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Concentrations and annual fluxes for selected water-quality constituents from the USGS National Stream Water Quality Accounting Network (NASQAN)

By Valerie J. Kelly, Richard P. Hooper, Brent T. Aulenbach, and Mary Janet

Summary Statistics--Columbia Basin, Water Years 1996-2000

Willamette River at Portland, Oregon (14211720)

Daily Mean Streamflow

Units                               N             Min     5th       25th     Median    75th      95th      Max

Cubic feet per second             1,827         8,450     9,100    13,600    28,000    55,900   140,000   420,000
Cubic meters per second           1,827           239       258       385       793     1,583     3,964    11,893

Field Parameters, Turbidity, and Suspended Sediment

Units in milligrams per liter, except where noted

Parameter                             N               Min      5th     25th    Median     75th     95th     Max

00010 Temperature (C)                74                 4.9     6.3      7.7      10.1     15.2     21.2     22.9
00076 Turbidity (NTU)                72                 0.5     1.8      3.0       7.4     20.0     98.0    270.0
00095 Conductance (uS/cm)            74                37.3    48.5     57.6      68.6     80.0     91.2    101.0
00300 Dissolved oxygen               71                 7.5     8.1     10.4      12.2     13.2     14.5     15.0
00400 pH (standard units)            74                 6.6     6.8      7.1       7.2      7.3      7.6      7.8
00452 CO3 (filtered)                 74                 0.0     0.0      0.0       0.0      0.0      0.0      0.0
00453 HCO3 (filtered)                74                13.0    17.0     24.0      28.5     33.0     38.0     39.0
39086 Alk (filtered, as CaCO3)       74                11.0    14.0     20.0      23.5     27.0     31.0     32.0
70331 % finer than 62 microns        73                74.0    83.0     95.0      97.0     98.0     99.0     99.0
80154 Suspended sediment             74                 3.0     5.0      8.0      15.5     49.0    224.0    456.0

Nutrients and Organic Carbon, dissolved (filtered at 0.45 microns) and whole-water (unfiltered)

Units in milligrams per liter

Note: because of changes in reporting levels (RL), all censored data in this summary are converted to the highest RL reported for this station

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

00608 NH3-N                   .015  74       95      < 0.015  < 0.015    0.027    0.040    0.055    0.086    0.150
00613 NO2-N                   .010  74       96      < 0.010    0.004    0.006    0.010    0.011    0.016    0.020
00623 Org+NH3-N (filtered)    .200  74       64      < 0.200  < 0.200  < 0.200    0.171    0.200    0.200    0.300
00625 Org+NH3-N (whole-water) .200  74       78      < 0.200  < 0.200    0.200    0.220    0.284    0.500    0.656
00631 NO2+NO3-N               .050  74      100        0.035    0.200    0.330    0.545    0.707    0.885    0.948
00665 Total P (whole-water)   .010  74      100        0.012    0.029    0.050    0.070    0.090    0.190    0.440
00666 Total P (filtered)      .010  74       89      < 0.010  < 0.010    0.020    0.030    0.040    0.070    0.081
00671 PO4-P                   .010  74      100        0.006    0.013    0.021    0.027    0.035    0.056    0.071
00681 DOC                     .300  72      100        1.100    1.200    1.400    1.644    2.000    3.000    4.000
00689 SOC                     .200  73       97      < 0.200    0.200    0.300    0.500    0.900    3.200    9.300

Major Ions, dissolved (filtered at 0.45 microns)

Units in milligrams per liter, except where noted

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

00915 Calcium                 .020  72      100        2.900    4.100    5.082    5.894    6.639    7.197    7.636
00925 Magnesium               .010  72      100        0.930    1.400    1.700    1.904    2.203    2.471    2.623
00930 Sodium                  .200  72      100        2.200    2.700    3.496    4.419    5.313    8.080    8.746
00935 Potassium               .010  72      100        0.470    0.590    0.680    0.730    0.895    1.130    1.240
00940 Chloride                .010  72      100        1.900    2.280    2.784    3.464    4.177    5.780    6.760
00945 Sulfate                 .010  73      100        1.402    1.785    2.394    2.940    3.467    5.030    6.100
00950 Fluoride                .100  73        3      < 0.100  < 0.100  < 0.100  < 0.100  < 0.100  < 0.100    0.100
00955 Silica                  .010  72      100        9.800    12.00    13.92    14.99    16.00    16.86    17.25

Trace Elements, dissolved (filtered at 0.45 microns)

Units in micrograms per liter

Note: because of changes in reporting levels (RL), all censored data in this summary are converted to the highest RL reported for this station

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

01000 Arsenic                  2.0  72        1      <   2.0  <   2.0  <   2.0  <   2.0  <   2.0  <   2.0      2.0
01005 Barium                   1.0  52      100          3.4      4.0      5.0      5.9      6.4      7.3     14.0
01010 Beryllium                1.0  52        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01020 Boron                   16.0  67        6      <  16.0  <  16.0  <  16.0  <  16.0  <  16.0     17.3     30.0
01025 Cadmium                  1.0  52        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01030 Chromium                 5.0  52        4      <   5.0  <   5.0  <   5.0  <   5.0  <   5.0  <   5.0      5.0
01035 Cobalt                   3.0  52        0      <   3.0  <   3.0  <   3.0  <   3.0  <   3.0  <   3.0  <   3.0
01040 Copper                   1.0  52       67      <   1.0  <   1.0  <   1.0      1.0      1.6      3.0      4.0
01046 Iron                     3.0  72      100         16.2     19.6     26.4     36.3     46.3    140.0    240.0
01049 Lead                     1.0  52        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01056 Manganese                1.0  52       94      <   1.0  <   1.0      5.2      8.2     13.3     26.0     41.0
01060 Molybdenum              10.0  52        0      <  10.0  <  10.0  <  10.0  <  10.0  <  10.0  <  10.0  <  10.0
01065 Nickel                   1.0  52       13      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0      1.3      7.2
01075 Silver                   1.0  52        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01080 Strontium                0.5  72      100         20.0     27.1     33.5     36.6     40.4     45.0     49.2
01085 Vanadium                 250  72        1      < 250.0  < 250.0  < 250.0  < 250.0  < 250.0  < 250.0    250.0
01090 Zinc                     1.0  52       92      <   1.0  <   1.0      1.3      2.0      3.0      7.0      9.0
01095 Antimony                 1.0  51        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01106 Aluminum                 1.0  52      100          2.6      3.0      5.3      8.9     33.0    141.0    159.0
01130 Lithium                  6.0  72        3      <   6.0  <   6.0  <   6.0  <   6.0  <   6.0  <   6.0      6.0
01145 Selenium                 2.4  72        1      <   2.4  <   2.4  <   2.4  <   2.4  <   2.4  <   2.4      2.4
22703 Uranium                  1.0  51        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0

Pesticides, dissolved (filtered at 0.7 microns)

Units in micrograms per liter, except where noted

Note: concentrations sometimes are estimated below the reporting level (RL); in this summary, all censored and estimated concentrations are converted to highest RL reported for this station; the percent detections described in the table include estimated concentrations, when appropriate

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

04024 Propachlor              .007  73        4      < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007    0.007
04028 Butylate                .002  73        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
04035 Simazine                .005  73       93      < 0.005  < 0.005    0.011    0.016    0.031    0.082    0.157
04037 Prometon                .018  73       14      < 0.018  < 0.018  < 0.018  < 0.018  < 0.018    0.018    0.018
04040 Desethyl atrazine       .002  73       84      < 0.002  < 0.002    0.004    0.006    0.009    0.016    0.020
04041 Cyanazine               .004  73        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
04095 Fonofos                 .003  73        7      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003    0.004    0.007
34253 alpha-HCH               .002  73        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
34653 p,p DDE                 .006  73        8      < 0.006  < 0.006  < 0.006  < 0.006  < 0.006    0.006    0.006
38933 Chlorpyrifos            .004  73       51      < 0.004  < 0.004  < 0.004    0.004    0.004    0.010    0.014
39341 gamma-HCH               .004  73        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
39381 Dieldrin                .001  73        1      < 0.001  < 0.001  < 0.001  < 0.001  < 0.001  < 0.001    0.001
39415 Metolachlor             .002  73       95      < 0.002  < 0.002    0.007    0.016    0.027    0.075    0.152
39532 Malathion               .005  73        3      < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005    0.011
39542 Parathion               .004  73        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
39572 Diazinon                .002  73       40      < 0.002  < 0.002  < 0.002  < 0.002    0.004    0.006    0.011
39632 Atrazine                .001  73       97      < 0.001    0.003    0.013    0.039    0.090    0.217    0.328
46342 Alachlor                .002  73        3      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.003
49260 Acetochlor              .002  73        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
82630 Metribuzin              .004  73       51      < 0.004  < 0.004  < 0.004    0.006    0.022    0.055    0.095
82660 Diethylanaline          .003  73        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
82661 Trifluralin             .002  73       15      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.006    0.009
82663 Ethalfluralin           .004  73        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82664 Phorate                 .002  73        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
82665 Terbacil                .007  73       51      < 0.007  < 0.007  < 0.007    0.007    0.013    0.032    0.039
82666 Linuron                 .002  73        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
82667 Methyl parathion        .006  73        0      < 0.006  < 0.006  < 0.006  < 0.006  < 0.006  < 0.006  < 0.006
82668 EPTC                    .010  73       21      < 0.010  < 0.010  < 0.010  < 0.010  < 0.010    0.010    0.026
82669 Pebulate                .004  73        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82670 Tebuthiuron             .010  73       22      < 0.010  < 0.010  < 0.010  < 0.010  < 0.010    0.011    0.018
82671 Molinate                .004  73        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82672 Ethoprop                .003  73       18      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003    0.012    0.029
82673 Benfluralin             .002  73        1      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.002
82674 Carbofuran              .004  73       14      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004    0.016    0.268
82675 Terbufos                .013  73        0      < 0.013  < 0.013  < 0.013  < 0.013  < 0.013  < 0.013  < 0.013
82676 Pronamide               .003  73       53      < 0.003  < 0.003  < 0.003    0.004    0.014    0.040    0.082
82677 Disulfoton              .017  73        0      < 0.017  < 0.017  < 0.017  < 0.017  < 0.017  < 0.017  < 0.017
82678 Triallate               .008  73       12      < 0.008  < 0.008  < 0.008  < 0.008  < 0.008    0.006    0.047
82679 Propanil                .004  73        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82680 Carbaryl                .007  73       27      < 0.007  < 0.007  < 0.007  < 0.007    0.004    0.009    0.041
82681 Thiobencarb             .002  73        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
82682 Dachthal (DCPA)         .002  73        4      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.002
82683 Pendimethalin           .030  73        5      < 0.030  < 0.030  < 0.030  < 0.030  < 0.030    0.004    0.030
82684 Napropamide             .003  73       33      < 0.003  < 0.003  < 0.003  < 0.003    0.004    0.013    0.023
82685 Propargite              .070  73        1      < 0.070  < 0.070  < 0.070  < 0.070  < 0.070  < 0.070    0.070
82686 Azinphos methyl         .010  73        1      < 0.010  < 0.010  < 0.010  < 0.010  < 0.010  < 0.010    0.032
82687 Permethrin              .005  73        0      < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005
91063 Diazinon-d10 (%)        .100  73      100        66.90    83.90    93.04    102.8    109.9    123.0    160.0
91064 Terbuthylazin (%)       .100  55      100        79.60    92.36    103.0    112.3    121.0    133.3    157.0
91065 HCH alpha-D6 (%)        .100  73      100        58.50    79.80    91.10    97.30    105.0    124.5    143.0

Suspended Sediment Chemistry

Units in parts per million (ppm) or parts per hundred (%)

Values censored higher than the reporting level (RL) indicate samples with insufficient sediment mass to quantify concentration above the RL

                                          Percent
Parameter                    RL       N  Detections    Min      5th      25th    Median    75th     95th     Max

29816 Antimony (ppm)        0.10     54     100       0.50     0.60     0.80     1.00      1.20     1.60      2.00
29818 Arsenic (ppm)         0.10     54     100       6.50     6.70     7.80     8.30      9.40    10.20     11.10
29820 Barium (ppm)          1.00     54     100      90.00    380.0    420.0    460.0     500.0    550.0     760.0
29822 Beryllium (ppm)       0.10     54     100       1.10     1.10     1.30     1.50      1.50     1.70      1.90
29826 Cadmium (ppm)         0.10     53      89    <  0.10  <  0.10     0.20     0.30      0.50     0.60      0.80
29829 Chromium (ppm)        1.00     54      91    <  1.00  <  1.00    69.00    78.00     88.00    150.0     210.0
29832 Copper (ppm)          1.00     54     100      14.00    43.00    51.00    57.00     66.00    120.0     390.0
29836 Lead (ppm)            1.00     54     100       8.00    14.00    17.00    22.50     31.00    60.00     120.0
29839 Manganese (ppm)       10.0     54     100       1100     1200     1400     1800      3100     3700      4100
29841 Mercury (ppm)         0.01     44      95    <  0.01     0.04     0.06     0.08      0.12     0.16      0.18
29843 Molybdenum (ppm)      5.00     52      13    <  4.00  <  5.00  <  5.00  < 10.00   < 11.50    25.00     50.00
29845 Nickel (ppm)          1.00     54      91    <  1.00  <  1.00    42.00    44.50     52.00    86.00     140.0
29847 Selenium (ppm)        0.10     54      98    <  0.10     0.20     0.30     0.40      0.50     0.50      0.60
29850 Silver (ppm)          0.50     54      15    <  0.50  <  0.50  <  0.70  <  1.00   <  2.50     5.00      5.00
29853 Vanadium (ppm)        1.00     54     100      130.0    140.0    150.0    160.0     170.0    180.0     190.0
29855 Zinc (ppm)            1.00     54     100      40.00    110.0    130.0    140.0     160.0    190.0     250.0
30221 Aluminum (%)          0.10     52     100       6.20     6.80     7.60     8.35      9.05     9.60      9.70
30244 Total carbon (%)      0.10     49      92    <  0.10  <  0.10     2.60     3.80      5.00     6.60      7.40
30269 Iron (%)              0.10     54     100       4.70     5.20     5.40     5.80      6.10     6.60      6.60
30292 Phosphorus (%)        0.01     54     100       0.12     0.13     0.16     0.18      0.22     0.25      0.30
30308 Sulfur (%)            0.10     45      73    <  0.10  <  0.10  <  0.10     0.20      0.30     0.50      3.30
30317 Titanium (%)          0.01     52     100       0.51     0.59     0.61     0.70      0.71     0.80      0.81
35031 Cobalt (ppm)          1.00     54     100      21.00    23.00    24.00    25.00     27.00    30.00     32.00
35040 Strontium (ppm)       0.01     54     100      190.0    190.0    220.0    230.0     250.0    300.0     320.0
35046 Uranium (ppm)         50.0     52       0    < 50.00  < 50.00  < 75.00  < 100.0   < 250.0  < 250.0     250.0
35050 Lithium (ppm)         1.00     54     100      19.00    21.00    24.00    27.00     30.00    37.00     160.0
49955 Thallium (ppm)        50.0     52       0    < 50.00  < 50.00  < 75.00  < 100.0   < 250.0  < 250.0     250.0
50279 Sediment (mg/L)       1.00     53     100       4.50     5.00     8.00    11.00     37.00    209.0     479.0
50465 Organic carbon (%)    0.10     40      88    <  0.10  <  0.10     2.05     3.60      4.25     5.75      7.10

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