (filtered)                48                31.0    48.0     55.5      59.5     67.5     79.0     90.0
39086 Alk (filtered, as CaCO3)       47                25.0    39.0     46.0      49.0     55.0     64.0     74.0
70331 % finer than 62 microns        49                77.3    81.5     95.1      97.5     98.3     99.7     99.7
80154 Suspended sediment             49                 2.0     3.0      7.0       9.0     12.0     22.2     39.0

Nutrients and Organic Carbon, dissolved (filtered at 0.45 microns) and whole-water (unfiltered)

Units in milligrams per liter

Note: because of changes in reporting levels (RL), all censored data in this summary are converted to the highest RL reported for this station

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

00608 NH3-N                   .020  50       70      < 0.020  < 0.020  < 0.020    0.033    0.051    0.066    0.125
00613 NO2-N                   .010  50       50      < 0.010  < 0.010  < 0.010  < 0.010    0.015    0.030    0.039
00623 Org+NH3-N (filtered)    .200  50       74      < 0.200  < 0.200  < 0.200    0.200    0.212    0.277    0.298
00625 Org+NH3-N (whole-water) .200  50       94      < 0.200  < 0.200    0.233    0.290    0.354    0.448    0.502
00631 NO2+NO3-N               .050  50       94      < 0.050  < 0.050    0.121    0.270    0.405    0.611    0.720
00665 Total P (whole-water)   .010  50       98      < 0.010    0.016    0.043    0.053    0.062    0.090    0.166
00666 Total P (filtered)      .050  50       78      < 0.050  < 0.050    0.010    0.020    0.035    0.050    0.059
00671 PO4-P                   .001  50       96      < 0.001    0.001    0.012    0.020    0.031    0.042    0.056
00681 DOC                     .300  50      100        0.800    1.800    1.900    2.100    2.300    2.741    3.126
00689 SOC                     .200  49       98      < 0.200    0.200    0.400    0.505    0.600    1.000    1.008

Major Ions, dissolved (filtered at 0.45 microns)

Units in milligrams per liter, except where noted

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

00915 Calcium                 .020  50      100        12.14    14.04    16.24    19.01    20.27    23.62    27.69
00925 Magnesium               .010  50      100        2.700    2.756    3.005    3.413    4.200    4.782    5.007
00930 Sodium                  .200  50      100        3.100    3.704    4.721    5.687    8.086    11.67    12.43
00935 Potassium               .010  50      100        1.300    1.310    1.480    1.640    1.800    1.960    2.140
00940 Chloride                .010  50      100        3.900    4.187    5.582    7.264    9.180    13.06    13.87
00945 Sulfate                 .010  50      100        7.430    8.183    9.800    11.00    12.34    16.87    17.56
00950 Fluoride                .100  50       12      < 0.100  < 0.100  < 0.100  < 0.100  < 0.100    0.116    0.137
00955 Silica                  .010  50      100        0.591    1.320    2.524    3.509    4.700    5.700    6.323

Trace Elements, dissolved (filtered at 0.45 microns)

Units in micrograms per liter

Note: because of changes in reporting levels (RL), all censored data in this summary are converted to the highest RL reported for this station

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

01000 Arsenic                  2.0  50       38      <   2.0  <   2.0  <   2.0  <   2.0      1.3      2.0      2.0
01005 Barium                   1.0  34      100         16.5     16.9     18.0     19.4     20.6     21.6     22.3
01010 Beryllium                1.0  34        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01020 Boron                   16.0  50       56      <  16.0  <  16.0  <  16.0     19.1     25.4     30.3     36.9
01025 Cadmium                  1.0  34        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01030 Chromium                 1.0  34       26      <   1.0  <   1.0  <   1.0  <   1.0      1.0      2.0      2.4
01035 Cobalt                   1.0  34        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01040 Copper                   1.0  34       24      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0      1.1      2.0
01046 Iron                    10.0  50       56      <  10.0  <  10.0  <  10.0     10.0     12.3     23.0     49.0
01049 Lead                     1.0  34        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01056 Manganese                1.0  34       50      <   1.0  <   1.0  <   1.0  <   1.0      2.0      3.8      4.2
01060 Molybdenum               1.0  34       26      <   1.0  <   1.0  <   1.0  <   1.0      1.0      1.4      1.5
01065 Nickel                   1.0  34        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01075 Silver                   1.0  34        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01080 Strontium                0.5  50      100         47.3     49.8     54.7     59.4     66.0     71.1     89.3
01085 Vanadium                10.0  50        0      <  10.0  <  10.0  <  10.0  <  10.0  <  10.0  <  10.0  <  10.0
01090 Zinc                     1.0  34       79      <   1.0  <   1.0      1.0      1.6      4.3      9.9     13.6
01095 Antimony                 1.0  34        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01106 Aluminum                 1.0  34      100          2.4      2.5      3.1      3.9      5.1     14.0     15.0
01130 Lithium                  6.0  50       10      <   6.0  <   6.0  <   6.0  <   6.0  <   6.0      6.0      6.0
01145 Selenium                 2.4  50        2      <   2.4  <   2.4  <   2.4  <   2.4  <   2.4  <   2.4      2.4
22703 Uranium                  1.0  34        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0

Pesticides, dissolved (filtered at 0.7 microns)

Units in micrograms per liter, except where noted

Note: concentrations sometimes are estimated below the reporting level (RL); in this summary, all censored and estimated concentrations are converted to highest RL reported for this station; the percent detections described in the table include estimated concentrations, when appropriate

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

04024 Propachlor              .007  50        0      < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007
04028 Butylate                .002  50        2      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.017
04035 Simazine                .005  50       96      < 0.005    0.006    0.010    0.016    0.023    0.042    0.044
04037 Prometon                .018  50       62      < 0.018  < 0.018  < 0.018    0.008    0.018    0.018    0.018
04040 Desethyl atrazine       .002  50      100        0.004    0.006    0.009    0.014    0.027    0.046    0.067
04041 Cyanazine               .004  50       44      < 0.004  < 0.004  < 0.004  < 0.004    0.012    0.088    0.222
04095 Fonofos                 .003  50        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
34253 alpha-HCH               .002  50        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
34653 p,p DDE                 .006  50        2      < 0.006  < 0.006  < 0.006  < 0.006  < 0.006  < 0.006    0.006
38933 Chlorpyrifos            .004  50       26      < 0.004  < 0.004  < 0.004  < 0.004    0.004    0.006    0.009
39341 gamma-HCH               .004  50        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
39381 Dieldrin                .001  50        0      < 0.001  < 0.001  < 0.001  < 0.001  < 0.001  < 0.001  < 0.001
39415 Metolachlor             .002  50      100        0.004    0.004    0.008    0.016    0.054    0.089    0.189
39532 Malathion               .005  50        0      < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005
39542 Parathion               .004  50        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
39572 Diazinon                .002  50       12      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.004    0.004
39632 Atrazine                .001  50      100        0.015    0.018    0.029    0.090    0.310    0.496    0.667
46342 Alachlor                .005  50       12      < 0.005  < 0.005  < 0.005  < 0.005  < 0.005    0.004    0.005
49260 Acetochlor              .002  50       30      < 0.002  < 0.002  < 0.002  < 0.002    0.006    0.014    0.017
82630 Metribuzin              .004  50        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82660 Diethylanaline          .003  50        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
82661 Trifluralin             .002  50        4      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.002
82663 Ethalfluralin           .004  50        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82664 Phorate                 .002  50        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
82665 Terbacil                .007  50        0      < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007
82666 Linuron                 .008  50        0      < 0.008  < 0.008  < 0.008  < 0.008  < 0.008  < 0.008  < 0.008
82667 Methyl parathion        .006  50        0      < 0.006  < 0.006  < 0.006  < 0.006  < 0.006  < 0.006  < 0.006
82668 EPTC                    .002  50        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
82669 Pebulate                .004  50        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82670 Tebuthiuron             .010  50       98      < 0.010    0.011    0.016    0.021    0.030    0.034    0.037
82671 Molinate                .004  50        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82672 Ethoprop                .003  50        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
82673 Benfluralin             .002  50        2      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.002
82674 Carbofuran              .025  50        0      < 0.025  < 0.025  < 0.025  < 0.025  < 0.025  < 0.025  < 0.025
82675 Terbufos                .013  50        0      < 0.013  < 0.013  < 0.013  < 0.013  < 0.013  < 0.013  < 0.013
82676 Pronamide               .003  50        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
82677 Disulfoton              .017  50        0      < 0.017  < 0.017  < 0.017  < 0.017  < 0.017  < 0.017  < 0.017
82678 Triallate               .001  50        0      < 0.001  < 0.001  < 0.001  < 0.001  < 0.001  < 0.001  < 0.001
82679 Propanil                .004  50        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82680 Carbaryl                .003  50        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
82681 Thiobencarb             .002  50        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
82682 Dachthal (DCPA)         .002  50        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
82683 Pendimethalin           .004  50        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82684 Napropamide             .003  50        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
82685 Propargite              .030  50        0      < 0.030  < 0.030  < 0.030  < 0.030  < 0.030  < 0.030  < 0.030
82686 Azinphos methyl         .001  50        0      < 0.001  < 0.001  < 0.001  < 0.001  < 0.001  < 0.001  < 0.001
82687 Permethrin              .005  50        0      < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005
91063 Diazinon-d10 (%)        .100  50      100        78.30    81.47    96.00    101.8    109.7    122.0    130.6
91064 Terbuthylazin (%)       .100  32      100        93.75    95.40    103.3    109.4    122.1    132.7    136.7
91065 HCH alpha-D6 (%)        .100  50      100        59.70    75.91    88.90    95.65    100.9    116.6    132.5

Suspended Sediment Chemistry

Units in parts per million (ppm) or parts per hundred (%)

Values censored higher than the reporting level (RL) indicate samples with insufficient sediment mass to quantify concentration above the RL

                                          Percent
Parameter                    RL       N  Detections    Min      5th      25th    Median    75th     95th     Max

29816 Antimony (ppm)        0.10     34      97    <  0.10     1.00     1.20     1.85      2.60     5.70      8.90
29818 Arsenic (ppm)         0.10     34     100       6.60     7.50    10.30    11.95     15.00    18.60     21.00
29820 Barium (ppm)          1.00     34     100      240.0    360.0    450.0    490.0     530.0    700.0     840.0
29822 Beryllium (ppm)       0.10     34     100       0.90     1.10     1.50     1.75      2.00     2.50      2.60
29826 Cadmium (ppm)         0.10     34      94    <  0.20  <  0.20     0.40     0.70      0.90     2.40      3.00
29829 Chromium (ppm)        1.00     34     100      58.00    67.00    84.00    96.00     130.0    260.0     290.0
29832 Copper (ppm)          1.00     34     100      16.00    22.00    26.00    28.50     33.00    76.00     110.0
29836 Lead (ppm)            1.00     34     100      19.00    20.00    28.00    35.00     42.00    120.0     130.0
29839 Manganese (ppm)       10.0     34     100       1500     1500     2300     2850      3900     8700      8800
29841 Mercury (ppm)         0.01     8       63    <  0.01  <  0.01     0.01     0.13      0.22     0.26      0.26
29843 Molybdenum (ppm)      5.00     34      26    <  5.00  <  5.00  < 10.00  < 10.00     15.00    50.00     50.00
29845 Nickel (ppm)          1.00     34     100      37.00    42.00    54.00    63.00     72.00    170.0     190.0
29847 Selenium (ppm)        0.10     34     100       0.50     0.60     0.80     0.80      1.00     2.00      2.20
29850 Silver (ppm)          0.50     34       3    <  0.50  <  0.50  <  0.60  <  1.00   <  1.50  <  5.00      5.00
29853 Vanadium (ppm)        1.00     34     100      44.00    49.00    70.00    84.50     97.00    120.0     130.0
29855 Zinc (ppm)            1.00     34     100      120.0    130.0    190.0    220.0     280.0    480.0     540.0
30221 Aluminum (%)          0.10     34     100       3.60     4.00     5.20     6.00      7.00     8.70      9.40
30244 Total carbon (%)      0.10     16      94    <  0.10  <  0.10     3.25     4.30      5.10     7.30      7.30
30269 Iron (%)              0.10     34     100       2.00     2.10     2.70     3.50      3.80     4.60      5.00
30292 Phosphorus (%)        0.01     34     100       0.10     0.13     0.15     0.19      0.22     0.27      0.27
30308 Sulfur (%)            0.10     14      93    <  0.10  <  0.10     0.20     0.35      0.40     1.10      1.10
30317 Titanium (%)          0.01     34     100       0.19     0.20     0.34     0.39      0.40     0.51      0.54
35031 Cobalt (ppm)          1.00     34     100      10.00    11.00    13.00    16.00     19.00    22.00     23.00
35040 Strontium (ppm)       0.01     34     100      60.00    90.00    120.0    140.0     170.0    330.0     380.0
35046 Uranium (ppm)         50.0     34       0    < 50.00  < 50.00  < 50.00  < 100.0   < 150.0  < 500.0   < 500.0
35050 Lithium (ppm)         1.00     34     100      22.00    24.00    40.00    44.00     55.00    64.00     150.0
49955 Thallium (ppm)        50.0     34       0    < 50.00  < 50.00  < 50.00  < 100.0   < 150.0  < 500.0   < 500.0
50279 Sediment (mg/L)       1.00     34     100       6.00     6.00     9.00    11.00     15.00    24.00     36.00
50465 Organic carbon (%)    0.10     4       50    <  0.10  <  0.10     0.10     1.45      3.45     4.10      4.10

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