Aromatic fluorine compounds. III. The fluoromesitylenes and derivatives
Journal of the American Chemical Society
By: G. C. Finger, F.H. Reed, E.W. Maynert, and A.M. Weiner
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Abstract
Nitration of mesitylene and difluoromesitylene in anhydrous hydrofluoric acid gave near quantitative yields of dinitromesitylene and 2,4-difluoro-6-nitromesitylene, respectively. Difluoro- and trifluoromesitylene were synthesized by the Schiemann reaction in record yields reported for this type of reaction. Various intermediates and derivatives are reported for the fluoromesitylenes. Among the products of exhaustive chlorination of trifluoromesitylene, 2,4,6-tris-(trichloromethyl)-1,-3,5-trifluorobenzene and 2,4,6-trichloro-1,3,5-trifluorobenzene were identified.
Suggested Citation
Finger, G.C., Reed, F., Maynert, E., and Weiner, A., 1951, Aromatic fluorine compounds. III. The fluoromesitylenes and derivatives: Journal of the American Chemical Society, v. 73, no. 1, p. 149-151, https://doi.org/10.1021/ja01145a053.
| Publication type | Article |
|---|---|
| Publication Subtype | Journal Article |
| Title | Aromatic fluorine compounds. III. The fluoromesitylenes and derivatives |
| Series title | Journal of the American Chemical Society |
| DOI | 10.1021/ja01145a053 |
| Volume | 73 |
| Issue | 1 |
| Publication Date | May 01, 2002 |
| Year Published | 1951 |
| Language | English |
| Publisher | American Chemical Society |
| Description | 3 p. |
| First page | 149 |
| Last page | 151 |