Aromatic fluorine compounds. VII. Replacement of aromatic -Cl and -NO2 groups by -F
Journal of the American Chemical Society
By: G. C. Finger and C.W. Kruse
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Abstract
Replacement of -Cl by -F in aryl chlorides with potassium fluoride has been extended from 2,4-dinitrochlorobenzene to less activated halides by the use of non-aqueous solvents, especially dimethylformamide (DMF) and dimethyl sulfoxide (DMSO). Also replacement of -NO2 by -F in substituted nitrobenzenes was studied in DMF. As a direct result of this study, many aromatic fluorine compounds can now be obtained by a relatively simple synthetic route.
| Publication type | Article |
|---|---|
| Publication Subtype | Journal Article |
| Title | Aromatic fluorine compounds. VII. Replacement of aromatic -Cl and -NO2 groups by -F |
| Series title | Journal of the American Chemical Society |
| DOI | 10.1021/ja01604a022 |
| Volume | 78 |
| Issue | 23 |
| Publication Date | May 01, 2002 |
| Year Published | 1956 |
| Language | English |
| Publisher | American Chemical Society |
| Description | 4 p. |
| First page | 6034 |
| Last page | 6037 |