Stabilized liquid membrane device (SLMD) for the passive, integrative sampling of labile metals in water
Water, Air, & Soil Pollution
By: W. G. Brumbaugh, J. D. Petty, J.N. Huckins, and S.E. Manahan
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Abstract
A stabilized liquid membrane device (SLMD) is described for potential use as an in situ, passive, integrative sampler for cadmium (Cd), cobalt (Co), copper (Cu), nickel (Ni), lead (Pb), and zinc (Zn) in natural waters. The SLMD (patent pending) consists of a 2.5-cm-wide by 15-cm-long strip of low-density polyethylene (LDPE) layflat tubing containing 1 mL of an equal mixture (v/v) of oleic acid (cis-9-octadecenoic acid) and EMO-8Q (7-[4-ethyl-1-methyloctyl]-8-quinolinol). The reagent mixture continuously diffuses to the exterior surface of the LDPE membrane, and provides for sequestration of several divalent metals for up to several weeks. Depending on sampler configuration, concentration factors of several thousand can be realized for these metal ions after just a few days. In addition to in situ deployment, the SLMD may be useful for laboratory determination of labile metal species in grab samples. Methods for minimizing the effects of water flow on the sampling rate are currently under investigation.
Suggested Citation
Brumbaugh, W.G., Petty, J.D., Huckins, J., and Manahan, S., 2002, Stabilized liquid membrane device (SLMD) for the passive, integrative sampling of labile metals in water: Water, Air, & Soil Pollution, v. 133, no. 1-4, p. 109-119, https://doi.org/10.1023/A:1012923529742.
ISSN: 1573-2932 (online)
| Publication type | Article |
|---|---|
| Publication Subtype | Journal Article |
| Title | Stabilized liquid membrane device (SLMD) for the passive, integrative sampling of labile metals in water |
| Series title | Water, Air, & Soil Pollution |
| DOI | 10.1023/A:1012923529742 |
| Volume | 133 |
| Issue | 1-4 |
| Year Published | 2002 |
| Language | English |
| Publisher | Springer |
| Contributing office(s) | Columbia Environmental Research Center |
| Description | 11 p. |
| First page | 109 |
| Last page | 119 |