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Concentrations and annual fluxes for selected water-quality constituents from the USGS National Stream Water Quality Accounting Network (NASQAN)

By Valerie J. Kelly, Richard P. Hooper, Brent T. Aulenbach, and Mary Janet

Summary Statistics--Mississippi Basin, Water Years 1997-2000

Wabash River at New Harmony, Indiana (03378500)

Daily Mean Streamflow

Units                               N             Min     5th       25th     Median    75th      95th      Max

Cubic feet per second             1,827         2,880     3,930     7,750    16,900    41,500    97,200   203,000
Cubic meters per second           1,827            82       111       219       479     1,175     2,752     5,748

Field Parameters, Turbidity, and Suspended Sediment

Units in milligrams per liter, except where noted

Parameter                             N               Min      5th     25th    Median     75th     95th     Max

00010 Temperature (C)                52                 2.3     4.1      8.0      16.2     25.0     28.0     30.5
00076 Turbidity (NTU)                52                 0.8     3.0     18.5      38.0     60.0    122.0    150.0
00095 Conductance (uS/cm)            52               248.0   316.0    417.0     502.0    590.5    697.0    783.0
00300 Dissolved oxygen               52                 5.5     5.6      7.8       9.7     11.3     13.1     13.2
00400 pH (standard units)            53                 7.3     7.3      7.6       7.8      8.0      8.4      8.5
00453 HCO3 (filtered)                49                47.0   108.0    140.0     168.0    203.0    231.0    285.0
39086 Alk (filtered, as CaCO3)       50                39.0    88.0    114.0     137.5    169.0    190.0    234.0
70331 % finer than 62 microns        51                70.4    84.8     90.1      95.6     98.0     99.3     99.7
80154 Suspended sediment             51                17.0    23.0     73.0     129.0    190.0    263.0    336.0

Nutrients and Organic Carbon, dissolved (filtered at 0.45 microns) and whole-water (unfiltered)

Units in milligrams per liter

Note: because of changes in reporting levels (RL), all censored data in this summary are converted to the highest RL reported for this station

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

00608 NH3-N                   .020  52       46      < 0.020  < 0.020  < 0.020  < 0.020    0.040    0.088    0.132
00613 NO2-N                   .010  52       81      < 0.010  < 0.010    0.011    0.018    0.030    0.089    0.114
00623 Org+NH3-N (filtered)    .200  52       94      < 0.200  < 0.200    0.300    0.348    0.448    0.543    1.061
00625 Org+NH3-N (whole-water) .200  52      100        0.300    0.581    0.843    0.984    1.178    1.473    1.808
00631 NO2+NO3-N               .050  52       96      < 0.050    0.237    1.683    3.105    3.988    5.876    6.492
00665 Total P (whole-water)   .010  52      100        0.024    0.087    0.150    0.225    0.295    0.414    0.538
00666 Total P (filtered)      .010  52       92      < 0.010  < 0.010    0.032    0.061    0.079    0.121    0.130
00671 PO4-P                   .001  52       92      < 0.001  < 0.001    0.028    0.062    0.085    0.105    0.119
00681 DOC                     .300  53      100        3.200    3.200    3.600    4.200    4.600    5.800    6.400
00689 SOC                     .200  50       96        0.800    1.100    1.700    2.850    3.500    4.900  > 5.000

Major Ions, dissolved (filtered at 0.45 microns)

Units in milligrams per liter, except where noted

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

00915 Calcium                 .020  52      100        28.36    39.07    46.54    57.70    63.07    73.96    78.10
00925 Magnesium               .010  52      100        7.748    10.63    14.30    18.37    22.42    25.97    27.42
00930 Sodium                  .200  52      100        5.455    6.519    10.54    13.00    22.74    38.83    44.23
00935 Potassium               .010  52      100        2.270    2.370    2.890    3.385    3.710    4.610    4.800
00940 Chloride                .010  52      100        11.41    12.84    18.67    22.87    34.05    52.23    56.67
00945 Sulfate                 .010  52      100        20.28    24.00    36.71    49.00    65.62    80.03    105.8
00950 Fluoride                .100  52      100        0.115    0.143    0.171    0.200    0.233    0.288    0.300
00955 Silica                  .010  52      100        0.060    0.240    3.313    5.500    6.512    7.300    7.891

Trace Elements, dissolved (filtered at 0.45 microns)

Units in micrograms per liter

Note: because of changes in reporting levels (RL), all censored data in this summary are converted to the highest RL reported for this station

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

01000 Arsenic                  2.0  52       56      <   2.0  <   2.0  <   2.0      1.0      1.4      2.0      2.6
01005 Barium                   1.0  40      100         27.4     31.0     39.8     45.3     51.1     54.7     56.8
01010 Beryllium                1.0  40        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01020 Boron                   16.0  52      100         26.1     31.2     43.3     63.4    104.8    178.0    223.7
01025 Cadmium                  1.0  40        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01030 Chromium                 1.0  40       78      <   1.0  <   1.0      1.0      1.6      2.3      3.9      4.6
01035 Cobalt                   1.0  40        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01040 Copper                   1.0  40       98      <   1.0      1.0      1.4      1.7      2.0      2.4      2.8
01046 Iron                    10.0  52       38      <  10.0  <  10.0  <  10.0  <  10.0     10.0     20.8     28.0
01049 Lead                     1.0  40        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01056 Manganese                1.0  40       68      <   1.0  <   1.0  <   1.0      1.8      2.6      8.1     10.0
01060 Molybdenum               1.0  40      100          1.0      1.6      2.0      2.9      5.3      7.8     10.8
01065 Nickel                   1.0  40       95      <   1.0  <   1.0      1.6      1.7      2.2      3.1      4.4
01075 Silver                   1.0  40        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01080 Strontium                0.5  52      100         71.6     95.1    140.2    174.7    216.3    297.5    330.0
01085 Vanadium                10.0  52        0      <  10.0  <  10.0  <  10.0  <  10.0  <  10.0  <  10.0  <  10.0
01090 Zinc                     1.0  40       83      <   1.0  <   1.0      1.0      2.0      2.6      6.3      8.4
01095 Antimony                 1.0  40        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01106 Aluminum                 1.0  40      100          1.4      2.0      4.0      4.8      5.5     10.3     14.0
01130 Lithium                  6.0  52       54      <   6.0  <   6.0  <   6.0      4.0      5.6      8.2     10.1
01145 Selenium                 2.4  52       15      <   2.4  <   2.4  <   2.4  <   2.4  <   2.4      2.4      2.4
22703 Uranium                  1.0  40       38      <   1.0  <   1.0  <   1.0  <   1.0      1.1      1.3      1.4

Pesticides, dissolved (filtered at 0.7 microns)

Units in micrograms per liter, except where noted

Note: concentrations sometimes are estimated below the reporting level (RL); in this summary, all censored and estimated concentrations are converted to highest RL reported for this station; the percent detections described in the table include estimated concentrations, when appropriate

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

04024 Propachlor              .007  51        2      < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007    0.031
04028 Butylate                .002  51        4      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.021
04035 Simazine                .005  51      100        0.014    0.021    0.036    0.095    0.287    0.897    1.320
04037 Prometon                .018  51       94      < 0.018  < 0.018    0.011    0.019    0.028    0.040    0.052
04040 Desethyl atrazine       .002  51      100        0.021    0.038    0.067    0.105    0.223    0.693    0.875
04041 Cyanazine               .004  51      100        0.011    0.015    0.041    0.077    0.190    1.760    3.330
04095 Fonofos                 .003  51        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
34253 alpha-HCH               .002  51        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
34653 p,p DDE                 .006  51        2      < 0.006  < 0.006  < 0.006  < 0.006  < 0.006  < 0.006    0.006
38933 Chlorpyrifos            .004  50       32      < 0.004  < 0.004  < 0.004  < 0.004    0.004    0.015    0.061
39341 gamma-HCH               .004  51        2      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004    0.004
39381 Dieldrin                .015  51        2      < 0.015  < 0.015  < 0.015  < 0.015  < 0.015  < 0.015    0.015
39415 Metolachlor             .002  51      100        0.050    0.056    0.144    0.236    0.948    4.040    10.30
39532 Malathion               .005  51        0      < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005
39542 Parathion               .018  51        0      < 0.018  < 0.018  < 0.018  < 0.018  < 0.018  < 0.018  < 0.018
39572 Diazinon                .002  51       33      < 0.002  < 0.002  < 0.002  < 0.002    0.004    0.007    0.012
39632 Atrazine                .001  51      100        0.091    0.135    0.273    0.646    2.870    10.40    19.80
46342 Alachlor                .010  51       80      < 0.010  < 0.010    0.007    0.012    0.028    0.248    0.694
49260 Acetochlor              .002  51       94      < 0.002  < 0.002    0.014    0.034    0.261    1.600    2.910
82630 Metribuzin              .010  51       67      < 0.010  < 0.010  < 0.010    0.018    0.067    0.116    0.175
82660 Diethylanaline          .003  51        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
82661 Trifluralin             .002  51       18      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.005    0.007
82663 Ethalfluralin           .004  51        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82664 Phorate                 .002  51        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
82665 Terbacil                .007  51        0      < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007
82666 Linuron                 .015  51        0      < 0.015  < 0.015  < 0.015  < 0.015  < 0.015  < 0.015  < 0.015
82667 Methyl parathion        .006  51        0      < 0.006  < 0.006  < 0.006  < 0.006  < 0.006  < 0.006  < 0.006
82668 EPTC                    .002  51       10      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.003    0.007
82669 Pebulate                .004  51        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82670 Tebuthiuron             .010  51       67      < 0.010  < 0.010  < 0.010    0.010    0.011    0.017    0.020
82671 Molinate                .004  51        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82672 Ethoprop                .003  51        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
82673 Benfluralin             .002  51        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
82674 Carbofuran              .030  51        8      < 0.030  < 0.030  < 0.030  < 0.030  < 0.030    0.030    0.157
82675 Terbufos                .013  51        0      < 0.013  < 0.013  < 0.013  < 0.013  < 0.013  < 0.013  < 0.013
82676 Pronamide               .003  51        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
82677 Disulfoton              .017  51        0      < 0.017  < 0.017  < 0.017  < 0.017  < 0.017  < 0.017  < 0.017
82678 Triallate               .001  51        0      < 0.001  < 0.001  < 0.001  < 0.001  < 0.001  < 0.001  < 0.001
82679 Propanil                .004  51        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82680 Carbaryl                .003  51        8      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003    0.004    0.007
82681 Thiobencarb             .002  51        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
82682 Dachthal (DCPA)         .002  51        6      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.002    0.003
82683 Pendimethalin           .035  51        8      < 0.035  < 0.035  < 0.035  < 0.035  < 0.035    0.022    0.035
82684 Napropamide             .003  51        2      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003    0.006
82685 Propargite              .090  51        0      < 0.090  < 0.090  < 0.090  < 0.090  < 0.090  < 0.090  < 0.090
82686 Azinphos methyl         .001  51        0      < 0.001  < 0.001  < 0.001  < 0.001  < 0.001  < 0.001  < 0.001
82687 Permethrin              .005  51        0      < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005
91063 Diazinon-d10 (%)        .100  51      100        74.70    82.63    97.63    105.1    112.8    134.2    142.7
91064 Terbuthylazin (%)       .100  36      100        0.086    84.90    109.1    117.5    130.3    145.5    153.2
91065 HCH alpha-D6 (%)        .100  51      100        62.40    75.64    91.01    97.32    103.9    111.0    120.0

Suspended Sediment Chemistry

Units in parts per million (ppm) or parts per hundred (%)

Values censored higher than the reporting level (RL) indicate samples with insufficient sediment mass to quantify concentration above the RL

                                          Percent
Parameter                    RL       N  Detections    Min      5th      25th    Median    75th     95th     Max

29816 Antimony (ppm)        0.10     37      97    <  0.10     0.60     0.80     0.90      1.20     4.80      7.70
29818 Arsenic (ppm)         0.10     37     100       8.50     8.50     9.80    11.10     12.00    15.80     16.70
29820 Barium (ppm)          1.00     37     100      370.0    380.0    450.0    470.0     500.0    570.0     630.0
29822 Beryllium (ppm)       0.10     37     100       1.10     1.10     1.40     1.50      1.70     2.10      2.10
29826 Cadmium (ppm)         0.10     37     100       0.10     0.30     0.40     0.50      0.60     0.90      5.90
29829 Chromium (ppm)        1.00     37     100      46.00    47.00    57.00    62.00     69.00    86.00     88.00
29832 Copper (ppm)          1.00     37     100      19.00    19.00    23.00    25.00     26.00    35.00     88.00
29836 Lead (ppm)            1.00     37     100      19.00    21.00    24.00    25.00     28.00    40.00     84.00
29839 Manganese (ppm)       10.0     37     100      860.0    930.0     1100     1300      1700     2900      3500
29841 Mercury (ppm)         0.01     37     100       0.02     0.02     0.04     0.06      0.09     0.47      1.10
29843 Molybdenum (ppm)      5.00     37       5    <  5.00  <  5.00  <  5.00  <  5.00   <  5.00    25.00     25.00
29845 Nickel (ppm)          1.00     37     100      26.00    28.00    34.00    38.00     42.00    48.00     53.00
29847 Selenium (ppm)        0.10     37     100       0.40     0.60     0.70     0.80      1.10     1.90      2.10
29850 Silver (ppm)          0.50     37       5    <  0.50  <  0.50  <  0.50  <  0.50   <  0.50     2.50      2.50
29853 Vanadium (ppm)        1.00     37     100      59.00    61.00    79.00    91.00     100.0    130.0     140.0
29855 Zinc (ppm)            1.00     37     100      90.00    110.0    130.0    130.0     140.0    200.0     220.0
30221 Aluminum (%)          0.10     37     100       3.80     4.20     5.50     6.10      6.80     8.30      8.40
30244 Total carbon (%)      0.10     37     100       2.30     2.40     2.70     3.20      4.40     6.40      8.70
30269 Iron (%)              0.10     37     100       2.30     2.40     2.90     3.20      3.50     4.30      4.50
30292 Phosphorus (%)        0.01     37     100       0.09     0.10     0.11     0.12      0.13     0.17      0.19
30308 Sulfur (%)            0.10     32     100       0.10     0.10     0.10     0.20      0.30     1.40      2.00
30317 Titanium (%)          0.01     37     100       0.24     0.25     0.34     0.39      0.40     0.44      0.45
35031 Cobalt (ppm)          1.00     37     100      10.00    11.00    12.00    13.00     14.00    16.00     17.00
35040 Strontium (ppm)       0.01     37     100      100.0    100.0    120.0    130.0     160.0    300.0     320.0
35046 Uranium (ppm)         50.0     37       0    < 50.00  < 50.00  < 50.00  < 50.00   < 50.00  < 250.0   < 250.0
35050 Lithium (ppm)         1.00     37     100      30.00    32.00    36.00    39.00     43.00    55.00     65.00
49955 Thallium (ppm)        50.0     37       0    < 50.00  < 50.00  < 50.00  < 50.00   < 50.00  < 250.0   < 250.0
50279 Sediment (mg/L)       1.00     37     100      25.00    42.00    95.00    130.0     222.0    264.0     326.0
50465 Organic carbon (%)    0.10     36     100       0.10     1.80     2.15     2.35      2.80     4.20      6.50

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