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Concentrations and annual fluxes for selected water-quality constituents from the USGS National Stream Water Quality Accounting Network (NASQAN)

By Valerie J. Kelly, Richard P. Hooper, Brent T. Aulenbach, and Mary Janet

Summary Statistics--Mississippi Basin, Water Years 1996-2000

Mississippi River at Thebes, Illinois (07022000)

Daily Mean Streamflow

Units                               N             Min     5th       25th     Median    75th      95th      Max

Cubic feet per second             1,827        79,000   105,000   141,000   194,000   305,000   506,000   630,000
Cubic meters per second           1,827         2,237     2,973     3,993     5,493     8,637    14,328    17,840

Field Parameters, Turbidity, and Suspended Sediment

Units in milligrams per liter, except where noted

Parameter                             N               Min      5th     25th    Median     75th     95th     Max

00010 Temperature (C)                73                 1.1     2.1      7.5      17.8     25.2     28.7     31.5
00076 Turbidity (NTU)                73                 0.3     4.6     25.0      38.0     74.0    200.0    380.0
00095 Conductance (uS/cm)            73               220.0   340.0    473.0     529.0    597.0    681.0    825.0
00300 Dissolved oxygen               73                 4.5     6.1      7.5       8.9     11.4     14.2     15.8
00400 pH (standard units)            73                 7.5     7.5      7.8       7.9      8.1      8.2      8.4
00452 CO3 (filtered)                 70                 0.0     0.0      0.0       0.0      0.0      0.0      7.0
00453 HCO3 (filtered)                70               129.0   144.0    170.0     188.5    197.0    230.0    471.0
39086 Alk (filtered, as CaCO3)       72               106.0   116.0    139.0     154.0    162.5    188.0    386.0
70331 % finer than 62 microns        72                47.4    62.0     74.0      81.0     85.6     93.0     96.0
80154 Suspended sediment             72                51.0    85.0    142.5     210.8    444.0    960.0   1760.0

Nutrients and Organic Carbon, dissolved (filtered at 0.45 microns) and whole-water (unfiltered)

Units in milligrams per liter

Note: because of changes in reporting levels (RL), all censored data in this summary are converted to the highest RL reported for this station

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

00608 NH3-N                   .020  74       69      < 0.020  < 0.020  < 0.020    0.035    0.080    0.230    0.320
00613 NO2-N                   .010  74       92      < 0.010  < 0.010    0.014    0.020    0.030    0.074    0.111
00623 Org+NH3-N (filtered)    .200  74       99      < 0.200    0.300    0.383    0.435    0.500    0.700    0.800
00625 Org+NH3-N (whole-water) .200  73      100        0.207    0.383    0.700    0.852    1.182    1.817    2.526
00631 NO2+NO3-N               .050  74      100        0.516    0.894    1.600    2.118    3.006    3.899    4.615
00665 Total P (whole-water)   .010  73      100        0.050    0.150    0.194    0.243    0.410    0.714    1.400
00666 Total P (filtered)      .010  74      100        0.043    0.064    0.081    0.103    0.122    0.145    0.175
00671 PO4-P                   .010  74      100        0.020    0.047    0.078    0.091    0.110    0.140    0.163
00681 DOC                     .300  73      100        3.700    3.900    4.300    4.800    5.433    7.963    8.600
00689 SOC                     .200  74       95        0.200    0.600    1.100    1.665    3.000  > 8.700  > 10.00

Major Ions, dissolved (filtered at 0.45 microns)

Units in milligrams per liter, except where noted

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

00915 Calcium                 .020  73      100        23.82    37.00    48.26    53.39    55.22    59.00    65.64
00925 Magnesium               .010  73      100        7.761    14.00    17.18    19.80    21.00    23.00    25.00
00930 Sodium                  .200  73      100        9.414    14.74    21.25    28.37    35.85    45.00    46.18
00935 Potassium               .010  73      100        0.910    2.520    3.740    4.300    4.700    5.300    5.700
00940 Chloride                .010  74      100        14.65    15.00    18.51    21.11    25.00    35.22    41.32
00945 Sulfate                 .010  74      100        38.22    43.02    57.07    75.00    96.00    125.3    136.0
00950 Fluoride                .100  74      100        0.160    0.200    0.232    0.273    0.300    0.377    0.420
00955 Silica                  .090  73       99      < 0.090    5.097    7.500    8.724    9.603    11.27    13.52

Trace Elements, dissolved (filtered at 0.45 microns)

Units in micrograms per liter

Note: because of changes in reporting levels (RL), all censored data in this summary are converted to the highest RL reported for this station

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

01000 Arsenic                  1.0  71       92      <   1.0  <   1.0      1.0      1.9      2.2      3.0      3.8
01005 Barium                   1.0  50      100         56.0     61.0     65.0     78.7     91.1    358.5    591.0
01010 Beryllium                1.0  50        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01020 Boron                   16.0  67       99      <  16.0     35.9     49.2     63.6     82.5    104.6    148.5
01025 Cadmium                  1.0  50        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01030 Chromium                 5.0  50       74      <   5.0  <   5.0  <   5.0      2.0      2.7      5.0     11.1
01035 Cobalt                   3.0  50        2      <   3.0  <   3.0  <   3.0  <   3.0  <   3.0  <   3.0      3.0
01040 Copper                   1.0  50      100          1.0      1.0      1.8      2.0      2.3      3.0      3.0
01046 Iron                    10.0  71       73      <  10.0  <  10.0  <  10.0     16.0     47.0    116.8    527.0
01049 Lead                     1.0  50        6      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0      1.0      1.0
01056 Manganese                1.0  50       60      <   1.0  <   1.0  <   1.0      2.0      4.1     11.0     21.0
01060 Molybdenum              10.0  52       94      <  10.0  <  10.0      2.0      2.4      3.0     10.0     10.0
01065 Nickel                   1.0  52      100          1.0      1.6      2.0      2.1      2.9      3.0      5.3
01075 Silver                   1.0  52        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01080 Strontium                0.5  73      100          0.7    142.8    206.7    236.2    280.0    340.0    383.5
01085 Vanadium                10.0  73        7      <  10.0  <  10.0  <  10.0  <  10.0  <  10.0     10.0     10.0
01090 Zinc                     3.0  52       62      <   3.0  <   3.0  <   3.0      1.4      3.0     18.9     35.7
01095 Antimony                 1.0  49        8      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0      2.1      3.6
01106 Aluminum                10.0  52       94      <  10.0  <  10.0      5.0      9.0     26.9     58.9    120.9
01130 Lithium                  8.9  73       99      <   8.9      6.7      9.8     14.8     19.2     27.6     29.7
01145 Selenium                 2.4  73       60      <   2.4  <   2.4  <   2.4      1.0      1.3      2.4      2.4
22703 Uranium                  1.0  47      100          1.0      1.0      2.0      2.5      3.0      3.5      4.0

Pesticides, dissolved (filtered at 0.7 microns)

Units in micrograms per liter, except where noted

Note: concentrations sometimes are estimated below the reporting level (RL); in this summary, all censored and estimated concentrations are converted to highest RL reported for this station; the percent detections described in the table include estimated concentrations, when appropriate

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

04024 Propachlor              .007  72        0      < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007
04028 Butylate                .002  72        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
04035 Simazine                .010  72       81      < 0.010  < 0.010    0.007    0.010    0.036    0.134    0.141
04037 Prometon                .018  71       89      < 0.018  < 0.018    0.007    0.009    0.012    0.018    0.026
04040 Desethyl atrazine       .002  71      100        0.004    0.005    0.016    0.029    0.080    0.229    0.315
04041 Cyanazine               .020  72       74      < 0.020  < 0.020  < 0.020    0.026    0.085    0.713    1.700
04095 Fonofos                 .003  72        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
34253 alpha-HCH               .002  72        1      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    1.880
34653 p,p DDE                 .006  72        4      < 0.006  < 0.006  < 0.006  < 0.006  < 0.006  < 0.006    0.006
38933 Chlorpyrifos            .030  70       14      < 0.030  < 0.030  < 0.030  < 0.030  < 0.030    0.020    0.050
39341 gamma-HCH               .004  72        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
39381 Dieldrin                .001  72        1      < 0.001  < 0.001  < 0.001  < 0.001  < 0.001  < 0.001    0.003
39415 Metolachlor             .002  72      100        0.025    0.040    0.075    0.252    0.708    1.460    2.600
39532 Malathion               .005  72        4      < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005    0.039
39542 Parathion               .004  72        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
39572 Diazinon                .010  72       49      < 0.010  < 0.010  < 0.010  < 0.010    0.006    0.019    0.093
39632 Atrazine                .001  72      100        0.054    0.093    0.170    0.265    1.445    4.440    5.960
46342 Alachlor                .017  72       82      < 0.017  < 0.017    0.007    0.012    0.038    0.125    0.259
49260 Acetochlor              .010  72       92      < 0.010  < 0.010    0.018    0.053    0.244    0.740    1.090
82630 Metribuzin              .020  72       31      < 0.020  < 0.020  < 0.020  < 0.020    0.012    0.026    0.029
82660 Diethylanaline          .003  72        6      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003    0.003    0.004
82661 Trifluralin             .002  72       14      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.004    0.005
82663 Ethalfluralin           .004  72        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82664 Phorate                 .002  72        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
82665 Terbacil                .007  72        0      < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007
82666 Linuron                 .002  72        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
82667 Methyl parathion        .070  72        4      < 0.070  < 0.070  < 0.070  < 0.070  < 0.070  < 0.070    0.070
82668 EPTC                    .002  72       13      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.003    0.006
82669 Pebulate                .004  72        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82670 Tebuthiuron             .020  72        6      < 0.020  < 0.020  < 0.020  < 0.020  < 0.020    0.010    0.020
82671 Molinate                .004  72        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82672 Ethoprop                .003  72        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
82673 Benfluralin             .002  72        1      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.002
82674 Carbofuran              .010  72        8      < 0.010  < 0.010  < 0.010  < 0.010  < 0.010    0.018    0.039
82675 Terbufos                .013  72        0      < 0.013  < 0.013  < 0.013  < 0.013  < 0.013  < 0.013  < 0.013
82676 Pronamide               .003  72        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
82677 Disulfoton              .017  72        1      < 0.017  < 0.017  < 0.017  < 0.017  < 0.017  < 0.017    0.017
82678 Triallate               .001  72        0      < 0.001  < 0.001  < 0.001  < 0.001  < 0.001  < 0.001  < 0.001
82679 Propanil                .004  72        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82680 Carbaryl                .003  72        4      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003    0.045
82681 Thiobencarb             .005  72        0      < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005
82682 Dachthal (DCPA)         .002  72       17      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.002    0.028
82683 Pendimethalin           .010  72        3      < 0.010  < 0.010  < 0.010  < 0.010  < 0.010  < 0.010    0.016
82684 Napropamide             .003  72        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
82685 Propargite              .013  72        1      < 0.013  < 0.013  < 0.013  < 0.013  < 0.013  < 0.013    0.024
82686 Azinphos methyl         .001  71        0      < 0.001  < 0.001  < 0.001  < 0.001  < 0.001  < 0.001  < 0.001
82687 Permethrin              .005  72        0      < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005
91063 Diazinon-d10 (%)        .000  72       99      < 0.000    51.10    79.10    90.12    100.0    120.0    203.7
91064 Terbuthylazin (%)       .000  56       98      < 0.000    0.070    80.70    96.12    108.3    140.0    302.6
91065 HCH alpha-D6 (%)        .000  72       99      < 0.000    44.67    77.35    88.80    99.32    122.6    233.0

Suspended Sediment Chemistry

Units in parts per million (ppm) or parts per hundred (%)

Values censored higher than the reporting level (RL) indicate samples with insufficient sediment mass to quantify concentration above the RL

                                          Percent
Parameter                    RL       N  Detections    Min      5th      25th    Median    75th     95th     Max

29816 Antimony (ppm)        0.10     52      98    <  0.10     0.70     0.90     1.20      3.00    10.00     13.00
29818 Arsenic (ppm)         0.10     52     100       4.90     6.30     7.95     8.80     10.10    12.90     16.80
29820 Barium (ppm)          1.00     52     100      290.0    390.0    590.0    640.0     655.0    700.0     910.0
29822 Beryllium (ppm)       0.10     52     100       1.00     1.00     1.25     1.35      1.50     1.70      1.80
29826 Cadmium (ppm)         0.10     52     100       0.10     0.20     0.40     0.50      0.60     1.30      1.50
29829 Chromium (ppm)        1.00     52      94    <  1.00  <  1.00    58.00    63.50     74.00    89.00     110.0
29832 Copper (ppm)          1.00     52     100      11.00    14.00    18.00    21.00     23.00    32.00     59.00
29836 Lead (ppm)            1.00     52     100      12.00    17.00    21.50    25.00     28.00    43.00     85.00
29839 Manganese (ppm)       10.0     52     100      230.0    260.0    805.0     1000      1200     1500      2700
29841 Mercury (ppm)         0.01     51      82    <  0.01  <  0.01     0.01     0.03      0.04     0.07      0.13
29843 Molybdenum (ppm)      5.00     52      15    <  5.00  <  5.00  <  5.00  <  5.00   < 10.00    25.00     25.00
29845 Nickel (ppm)          1.00     52      94    <  1.00  <  1.00    33.50    37.50     45.00    62.00     75.00
29847 Selenium (ppm)        0.10     52      96    <  0.10     0.50     0.70     0.90      1.10     1.40      2.20
29850 Silver (ppm)          0.50     52       4    <  0.50  <  0.50  <  0.50  <  0.50   <  2.50  <  2.50      5.00
29853 Vanadium (ppm)        1.00     52     100      45.00    50.00    72.50    84.00     92.00    110.0     120.0
29855 Zinc (ppm)            1.00     52     100      60.00    70.00    90.00    90.00     110.0    140.0     510.0
30221 Aluminum (%)          0.10     52     100       3.80     4.30     5.00     5.55      6.00     6.60      7.20
30244 Total carbon (%)      0.10     52      92    <  0.10  <  0.10     2.00     2.45      2.80     4.70      5.50
30269 Iron (%)              0.10     52     100       1.40     1.60     2.30     2.55      2.90     3.50      3.60
30292 Phosphorus (%)        0.01     52     100       0.07     0.07     0.08     0.09      0.10     0.15      0.24
30308 Sulfur (%)            0.10     47      87    <  0.10  <  0.10     0.20     0.40      0.70     1.40      1.90
30317 Titanium (%)          0.01     52     100       0.17     0.20     0.29     0.30      0.31     0.40      0.40
35031 Cobalt (ppm)          1.00     52     100       5.00     8.00    10.00    11.00     12.00    14.00     18.00
35040 Strontium (ppm)       0.01     52     100      130.0    140.0    160.0    180.0     225.0    320.0     390.0
35046 Uranium (ppm)         50.0     52       0    < 50.00  < 50.00  < 50.00  < 50.00   < 250.0  < 250.0   < 250.0
35050 Lithium (ppm)         1.00     52     100      16.00    23.00    28.00    32.00     35.00    41.00     48.00
49955 Thallium (ppm)        50.0     52       0    < 50.00  < 50.00  < 50.00  < 50.00   < 250.0  < 250.0   < 250.0
50279 Sediment (mg/L)       1.00     52     100      13.00    39.00    105.5    169.0     302.0    825.0      1622
50465 Organic carbon (%)    0.10     51      92    <  0.10  <  0.10     1.60     1.90      2.20     4.70      7.30

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