Aromatic fluorine compounds. III. The fluoromesitylenes and derivatives
Journal of the American Chemical Society
By: G. C. Finger, F.H. Reed, E.W. Maynert, and A.M. Weiner
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Abstract
Nitration of mesitylene and difluoromesitylene in anhydrous hydrofluoric acid gave near quantitative yields of dinitromesitylene and 2,4-difluoro-6-nitromesitylene, respectively. Difluoro- and trifluoromesitylene were synthesized by the Schiemann reaction in record yields reported for this type of reaction. Various intermediates and derivatives are reported for the fluoromesitylenes. Among the products of exhaustive chlorination of trifluoromesitylene, 2,4,6-tris-(trichloromethyl)-1,-3,5-trifluorobenzene and 2,4,6-trichloro-1,3,5-trifluorobenzene were identified.
| Publication type | Article |
|---|---|
| Publication Subtype | Journal Article |
| Title | Aromatic fluorine compounds. III. The fluoromesitylenes and derivatives |
| Series title | Journal of the American Chemical Society |
| Volume | 73 |
| Issue | 1 |
| Year Published | 1951 |
| Language | English |
| Larger Work Type | Article |
| Larger Work Subtype | Journal Article |
| Larger Work Title | Journal of the American Chemical Society |
| First page | 149 |
| Last page | 151 |
| Google Analytic Metrics | Metrics page |