The Silent Canyon volcanic center consists of a buried Miocene peralkaline caldera complex and outlying peralkaline lava domes. Its location has been corroborated by geophysical data and more than 50 drill holes. Two widespread ash flow sheets, the Tub Spring and overlying Grouse Canyon members of the Miocene Belted Range Tuff, were erupted from the caldera complex and have volumes of 60–100 km³ and 200 km³, respectively. Eruption of the ash flows was preceded by widespread extrusion of precaldera comendite domes and was followed by extrusion of postcollapse peralkaline lavas and tuffs within and outside the caldera complex. Lava flows and tuffs were also deposited between the two major ash flow sheets. Rocks of the Silent Canyon center vary significantly in silica content and peralkalinity. The most mafic rocks are precollapse and postcollapse trachytes (65–69% SiO₂). Low-silica comendites (69–73% SiO₂) were erupted as the mafic upper part of the chemically zoned Grouse Canyon Member and as postcollapse lavas. The lower part of the Grouse Canyon Member and the underlying rhyolite of Split Ridge are moderately peralkaline comendite (PI is molar ratio Na + K/Al is 1.17–1.26). These comendites have major element characteristics and trace element enrichments approaching those of pantellerites. The Tub Spring Member, by contrast, is a weakly peralkaline chemically unzoned silicic comendite (75–76% SiO₂) ash flow tuff. Weakly peralkaline silicic comendites (PI 1.0–1.1) are the most abundant precaldera lavas. Postcollapse lavas range from trachyte to silicic comendite; some have anomalous light rare earth element (LREE) enrichments. Silent Canyon rocks follow a common petrologic evolution from trachyte to low-silica comendite; above 73% SiO₂, compositions of the moderately peralkaline comendites diverge from those of the weakly peralkaline silicic comendites. These contrasting differentiation paths are shown in the behavior of Fe and other transition metals, Al, Na, K; the trace elements Ba, Zr, Nb; and probably F and Cl. Weakly peralkaline silicic comendites show a LREE/heavy REE crossover in early erupted/late erupted rocks; moderately peralkaline comendites are enriched in all REE. The development of divergent peralkaline magmas, toward both pantelleritic and weakly peralkaline compositions, is unusual in a single volcanic center.