Atomic absorption spectrometric determination of copper, zinc, and lead in geological materials
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Abstract
An atomic absorption spectrometric method is described for the determination of copper, zinc, and lead in geological materials. The sample is digested with HF—HCl—H2O2; the final solution for analysis is in 10 % (v/v) HCl. Copper and zinc are determined directly by aspirating the solution into an air—acetylene flame. A separate aliquot of the solution is used for determination of lead; lead is extracted into TOPO-MIBK from the acidic solution in the presence of iodide and ascorbic acid. For a 0.50-g sample, the limits of determination are 10–2000 p.p.m. for Cu and Zn, and 5–5000 p.p.m. for Pb. As much as 40 % Fe or Ca. and 10 % Al, Mg, or Mn in the sample do not interfere. The proposed method can be applied to the determination of copper, zinc, and lead in a wide range of geological materials including iron- and manganese-rich, calcareous and carbonate samples.
| Publication type | Article |
|---|---|
| Publication Subtype | Journal Article |
| Title | Atomic absorption spectrometric determination of copper, zinc, and lead in geological materials |
| Series title | Analytica Chimica Acta |
| DOI | 10.1016/S0003-2670(01)83030-0 |
| Volume | 86 |
| Issue | C |
| Year Published | 1976 |
| Language | English |
| Publisher | Elsevier |
| Description | 6 p. |
| First page | 163 |
| Last page | 168 |
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