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A rapid geochemical spectrophotometric determination of tungsten with dithiol

Talanta
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Abstract

1-g sample is decomposed with nitric and hydrofluoric acids, and after evaporation of the solution to dryness the residue is dissolved in concentrated hydrochloric acid. A clear aliquot is treated with stannous chloride to inhibit interferences. The blue tungsten dithiol complex is developed at a temperature of 85?? over a half-hour period. The complex is extracted into 2 ml of heptane and the tungsten is determined spectrophotometrically with a sensitivity of 0.5 ppm. Fifty samples per man-day can be analysed in this manner. ?? 1983.
Publication type Article
Publication Subtype Journal Article
Title A rapid geochemical spectrophotometric determination of tungsten with dithiol
Series title Talanta
Volume 30
Issue 11
Year Published 1983
Language English
Larger Work Type Article
Larger Work Subtype Journal Article
Larger Work Title Talanta
First page 876
Last page 878
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