Glass electrodes sensitive to divalent cations

Science
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Abstract

Glass electrodes suitable for measurement of divalent cations have been made and tested. Empirical and theoretical electrode equations have been presented to describe electrode behavior in a variety of aqueous solutions. Most electrodes show response interpretable as showing nearly ideal solid-solution behavior of the cations in the glass surface. The electrodes should be useful in the measurement of divalent-cation activities in natural waters and biological fluids, and useful in general analytical chemistry.

Suggested Citation

Garrels, R., Sato, M., Thompson, M., and Truesdell, A., 1962, Glass electrodes sensitive to divalent cations: Ion exchange models for new electrode glasses simplify analyses for calcium and other ions: Science, v. 135, no. 3508, p. 1045-1048.

Publication type Article
Publication Subtype Journal Article
Title Glass electrodes sensitive to divalent cations
Series title Science
DOI 10.1126/science.135.3508.1045
Volume 135
Issue 3508
Year Published 1962
Language English
Publisher American Association for the Advancement of Science
Description 4 p.
First page 1045
Last page 1048
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