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Concentrations and annual fluxes for selected water-quality constituents from the USGS National Stream Water Quality Accounting Network (NASQAN)

By Valerie J. Kelly, Richard P. Hooper, Brent T. Aulenbach, and Mary Janet

Summary Statistics--Mississippi Basin, Water Years 1996-2000

Yellowstone River near Sidney, Montana (06329500)

Daily Mean Streamflow

Units                               N             Min     5th       25th     Median    75th      95th      Max

Cubic feet per second             1,827         2,000     4,880     7,440     9,140    14,500    40,000    84,900
Cubic meters per second           1,827            57       138       211       259       411     1,133     2,404

Field Parameters, Turbidity, and Suspended Sediment

Units in milligrams per liter, except where noted

Parameter                             N               Min      5th     25th    Median     75th     95th     Max

00010 Temperature (C)                65                 0.0     0.0      8.0      16.0     20.0     23.5     24.5
00076 Turbidity (NTU)                54                 2.8     3.9     33.0      65.0    170.0    335.0   1560.0
00095 Conductance (uS/cm)            65               237.0   289.0    413.0     614.0    718.0    893.0   1009.0
00300 Dissolved oxygen               64                 6.3     7.4      8.0       8.6     10.3     12.9     15.0
00400 pH (standard units)            65                 7.5     7.8      8.2       8.4      8.5      8.7      8.8
00452 CO3 (filtered)                 60                 0.0     0.0      0.0       2.0      6.0     10.0     12.0
00453 HCO3 (filtered)                64                84.9    95.0    111.5     157.5    192.0    210.0    231.0
39086 Alk (filtered, as CaCO3)       64                69.6    78.0     99.0     137.0    162.5    177.0    189.0
70331 % finer than 62 microns        52                11.0    48.0     68.8      77.5     93.0     99.0     99.4
80154 Suspended sediment             65                10.0    15.0    103.0     255.0    543.0   1790.0   4070.0

Nutrients and Organic Carbon, dissolved (filtered at 0.45 microns) and whole-water (unfiltered)

Units in milligrams per liter

Note: because of changes in reporting levels (RL), all censored data in this summary are converted to the highest RL reported for this station

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

00608 NH3-N                   .020  65       63      < 0.020  < 0.020  < 0.020    0.019    0.028    0.077    0.180
00613 NO2-N                   .010  65       46      < 0.010  < 0.010  < 0.010  < 0.010    0.010    0.012    0.020
00623 Org+NH3-N (filtered)    .200  65       78      < 0.200  < 0.200    0.159    0.200    0.216    0.289    0.600
00625 Org+NH3-N (whole-water) .200  65      100        0.145    0.223    0.331    0.481    0.752    1.849    3.850
00631 NO2+NO3-N               .050  65       77      < 0.050  < 0.050    0.050    0.168    0.286    0.425    0.604
00665 Total P (whole-water)   .050  65       97      < 0.050    0.013    0.068    0.130    0.269    1.355    1.850
00666 Total P (filtered)      .050  65       54      < 0.050  < 0.050  < 0.050    0.010    0.010    0.020    0.050
00671 PO4-P                   .010  65       66      < 0.010  < 0.010  < 0.010    0.010    0.013    0.030    0.032
00681 DOC                     .300  62      100        2.100    2.500    2.733    3.036    3.400    4.100    8.400
00689 SOC                     .200  63       98        0.200    0.300    0.800    2.000    3.735    9.200  > 20.00

Major Ions, dissolved (filtered at 0.45 microns)

Units in milligrams per liter, except where noted

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

00915 Calcium                 .020  64      100        20.27    25.23    32.45    45.81    57.90    66.67    70.17
00925 Magnesium               .010  64      100        6.841    8.536    11.48    18.08    22.67    28.07    31.23
00930 Sodium                  .200  64      100        15.91    20.48    31.47    51.06    61.59    85.75    96.93
00935 Potassium               .010  64      100        0.770    1.780    2.390    3.255    3.730    4.190    6.090
00940 Chloride                .010  64      100        2.900    3.230    5.169    8.055    11.23    14.19    16.05
00945 Sulfate                 .010  64      100        40.87    56.96    91.44    150.8    194.1    275.0    339.2
00950 Fluoride                .100  64      100        0.100    0.221    0.283    0.396    0.443    0.500    0.572
00955 Silica                  .010  64      100        4.488    6.796    8.393    9.973    10.72    11.96    12.19

Trace Elements, dissolved (filtered at 0.45 microns)

Units in micrograms per liter

Note: because of changes in reporting levels (RL), all censored data in this summary are converted to the highest RL reported for this station

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

01000 Arsenic                  1.0  60      100          2.0      2.2      3.5      4.0      4.7      5.9      6.4
01005 Barium                   1.0  51      100         27.2     29.8     37.0     44.5     50.0     55.0     59.7
01010 Beryllium                1.0  51        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01020 Boron                   16.0  54      100         46.5     48.6     72.8    112.8    136.3    163.5    172.7
01025 Cadmium                  1.0  51        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01030 Chromium                 1.0  51       49      <   1.0  <   1.0  <   1.0  <   1.0      2.0      4.1      9.1
01035 Cobalt                   1.0  51        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01040 Copper                   1.0  51       96      <   1.0      1.0      1.6      2.0      2.4      3.2      4.0
01046 Iron                    10.0  63       16      <  10.0  <  10.0  <  10.0  <  10.0  <  10.0     10.0     29.0
01049 Lead                     1.0  51        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01056 Manganese                3.0  55       60      <   3.0  <   3.0  <   3.0      1.4      3.3      9.5     10.0
01060 Molybdenum               1.0  51       96      <   1.0      1.0      1.4      1.8      2.0      2.4      2.6
01065 Nickel                   1.0  51       80      <   1.0  <   1.0      1.0      1.3      2.0      3.0      5.4
01075 Silver                   1.0  51        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01080 Strontium                0.5  54      100        184.1    220.0    299.5    440.0    585.2    731.9    745.7
01085 Vanadium                10.0  54        7      <  10.0  <  10.0  <  10.0  <  10.0  <  10.0     10.0     10.0
01090 Zinc                     1.0  50       40      <   1.0  <   1.0  <   1.0  <   1.0      1.2      3.1      5.5
01095 Antimony                 1.0  51        0      <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0  <   1.0
01106 Aluminum                 1.0  51       92      <   1.0  <   1.0      1.6      3.2      5.9     14.3     16.0
01130 Lithium                  4.0  54      100         11.0     14.2     21.0     31.0     38.1     46.6     47.6
01145 Selenium                 2.4  60       40      <   2.4  <   2.4  <   2.4  <   2.4      1.3      2.4      2.4
22703 Uranium                  1.0  51      100          1.0      1.3      2.0      3.0      4.1      4.8      5.1

Pesticides, dissolved (filtered at 0.7 microns)

Units in micrograms per liter, except where noted

Note: concentrations sometimes are estimated below the reporting level (RL); in this summary, all censored and estimated concentrations are converted to highest RL reported for this station; the percent detections described in the table include estimated concentrations, when appropriate

                                          Percent
Parameter                       RL  N    Detections    Min      5th      25th    Median    75th     95th     Max

04024 Propachlor              .007  62        0      < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007
04028 Butylate                .002  62        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
04035 Simazine                .005  62        6      < 0.005  < 0.005  < 0.005  < 0.005  < 0.005    0.005    0.014
04037 Prometon                .018  62       23      < 0.018  < 0.018  < 0.018  < 0.018  < 0.018    0.018    0.018
04040 Desethyl atrazine       .004  63       48      < 0.004  < 0.004  < 0.004  < 0.004    0.003    0.005    0.098
04041 Cyanazine               .004  62       26      < 0.004  < 0.004  < 0.004  < 0.004    0.004    0.014    0.035
04095 Fonofos                 .003  62        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
34253 alpha-HCH               .002  62        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
34653 p,p DDE                 .006  62        5      < 0.006  < 0.006  < 0.006  < 0.006  < 0.006  < 0.006    0.006
38933 Chlorpyrifos            .004  62        8      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004    0.004    0.004
39341 gamma-HCH               .004  62        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
39381 Dieldrin                .001  62        0      < 0.001  < 0.001  < 0.001  < 0.001  < 0.001  < 0.001  < 0.001
39415 Metolachlor             .002  62       58      < 0.002  < 0.002  < 0.002    0.002    0.005    0.009    0.015
39532 Malathion               .008  62        2      < 0.008  < 0.008  < 0.008  < 0.008  < 0.008  < 0.008    0.008
39542 Parathion               .004  62        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
39572 Diazinon                .002  62        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
39632 Atrazine                .009  63       81      < 0.009  < 0.009    0.004    0.006    0.006    0.019    0.177
46342 Alachlor                .004  62       10      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004    0.004    0.056
49260 Acetochlor              .002  62        8      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.008    0.016
82630 Metribuzin              .004  62        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82660 Diethylanaline          .003  62        2      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003    0.006
82661 Trifluralin             .002  62        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
82663 Ethalfluralin           .004  62        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82664 Phorate                 .002  62        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
82665 Terbacil                .007  62        0      < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007  < 0.007
82666 Linuron                 .002  62        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
82667 Methyl parathion        .006  62        0      < 0.006  < 0.006  < 0.006  < 0.006  < 0.006  < 0.006  < 0.006
82668 EPTC                    .070  62       18      < 0.070  < 0.070  < 0.070  < 0.070  < 0.070    0.010    0.070
82669 Pebulate                .004  62        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82670 Tebuthiuron             .010  63       14      < 0.010  < 0.010  < 0.010  < 0.010  < 0.010    0.010    0.222
82671 Molinate                .004  62        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82672 Ethoprop                .003  62        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
82673 Benfluralin             .002  62        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
82674 Carbofuran              .030  62        6      < 0.030  < 0.030  < 0.030  < 0.030  < 0.030    0.008    0.030
82675 Terbufos                .013  62        0      < 0.013  < 0.013  < 0.013  < 0.013  < 0.013  < 0.013  < 0.013
82676 Pronamide               .003  62        0      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003
82677 Disulfoton              .017  62        0      < 0.017  < 0.017  < 0.017  < 0.017  < 0.017  < 0.017  < 0.017
82678 Triallate               .005  62       39      < 0.005  < 0.005  < 0.005  < 0.005    0.003    0.006    0.008
82679 Propanil                .004  62        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82680 Carbaryl                .003  62        3      < 0.003  < 0.003  < 0.003  < 0.003  < 0.003  < 0.003    0.005
82681 Thiobencarb             .002  62        0      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002  < 0.002
82682 Dachthal (DCPA)         .002  62        6      < 0.002  < 0.002  < 0.002  < 0.002  < 0.002    0.002    0.002
82683 Pendimethalin           .004  62        0      < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004  < 0.004
82684 Napropamide             .020  62        0      < 0.020  < 0.020  < 0.020  < 0.020  < 0.020  < 0.020  < 0.020
82685 Propargite              .020  56        0      < 0.020  < 0.020  < 0.020  < 0.020  < 0.020  < 0.020  < 0.020
82686 Azinphos methyl         .001  62        0      < 0.001  < 0.001  < 0.001  < 0.001  < 0.001  < 0.001  < 0.001
82687 Permethrin              .005  62        0      < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005  < 0.005
91063 Diazinon-d10 (%)        .100  62      100        71.70    85.40    95.92    101.3    107.7    121.6    135.1
91064 Terbuthylazin (%)       .100  37      100        88.44    92.95    103.6    110.2    119.1    129.4    129.6
91065 HCH alpha-D6 (%)        .100  62      100        57.70    79.43    90.71    98.18    101.9    114.2    117.4

Suspended Sediment Chemistry

Units in parts per million (ppm) or parts per hundred (%)

Values censored higher than the reporting level (RL) indicate samples with insufficient sediment mass to quantify concentration above the RL

                                          Percent
Parameter                    RL       N  Detections    Min      5th      25th    Median    75th     95th     Max

29816 Antimony (ppm)        0.10     35     100       0.70     0.80     1.00     1.20      2.70     9.30     11.10
29818 Arsenic (ppm)         0.10     35     100       8.90     9.30    10.60    11.80     13.20    15.90     19.60
29820 Barium (ppm)          1.00     35     100      200.0    430.0    590.0    660.0     710.0    800.0     830.0
29822 Beryllium (ppm)       0.10     35     100       1.00     1.20     1.30     1.50      1.80     2.20      2.30
29826 Cadmium (ppm)         0.10     35      97    <  0.10     0.20     0.20     0.30      0.40     0.60      0.80
29829 Chromium (ppm)        1.00     35     100      49.00    59.00    64.00    69.00     82.00    110.0     150.0
29832 Copper (ppm)          1.00     35     100      12.00    14.00    19.00    21.00     25.00    36.00     36.00
29836 Lead (ppm)            1.00     35     100      14.00    14.00    16.00    18.00     21.00    24.00     32.00
29839 Manganese (ppm)       10.0     35     100      390.0    400.0    460.0    520.0     590.0    760.0     850.0
29841 Mercury (ppm)         0.01     35      91    <  0.01  <  0.01     0.02     0.04      0.05     0.07      0.08
29843 Molybdenum (ppm)      5.00     35       6    <  1.00  <  5.00  <  5.00  <  5.00   < 10.00    25.00     25.00
29845 Nickel (ppm)          1.00     35     100      25.00    27.00    32.00    36.00     42.00    93.00     120.0
29847 Selenium (ppm)        0.10     35     100       0.30     0.30     0.50     0.50      0.70     1.00      1.10
29850 Silver (ppm)          0.50     35       3    <  0.50  <  0.50  <  0.50  <  0.50   <  1.00  <  2.50      2.50
29853 Vanadium (ppm)        1.00     35     100      61.00    65.00    84.00    94.00     120.0    150.0     150.0
29855 Zinc (ppm)            1.00     35     100      70.00    70.00    70.00    80.00     100.0    120.0     130.0
30221 Aluminum (%)          0.10     35     100       4.00     4.70     5.50     6.20      6.70     9.30      9.90
30244 Total carbon (%)      0.10     35     100       1.00     1.00     1.50     1.70      2.00     3.10      3.20
30269 Iron (%)              0.10     35     100       2.00     2.10     2.40     2.80      3.20     3.60      3.80
30292 Phosphorus (%)        0.01     35     100       0.06     0.06     0.07     0.07      0.08     0.09      0.10
30308 Sulfur (%)            0.10     31      97    <  0.10     0.10     0.20     0.50      0.90     1.70      2.00
30317 Titanium (%)          0.01     34     100       0.20     0.21     0.28     0.30      0.30     0.40      0.44
35031 Cobalt (ppm)          1.00     35     100       8.00     8.00     9.00    11.00     12.00    15.00     19.00
35040 Strontium (ppm)       0.01     35     100      180.0    180.0    240.0    260.0     270.0    410.0     430.0
35046 Uranium (ppm)         50.0     35       0    < 50.00  < 50.00  < 50.00  < 50.00   < 50.00  < 250.0   < 250.0
35050 Lithium (ppm)         1.00     35     100      19.00    23.00    28.00    34.00     42.00    54.00     57.00
49955 Thallium (ppm)        50.0     35       0    < 50.00  < 50.00  < 50.00  < 50.00   < 50.00  < 250.0   < 250.0
50279 Sediment (mg/L)       1.00     35     100       1.00    41.00    181.0    274.0     503.0     1199      1743
50465 Organic carbon (%)    0.10     34     100       0.40     0.80     1.00     1.20      1.40     2.20      2.80

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