Boron-oxygen polyanion in the crystal structure of tunellite
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Abstract
The crystal structure of tunellite, SrO·3B2O3·4H2O, with infinite sheets of composition n[B6O9(OH)2]2-, has cations and water molecules in the spaces within the sheets. Adjacent sheets are held together by hydrogen bonding through the water molecules. The boron-oxygen polyanions provide the first example in hydrated borate crystals of one oxygen linked to three borons.
Publication type | Article |
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Publication Subtype | Journal Article |
Title | Boron-oxygen polyanion in the crystal structure of tunellite |
Series title | Science |
DOI | 10.1126/science.141.3586.1178 |
Volume | 141 |
Issue | 3586 |
Year Published | 1963 |
Language | English |
Publisher | AAAS |
Description | 2 p. |
First page | 1178 |
Last page | 1179 |
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