In the Greenville quadrangle, west-central Maine, slate, siltstone, and sandstone (calcareous and noncalcareous) of probable Silurian to Early Devonian age are intruded by a large mafic pluton and two granitic stocks of probable Early Devonian age. Ages of the sedimentary rocks are based upon tentative correlations with fossiliferous beds in adjacent quadrangles because the few fossils in the Greenville quadrangle are nondiagnostic; ages of the intrusive rocks are based upon radiometric age determinations. The sedimentary rocks are tightly folded about northeast-trending axes and have strong slaty cleavage. Widespread graded bedding is very useful in determining the tops of beds and thus the location of fold axes. The sedimentary rocks are in the chlorite zone of metamorphism except in the contact aureoles where the metamorphism ranges from the biotite zone, through the andalusiite-amphibole zone, to the sillimanite-cordierite zone adjacent to the intrusions; retrograde metamorphism is a minor local feature.

The mafic rocks are part of the Moxie pluton, which extends southwest and northeast of the Greenville quadrangle for a total distance of about 45 miles. Troctolite and norite are the principal rock types; gabbro is less common. Plagioclase is the dominant mineral; it usually makes up 50-75 percent of the rock. Olivine and orthopyroxene are widespread, clinopyroxene is uncommon and biotite and hornblende are generally present in small amounts. The rocks can be separated into magnesium-rich and iron-rich varieties; magnesium-rich olivine and orthopyroxene are usually accompanied by plagioclase containing from 57 to 77 percent anorthite, and iron-rich olivine and orthopyroxene are associated with plagioclase containing about 50-62 percent anorithite. Compositional layering is rare, but flow structure is very common. Flow structure generally dips northward to eastward, whereas geophysical data indicate that the contacts of the pluton dip southeastward. The granitic stocks are discordant pipelike bodies that range from granodiorite to quartz monzonite in composition. Both the mafic and the felsic intrusions are undeformed and unmetamorphosed.

Slate quarrying was once an important industry in the region, but in 1965 only one quarry was active at Monson just east of the report area. Slate is a potential source of raw material for lightweight concrete aggregate. There are several possible sites for stone quarries in the intrusive masses. Sand and gravel resources seem to be limited. Small amounts of sulfides that have low copper and nickel values are known at a few places in the mafic pluton.