Low-temperature heat capacity and entropy of chalcopyrite (CuFeS2): estimates of the standard molar enthalpy and Gibbs free energy of formation of chalcopyrite and bornite (Cu5FeS4)
Journal of Chemical Thermodynamics
By: R. A. Robie, L.B. Wiggins, P. B. Barton Jr., and B. S. Hemingway
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Abstract
The heat capacity of CuFeS2 (chalcopyrite) was measured between 6.3 and 303.5 K. At 298.15 K, Cp,mo and Smo(T) are (95.67??0.14) J??K-1??mol-1 and (124.9??0.2) J??K-1??mol-1, respectively. From a consideration of the results of two sets of equilibrium measurements we conclude that ??fHmo(CuFeS2, cr, 298.15 K) = -(193.6??1.6) kJ??mol-1 and that the recent bomb-calorimetric determination by Johnson and Steele (J. Chem. Thermodynamics 1981, 13, 991) is in error. The standard molar Gibbs free energy of formation of bornite (Cu5FeS4) is -(444.9??2.1) kJ??mol-1 at 748 K. ?? 1985.
Suggested Citation
Robie, R.A., Wiggins, L., Barton, P.B., Hemingway, B.S., 1985, Low-temperature heat capacity and entropy of chalcopyrite (CuFeS2): estimates of the standard molar enthalpy and Gibbs free energy of formation of chalcopyrite and bornite (Cu5FeS4): Journal of Chemical Thermodynamics, v. 17, no. 5, p. 481-488, https://doi.org/10.1016/0021-9614(85)90147-8.
| Publication type | Article |
|---|---|
| Publication Subtype | Journal Article |
| Title | Low-temperature heat capacity and entropy of chalcopyrite (CuFeS2): estimates of the standard molar enthalpy and Gibbs free energy of formation of chalcopyrite and bornite (Cu5FeS4) |
| Series title | Journal of Chemical Thermodynamics |
| DOI | 10.1016/0021-9614(85)90147-8 |
| Volume | 17 |
| Issue | 5 |
| Year Published | 1985 |
| Language | English |
| Publisher | Elsevier |
| Larger Work Type | Article |
| Larger Work Subtype | Journal Article |
| Larger Work Title | Journal of Chemical Thermodynamics |
| First page | 481 |
| Last page | 488 |