METHODS FOR SAMPLING AND
INORGANIC ANALYSIS OF COAL
U.S. Geological Survey
Bulletin 1823
Edited by D.W. Golightly and F.O. Simon
Table 18. Compositions of coal ashes determined by methods based on atomic absorption spectrometry (AAS) or spectrophotometry (Sa) and on X-ray fluorescence (XRF) spectrometryb
Concentration (percentc) | ||||||||||||||||||||
Sample | SiO2 | Al2O3 | Fe2O3d | MgO | CaO | Na2O | K2O | TiO2 | P2O5 | MnO | ||||||||||
AAS,S | XRF | AAS,S | XRF | AAS,S | XRF | AAS,S | XRF | AAS,S | XRF | AAS,S | XRF | AAS,S | XRF | AAS,S | XRF | AAS,S | XRF | AAS,S | XRF | |
NBS 1633A | 48.6 | 48.8 | 27.1 | 27.0 | 13.5 | 13.4 | 0.78 | 0.75 | 1.6 | 1.6 | 0.19 | 0.23 | 2.2 | 2.3 | 1.4 | 1.3 | 0.42 | ND | 0.05 | 0.02 |
Ash 1 | 6.2 | 9.9 | 4.0 | 4.1 | 67.4 | 60.3 | 0.28 | ND | 9.0 | 9.4 | 0.26 | ND | 0.30 | 0.26 | 0.18 | 0.13 | 0.02 | 0.05 | 0.08 | 0.09 |
Ash 2 | 37.5 | 38.1 | 24.2 | 25.2 | 12.3 | 11.9 | 0.52 | ND | 9.5 | 9.5 | 0.75 | ND | 1.2 | 1.2 | 1.0 | 0.97 | 0.21 | 0.18 | 0.06 | 0.06 |
Ash 3 | 53.4 | 54.5 | 22.3 | 23.8 | 13.4 | 15.3 | 1.0 | ND | 0.44 | 0.40 | 0.49 | ND | 2.9 | 2.8 | 1.0 | 1.2 | 0.16 | 0.09 | 0.03 | 0.03 |
Ash 4 | 26.2 | 26.3 | 12.0 | 10.9 | 47.6 | 45.5 | 0.59 | ND | 3.4 | 3.6 | 0.38 | ND | 1.2 | 1.2 | 0.59 | 0.64 | 0.15 | 0.12 | 0.06 | 0.07 |
Ash 5 | 56.9 | 57.6 | 24.5 | 25.3 | 7.3 | 7.5 | 1.2 | ND | 0.67 | 0.57 | 0.43 | ND | 3.3 | 3.3 | 1.2 | 1.3 | 0.39 | 0.30 | 0.02 | 0.02 |
Ash 6 | 51.5 | 47.6 | 30.3 | 30.4 | 6.2 | 6.1 | 0.96 | ND | 0.40 | 0.40 | 0.25 | ND | 4.1 | 4.0 | 1.2 | 1.1 | 0.12 | 0.15 | 0.01 | 0.05 |
Ash 7 | 15.1 | 18.9 | 22.0 | 21.2 | 26.6 | 28.2 | 1.2 | ND | 9.3 | 10.2 | 0.43 | ND | 0.10 | 0.13 | 0.88 | 0.87 | 2.4 | 2.8 | 0.02 | 0.03 |
Ash 8 | 48.6 | 47.5 | 26.9 | 29.8 | 15.8 | 16.9 | 0.40 | ND | 1.8 | 1.7 | 0.15 | ND | 0.57 | 0.62 | 0.94 | 0.94 | 0.17 | 0.12 | 0.01 | 0.03 |
Ash 9 | 45.4 | 48.5 | 15.4 | 18.7 | 4.7 | 4.4 | 2.2 | ND | 16.6 | 17.3 | 0.12 | ND | 1.1 | 1.1 | 1.4 | 1.3 | 0.15 | 0.25 | 0.10 | 0.11 |
a Only Al2O3,
P2O5, SiO2, and TiO2
were determined by spectrophotometric methods. b Analyst: George Sellers. c ND: not determined. d Total Fe is reported as Fe2O3. |
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