Concentrations and co-occurrence correlations of 88 volatile organic compounds (VOCs) in the ambient air of 13 semi-rural to urban locations in the United States
Atmospheric Environment
By: J. F. Pankow, W. Luo, D.A. Bender, L.M. Isabelle, J.S. Hollingsworth, C. Chen, W.E. Asher, and J.S. Zogorski
Links
- More information: Publisher Index Page (via DOI)
- Download citation as: RIS | Dublin Core
Abstract
The ambient air concentrations of 88 volatile organic compounds were determined in samples taken at 13 semi-rural to urban locations in Maine, Massachusetts, New Jersey, Pennsylvania, Ohio, Illinois, Louisiana, and California. The sampling periods ranged from 7 to 29 months, yielding a large data set with a total of 23,191 individual air concentration values, some of which were designated "ND" (not detected). For each compound at each sampling site, the air concentrations (ca, ppbV) are reported in terms of means, medians, and means of the detected values. The analytical method utilized adsorption/thermal desorption with air-sampling cartridges. The analytes included numerous halogenated alkanes, halogenated alkenes, ethers, alcohols, nitriles, esters, ketones, aromatics, a disulfide, and a furan. At some sites, the air concentrations of the gasoline-related aromatic compounds and the gasoline additive methyl tert-butyl ether were seasonally dependent, with concentrations that maximized in the winter. For each site studied here, the concentrations of some compounds were highly correlated one with another (e.g., the BTEX group (benzene, toluene, ethylbenzene, and the xylenes). Other aromatic compounds were also all generally correlated with one another, while the concentrations of other compound pairs were not correlated (e.g., benzene was not correlated with CFC-12). The concentrations found for the BTEX group were generally lower than the values that have been previously reported for urbanized and industrialized areas of other nations. ?? 2003 Elsevier Ltd. All rights reserved.
Suggested Citation
Pankow, J.F., Luo, W., Bender, D., Isabelle, L., Hollingsworth, J., Chen, C., Asher, W., and Zogorski, J., 2003, Concentrations and co-occurrence correlations of 88 volatile organic compounds (VOCs) in the ambient air of 13 semi-rural to urban locations in the United States: Atmospheric Environment, v. 37, no. 36, p. 5023-5046, https://doi.org/10.1016/j.atmosenv.2003.08.006.
| Publication type | Article |
|---|---|
| Publication Subtype | Journal Article |
| Title | Concentrations and co-occurrence correlations of 88 volatile organic compounds (VOCs) in the ambient air of 13 semi-rural to urban locations in the United States |
| Series title | Atmospheric Environment |
| DOI | 10.1016/j.atmosenv.2003.08.006 |
| Volume | 37 |
| Issue | 36 |
| Year Published | 2003 |
| Language | English |
| Larger Work Type | Article |
| Larger Work Subtype | Journal Article |
| Larger Work Title | Atmospheric Environment |
| First page | 5023 |
| Last page | 5046 |