Phosphate glass electrode with good selectivity for alkaline-earth cations

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Abstract

A phosphate glass has been found to have a significant electrode specificity toward alkaline-earth ions. The order of selectivity is 2H+ > Ba++ > Sr++ > Ca++ > 2K+ > 2Na+ > Mg++. Exchange properties are discussed in relation to possible structure. Its use to determine activity of Ca++ in natural systems containing Mg++ is suggested.

Suggested Citation

Truesdell, A., Pommer, A., 1963, Phosphate glass electrode with good selectivity for alkaline-earth cations: Science, v. 142, no. 3597, p. 1292-1294, https://doi.org/10.1126/science.142.3597.1292.

Publication type Article
Publication Subtype Journal Article
Title Phosphate glass electrode with good selectivity for alkaline-earth cations
Series title Science
DOI 10.1126/science.142.3597.1292
Volume 142
Issue 3597
Year Published 1963
Language English
Publisher American Association for the Advancement of Science
Description 3 p.
First page 1292
Last page 1294
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