Transformation of montmorillonite to kaolinite during weathering

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Abstract

Extensive deposits of kaolinite in Florida are formed by transformation of montmorillonite during low-temperature supergene weathering. The transformation occurs by intracrystalline leaching of interlayer cations and tetrahedral silica layers. Interposition of stripped layers within montmorillonite creates a regular 1:1 mixed-layered montmorillonite-kaolinite, a new clay structure. Kaolin-like layers are nourished by lateral epitaxy, as the iron-rich montmorillonite decomposes. Hexagonal outgrowths of new kaolinite develop at the edges of montmorillonite flakes and nucleate new vertical growth. Kaolinitic sands impregnated with goethite are ultimately formed, and the released silica enriches groundwater and forms secondary chert.

Suggested Citation

Altschuler, Z., Dwornik, E., and Kramer, H., 1963, Transformation of montmorillonite to kaolinite during weathering: Science, v. 141, no. 3576, p. 148-152, https://doi.org/10.1126/science.141.3576.148.

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Publication type Article
Publication Subtype Journal Article
Title Transformation of montmorillonite to kaolinite during weathering
Series title Science
DOI 10.1126/science.141.3576.148
Volume 141
Issue 3576
Year Published 1963
Language English
Publisher American Association for the Advancement of Science
Description 5 p.
First page 148
Last page 152
Country United States
State Florida
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