Halogenated benzene radical cations and ground state degeneracy splitting by asymmetric substitution
Journal of Chemical Physics
By: V.E. Bondybey, C.R. Vaughn, T.A. Miller, J.H. English, and R.H. Shiley
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Abstract
The absorption and laser induced fluorescence of several halogenated benzene radical cations were studied in solid Ne matrices. The spectra of 1,2,4-trifluorobenzene, l,3-dichloro-5-fluorobenzene, and l-chloro-3,5- difluorobenzene radical cations are observed and analyzed. Studies of fluorescence polarization and a photoselection technique were used to examine the splitting of the degeneracy of the benzene cation ground state by asymmetric subsitution. ?? 1981 American Institute of Physics.
| Publication type | Article |
|---|---|
| Publication Subtype | Journal Article |
| Title | Halogenated benzene radical cations and ground state degeneracy splitting by asymmetric substitution |
| Series title | Journal of Chemical Physics |
| DOI | 10.1063/1.441120 |
| Volume | 74 |
| Issue | 12 |
| Year Published | 1981 |
| Language | English |
| Publisher | American Institute of Physics |
| Larger Work Type | Article |
| Larger Work Subtype | Journal Article |
| Larger Work Title | Journal of Chemical Physics |
| First page | 6584 |
| Last page | 6591 |