Quadratic elongation: A quantitative measure of distortion in coordination polyhedra

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Abstract

Quadratic elongation and the variance of bond angles are linearly correlated for distorted octahedral and tetrahedral coordination complexes, both of which show variations in bond length and bond angle. The quadratic elonga tion is dimensionless, giving a quantitative measure of polyhedral distortion which is independent of the effective size of the polyhedron.

Suggested Citation

Robinson, K., Gibbs, G., Ribbe, P., 1971, Quadratic elongation: A quantitative measure of distortion in coordination polyhedra: Science, v. 172, no. 3983, p. 567-570, https://doi.org/10.1126/science.172.3983.567.

Publication type Article
Publication Subtype Journal Article
Title Quadratic elongation: A quantitative measure of distortion in coordination polyhedra
Series title Science
DOI 10.1126/science.172.3983.567
Volume 172
Issue 3983
Year Published 1971
Language English
Publisher American Association for the Advancement of Science
Description 4 p.
First page 567
Last page 570
Additional publication details