Thermodynamic calculations in the system CH4-H2O and methane hydrate phase equilibria
Journal of Physical Chemistry B
By: S. Circone, S. H. Kirby, and L.A. Stern
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Abstract
Using the Gibbs function of reaction, equilibrium pressure, temperature conditions for the formation of methane clathrate hydrate have been calculated from the thermodynamic properties of phases in the system CH4-H 2O. The thermodynamic model accurately reproduces the published phase-equilibria data to within ??2 K of the observed equilibrium boundaries in the range 0.08-117 MPa and 190-307 K. The model also provides an estimate of the third-law entropy of methane hydrate at 273.15 K, 0.1 MPa of 56.2 J mol-1 K-1 for 1/n CH4??H 2O, where n is the hydrate number. Agreement between the calculated and published phase-equilibria data is optimized when the hydrate composition is fixed and independent of the pressure and temperature for the conditions modeled. ?? 2006 American Chemical Society.
Suggested Citation
Circone, S., Kirby, S.H., and Stern, L., 2006, Thermodynamic calculations in the system CH4-H2O and methane hydrate phase equilibria: Journal of Physical Chemistry B, v. 110, no. 16, p. 8232-8239, https://doi.org/10.1021/jp055422f.
| Publication type | Article |
|---|---|
| Publication Subtype | Journal Article |
| Title | Thermodynamic calculations in the system CH4-H2O and methane hydrate phase equilibria |
| Series title | Journal of Physical Chemistry B |
| DOI | 10.1021/jp055422f |
| Volume | 110 |
| Issue | 16 |
| Publication Date | April 04, 2006 |
| Year Published | 2006 |
| Language | English |
| Larger Work Type | Article |
| Larger Work Subtype | Journal Article |
| Larger Work Title | Journal of Physical Chemistry B |
| First page | 8232 |
| Last page | 8239 |