Critical behavior of dilute NaCl in H2O
Chemical Physics Letters
By: Kenneth S. Pitzer, James L. Bischoff, and Robert J. Rosenbauer
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Abstract
The compositions of the saturated vapor and liquid phases are measured for the system NaCl-H2O at 380°C, which is close to the critical point of pure water. The shape of the phase equilibrium curve is classical, which confirms a conclusion reached earlier on the basis of less accurate data. This implies that the long-range forces introduced by the NaCl suppress the non-classical effects present in pure H2O. An empirical equation of a classical type fits these data.
| Publication type | Article |
|---|---|
| Publication Subtype | Journal Article |
| Title | Critical behavior of dilute NaCl in H2O |
| Series title | Chemical Physics Letters |
| DOI | 10.1016/0009-2614(87)80014-3 |
| Volume | 134 |
| Issue | 1 |
| Year Published | 1987 |
| Language | English |
| Publisher | Elsevier |
| Contributing office(s) | Pacific Coastal and Marine Science Center |
| Description | 4 p. |
| First page | 60 |
| Last page | 63 |